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RESEARCH PAPER · Chemical Society Reviews · 2016

Metal–organic frameworks as competitive materials for non-linear optics

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Metal–organic frameworks as competitive materials for non-linear opticsOriginalChemInform Abstract: Metal—Organic Frameworks as Competitive Materials for Non‐Linear Optics0SHG-active Ln III –[Mo I (CN) 5 (NO)] 3− (Ln = Gd, Eu) magnetic coordination chains: a new route towards non-centrosymmetric molecule-based magnets15A second-order nonlinear optical material with a 5-fold interpenetrating diamondoid framework based on two achiral precursors: spontaneous resolution to absolute chiral induction29Alkoxido-bridged binuclear copper( ii ) complexes derived from aminoalcohols – useful building blocks in designing coordination polymers with a rich structural variety5An updated roadmap for the integration of metal–organic frameworks with electronic devices and chemical sensors1210Biomimetic mineralization of metal–organic frameworks around polysaccharides90Enhancement of second harmonic generation in chiral metal-organic frameworks with silicon nanoparticles0Nonlinear optical properties, upconversion and lasing in metal–organic frameworks683Optical spatial modulation of luminescent properties of van der Waals metal-organic framework0Recent advances on supramolecular isomerism in metal organic frameworks861D Coordination Polymers from Zinc(II) and Cadmium(II) Halides and 2,2′‐Dithiobis(pyridine N‐oxide): Isostructurality and Structural Diversity8Supramolecular assembly based on “emerging” intermolecular interactions of particular interest to coordination chemists221van der Waals Metal‐Organic Framework as an Excitonic Material for Advanced Photonics80A New Class of Lasing Materials: Intrinsic Stimulated Emission from Nonlinear Optically Active Metal–Organic Frameworks129Synthesis, X-ray crystal structure and highly non-linear optical properties of inorganic-organic hybrid compound: 1,4-Diazbicyclo-octane oxonium tri- nitrates single crystal34CoII/MnII MOFs containing the characteristic double metal chains: Synthesis, structure and magnetic property21A Cd(II) metal–organic framework based on semi-rigid ligand 3,5-(4-carboxybenzyloxy) benzoic acid with high stability by intramolecular hydrogen-bonding11Design of an efficient solution grown semiorganic NLO crystal for short wavelength generation: Bis(L-Threonine) magnesium (II) monohydrate5A twofold interpenetrating three-dimensional heterometallic metal–organic framework with pcu topology based on 2-methylbiphenyl-4,4′-dicarboxylic acid4Nonlinear Metasurfaces: A Paradigm Shift in Nonlinear Optics0Nonlinear metasurfaces: a paradigm shift in nonlinear optics611A Recyclable Metal–Organic Framework as a Dual Detector and Adsorbent for Ammonia58Nonlinear optical and microscopic analysis of Cu2+ doped zinc thiourea chloride (ZTC) monocrystal26A Host Material for Deep-Blue Electrophosphorescence Based on a Cuprous Metal–Organic Framework18The Impact of Charge‐Distribution on Photochromic Properties in 1D Coordination Polymers8Influence of Cu2+ ion on structural, luminescence and dielectric properties of zinc thiourea chloride metal-organic complex crystal21The Power of Heterometalation through Lithium for Helix Chain-Based Noncentrosymmetric Metal–Organic Frameworks with Tunable Second-Harmonic Generation Effects19Emergence of Nonlinear Optical Activity by Incorporation of a Linker Carrying the p -Nitroaniline Motif in MIL-53 Frameworks21Two luminescent Zn(II) metal–organic frameworks for exceptionally selective detection of picric acid18cis - and trans -9,10-di(1 H -imidazol-1-yl)-anthracene based coordination polymers of Zn II and Cd II : synthesis, crystal structures and luminescence properties21Synthesis, crystal structure and fluorescent properties of indolo[3,2-b]carbazole-based metal–organic coordination polymers9Photoelectron Transfer at ZnTPyP Self-Assembly/TiO2 Interfaces for Enhanced Two-Photon Photodynamic Therapy21Broadband optical limiting of a novel twisted tetrathiafulvalene incorporated donor–acceptor material and its Ormosil gel glasses29Coordination supramolecules with oxazoline-containing ligands11Degradation paths of manganese-based MOF