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RESEARCH PAPER · Inorganic Chemistry · 2014

Cooperative Effects of Cation Size and Variable Coordination Modes of Te4+ on the Frameworks of New Alkali Metal Indium Tellurites, NaIn(TeO3)2, KIn(TeO3)2, RbInTe3O8, and CsInTe3O8

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Cooperative Effects of Cation Size and Variable Coordination Modes of Te4+ on the Frameworks of New Alkali Metal Indium Tellurites, NaIn(TeO3)2, KIn(TeO3)2, RbInTe3O8, and CsInTe3O8OriginalChemInform Abstract: Cooperative Effects of Cation Size and Variable Coordination Modes of Te4+ on the Frameworks of New Alkali Metal Indium Tellurites, NaIn(TeO3)2, KIn(TeO3)2, RbInTe3O8, and CsInTe3O8.0Rich Structural Chemistry in New Alkali Metal Yttrium Tellurites: Three-Dimensional Frameworks of NaYTe4O10, KY(TeO3)2, RbY(TeO3)2, and a Novel Variant of Hexagonal Tungsten Bronze, CsYTe3O823ACdCO 3 F (A = K and Rb): new noncentrosymmetric materials with remarkably strong second-harmonic generation (SHG) responses enhanced via π-interaction61Effect of cation substitution on structural transition: synthesis, characterization and theoretical studies of NaCa 4 B 3 O 9 , NaCaBO 3 , NaSrBO 3 and Li 4 CaB 2 O 618Effect of the cation size on the framework structures of magnesium tungstate, A 4 Mg(WO 4 ) 3 (A = Na, K), R 2 Mg 2 (WO 4 ) 3 (R = Rb, Cs)31Sr 2 (OH) 3 NO 3 : the first nitrate as a deep UV nonlinear optical material with large SHG responses166Synthesis and Characterization of Mid-Infrared Transparency Compounds: Acentric BaHgS2 and Centric Ba8Hg4S5Se752Na4MgM2Se6 (M = Si, Ge): The First Noncentrosymmetric Compounds with Special Ethane-like [M2Se6]6– Units Exhibiting Large Laser-Damage Thresholds56Synthesis and characterization of CsSrCO 3 F – a beryllium-free new deep-ultraviolet nonlinear optical material34New fluoroborate Cd 8 B 5 O 15 F with two different isolated borate anions prepared by an open high-temperature solution method7Na 2 ZnGe 2 S 6 : A New Infrared Nonlinear Optical Material with Good Balance between Large Second-Harmonic Generation Response and High Laser Damage Threshold302Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures601Li 3 Ge 3 Se 6 : the first ternary lithium germanium selenide with interesting ∞ [Ge 6 Se 12 ] n chains constructed by ethane-like [Ge 2 Se 6 ] 6− clusters8Na 2 CdGe 2 Q 6 (Q = S, Se): two metal-mixed chalcogenides with phase-matching abilities and large second-harmonic generation responses78Syntheses, Structures, and Characterization of Quaternary Tellurites, Li3MTe4O11 (M = Al, Ga, and Fe)13Four alkali metal molybdates with two types of Mo–O chains, ABMo 3 O 10 (A = Li, B = Rb; A = Li, Na, K, B = Cs): synthesis, structure comparison and optical properties10Na 6 Zn 3 MIII2Q 9 (M III = Ga, In; Q = S, Se): four new supertetrahedron-layered chalcogenides with unprecedented vertex-sharing T 3 -clusters and desirable photoluminescence performances31NaBaM III Q 3 (M III = Al, Ga; Q = S, Se): first quaternary chalcogenides with isolated edge-sharing (MIII2Q 6 ) 6− dimers8LiNa4B15O25: Featuring Unprecedented B15O30 Fundamental Building Block and Deep-UV Cutoff Edge20Synergetic Influence of Alkali-Metal and Lone-Pair Cations on Frameworks of Tellurites15Module-Guided Design Scheme for Deep-Ultraviolet Nonlinear Optical Materials195The Rubidium Barium Borate Resulting from B7O15 Fundamental Building Block Exhibits DUV Cutoff Edge17Structural modulation induced by M IIIA metals in Ba 3 MQ 4 X (M = Al, Ga, In; Q = S, Se; X = Cl, Br): an experimental and computational analysis7Two Indium Sulfate Tellurites: Centrosymmetric In 2 (SO 4 )(TeO 3 )(OH) 2 (H 2 O) and Non-centrosymmetric In 3 (SO 4 )(TeO 3 ) 2 F 3 (H 2 O)33Lone-pair self-containment in pyritohedron-shaped closed cavities: optimized hydrothermal synthesis, structure, magnetism and lattice thermal conductivity of Co 15 F 2 (TeO 3 ) 1413MII2M3IIIF3(Te6F2O16) (MII = Pb, Ba; MIII = Al, Ga): New mixed anionic tellurites with isolated Te6 coplanar rings23LiBa4Ga5Q12 (Q = S, Se): Noncentrosymmetric Metal Chalcogenides with a Cesium Chloride Topological Structure Displaying a Remarkable Laser Damage Threshold32Unique synthesis, structure determination, and optical properties of seven new layered rare earth tellurite nitrates, RE(TeO3)(NO3) (RE = La, Nd, Eu, Gd, Dy, Er, and Y)15Rb3In(SO4)3: a defluorinated mixed main-group metal sulfate for ultraviolet transparent nonlinear optical materials with a large optical band gap26Mixed-valent titanium tellurium oxides, Ti1-xTexTe3O8+x (x = 0, 0.1, and 0.12): Hydrothermal synthesis, structure, and characterization3KIn0.33IIITe0.67VITe2IVO7: Zirconolite-like Mixed-Valent Metal Oxide with a 3D Framework2Shedding light on intrinsic characteristics and optical properties of novel selenite and tellurite crystals ZrSe 2 O 6 , HfSe 2 O 6 and HfTe 3 O 87Metal tellurite oxides: Lone-pair-enabled coordination chemistry, polymerized architectures, and functional materials opportunities1

