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RESEARCH PAPER · Journal of the American Chemical Society · 2012

The Role of Polar, Lamdba (Λ)-Shaped Building Units in Noncentrosymmetric Inorganic Structures

Martin D. Donakowski, Romain Gautier, Jeongho Yeon, Donald T. Moore, Juan C. Nino, P. Shiv Halasyamani, Kenneth Reinhard Poeppelmeier

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The Role of Polar, Lamdba (Λ)-Shaped Building Units in Noncentrosymmetric Inorganic StructuresOriginalDesign of SHG materials with mid-infrared transparency based on genetic engineering for Ba2BiInA5 (A = Se, Te)22The Dimeric [V2O4F6]4– Vanadium Oxide‐Fluoride Anion in Na2(M(H2O)2)(V2O4F6) (M = Co2+, Ni2+, and Cu2+)8ChemInform Abstract: The Role of Polar, Lamdba (Λ)‐Shaped Building Units in Noncentrosymmetric Inorganic Structures.0Synthesis, Structure, and Characterization of New Li+ – d0 –Lone-Pair – Oxides: Noncentrosymmetric Polar Li6(Mo2O5)3(SeO3)6 and Centrosymmetric Li2(MO3)(TeO3) (M = Mo6+ or W6+)47Role of Hydrogen-Bonding in the Formation of Polar Achiral and Nonpolar Chiral Vanadium Selenite Frameworks26From Racemic Units to Polar Materials23ZnTeMoO6: a strong second-harmonic generation material originating from three types of asymmetric building units53The dimeric [V2O2F8]4− anion: Structural characterization of a magnetic basic-building-unit18New Fluoride Carbonates: Centrosymmetric KPb2(CO3)2F and Noncentrosymmetric K2.70Pb5.15(CO3)5F367Cs2B4SiO9: A Deep‐Ultraviolet Nonlinear Optical Crystal278Cs2B4SiO9: A Deep‐Ultraviolet Nonlinear Optical Crystal224Synthesis, Structure, and Characterization of Two New Polar Sodium Tungsten Selenites: Na2(WO3)3(SeO3)·2H2O and Na6(W6O19)(SeO3)247Designing a Deep-Ultraviolet Nonlinear Optical Material with a Large Second Harmonic Generation Response598Ba2YFeO5.5: A Ferromagnetic Pyroelectric Phase Prepared by Topochemical Oxidation.17New Salt-Inclusion Borate, Li3Ca9(BO3)7·2[LiF]: A Promising UV NLO Material with the Coplanar and High Density BO3 Triangles56Semiorganic nonlinear optical material: Crystal growth, structure and optical properties of NaB(L-C4H4O5)27Polar and Magnetic Mn2FeMO6 (M=Nb, Ta) with LiNbO3‐type Structure: High‐Pressure Synthesis87Polar and Magnetic Mn2FeMO6 (M=Nb, Ta) with LiNbO3‐type Structure: High‐Pressure Synthesis15Effect of Rigid Units on the Symmetry of the Framework: Design and Synthesis of Centrosymmetric NaBa4(B5O9)2F2Cl and Noncentrosymmetric NaBa4(AlB4O9)2Br350Nonlinear Active Materials: An Illustration of Controllable Phase Matchability113Noncentrosymmetric Cubic CsCdBO3 with Bichromophore23CsPbCO3F: A Strong Second-Harmonic Generation Material Derived from Enhancement via p−π Interaction271Polar Alignment of Λ-Shaped Basic Building Units within Transition Metal Oxide Fluoride Materials15Influence of the cation size on the second harmonic generation response of chiral A(VO 2 ) 2 (PO 4 )·3H 2 O (A = K + , NH 4 + and Rb + )3Polar metal phosphonate containing unusual μ4-OH bridged double chains showing canted antiferromagnetism with large coercivity43Strong enhancement of second harmonic generation in nonlinear optical crystals: 2-amino-3-nitropyridinium halides (Cl, Br, I)20Specific Chemistry of the Anions: [TaOF5]2–, [TaF6]−, and [TaF7]2–20Synthesis and Magnetic Properties of β‐KVOF317Syntheses, characterization and nonlinear optical properties of a bismuth subcarbonate Bi2O2CO363A New UV Nonlinear Optical Material CsZn2B3O7: ZnO4 Tetrahedra Double the Efficiency of Second-Harmonic Generation121A Nitrate Nonlinear Optical Crystal Pb16(OH)16(NO3)16 with a Large Second-Harmonic Generation Response57Designing Polar and Magnetic Oxides: Zn2FeTaO6 - in Search of Multiferroics80Synthesis, Crystal Structure, Vibrational and Optical Properties of (Hdea)4(V7O19F)∙0.42H2O, an Original (V7O19F)4− Cluster Oxyfluoride9Syntheses of Two Vanadium Oxide–Fluoride Materials That Differ in Phase Matchability46Effect