materials in a model oxidative environment: a computational study17Hybrid materials based on transition metal–BTC–benzimidazole: solvent assisted crystallographic and structural switching12Photonic functional metal–organic frameworks661Supramolecular self-assembly for designing non-centrosymmetric crystals based on Keggin polyoxometallates and crown ether4Synthesis of glycerol carbonate over a 2D coordination polymer built with Nd 3+ ions and organic ligands7Tuning structures and emissive properties in a series of Zn( ii ) and Cd( ii ) coordination polymers containing dicarboxylic acids and nicotinamide pillars27Shape engineering of metal–organic frameworks240Recent Advances in Micro‐/Nanostructured Metal–Organic Frameworks towards Photonic and Electronic Applications54pH-Controlled Assembly of 3D and 2D Zinc-Based Metal-Organic Frameworks with Tetrazole Ligands31Zeolite imidazolate frameworks in catalysis: Synthesis of benzimidazoles via cascade redox condensation using Co-ZIF-67 as an efficient heterogeneous catalyst58Enantiopure Chiral Coordination Polymers Based on Polynuclear Paddlewheel Helices and Arsenyl Tartrate9Plasmon augmented two photon absorption in a strongly coupled nano-molecular hybrid8Functional Diagnostic and Therapeutic Nanoconstructs for Efficient Probing of Circulating Tumor Cells19Luminescence, laser induced nonlinear optical and surface microscopic studies of potassium thiourea chloride crystal27Syntheses, structures and properties of three chiral metal–organic coordination polymers based on (R)-4-(4-(1-carboxyethoxy)phenoxy)-3-nitrobenzoic acid10Reinvestigation of the crystal structure, vibrational spectroscopic studies and DFT calculations of 4, 4′-bipyridinium dinitrate: An efficient SHG material for electro-optic devices8Nonlinear-Optical Behaviors of a Chiral Metal–Organic Framework Comprised of an Unusual Multioriented Double-Helix Structure48Porous Metal–Organic Framework@Polymer Beads for Iodine Capture and Recovery Using a Gas‐Sparged Column217Ln(III)-MOFs (Ln = Tb, Eu, Dy, and Sm) based on triazole carboxylic ligand with carboxylate and nitrogen donors with applications as chemical sensors and magnetic materials13Simplest MOF Units for Effective Photodriven Hydrogen Evolution Reaction67Two New Isomorphous Zinc(II) and Nickel(II) Supramolecular Coordination Polymers Based on the (benzotriazol-1-yloxy)-Acetic Acid Ligand: Syntheses, Structures, Properties, and DFT Analyses0A zirconium-based metal-organic framework with encapsulated anionic drug for uncommonly controlled oral drug delivery56Nanometer scale metal-organic framework nanoparticles for optical application1Second harmonic generation from metal-organic framework derivatives2Improved CO2 capture and separation performances of a Cr-based metal–organic framework induced by post-synthesis modification of amine groups7Photoluminescent, upconversion luminescent and nonlinear optical metal-organic frameworks: From fundamental photophysics to potential applications206Synthesis, structure, computational modeling, and biological activity of two novel bimesitylene derivatives7Nitrobenzene-detection cadmium thiophenedicarboxylate coordination polymers with flexible dipyridylamide ligands and diverse topologies17CoFe2O4/TMU‐17‐NH2 as a hybrid magnetic nanocomposite catalyst for multicomponent synthesis of dihydropyrimidines25Development of Organic Linkers and Functionalized Metal Coordination Complexes: An Industrial Nose0Eu-based coordination polymer microrods for low-loss optical waveguiding application8Hydrogen-bonded organo-amino phosphonium halides: dielectric, piezoelectric and possible ferroelectric properties12Light-controllable systems based on TiO 2 -ZIF-8 composites for targeted drug release: communicating with tumour cells33Molecular engineering of organic and organometallic second-order nonlinear optical materials12Photofunctional MOF-based hybrid materials for the chemical sensing of biomarkers135Push–pull unsymmetrical substitution in nickel( ii ) complexes with tetradentate N 2 O 2 Schiff base ligands: synthesis, structures and linear–nonlinear optical studies29Rare metal-ion metathesis of a tetrahedral Zn( ii ) core of a noncentrosymmetric (3,4)-connected 3D MOF9Uniform and directional growth of centimeter-sized single crystals