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RESEARCH PAPER · Dalton Transactions · 2015

SnGa 2 GeS 6 : synthesis, structure, linear and nonlinear optical properties

Zuohong Lin, Chao Li, Lei Kang, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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SnGa 2 GeS 6 : synthesis, structure, linear and nonlinear optical propertiesOriginalBaGa 2 SnSe 6 : a new phase-matchable IR nonlinear optical material with strong second harmonic generation response58Metal Thiophosphates with Good Mid-infrared Nonlinear Optical Performances: A First-Principles Prediction and Analysis441All-metal electride molecules CuAg@Ca 7 M (M = Be, Mg, and Ca) with multi-excess electrons and all-metal polyanions: molecular structures and bonding modes as well as large infrared nonlinear optical responses27BaCdSnS 4 and Ba 3 CdSn 2 S 8 : syntheses, structures, and non-linear optical and photoluminescence properties97Recent achievements on middle and far-infrared second-order nonlinear optical materials433Ba 6 Li 2 CdSn 4 S 16 : lithium substitution simultaneously enhances band gap and SHG intensity44Na 2 CdGe 2 Q 6 (Q = S, Se): two metal-mixed chalcogenides with phase-matching abilities and large second-harmonic generation responses78Syntheses and characterization of three new sulfides with large band gaps: acentric Ba 4 Ga 4 SnS 12 , centric Ba 12 Sn 4 S 23 and Ba 7 Sn 3 S 1327Mid-Infrared Nonlinear Optical Materials Based on Metal Chalcogenides: Structure–Property Relationship338Synthesis and characterization of two lead-containing metal chalcogenides: Ba5Pb2Sn3S13 and Ba6PbSn3Se137Electronic, optical and thermoelectric properties of SnGa2GeX6 (X = S, Se) compounds10PbGa2GeS6: An Infrared Nonlinear Optical Material Synthesized by an Intermediate-Temperature Self-Fluxing Method42Na 6 Zn 3 MIII2Q 9 (M III = Ga, In; Q = S, Se): four new supertetrahedron-layered chalcogenides with unprecedented vertex-sharing T 3 -clusters and desirable photoluminescence performances31NaBaM III Q 3 (M III = Al, Ga; Q = S, Se): first quaternary chalcogenides with isolated edge-sharing (MIII2Q 6 ) 6− dimers8Structural insights into T 2 -cluster-containing chalcogenides with vertex-, edge- and face-sharing connection modes of NaQ 6 ligands: Na 3 ZnM III Q 4 (M III = In, Ga; Q = S, Se)13PbGa2GeS6 crystal as a novel nonlinear optical material: Band structure aspects36Synthesis, structure, magnetic and optoelectric properties of layered NaM0.5Sn0.5S2 (M= Mn, Fe)1Effect of Element Substitution on Structural Transformation and Optical Performances in I2BaMIVQ4 (I = Li, Na, Cu, and Ag; MIV = Si, Ge, and Sn; Q = S and Se)63Quaternary sulfide Ba5Cd2Ga2S10 containing chains of edge- and corner-sharing tetrahedra16Growth and Characterization of PbGa2GeSе6: A New Quaternary Chalcogenide Nonlinear Crystal for the Mid-IR0Lone pair effects on ternary infrared nonlinear optical materials19SnGa 2 GeSe 6 , a benign addition to the AMIII2M IV Q 6 family: synthesis, crystal structure and nonlinear optical performance20Polycrystal Synthesis, Crystal Growth, Structure, and Optical Properties of AgGaGe n S 2( n +1) ( n = 2, 3, 4, and 5) Single Crystals for Mid-IR Laser Applications27Growth and Characterization of PbGa 2 GeSe 6 : A New Quaternary Chalcogenide Nonlinear Crystal for the Mid-IR0Crystal Growth and Characterization of a New Quaternary Chalcogenide Nonlinear Crystal for the Mid-Infrared: PbGa2GeSe611Sn 2 Ga 2 S 5 : A Polar Semiconductor with Exceptional Infrared Nonlinear Optical Properties Originating from the Combined Effect of Mixed Asymmetric Building Motifs81Vibration uncoupling of germanium with different valence states lowers thermal conductivity of Cs2Ge3Ga6Se1410Rational design of infrared nonlinear optical chalcogenides by chemical substitution287Non-centrosymmetric sulfides A 2 Ba 6 MnSn 4 S 16 (A = Li, Ag): syntheses, structures and properties21Highly anisotropic layered selenophosphate AgSbP2Se6: The electronic structure and optical properties by experimental measurements and first-principles calculations9Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials95Design and synthesis of Ba 3 SiSe 5 with suitable birefringence modulated via M IV atoms in the Ba–M IV –Q (M IV = Si, Ge; Q = S, Se) system3K 3 Na(TaF 7 )(SiF 6 ): a mixed-anion pentanary fluoride with zero-dimensional anions exhibiting a large band gap14Synthesis, characterization and theoretical investigation of a new chalcohalide, Ba 4 GaS 4 F 311Structural Transformation and Second-Harmonic-Generation Activity in Rare-Earth and d0 Transition-Metal Oxysulfides RE3NbS3O4 (RE = Ce, Sm, Gd, Dy)38SnPQ3 (Q = S, Se, S/Se): A Series of Lone-Pair Cationic Chalcogenophosphates Exhibiting Balanced NLO Activity Originating from SnQ8 Units49NaBaBS3: A Promising Infrared Functional Material with Large Birefringence Induced by π-Conjugated [BS3] Units32A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applications115Na 6 Sn 3 P 4 S 16 : Sn( ii )-chelated PS 4 groups inspired an ultra-strong SHG response22Synthesis, Structure, and optical properties of Y3GaGe0.5S7: A new member in the polar R3MTQ7 family4Ga-based IR nonlinear optical materials: Synthesis, structures, and properties65Cationic substitution engineering induces a new quaternary chalcogenide in the A–M IIIA –M IVA –Q system for optical crystal applications1Syntheses, crystal structures, and physical properties of three new chalcospinels: Ag2Sc2Sn2S8, Cu1.9(1)Sc1.9(1)Sn2.1(1)S8, and Cu1.4(1)Sc1.4(1)Sn2.6(1)Se81Thermo-Mechanical Characterization of the Orthorhombic Nonlinear Optical Crystal PbGa2GeSe60Structure-property relationships in IR nonlinear optical chalcogenides with stereochemically active lone pairs29Modulating Nonlinear Optical Performances in α/β-SnGa2GeS6 Polymorphs via Atomic Coordination Engineering1