of Halogen (Cl, Br) on the Symmetry of Flexible Perovskite-Related Framework37A New Vanadium (V) Coordination Based on [(H2C4O4)VO2F] n 2n− Polymeric Chains and Diethylammonium Cations, Synthesis, Crystal Structure, Vibrational and Optical Properties2Synthesis and structural characterization of a new rubidium borosulfate, Rb5BS4O1616Synthetic strategies for new vanadium oxyfluorides containing novel building blocks: structures of V( iv ) and V( v ) containing Sr 4 V 3 O 5 F 13 , Pb 7 V 4 O 8 F 18 , Pb 2 VO 2 F 5 , and Pb 2 VOF 617On the Origin of the Differences in Structure Directing Properties of Polar Metal Oxyfluoride [MOxF6–x]2– (x = 1, 2) Building Units55Beryllium-Free Rb3Al3B3O10F with Reinforced Interlayer Bonding as a Deep-Ultraviolet Nonlinear Optical Crystal270Pb7O(OH)3(CO3)3(BO3): First Mixed Borate and Carbonate Nonlinear Optical Material Exhibiting Large Second-Harmonic Generation Response74Polar Polymorphism: α-, β-, and γ-Pb2Ba4Zn4B14O31–Synthesis, Characterization, and Nonlinear Optical Properties79RbMgCO3F: A New Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material342Luminescence and scintillation properties of La 2 [Si 2 O 7 ]:Ce 3+ functional pigment – A concept for UV-protection of coatings8K2Pb3(CO3)3F2 and KCdCO3F: Novel Fluoride Carbonates with Layered and 3D Framework Structures421,4-Diazabicyclo[2.2.2]octane-based disalts showing non-centrosymmetric structures and phase transition behaviors14Design of noncentrosymmetric perovskites from centric and acentric basic building units39Influence of an oxygen vacancy on the electronic structure of the asymmetric mixed borate–carbonate Pb 7 O(OH) 3 (CO 3 ) 3 (BO 3 )3Nonlinear optical response mechanism of noncentrosymmetric lead borate Pb 6 [B 4 O 7 (OH) 2 ] 3 with three crystallographically independent [B 4 O 7 (OH) 2 ] 4− chains8Synthesis and characterization of new fluoride-containing manganese vanadates A2Mn2V2O7F2 (A=Rb, Cs) and Mn2VO4F19Na 2 ZnGe 2 S 6 : A New Infrared Nonlinear Optical Material with Good Balance between Large Second-Harmonic Generation Response and High Laser Damage Threshold302Packing of Helices: Is Chirality the Highest Crystallographic Symmetry?8Directed Lifting of Inversion Symmetry in Ruddlesden–Popper Oxide–Fluorides: Toward Ferroelectric and Multiferroic Behavior57Cd3(MoO4)(TeO3)2: A Polar 3D Compound Containing d10–d0 SCALP-Effect Cations85Mixed-Metal Carbonate Fluorides as Deep-Ultraviolet Nonlinear Optical Materials258Enhancing optical anisotropy of crystals by optimizing bonding electron distribution in anionic groups237Na 2 CdGe 2 Q 6 (Q = S, Se): two metal-mixed chalcogenides with phase-matching abilities and large second-harmonic generation responses77Nature of phase transitions in ammonium oxofluorovanadates, a vibrational spectroscopy study of (NH4)3VO2F4 and (NH4)3VOF57Li3VO4: A Promising Mid-Infrared Nonlinear Optical Material with Large Laser Damage Threshold51Design and Synthesis of a Series of Novel Mixed Borate and Carbonate Halides21Orientational disorder and phase transitions in ammonium oxofluorovanadates, (NH4)3VOF5 and (NH4)3VO2F41An overview of double perovskites A2B′B″O6 with small ions at A site: Synthesis, structure and magnetic properties209Tailored fabrication of a prospective acousto–optic crystal TiTe 3 O 8 endowed with high performance26From AgGaS2 to Li2ZnSiS4: Realizing Impressive High Laser Damage Threshold Together with Large Second-Harmonic Generation Response134Effect of Element Substitution on Structural Transformation and Optical Performances in I2BaMIVQ4 (I = Li, Na, Cu, and Ag; MIV = Si, Ge, and Sn; Q = S and Se)64Eu2P7X and Ba2As7X (X = Br, I): Chiral double-Zintl salts containing heptapnictotricyclane clusters4MgSiAs: An Unexplored System with Promising Nonlinear Optical Properties53From Sr2Nb2O7to CaxSr2–xNb2O7: An Effective Enhancement of Nonlinear Optical Activity by a Simple Way of Cation Substituting11Assisting the