of cyclodextrin-based metal organic frameworks18Synthesis, crystal structures, second harmonic generation response and temperature phase transitions of two noncentrosymmetric Cu(II)-hybrid halides compounds: [(R)-C7H16N2][CuX4] (X = Cl or Br)25Co(II)-based Metal–Organic Frameworks and Their Application in Gas Sorption and Solvatochromism38A new route to triphenylpyridines utilizing ketoximes as building blocks via cascade reactions under iron‐organic framework catalysis2Growth and physicochemical investigations on wide bandgap 2D polymeric amino acetic acid sulfato dilithium metal–organic framework1Selective, sensitive, and recyclable sensing of ascorbic acid in water based on a water-stable Zn (II) coordination polymer8Metal-organic framework structures: adsorbents for natural gas storage85General framework for the frequency shifting of electromagnetic pulses using time-dependent surfaces4Controlling Multiphoton Absorption Efficiency by Chromophore Packing in Metal–Organic Frameworks86Metal–Organic Frameworks in Modern Physics: Highlights and Perspectives104Design strategies and applications of charged metal organic frameworks104Halogen-Bond-Modulated Organization of [Ni(terpy-ph)2]I2 Complexes in Heteromeric Three-Component Systems11Structural Diversity in Luminescent MOFs Containing a Bent Electron‐rich Dicarboxylate Linker and a Flexible Capping Ligand: Selective Detection of 4‐Nitroaniline in Water26Metal–organic frameworks: A tunable platform to access single-site heterogeneous catalysts126Four Zinc(II) coordination polymers with dicarboxylate and Tri(4-pyridylphenyl)amine ligand: Syntheses, crystal structures and physical properties6Giant Enhancement of Second Harmonic Generation Accompanied by the Structural Transformation of 7‐Fold to 8‐Fold Interpenetrated Metal–Organic Frameworks (MOFs)94Giant Enhancement of Second Harmonic Generation Accompanied by the Structural Transformation of 7‐Fold to 8‐Fold Interpenetrated Metal–Organic Frameworks (MOFs)35Facile synthesis of Ni-MOF using microwave irradiation method and application in the photocatalytic degradation45Solid-State Nonlinear Optical Properties of Mononuclear Copper(II) Complexes with Chiral Tridentate and Tetradentate Schiff Base Ligands27Ratiometric fluorescence sensing of metal-organic frameworks: Tactics and perspectives443Metal Oxide Nanoparticles in Therapeutic Regulation of Macrophage Functions89A highly stable luminescent coordination polymer for sensing of volatile iodine and its metal-ion exchange properties with Cu2+ ions26Quaternary phosphonium salt-functionalized Cr-MIL-101: A bifunctional and efficient catalyst for CO2 cycloaddition with epoxides118Accurate tuning of rare earth metal–organic frameworks with unprecedented topology for white-light emission32Synthesis and properties of Mg2+ and Sr2+ coordination compounds based on in situ synthetized pyromellitdihydrazidate ligand8Efficient Construction of Near-Infrared Absorption Donor–Acceptor Copolymers with and without Pt(II)-Incorporation toward Broadband Nonlinear Optical Materials52Architectural and catalytic aspects of designer materials built using metalloligands of pyridine-2,6-dicarboxamide based ligands20Engineering micromechanics of soft porous crystals for negative gas adsorption49Octacyanidometallates for multifunctional molecule-based materials164Optical properties of 3-substituted indoles35Síntese e estudo das propriedades estruturais, vibracionais e térmicas do monocristal de L-Treonina complexado com íon Cu2+ pelo método de evaporação lenta do solvente0Spectroscopy, microscopy, diffraction and scattering of archetypal MOFs: formation, metal sites in catalysis and thin films116Surface-coordinated metal–organic framework thin films (SURMOFs) for electrocatalytic applications58Synthesis of a biocompatible nanoporous zeolitic imidazolate framework-8 in the presence of Gum Arabic inspired by the biomineralization process11Taking lanthanides out of isolation: tuning the optical properties of metal–organic frameworks24The affinity of copper( ii ) ions towards l -amino acids in the solid-state: a simple route towards mixed complexes4Optical limiting properties of metalloporphyrin-based zirconium-polyphenolate frameworks13Linear and nonlinear optical probing of various excitons in 2D