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  1. BaGa 2 SnSe 6 : a new phase-matchable IR nonlinear optical material with strong second harmonic generation response

    Journal of Materials Chemistry C · 2015-01-01

    Xiaoshuang Li, Chao Li, Pifu Gong, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  2. Metal Thiophosphates with Good Mid-infrared Nonlinear Optical Performances: A First-Principles Prediction and Analysis

    Journal of the American Chemical Society · 2015-09-23

    Lei Kang, Molin Zhou, Jiyong Yao, Zheshuai Lin, Yicheng Wu, Chuangtian Chen

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  3. All-metal electride molecules CuAg@Ca 7 M (M = Be, Mg, and Ca) with multi-excess electrons and all-metal polyanions: molecular structures and bonding modes as well as large infrared nonlinear optical responses

    Dalton Transactions · 2015-12-22

    Huimin He, Ying Li, Wei‐Ming Sun, Jiajun Wang, Di Wu, Rong‐Lin Zhong, Zhong‐Jun Zhou, Zhi‐Ru Li

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  4. BaCdSnS 4 and Ba 3 CdSn 2 S 8 : syntheses, structures, and non-linear optical and photoluminescence properties

    Dalton Transactions · 2016-01-01

    Ni Zhen, Kui Wu, Ying Wang, Qiang Li, Wenhui Gao, Dianwei Hou, Zhihua Yang, Huaidong Jiang, Yongjun Dong, Shilie Pan

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  5. Recent achievements on middle and far-infrared second-order nonlinear optical materials

    Coordination Chemistry Reviews · 2016-12-27

    Sheng‐Ping Guo, Yang Chi, Guo‐Cong Guo

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  6. Ba 6 Li 2 CdSn 4 S 16 : lithium substitution simultaneously enhances band gap and SHG intensity

    Journal of Materials Chemistry C · 2017-01-01

    Ruihuan Duan, Pengfei Liu, Hua Lin, Yi‐Wen Zheng, Ju‐Song Yu, Xin‐Tao Wu, Shangxiong Huangfu, Ling Chen