Effective Design of Polar Iodates with Early Transition-Metal Oxide Fluoride Anions207Polymorphic Smooth Interfaces Formation Based on the Biphasic BaTeMo2O9 Using Top Multi-Seeded Growth9Second-order nonlinear optical crystals with mixed anions251Rational Design of a LiNbO3-like Nonlinear Optical Crystal, Li2ZrTeO6, with High Laser-Damage Threshold and Wide Mid-IR Transparency Window152Manifestations of Weak O–H···F Hydrogen Bonding in M(H2O)n(B12F12) Salt Hydrates: Unusually Sharp Fourier Transform Infrared ν(OH) Bands and Latent Porosity (M = Mg–Ba, Co, Ni, Zn)13Reversible Structural Transformation between Polar Polymorphs of Li2GeTeO617Cyclohexylammonium sulfanilate: A simple representative of the chiral materials containing only achiral building units8Exploration of New Birefringent Crystals in Bismuth d0 Transition Metal Selenites35A Niobium Oxyiodate Sulfate with a Strong Second‐Harmonic‐Generation Response Built by Rational Multi‐Component Design114A Niobium Oxyiodate Sulfate with a Strong Second‐Harmonic‐Generation Response Built by Rational Multi‐Component Design25Chemical Flexibility of Mg in Pnictide Materials: Structure and Properties Diversity27A x Ce 9 (IO 3 ) 36 (A = K, La): the effects of a change in the intermediate valence on the second-harmonic generation response7K5(W3O9F4)(IO3): An Efficient Mid-Infrared Nonlinear Optical Compound with High Laser Damage Threshold114Influence of structure-directing polyhedra and heterocyclic ligands on the chain structures and O/F ordering in a series of zinc vanadium oxyfluorides1Ca 2 B 5 O 9 Cl and Sr 2 B 5 O 9 Cl: Nonlinear Optical Crystals with Deep-Ultraviolet Transparency Windows46Designing Silicates as Deep‐UV Nonlinear Optical (NLO) Materials using Edge‐Sharing Tetrahedra148Designing Silicates as Deep‐UV Nonlinear Optical (NLO) Materials using Edge‐Sharing Tetrahedra43Synthesis, Structure, and Characterization of d0 Transition-Metal Iodate: BaTi(IO3)6·0.5H2O12Symmetry-Dependent Intermolecular π–π Stacking Directed by Hydrogen Bonding in Racemic Copper-Phenanthroline Compounds12Hydrogen-Bond-Assisted Alignment of [MCu(SeO 3 ) 4 Cl(H 2 O)] 4– (M = Fe, Ga) Anionic Layers to Form Two Polar Oxychlorides: Pb 2 MCu(SeO 3 ) 4 Cl(H 2 O)10Ba 2 [FeF 4 (IO 3 ) 2 ]IO 3 : a promising nonlinear optical material achieved by chemical-tailoring-induced structure evolution8Guanidinium sulfates as directors of noncentrosymmetric structures9K 2 Pb(H 2 C 3 N 3 O 3 ) 4 (H 2 O) 4 : a potential UV nonlinear optical material with large birefringence50Zn(NH 3 )CO 3 : a “three-in-one” UV nonlinear optical crystal built by a polar molecule bonding strategy18Interplay between Oxo and Fluoro in Vanadium Oxyfluorides for Centrosymmetric and Non-Centrosymmetric Structure Formation4Crystal structures of [Cu(phen)(H2O)3(MF6)]·H2O (M = Ti, Zr, Hf) and [Cu(phen)(H2O)2F]2[HfF6]·H2O1Na 6 MQ 4 (M=Zn, Cd; Q=S, Se): Promising New Ternary Infrared Nonlinear Optical Materials25Noncentrosymmetric Tetrel Pnictides RuSi4P4 and IrSi3P3: Nonlinear Optical Materials with Outstanding Laser Damage Threshold47Discovery of NLO Semiorganic (C 5 H 6 ON) + (H 2 PO 4 ) − : Dipole Moment Modulation and Superior Synergy in Solar-Blind UV Region270Fluoridation of HfO27Study of Integer Spin S = 1 in the Polar Magnet β-Ni(IO3)27β-BaGa 4 Se 7 : a promising IR nonlinear optical crystal designed by predictable structural rearrangement46Phase transitions and potential ferroelectricity in noncentrosymmetric KNaNbOF52Anomalous magnetic exchange in a dimerized quantum magnet composed of unlike spin species3Ba 2 [WO 3 F(IO 3 )][WO 3 F 2 ]: the first polar fluorinated tungsten iodate featuring a direct W–O–I bond7New quinary cesium vanadium (IV) fluorophosphates, CsVOF(PO3F) and CsV2O2F(PO3F)2·H2O3Two Distinct Cu(II)–V(IV) Superexchange Interactions with Similar Bond Angles in a Triangular “CuV2” Fragment4Preparation, Characterization and Photocatalytic Activity studies of Ag+, Cu2+ and Sn2+-doped Li2GeTeO6 under Visible Light Irradiation0Additive‐Triggered Polar Polymorph Formation: β‐Sc(IO 3 ) 3 , a Promising Next‐Generation Mid‐Infrared Nonlinear Optical Material42Additive‐Triggered Polar Polymorph Formation: β‐Sc(IO3)3, a Promising Next‐Generation Mid‐Infrared Nonlinear Optical Material3Mixed anion materials0PbBi(SeO 3 ) 2 F and Pb 2 Bi(SeO 3 ) 2 Cl 3 : Coexistence of Three Kinds of Stereochemically Active Lone-Pair Cations Exhibiting Excellent Nonlinear Optical Properties57Isomeric Cd(NH4)2(PO3F)2·2H2O: Solution concentration-driven elimination of antiparallel dipole-dipole interaction generating an SHG β phase12K2(H2O)WO3F2: A new nonlinear optical material with remarkable second-harmonic generation response and enhanced laser damage threshold9A selenite containing unusual [Ga2F(Se2O5)4(HSeO3)2]5- clusters with the polarization ‘lighted’ by F− anions15Multifunctional properties of a polar spin chain compound [N(C3H7)4][Cu(C8H4NO4)]·H2O exhibiting both one-dimensional magnetism and nonlinear optical activity15Highly Birefringent d 0 Transition Metal Fluoroantimonite in the Mid Infrared Band: Order–Disorder Regulation by Cationic Size84Cu(I)-thioether coordination complexes based on a chiral cyclic β-amino acid ligand4Targeting Oxide Concentration in Tantalum Oxide-Fluoride Anions0NaMoO 3 (IO 3 )(H 2 O): water molecule introduction induces strong second harmonic generation response, widened band gap and large anisotropy8Advances in Solid-State Nonlinear Optical Materials: From Fundamentals to Applications61Secondary‐Bond‐Driven Construction of a Polar Material Exhibiting Strong Broad‐Spectrum Second‐Harmonic Generation and Large Birefringence9Secondary‐Bond‐Driven Construction of a Polar Material Exhibiting Strong Broad‐Spectrum Second‐Harmonic Generation and Large Birefringence41From NaGa(IO3)3F to NaGa(IO3)2F2 and NaGa(IO3)4: The Effects of Chemical Substitution between F– Anions and IO3– Groups on the Structures and Properties of Gallium Iodates13Novel ternary Zintl phosphide halides Ba 3 P 5 X (X = Cl, Br) with 1D helical phosphorus chains: synthesis, crystal and electronic structure11Centrosymmetric CaBaMF8 and Noncentrosymmetric Li2CaMF8 (M = Zr, Hf): Dimension Variation and Nonlinear Optical Activity Resulting from an Isovalent Cation Substitution-Oriented Design17A Noncentrosymmetric Metal‐Free Borophosphate: Achieving a Large Birefringence and Excellent Stability by Covalent‐Linkage27Noncentrosymmetric Crystal [C10H8NO2]2SiF6·H2O with Large Birefringence12Rational Design of Novel Polar Nonlinear Optical Materials in Alkali Metal Rare Earth Iodates5New mixed 3d metal-based oxyfluorinated materials as anodic catalysts for water splitting : from elaboration to mechanistic study0Effects of the anion exchange between I − and NCS − coordinated to Co 2+ -centered tetrahedra in the organic–inorganic hybrid halides0Fluorine as a Key Element in Solid-State Chemistry of Mixed Anions 3d Transition Metal-Based Materials for Electronic Properties and Energy24A-Site Cation Substitution toward Structural Transformation in Phosphates Exhibiting Short UV Transparency and Second Harmonic Response3Rational Design of a Deep-Ultraviolet Nonlinear Optical Crystal26[Pb(ptz)(OH)(H2O)]: A Hybrid Nonlinear Optical Crystal with Large Birefringence0Metal Chloride‐Iodate Nonlinear Optical Materials via Direct Chlorination of Centrosymmetric Metal Iodate Crystals0Recent achievements of d0 transition-metal-based oxyfluorides: Crystal chemistry and application in second-order NLO materials10A universal synthetic strategy for noncentrosymmetric lead oxyhalide frameworks with strong second-harmonic generation01D Cobalt‐Cytidine Monophosphate Coordination Polymer Exhibiting Efficient Ultraviolet Second‐Harmonic Generation7Heterometallic spin- 1 2 quantum magnet under hydrostatic pressure0Λ‐Shaped Dimers Enables Polar Antiperovskites Through A‐Site Displacement Mechanism0