inorganic-organic hybrid structures19Second harmonic generation enhancement of 2D metal-organic framework using silicon nanoparticles0Understanding the Linear and Second-Order Nonlinear Optical Properties of UiO-66-Derived Metal–Organic Frameworks: A Comprehensive DFT Study52Polymer Matrix Incorporated with ZIF-8 for Application in Nonlinear Optics27Nanocomposite for photonics — Nickel pyrophosphate nanocrystals synthesised in silica nanoreactors23Chiral and SHG-Active Metal–Organic Frameworks Formed in Solution and on Surfaces: Uniformity, Morphology Control, Oriented Growth, and Postassembly Functionalization56Photofunctional metal-organic framework thin films for sensing, catalysis and device fabrication22Vinylene‐Linked Covalent Organic Frameworks (COFs) with Symmetry‐Tuned Polarity and Photocatalytic Activity332Vinylene‐Linked Covalent Organic Frameworks (COFs) with Symmetry‐Tuned Polarity and Photocatalytic Activity71Phonons splitting induces the second harmonic of tetragonal KH2PO4 by first-principles calculations3Tuning Optical Properties by Controlled Aggregation: Electroluminescence Assisted by Thermally‐Activated Delayed Fluorescence from Thin Films of Crystalline Chromophores37Nonlinear optical metal-organic frameworks for ratiometric temperature sensing in physiological range34Structural, thermal and electro-optical properties of guanidine based Metal-Organic Framework (MOF)29Integration of multifunctionalities on ionic liquid-anchored MIL-101(Cr): A robust and efficient heterogeneous catalyst for conversion of CO2 into cyclic carbonates50A Facile Electrosynthesis of Terephthalate (tp)‐Based Metal‐Organic Framework, Ni3(OH)2(H2O)2(tp)2 with Superior Catalytic Activity for Hydrogen Evolution Reaction10A nonlinear optical cadmium( ii )-based metal–organic framework with chiral helical chains derived from an achiral bent dicarboxylate ligand15Anisotropic Band-Edge Absorption of Millimeter-Size Zn(3-Ptz)2 Single Crystal Metal-Organic Frameworks0Bioresponsive metal–organic frameworks: Rational design and function29Synthesis, Characterization, and Photophysics of Self-Assembled Mn(II)-MOF with Naphthalene Chromophore29Engineering entangled photon pairs with metal–organic frameworks19First transition series metal–organic frameworks: synthesis, properties and applications73Homochiral three-dimensional noncentrosymmetric lanthanide coordination polymers directed by chiral linkers: syntheses, crystal structures, and optical properties8Large MOFs: synthesis strategies and applications where size matters51Non-traditional thermal behavior of Co( ii ) coordination networks showing slow magnetic relaxation16pH response of a hydroxyl-functionalized luminescent metal–organic framework based phosphor13Seven Modern Trends in the DeNOx Catalyst Development7Vibrational Sum-Frequency Generation Hyperspectral Microscopy for Molecular Self-Assembled Systems42Nonlinear Optical Responsive Molecular Switches7Two-dimensional MOF and COF nanosheets for next-generation optoelectronic applications190Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications928MnO2 decorated ZIF-8@GOx for synergistic chemodynamic and starvation therapy of cancer28Asymmetric catalysis using metal-organic frameworks142Charge-Transfer-Induced Electrical Conductivity in a Tetrathiafulvalene-Based Metal–Organic Framework31Crystalline Porous Materials for Nonlinear Optics91Research progress on nanoporous carbons produced by the carbonization of metal organic frameworks31Composite Materials Manufactured by Photopolymer 3D Printing with Metal-Organic Frameworks17Multifunctional Properties of a Zn(II) Coordination Complex16Third-Order Nonlinear Optical Behavior of an Amide-Tricarboxylate Zinc(II) Metal–Organic Framework with Two-Fold 3D+3D Interpenetration140A 3D supramolecular framework assembled via π⋅⋅⋅π interactions and CH⋅⋅⋅Cl hydrogen-bonds with second-harmonic generation response2Millimeter-Scale Zn(3-ptz)2 Metal–Organic Framework Single Crystals: Self-Assembly Mechanism and Growth Kinetics19Topological methods for analysis and design of coordination polymers50Multifunctional DyIII Enantiomeric Pairs Showing Enhanced Photoluminescences and Third-Harmonic Generation Responses through the Coordination Role of Homochiral Tridentate N,N,N-Pincer Ligands32