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  7. Na 2 CdGe 2 Q 6 (Q = S, Se): two metal-mixed chalcogenides with phase-matching abilities and large second-harmonic generation responses

    Dalton Transactions · 2017-01-01

    Guangmao Li, Qiong Liu, Kui Wu, Zhihua Yang, Shilie Pan

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  8. Syntheses and characterization of three new sulfides with large band gaps: acentric Ba 4 Ga 4 SnS 12 , centric Ba 12 Sn 4 S 23 and Ba 7 Sn 3 S 13

    Dalton Transactions · 2017-01-01

    Ruihuan Duan, Pengfei Liu, Hua Lin, Shangxiong Huangfu, Li‐Ming Wu

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  9. Mid-Infrared Nonlinear Optical Materials Based on Metal Chalcogenides: Structure–Property Relationship

    Crystal Growth & Design · 2017-03-15

    Fei Liang, Lei Kang, Zheshuai Lin, Yicheng Wu

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  10. Synthesis and characterization of two lead-containing metal chalcogenides: Ba5Pb2Sn3S13 and Ba6PbSn3Se13

    Journal of Solid State Chemistry · 2017-08-16

    Ailijiang Abudurusuli, Hanqin Ding, Kui Wu

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  11. Electronic, optical and thermoelectric properties of SnGa2GeX6 (X = S, Se) compounds

    Journal of Alloys and Compounds · 2017-12-07

    Naveed Yousaf, Wilayat Khan, Shah Haider Khan, Muhammad Shahzad Yaseen, A. Laref, Ghulam Murtaza

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  12. PbGa2GeS6: An Infrared Nonlinear Optical Material Synthesized by an Intermediate-Temperature Self-Fluxing Method

    Crystal Growth & Design · 2017-12-28

    Yi‐Zhi Huang, Hao Zhang, Chensheng Lin, Wen‐Dan Cheng, Zhengxiao Guo, Guoliang Chai

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  13. Na 6 Zn 3 MIII2Q 9 (M III = Ga, In; Q = S, Se): four new supertetrahedron-layered chalcogenides with unprecedented vertex-sharing T 3 -clusters and desirable photoluminescence performances

    Inorganic Chemistry Frontiers · 2018-01-01

    Ailijiang Abudurusuli, Kui Wu, Yilimiranmu Rouzhahong, Zhihua Yang, Shilie Pan

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  14. NaBaM III Q 3 (M III = Al, Ga; Q = S, Se): first quaternary chalcogenides with isolated edge-sharing (MIII2Q 6 ) 6− dimers

    Dalton Transactions · 2018-01-01

    Ailijiang Abudurusuli, Kui Wu, Yilimiranmu Rouzhahong, Zhihua Yang, Shilie Pan

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  15. Structural insights into T 2 -cluster-containing chalcogenides with vertex-, edge- and face-sharing connection modes of NaQ 6 ligands: Na 3 ZnM III Q 4 (M III = In, Ga; Q = S, Se)

    Dalton Transactions · 2018-01-01

    Ruijiao Chen, Xiaowen Wu, Zhi Su

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  16. PbGa2GeS6 crystal as a novel nonlinear optical material: Band structure aspects

    Journal of Alloys and Compounds · 2018-01-02

    A.O. Fedorchuk, O.V. Parasyuk, Oleksandr Cherniushok, Bohdan V. Andriyevsky, G.L. Myronchuk, Oleg Yu Khyzhun, Gandham Lakshminarayana, Jarosław Jedryka, Ivan V. Kityk, Ahmed M. El-Naggar, A.A. Albassam, Michał Piasecki

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  17. Synthesis, structure, magnetic and optoelectric properties of layered NaM0.5Sn0.5S2 (M= Mn, Fe)

    Journal of Alloys and Compounds · 2018-02-23

    Jianqiao He, Xian Zhang, Chong Zheng, Fuqiang Huang

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  18. Effect of Element Substitution on Structural Transformation and Optical Performances in I2BaMIVQ4 (I = Li, Na, Cu, and Ag; MIV = Si, Ge, and Sn; Q = S and Se)

    Inorganic Chemistry · 2018-03-06

    Leyan Nian, Kui Wu, Guijie He, Zhihua Yang, Shilie Pan

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  19. Quaternary sulfide Ba5Cd2Ga2S10 containing chains of edge- and corner-sharing tetrahedra