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  1. Design of SHG materials with mid-infrared transparency based on genetic engineering for Ba2BiInA5 (A = Se, Te)

    Journal of Materials Chemistry · 2012-01-01

    Chensheng Lin, Zhong‐Zhen Luo, Wen‐Dan Cheng, Hao Zhang, Weilong Zhang

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  2. The Dimeric [V2O4F6]4– Vanadium Oxide‐Fluoride Anion in Na2(M(H2O)2)(V2O4F6) (M = Co2+, Ni2+, and Cu2+)

    Zeitschrift für anorganische und allgemeine Chemie · 2012-06-27

    Martin D. Donakowski, Anastasiya I. Vinokur, Kenneth Reinhard Poeppelmeier

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  3. ChemInform Abstract: The Role of Polar, Lamdba (Λ)‐Shaped Building Units in Noncentrosymmetric Inorganic Structures.

    ChemInform · 2012-08-02

    Martin D. Donakowski, Romain Gautier, Jeongho Yeon, Donald T. Moore, Juan C. Nino, P. Shiv Halasyamani, Kenneth Reinhard Poeppelmeier

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  4. Synthesis, Structure, and Characterization of New Li+ – d0 –Lone-Pair – Oxides: Noncentrosymmetric Polar Li6(Mo2O5)3(SeO3)6 and Centrosymmetric Li2(MO3)(TeO3) (M = Mo6+ or W6+)

    Inorganic Chemistry · 2012-08-23

    Sau Doan Nguyen, P. Shiv Halasyamani

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  5. Role of Hydrogen-Bonding in the Formation of Polar Achiral and Nonpolar Chiral Vanadium Selenite Frameworks

    Inorganic Chemistry · 2012-09-24

    Jacob H. Olshansky, T. Thao Tran, Kristen J. Hernandez, Mat­thias Zeller, P. Shiv Halasyamani, Joshua Schrier, Alexander J. Norquist

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  6. From Racemic Units to Polar Materials

    Crystal Growth & Design · 2012-11-06

    Romain Gautier, Alexander J. Norquist, Kenneth Reinhard Poeppelmeier

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  7. ZnTeMoO6: a strong second-harmonic generation material originating from three types of asymmetric building units

    RSC Advances · 2013-01-01

    Sangen Zhao, Junhua Luo, Pan Zhou, Shuquan Zhang, Zhihua Sun, Maochun Hong

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  8. The dimeric [V2O2F8]4− anion: Structural characterization of a magnetic basic-building-unit

    Journal of Solid State Chemistry · 2013-01-26

    Hongcheng Lu, Romain Gautier, Zuo-Xi Li, Wanqi Jie, Zheng‐Tang Liu, Kenneth Reinhard Poeppelmeier

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  9. New Fluoride Carbonates: Centrosymmetric KPb2(CO3)2F and Noncentrosymmetric K2.70Pb5.15(CO3)5F3

    Inorganic Chemistry · 2013-02-08

    T. Thao Tran, P. Shiv Halasyamani

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  10. Cs2B4SiO9: A Deep‐Ultraviolet Nonlinear Optical Crystal

    Angewandte Chemie International Edition · 2013-02-13

    Hongping Wu, Hao Yu, Shilie Pan, Zhenjun Huang, Zhihua Yang, Xin Su, Kenneth Reinhard Poeppelmeier

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  11. Cs2B4SiO9: A Deep‐Ultraviolet Nonlinear Optical Crystal