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  1. ChemInform Abstract: Cooperative Effects of Cation Size and Variable Coordination Modes of Te4+ on the Frameworks of New Alkali Metal Indium Tellurites, NaIn(TeO3)2, KIn(TeO3)2, RbInTe3O8, and CsInTe3O8.

    ChemInform · 2014-12-04

    Su‐whan Bae, Choong‐Yeol Kim, Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·
  2. Rich Structural Chemistry in New Alkali Metal Yttrium Tellurites: Three-Dimensional Frameworks of NaYTe4O10, KY(TeO3)2, RbY(TeO3)2, and a Novel Variant of Hexagonal Tungsten Bronze, CsYTe3O8

    Inorganic Chemistry · 2014-12-17

    Youngkwon Kim, Dong Woo Lee, Kang Min Ok

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  3. ACdCO 3 F (A = K and Rb): new noncentrosymmetric materials with remarkably strong second-harmonic generation (SHG) responses enhanced via π-interaction

    RSC Advances · 2015-01-01

    Guohong Zou, Gnu Nam, Hyung Gu Kim, Hongil Jo, Tae‐Soo You, Kang Min Ok

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  4. Effect of cation substitution on structural transition: synthesis, characterization and theoretical studies of NaCa 4 B 3 O 9 , NaCaBO 3 , NaSrBO 3 and Li 4 CaB 2 O 6

    Physical Chemistry Chemical Physics · 2015-01-01

    Yun Mo Yang, Xin Su, Shilie Pan, Zhihua Yang

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  5. Effect of the cation size on the framework structures of magnesium tungstate, A 4 Mg(WO 4 ) 3 (A = Na, K), R 2 Mg 2 (WO 4 ) 3 (R = Rb, Cs)

    Dalton Transactions · 2015-01-01

    Shujuan Han, Ying Wang, Qun Jing, Hongping Wu, Shilie Pan, Zhihua Yang

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  6. Sr 2 (OH) 3 NO 3 : the first nitrate as a deep UV nonlinear optical material with large SHG responses

    Journal of Materials Chemistry C · 2015-01-01

    Ling Huang, Guohong Zou, Huaqiang Cai, Shichao Wang, Chensheng Lin, Ning Ye

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  7. Synthesis and Characterization of Mid-Infrared Transparency Compounds: Acentric BaHgS2 and Centric Ba8Hg4S5Se7

    Inorganic Chemistry · 2015-03-05

    Kui Wu, Xin Su, Shilie Pan, Zhihua Yang

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  8. Na4MgM2Se6 (M = Si, Ge): The First Noncentrosymmetric Compounds with Special Ethane-like [M2Se6]6– Units Exhibiting Large Laser-Damage Thresholds