    Journal of Alloys and Compounds · 2018-06-22

    Mingjing Tang, Abishek K. Iyer, Dong Zhang, Wenlong Yin, Arthur Mar

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  20. Growth and Characterization of PbGa2GeSе6: A New Quaternary Chalcogenide Nonlinear Crystal for the Mid-IR

    Conference on Lasers and Electro-Optics · 2019-01-01

    Valeriy V. Badikov, Dmitrii V. Badikov, Li Wang, Galina S. Shevyrdyaeva, Vladimir L. Panyutin, Anna A. Fintisova, Svetlana G. Sheina, Valentin P. Petrov

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  21. Lone pair effects on ternary infrared nonlinear optical materials

    Physical Chemistry Chemical Physics · 2019-01-01

    Ruonan Yin, Cong Hu, Bing‐Hua Lei, Shilie Pan, Zhihua Yang

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  22. SnGa 2 GeSe 6 , a benign addition to the AMIII2M IV Q 6 family: synthesis, crystal structure and nonlinear optical performance

    Dalton Transactions · 2019-01-01

    Zhuang Li, Shengzi Zhang, Yangwu Guo, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  23. Polycrystal Synthesis, Crystal Growth, Structure, and Optical Properties of AgGaGe n S 2( n +1) ( n = 2, 3, 4, and 5) Single Crystals for Mid-IR Laser Applications

    Inorganic Chemistry · 2019-04-12

    Wei Huang, Z. Y. He, Shifu Zhu, Beijun Zhao, Baojun Chen, Sijia Zhu

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  24. Growth and Characterization of PbGa 2 GeSe 6 : A New Quaternary Chalcogenide Nonlinear Crystal for the Mid-IR

    Conference on Lasers and Electro-Optics · 2019-05-05

    Valeriy V. Badikov, Dmitrii V. Badikov, Li Wang, Galina S. Shevyrdyaeva, Vladimir L. Panyutin, Anna A. Fintisova, Svetlana Sheina, Valentin P. Petrov

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  25. Crystal Growth and Characterization of a New Quaternary Chalcogenide Nonlinear Crystal for the Mid-Infrared: PbGa2GeSe6

    Crystal Growth & Design · 2019-07-02

    Valeriy V. Badikov, Dmitrii V. Badikov, Li Wang, Galina S. Shevyrdyaeva, Vladimir L. Panyutin, Anna A. Fintisova, Svetlana G. Sheina, Valentin P. Petrov

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  26. Sn 2 Ga 2 S 5 : A Polar Semiconductor with Exceptional Infrared Nonlinear Optical Properties Originating from the Combined Effect of Mixed Asymmetric Building Motifs

    Chemistry of Materials · 2019-07-26

    Mengyue Li, Bingxuan Li, Hua Lin, Zuju Ma, Li‐Ming Wu, Xin‐Tao Wu, Qi‐Long Zhu

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  27. Vibration uncoupling of germanium with different valence states lowers thermal conductivity of Cs2Ge3Ga6Se14

    Science China Materials · 2019-10-25

    Ni Ma, Lin Xiong, Ling Chen, Li‐Ming Wu

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  28. Rational design of infrared nonlinear optical chalcogenides by chemical substitution

    Coordination Chemistry Reviews · 2019-12-21

    Hua Lin, Wenbo Wei, Hong Chen, Xintao Wu, Qi‐Long Zhu

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  29. Non-centrosymmetric sulfides A 2 Ba 6 MnSn 4 S 16 (A = Li, Ag): syntheses, structures and properties

    Dalton Transactions · 2020-01-01

    Ruihuan Duan, Hua Lin, Yue Wang, Yuqiao Zhou, Li‐Ming Wu

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  30. Highly anisotropic layered selenophosphate AgSbP2Se6: The electronic structure and optical properties by experimental measurements and first-principles calculations

    Chemical Physics · 2020-04-20

    Tuan V. Vu, Anatoliy A. Lavrentyev, B.V. Gabrelian, Dat Duy Vo, V.I. Sabov, M. Yu. Sabov, I. E. Barchiy, Michał Piasecki, Oleg Yu Khyzhun

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  31. Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials

    Crystal Growth & Design · 2020-12-22

    Mei Yan, Huaiguo Xue, Sheng‐Ping Guo

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  32. Design and synthesis of Ba 3 SiSe 5 with suitable birefringence modulated via M IV atoms in the Ba–M IV –Q (M IV = Si, Ge; Q = S, Se) system

    Dalton Transactions · 2021-01-01

    Huanhuan Cheng, Abudukadi Tudi, Peng Wang, Kewang Zhang, Zhihua Yang, Shilie Pan

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  33. K 3 Na(TaF 7 )(SiF 6 ): a mixed-anion pentanary fluoride with zero-dimensional anions exhibiting a large band gap

    Dalton Transactions · 2021-01-01

    Ru‐Ling Tang, Xin Lian, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  34. Synthesis, characterization and theoretical investigation of a new chalcohalide, Ba 4 GaS 4 F 3

    Dalton Transactions · 2021-01-01

    Hongbo Gao, Ruijiao Chen, Kewang Zhang, Ailijiang Abudurusuli, Kangrong Lai, Junjie Li

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  35. Structural Transformation and Second-Harmonic-Generation Activity in Rare-Earth and d0 Transition-Metal Oxysulfides RE3NbS3O4 (RE = Ce, Sm, Gd, Dy)

    Inorganic Chemistry · 2021-07-09

    Xin Lian, Zhen‐Tao Lu, Wen‐Dong Yao, Sihan Yang, Wenlong Liu, Ru‐Ling Tang, Sheng‐Ping Guo

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  36. SnPQ3 (Q = S, Se, S/Se): A Series of Lone-Pair Cationic Chalcogenophosphates Exhibiting Balanced NLO Activity Originating from SnQ8 Units

    Inorganic Chemistry · 2021-08-31

    Zhi‐Hui Shi, Mei Yang, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  37. NaBaBS3: A Promising Infrared Functional Material with Large Birefringence Induced by π-Conjugated [BS3] Units

    Chemistry of Materials · 2022-05-25

    Yihan Yun, Wenlong Xie, Yi Huang, Zhihua Yang, Kui Wu, Guangmao Li, Shilie Pan

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  38. A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applications

    Coordination Chemistry Reviews · 2022-07-19

    Hong Chen, Mao‐Yin Ran, Wenbo Wei, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  39. Na 6 Sn 3 P 4 S 16 : Sn( ii )-chelated PS 4 groups inspired an ultra-strong SHG response

    Inorganic Chemistry Frontiers · 2023-01-01

    Chenyao Zhao, Bingbing Zhang, Xinyu Tian, Guoqiang Zhou, Jingjing Xu, Kui Wu

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  40. Synthesis, Structure, and optical properties of Y3GaGe0.5S7: A new member in the polar R3MTQ7 family

    Inorganic Chemistry Communications · 2023-05-16

    Yue Wang, Yong‐Fang Shi, Yuan Hua Lin, Zhe Chen, Liting Li

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  41. Ga-based IR nonlinear optical materials: Synthesis, structures, and properties

    Coordination Chemistry Reviews · 2023-12-21

    Jiaxiang Zhang, Ping Feng, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  42. Cationic substitution engineering induces a new quaternary chalcogenide in the A–M IIIA –M IVA –Q system for optical crystal applications

    CrystEngComm · 2025-01-01

    Yue Wang, Xuezhong Li, Zihao Lou, Yong‐Fang Shi

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  43. Syntheses, crystal structures, and physical properties of three new chalcospinels: Ag2Sc2Sn2S8, Cu1.9(1)Sc1.9(1)Sn2.1(1)S8, and Cu1.4(1)Sc1.4(1)Sn2.6(1)Se8

    Solid State Sciences · 2025-03-19

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  44. Thermo-Mechanical Characterization of the Orthorhombic Nonlinear Optical Crystal PbGa2GeSe6

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  45. Structure-property relationships in IR nonlinear optical chalcogenides with stereochemically active lone pairs

    Coordination Chemistry Reviews · 2025-09-03

    Hong Chen, Xin‐Tao Wu, Hua Lin

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  46. Modulating Nonlinear Optical Performances in α/β-SnGa2GeS6 Polymorphs via Atomic Coordination Engineering

    Inorganic Chemistry · 2025-09-20

    Jingjing Xu, Yan Xiao, Dazhi Lu, Bingbing Zhang, Kui Wu, Haohai Yu, Huaijin Zhang

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