    Angewandte Chemie · 2013-02-13

    Hongping Wu, Hongwei Yu, Shilie Pan, Zhenjun Huang, Zhihua Yang, Xin Su, Kenneth Reinhard Poeppelmeier

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  12. Synthesis, Structure, and Characterization of Two New Polar Sodium Tungsten Selenites: Na2(WO3)3(SeO3)·2H2O and Na6(W6O19)(SeO3)2

    Inorganic Chemistry · 2013-02-20

    Sau Doan Nguyen, P. Shiv Halasyamani

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  13. Designing a Deep-Ultraviolet Nonlinear Optical Material with a Large Second Harmonic Generation Response

    Journal of the American Chemical Society · 2013-02-28

    Hongping Wu, Hongwei Yu, Zhihua Yang, Xueling Hou, Xin Su, Shilie Pan, Kenneth Reinhard Poeppelmeier, James M. Rondinelli

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  14. Ba2YFeO5.5: A Ferromagnetic Pyroelectric Phase Prepared by Topochemical Oxidation.

    Chemistry of Materials · 2013-04-09

    Kun Luo, Roger D. Johnson, T. Thao Tran, P. Shiv Halasyamani, Paolo G. Radaelli, Michael A. Hayward

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  15. New Salt-Inclusion Borate, Li3Ca9(BO3)7·2[LiF]: A Promising UV NLO Material with the Coplanar and High Density BO3 Triangles

    Inorganic Chemistry · 2013-04-12

    Hongwei Yu, Hongping Wu, Shilie Pan, Ying Wang, Zhihua Yang, Xin Su

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  16. Semiorganic nonlinear optical material: Crystal growth, structure and optical properties of NaB(L-C4H4O5)2

    Materials Research Bulletin · 2013-05-04

    Hongwei Huang, Wenjiao Yao, Ying He, Na Tian, Chuangtian Chen, Yihe Zhang

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  17. Polar and Magnetic Mn2FeMO6 (M=Nb, Ta) with LiNbO3‐type Structure: High‐Pressure Synthesis

    Angewandte Chemie International Edition · 2013-06-27

    Man‐Rong Li, David Walker, M. Retuerto, Tapati Sarkar, Joke Hadermann, Peter W. Stephens, Mark Croft, Alexander Ignatov, Christoph P. Grams, J. Hemberger, I. Nowik, P. Shiv Halasyamani, T. Thao Tran, Swarnakamal Mukherjee, Tanusri Saha‐Dasgupta, M. Greenblatt

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  18. Polar and Magnetic Mn2FeMO6 (M=Nb, Ta) with LiNbO3‐type Structure: High‐Pressure Synthesis

    Angewandte Chemie · 2013-06-28

    Man‐Rong Li, David Walker, M. Retuerto, Tapati Sarkar, Joke Hadermann, Peter W. Stephens, Mark Croft, Alexander Ignatov, Christoph P. Grams, J. Hemberger, I. Nowik, P. Shiv Halasyamani, T. Thao Tran, Swarnakamal Mukherjee, Tanusri Saha‐Dasgupta, M. Greenblatt

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  19. Effect of Rigid Units on the Symmetry of the Framework: Design and Synthesis of Centrosymmetric NaBa4(B5O9)2F2Cl and Noncentrosymmetric NaBa4(AlB4O9)2Br3

    Crystal Growth & Design · 2013-07-01

    Hongwei Yu, Shilie Pan, Hongping Wu, Zhihua Yang, Lingyun Dong, Xin Su, Bingbing Zhang, Hongyi Li

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  20. Nonlinear Active Materials: An Illustration of Controllable Phase Matchability

    Journal of the American Chemical Society · 2013-07-18

    Hongcheng Lu, Romain Gautier, Martin D. Donakowski, T. Thao Tran, Bryce W. Edwards, Juan C. Nino, P. Shiv Halasyamani, Zheng‐Tang Liu, Kenneth Reinhard Poeppelmeier

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  21. Noncentrosymmetric Cubic CsCdBO3 with Bichromophore

    European Journal of Inorganic Chemistry · 2013-10-02

    Hongwei Yu, Hongping Wu, Shilie Pan, Bingbing Zhang, Ming Wen, Zhihua Yang, Hongyi Li, Xiangzhan Jiang

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  22. CsPbCO3F: A Strong Second-Harmonic Generation Material Derived from Enhancement via p−π Interaction

    Journal of the American Chemical Society · 2013-11-22

    Guohong Zou, Ling Huang, Ning Ye, Chensheng Lin, Wendan Cheng, Hui Huang

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  23. Polar Alignment of Λ-Shaped Basic Building Units within Transition Metal Oxide Fluoride Materials