    Inorganic Chemistry · 2015-10-20

    Kui Wu, Zhihua Yang, Shilie Pan

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  9. Synthesis and characterization of CsSrCO 3 F – a beryllium-free new deep-ultraviolet nonlinear optical material

    New Journal of Chemistry · 2015-12-22

    Qingfei Li, Guohong Zou, Chensheng Lin, Ning Ye

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  10. New fluoroborate Cd 8 B 5 O 15 F with two different isolated borate anions prepared by an open high-temperature solution method

    Dalton Transactions · 2016-01-01

    Yun Mo Yang, Xiaoyu Dong, Shilie Pan

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  11. Na 2 ZnGe 2 S 6 : A New Infrared Nonlinear Optical Material with Good Balance between Large Second-Harmonic Generation Response and High Laser Damage Threshold

    Journal of the American Chemical Society · 2016-05-19

    Guangmao Li, Kui Wu, Qiong Liu, Zhihua Yang, Shilie Pan

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  12. Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures

    Accounts of Chemical Research · 2016-11-14

    Kang Min Ok

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  13. Li 3 Ge 3 Se 6 : the first ternary lithium germanium selenide with interesting ∞ [Ge 6 Se 12 ] n chains constructed by ethane-like [Ge 2 Se 6 ] 6− clusters

    Dalton Transactions · 2017-01-01

    Guangmao Li, Ni Zhen, Yu Chu, Zhongxiang Zhou

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  14. Na 2 CdGe 2 Q 6 (Q = S, Se): two metal-mixed chalcogenides with phase-matching abilities and large second-harmonic generation responses

    Dalton Transactions · 2017-01-01

    Guangmao Li, Qiong Liu, Kui Wu, Zhihua Yang, Shilie Pan

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  15. Syntheses, Structures, and Characterization of Quaternary Tellurites, Li3MTe4O11 (M = Al, Ga, and Fe)

    Inorganic Chemistry · 2017-04-25

    Minfeng Lü, Hongil Jo, Seung‐Jin Oh, Suheon Lee, Kwang‐Yong Choi, Yang Yu, Kang Min Ok

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  16. Four alkali metal molybdates with two types of Mo–O chains, ABMo 3 O 10 (A = Li, B = Rb; A = Li, Na, K, B = Cs): synthesis, structure comparison and optical properties

    New Journal of Chemistry · 2018-01-01

    Shujuan Han, Bingbing Zhang, Tinghao Tong, Zhihua Yang, Shilie Pan

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  17. Na 6 Zn 3 MIII2Q 9 (M III = Ga, In; Q = S, Se): four new supertetrahedron-layered chalcogenides with unprecedented vertex-sharing T 3 -clusters and desirable photoluminescence performances

    Inorganic Chemistry Frontiers · 2018-01-01

    Ailijiang Abudurusuli, Kui Wu, Yilimiranmu Rouzhahong, Zhihua Yang, Shilie Pan

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  18. NaBaM III Q 3 (M III = Al, Ga; Q = S, Se): first quaternary chalcogenides with isolated edge-sharing (MIII2Q 6 ) 6− dimers

    Dalton Transactions · 2018-01-01

    Ailijiang Abudurusuli, Kui Wu, Yilimiranmu Rouzhahong, Zhihua Yang, Shilie Pan

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  19. LiNa4B15O25: Featuring Unprecedented B15O30 Fundamental Building Block and Deep-UV Cutoff Edge

    Inorganic Chemistry · 2018-02-14

    Yun Mo Yang, Qingrong Kong, Zhihua Yang, Shilie Pan

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  20. Synergetic Influence of Alkali-Metal and Lone-Pair Cations on Frameworks of Tellurites

    Inorganic Chemistry · 2018-04-11

    Yi-Gang Chen, Nan Qing Yang, Xiao-Ni Yao, Chengbo Li, Yao Guo, Xian‐Ming Zhang

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  21. Module-Guided Design Scheme for Deep-Ultraviolet Nonlinear Optical Materials

    Journal of the American Chemical Society · 2018-07-27

    Bing‐Hua Lei, Zhihua Yang, Hongwei Yu, Chao Cao, Zhi Li, Cong Hu, Kenneth Reinhard Poeppelmeier, Shilie Pan

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  22. The Rubidium Barium Borate Resulting from B7O15 Fundamental Building Block Exhibits DUV Cutoff Edge