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  1. ChemInform Abstract: Metal—Organic Frameworks as Competitive Materials for Non‐Linear Optics

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  2. SHG-active Ln III –[Mo I (CN) 5 (NO)] 3− (Ln = Gd, Eu) magnetic coordination chains: a new route towards non-centrosymmetric molecule-based magnets

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  3. A second-order nonlinear optical material with a 5-fold interpenetrating diamondoid framework based on two achiral precursors: spontaneous resolution to absolute chiral induction

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  4. Alkoxido-bridged binuclear copper( ii ) complexes derived from aminoalcohols – useful building blocks in designing coordination polymers with a rich structural variety

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  5. An updated roadmap for the integration of metal–organic frameworks with electronic devices and chemical sensors

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  6. Biomimetic mineralization of metal–organic frameworks around polysaccharides

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  13. van der Waals Metal‐Organic Framework as an Excitonic Material for Advanced Photonics

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  14. A New Class of Lasing Materials: Intrinsic Stimulated Emission from Nonlinear Optically Active Metal–Organic Frameworks

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  17. A Cd(II) metal–organic framework based on semi-rigid ligand 3,5-(4-carboxybenzyloxy) benzoic acid with high stability by intramolecular hydrogen-bonding

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  18. Design of an efficient solution grown semiorganic NLO crystal for short wavelength generation: Bis(L-Threonine) magnesium (II) monohydrate

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  20. Nonlinear Metasurfaces: A Paradigm Shift in Nonlinear Optics

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  21. Nonlinear metasurfaces: a paradigm shift in nonlinear optics

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  24. A Host Material for Deep-Blue Electrophosphorescence Based on a Cuprous Metal–Organic Framework

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  25. The Impact of Charge‐Distribution on Photochromic Properties in 1D Coordination Polymers

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  26. Influence of Cu2+ ion on structural, luminescence and dielectric properties of zinc thiourea chloride metal-organic complex crystal

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  27. The Power of Heterometalation through Lithium for Helix Chain-Based Noncentrosymmetric Metal–Organic Frameworks with Tunable Second-Harmonic Generation Effects

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  29. Two luminescent Zn(II) metal–organic frameworks for exceptionally selective detection of picric acid

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  32. Photoelectron Transfer at ZnTPyP Self-Assembly/TiO2 Interfaces for Enhanced Two-Photon Photodynamic Therapy

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  33. Broadband optical limiting of a novel twisted tetrathiafulvalene incorporated donor–acceptor material and its Ormosil gel glasses

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  34. Coordination supramolecules with oxazoline-containing ligands

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  35. Degradation paths of manganese-based MOF materials in a model oxidative environment: a computational study

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  36. Hybrid materials based on transition metal–BTC–benzimidazole: solvent assisted crystallographic and structural switching

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  38. Supramolecular self-assembly for designing non-centrosymmetric crystals based on Keggin polyoxometallates and crown ether

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  39. Synthesis of glycerol carbonate over a 2D coordination polymer built with Nd 3+ ions and organic ligands

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  40. Tuning structures and emissive properties in a series of Zn( ii ) and Cd( ii ) coordination polymers containing dicarboxylic acids and nicotinamide pillars

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  41. Shape engineering of metal–organic frameworks

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  42. Recent Advances in Micro‐/Nanostructured Metal–Organic Frameworks towards Photonic and Electronic Applications

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  43. pH-Controlled Assembly of 3D and 2D Zinc-Based Metal-Organic Frameworks with Tetrazole Ligands

    ACS Omega · 2018-01-22

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  44. Zeolite imidazolate frameworks in catalysis: Synthesis of benzimidazoles via cascade redox condensation using Co-ZIF-67 as an efficient heterogeneous catalyst

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  45. Enantiopure Chiral Coordination Polymers Based on Polynuclear Paddlewheel Helices and Arsenyl Tartrate

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