    Inorganic Chemistry · 2013-12-12

    Michael A. Holland, Martin D. Donakowski, Eric A. Pozzi, Andrew M. Rasmussen, T. Thao Tran, Shannon E. Pease-Dodson, P. Shiv Halasyamani, Tamar Seideman, Richard P. Van Duyne, Kenneth Reinhard Poeppelmeier

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  24. Influence of the cation size on the second harmonic generation response of chiral A(VO 2 ) 2 (PO 4 )·3H 2 O (A = K + , NH 4 + and Rb + )

    CrystEngComm · 2014-01-01

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  25. Polar metal phosphonate containing unusual μ4-OH bridged double chains showing canted antiferromagnetism with large coercivity

    Chemical Communications · 2014-01-01

    Xiao-Jing Yang, Song-Song Bao, Min Ren, Norihisa Hoshino, Tomoyuki Akutagawa, Li‐Min Zheng

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  26. Strong enhancement of second harmonic generation in nonlinear optical crystals: 2-amino-3-nitropyridinium halides (Cl, Br, I)

    Journal of Materials Chemistry C · 2014-01-01

    Tianliang Chen, Zhihua Sun, Xitao Liu, Jin-Yun Wang, Yuelan Zhou, Chengmin Ji, Shuquan Zhang, Lina Li, Zhong‐Ning Chen, Junhua Luo

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  27. Specific Chemistry of the Anions: [TaOF5]2–, [TaF6]−, and [TaF7]2–

    Crystal Growth & Design · 2014-01-06

    Hongcheng Lu, Romain Gautier, Martin D. Donakowski, Lindsay Fuoco, Zheng‐Tang Liu, Kenneth Reinhard Poeppelmeier

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  28. Synthesis and Magnetic Properties of β‐KVOF3

    Zeitschrift für anorganische und allgemeine Chemie · 2014-01-23

    Martin D. Donakowski, Hongcheng Lu, Romain Gautier, Rana Saha, Athinarayanan Sundaresan, Kenneth Reinhard Poeppelmeier

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  29. Syntheses, characterization and nonlinear optical properties of a bismuth subcarbonate Bi2O2CO3

    Solid State Sciences · 2014-02-05

    Hongwei Huang, Na Tian, Shifeng Jin, Yihe Zhang, Shuobo Wang

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  30. A New UV Nonlinear Optical Material CsZn2B3O7: ZnO4 Tetrahedra Double the Efficiency of Second-Harmonic Generation

    Inorganic Chemistry · 2014-02-10

    Sangen Zhao, Jia Zhang, Shuquan Zhang, Zhihua Sun, Zheshuai Lin, Yicheng Wu, Maochun Hong, Junhua Luo

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  31. A Nitrate Nonlinear Optical Crystal Pb16(OH)16(NO3)16 with a Large Second-Harmonic Generation Response

    Inorganic Chemistry · 2014-03-11

    Li‐Xian Chang, Li Wang, Xin Su, Shilie Pan, Reshalaiti Hailili, Hongwei Yu, Zhihua Yang

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  32. Designing Polar and Magnetic Oxides: Zn2FeTaO6 - in Search of Multiferroics

    Journal of the American Chemical Society · 2014-05-19

    Man‐Rong Li, Peter W. Stephens, M. Retuerto, Tapati Sarkar, Christoph P. Grams, J. Hemberger, Mark Croft, David Walker, M. Greenblatt

    Read original paper ↗ ·

  33. Synthesis, Crystal Structure, Vibrational and Optical Properties of (Hdea)4(V7O19F)∙0.42H2O, an Original (V7O19F)4− Cluster Oxyfluoride

    Journal of Cluster Science · 2014-08-14

    Issam Omri, Mohsen Graia, Tahar Mhiri

    Read original paper ↗ ·

  34. Syntheses of Two Vanadium Oxide–Fluoride Materials That Differ in Phase Matchability

    Inorganic Chemistry · 2014-08-19

    Martin D. Donakowski, Romain Gautier, Hongcheng Lu, T. Thao Tran, Jacqueline Cantwell, P. Shiv Halasyamani, Kenneth Reinhard Poeppelmeier

    Read original paper ↗ ·

  35. Effect of Halogen (Cl, Br) on the Symmetry of Flexible Perovskite-Related Framework

    Inorganic Chemistry · 2014-09-26

    Chunyan Bai, Hongwei Yu, Shujuan Han, Shilie Pan, Bingbing Zhang, Ying Wang, Hongping Wu, Zhihua Yang