    Inorganic Chemistry · 2018-10-12

    Yun Mo Yang, Xiaoyu Dong, Shilie Pan, Hongping Wu

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  23. Structural modulation induced by M IIIA metals in Ba 3 MQ 4 X (M = Al, Ga, In; Q = S, Se; X = Cl, Br): an experimental and computational analysis

    Dalton Transactions · 2019-01-01

    Abudukadi Tudi, Shujuan Han, Ailijiang Abudurusuli, Haohai Yu, Zhihua Yang, Shilie Pan

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  24. Two Indium Sulfate Tellurites: Centrosymmetric In 2 (SO 4 )(TeO 3 )(OH) 2 (H 2 O) and Non-centrosymmetric In 3 (SO 4 )(TeO 3 ) 2 F 3 (H 2 O)

    Inorganic Chemistry · 2019-07-31

    Ya-Ping Gong, Yun‐Xiang Ma, Shao‐Ming Ying, Jiang‐Gao Mao, Fang Kong

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  25. Lone-pair self-containment in pyritohedron-shaped closed cavities: optimized hydrothermal synthesis, structure, magnetism and lattice thermal conductivity of Co 15 F 2 (TeO 3 ) 14

    Dalton Transactions · 2020-01-01

    Minfeng Lü, Jianhua Jiang, Bei Zhu, Yuwei Zhao, Tianyu Zhu, Haoming Yang, Yong Jin, Houria Kabbour, Kwang‐Yong Choi, William T. A. Harrison

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  26. MII2M3IIIF3(Te6F2O16) (MII = Pb, Ba; MIII = Al, Ga): New mixed anionic tellurites with isolated Te6 coplanar rings

    Journal of Solid State Chemistry · 2020-02-29

    Pengfei Li, Fang Kong, Jiang‐Gao Mao

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  27. LiBa4Ga5Q12 (Q = S, Se): Noncentrosymmetric Metal Chalcogenides with a Cesium Chloride Topological Structure Displaying a Remarkable Laser Damage Threshold

    Inorganic Chemistry · 2020-04-04

    Ailijiang Abudurusuli, Junjie Li, Tinghao Tong, Zhihua Yang, Shilie Pan

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  28. Unique synthesis, structure determination, and optical properties of seven new layered rare earth tellurite nitrates, RE(TeO3)(NO3) (RE = La, Nd, Eu, Gd, Dy, Er, and Y)

    Journal of Alloys and Compounds · 2020-08-28

    Hye‐Eun Lee, Hongil Jo, Min Hyung Lee, Kang Min Ok

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  29. Rb3In(SO4)3: a defluorinated mixed main-group metal sulfate for ultraviolet transparent nonlinear optical materials with a large optical band gap

    Journal of Materials Chemistry C · 2021-01-01

    Qinke Xu, Xingxing Jiang, Chao Wu, Lin Lin, Zhipeng Huang, Zheshuai Lin, Mark Graeme Humphrey, Chi Zhang

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  30. Mixed-valent titanium tellurium oxides, Ti1-xTexTe3O8+x (x = 0, 0.1, and 0.12): Hydrothermal synthesis, structure, and characterization

    Journal of Solid State Chemistry · 2021-02-06

    Dong Woo Lee, Hye Ran Noh, Tae-Hyeong Kim, Jeongmook Lee, Jong‐Yun Kim, Kyung‐Tae Ko, Sang Ho Lim

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  31. KIn0.33IIITe0.67VITe2IVO7: Zirconolite-like Mixed-Valent Metal Oxide with a 3D Framework

    Inorganic Chemistry · 2021-09-29

    Dong Woo Lee, Tae-Hyeong Kim, Jeongmook Lee, Jung-Hwan Park, Jong‐Yun Kim, Kang Min Ok, Sang Ho Lim

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  32. Shedding light on intrinsic characteristics and optical properties of novel selenite and tellurite crystals ZrSe 2 O 6 , HfSe 2 O 6 and HfTe 3 O 8

    CrystEngComm · 2023-01-01

    Junai Lv, Qi Li, Xin Guan, Na Lin, Jian Zhang, Zhitai Jia, Xutang Tao

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  33. Metal tellurite oxides: Lone-pair-enabled coordination chemistry, polymerized architectures, and functional materials opportunities

    Coordination Chemistry Reviews · 2026-05-07

    Yiyun Wang, Hongbo Cui, Jiayi Guo, Guijian Guan, Ming‐Yong Han

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