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  36. A New Vanadium (V) Coordination Based on [(H2C4O4)VO2F] n 2n− Polymeric Chains and Diethylammonium Cations, Synthesis, Crystal Structure, Vibrational and Optical Properties

    Journal of Cluster Science · 2014-11-08

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  37. Synthesis and structural characterization of a new rubidium borosulfate, Rb5BS4O16

    Materials Research Bulletin · 2014-11-25

    Lingyun Dong, Shilie Pan, Ying Wang, Hongwei Yu, Xiaoxia Nina Lin, Shujuan Han

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  38. Synthetic strategies for new vanadium oxyfluorides containing novel building blocks: structures of V( iv ) and V( v ) containing Sr 4 V 3 O 5 F 13 , Pb 7 V 4 O 8 F 18 , Pb 2 VO 2 F 5 , and Pb 2 VOF 6

    CrystEngComm · 2015-01-01

    Jeongho Yeon, Justin B. Felder, Mark D. Smith, Gregory W. Morrison, Hans‐Conrad zur Loye

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  39. On the Origin of the Differences in Structure Directing Properties of Polar Metal Oxyfluoride [MOxF6–x]2– (x = 1, 2) Building Units

    Inorganic Chemistry · 2015-01-22

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  40. Beryllium-Free Rb3Al3B3O10F with Reinforced Interlayer Bonding as a Deep-Ultraviolet Nonlinear Optical Crystal

    Journal of the American Chemical Society · 2015-01-30

    Sangen Zhao, Pifu Gong, Siyang Luo, Sijie Liu, Lina Li, Muhammad Adnan Asghar, Tariq Mehmood Khan, Maochun Hong, Zheshuai Lin, Junhua Luo

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  41. Pb7O(OH)3(CO3)3(BO3): First Mixed Borate and Carbonate Nonlinear Optical Material Exhibiting Large Second-Harmonic Generation Response

    Inorganic Chemistry · 2015-03-31

    Maierhaba Abudoureheman, Li Wang, Xian‐Ming Zhang, Hongwei Yu, Zhihua Yang, Lei Chen, Jian Wei Han, Shilie Pan

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  42. Polar Polymorphism: α-, β-, and γ-Pb2Ba4Zn4B14O31–Synthesis, Characterization, and Nonlinear Optical Properties

    Chemistry of Materials · 2015-06-04

    Hongwei Yu, Hongping Wu, Qun Jing, Zhihua Yang, P. Shiv Halasyamani, Shilie Pan

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  43. RbMgCO3F: A New Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material

    Journal of the American Chemical Society · 2015-08-10

    T. Thao Tran, Jiangang He, James M. Rondinelli, P. Shiv Halasyamani

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  44. Luminescence and scintillation properties of La 2 [Si 2 O 7 ]:Ce 3+ functional pigment – A concept for UV-protection of coatings

    Dyes and Pigments · 2015-08-20

    Monika E. Bohem, Niels‐Patrick Pook, Arnold E. W. Adam, T. Thao Tran, P. Shiv Halasyamani, Marc Entenmann, Thomas Schleid

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  45. K2Pb3(CO3)3F2 and KCdCO3F: Novel Fluoride Carbonates with Layered and 3D Framework Structures

    Inorganic Chemistry · 2015-10-21

    Yuan Hua Lin, Chun‐Li Hu, Jiang‐Gao Mao

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  46. 1,4-Diazabicyclo[2.2.2]octane-based disalts showing non-centrosymmetric structures and phase transition behaviors

    CrystEngComm · 2016-01-01

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  47. Design of noncentrosymmetric perovskites from centric and acentric basic building units

    Journal of Materials Chemistry C · 2016-01-01

    Joshua Young, Parth Lalkiya, James M. Rondinelli

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  48. Influence of an oxygen vacancy on the electronic structure of the asymmetric mixed borate–carbonate Pb 7 O(OH) 3 (CO 3 ) 3 (BO 3 )

    RSC Advances · 2016-01-01

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  49. Nonlinear optical response mechanism of noncentrosymmetric lead borate Pb 6 [B 4 O 7 (OH) 2 ] 3 with three crystallographically independent [B 4 O 7 (OH) 2 ] 4− chains

    RSC Advances · 2016-01-01

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  50. Synthesis and characterization of new fluoride-containing manganese vanadates A2Mn2V2O7F2 (A=Rb, Cs) and Mn2VO4F

    Journal of Solid State Chemistry · 2016-05-10

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