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RESEARCH PAPER · Inorganic Chemistry · 2015

On the Origin of the Differences in Structure Directing Properties of Polar Metal Oxyfluoride [MOxF6–x]2– (x = 1, 2) Building Units

Romain Gautier, Régis Gautier, Kelvin B. Chang, Kenneth Reinhard Poeppelmeier

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On the Origin of the Differences in Structure Directing Properties of Polar Metal Oxyfluoride [MOxF6–x]2– (x = 1, 2) Building UnitsOriginalThe selectivity of diglycolamide (TODGA) and bis-triazine-bipyridine (BTBP) ligands in actinide/lanthanide complexation and solvent extraction separation – a theoretical approach99Synthetic strategies for new vanadium oxyfluorides containing novel building blocks: structures of V( iv ) and V( v ) containing Sr 4 V 3 O 5 F 13 , Pb 7 V 4 O 8 F 18 , Pb 2 VO 2 F 5 , and Pb 2 VOF 617Preparation, nonlinear optical properties, and theoretical analysis of the non-centrosymmetric bismuth oxyfluoride, Bi 7 F 11 O 525Design of noncentrosymmetric perovskites from centric and acentric basic building units39Ferroelastic and Ferroelectric Phase Transitions in Fluoro- and Oxyfluorometallates7Synthesis, Bonding, and Reactivity of Vanadium(IV) Oxido–Fluorido Compounds with Neutral Chelate Ligands of the General Formula cis-[VIV(═O)(F)(LN–N)2]+7Thermal properties and phase transition in the fluoride, (NH4)3SnF712On the identification of oxygen and fluorine atoms in disordered inorganic oxyfluoride compounds8Synthesis and characterization of new fluoride-containing manganese vanadates A2Mn2V2O7F2 (A=Rb, Cs) and Mn2VO4F19Temperature-Independent, Large Dielectric Constant Induced by Vacancy and Partial Anion Order in the Oxyfluoride Pyrochlore Pb2Ti2O6−δF2δ42Directed Lifting of Inversion Symmetry in Ruddlesden–Popper Oxide–Fluorides: Toward Ferroelectric and Multiferroic Behavior57Syntheses and characterizations of multinuclear, chain and layer silver(I) complexes assembled from bispyridine analogues of pyridinyl-hexahydropyrimidine2Effect of Deuteration on the Thermodynamic Properties of Dioxotetrafluoromolybdate(VI), (NH4)2MoO2F41Orientational disorder and phase transitions in ammonium oxofluorovanadates, (NH4)3VOF5 and (NH4)3VO2F41Two halide-containing cesium manganese vanadates: synthesis, characterization, and magnetic properties12Structural Diversity from Anion Order in Heteroanionic Materials53A Stable, Narrow-Gap Oxyfluoride Photocatalyst for Visible-Light Hydrogen Evolution and Carbon Dioxide Reduction171Variable Asymmetric Chains in Transition Metal Oxyfluorides: Structure–Second-Harmonic-Generation Property Relationships16A series of oxyfluoride chains containing asymmetric basic building units of both early- and late-transition metal cations5PbCdF(SeO 3 )(NO 3 ): A Nonlinear Optical Material Produced by Synergistic Effect of Four Functional Units52Reactivity of VOF3 with N-Heterocyclic Carbene and Imidazolium Fluoride: Analysis of Ligand–VOF3 Bonding with Evidence of a Minute π Back-Donation of Fluoride17Rb 3 SbF 3 (NO 3 ) 3 : an excellent antimony nitrate nonlinear optical material with a strong second harmonic generation response fabricated by a rational multi-component design44RbSbSO 4 Cl 2 : an excellent sulfate nonlinear optical material generated due to the synergistic effect of three asymmetric chromophores79Effect of Deuteration on Phase Transitions in Vanadium Dioxotetrafluoride2Variable Chains Found in Mixed Transition Metal Oxyfluorides with Heterocyclic Ligands9Mixed Transition Metal (Oxy)fluoride Paramagnet Chains: Synthesis, Structure, and Characterization11Designing excellent mid-infrared nonlinear optical materials with fluorooxo-functional group of d0 transition metal oxyfluorides63Influence of structure-directing polyhedra and heterocyclic ligands on the chain structures and O/F ordering in a series of zinc vanadium oxyfluorides1An Exceptional Peroxide Birefringent Material Resulting from d–π Interactions100An Exceptional Peroxide Birefringent Material Resulting from d–π Interactions15Crystal structure and Hirshfeld surface analysis of 4,4′-(propane-1,3-diyl)bis(4H-1,2,4-triazol-1-ium) pentafluoridooxidovanadate(V)4Synthesis of NaMoO3F and Na5W3O9F5 with Morphological Controllability in Non-Aqueous Solvents15Zero-Dimensional Organic-Inorganic Hybrid Material with Ultra-Narrow-Red Emission at Room Temperature0Mn4+ doped zero-dimensional organic-inorganic hybrid material with narrow-red emission30Symmetry-Dependent Intermolecular π–π Stacking Directed by Hydrogen Bonding in Racemic Copper-Phenanthroline Compounds12Distinctive modulation of optical anisotropy by halogens in α/β-Cd–P–X (X = Cl, Br, and I)2Order and Disorder: Toward the Thermodynamically Stable α-BaMoO2F4 from the Metastable Polymorph31Strong Hydrogen Bond in the Crystal Structure Design of CuNbOF 5·4H 2O0Designing new polar materials1Novel layered heterobimetallic fluorides with large optical band gaps3Introducing a New d0 Sc3+ Asymmetric Ion for Functional Materials: Large Birefringence Enhancement by ScO6 in Ba3Sc2(BO3)411Regulated room temperature phosphorescence from zero-dimensional organometallic halide hybrids for anti-counterfeiting and encryption9Strong hydrogen bond in the crystal structure design of CuNbOF5·4H2O3Beyond π–π Stacking: Understanding Inversion Symmetry Breaking in Crystalline Racemates27The Role of Chemical Pressure in the Formation of the Structure and Barocaloric Properties of Complex Fluorides and Oxyfluorides0The Role of Chemical Pressure in the Formation of the Structure and Barocaloric Properties of Complex Fluorides and Oxyfluorides1NaVSeO 5 : synergistic combinations to synthesize excellent birefringent materials8Dual-Anion Strategy Induces Dual Enhancement Toward Ultrashort Phase-Matching Wavelength in Deep-UV Transparent d0 Transition Metal Oxyfluorides22Chiral Metal Self‐Assemblies of Zirconium‐Tetrahedra and Their Second Harmonic Generation Activity6Chiral Metal Self‐Assemblies of Zirconium‐Tetrahedra and Their Second Harmonic Generation Activity0Bonding-Type-Driven Structural Transformation toward Novel Fluoroiodosulfates: Achieving Non-Centrosymmetry and Enhanced Optical Properties in K2(IO3F)SO30Syntheses, Crystal Structures, and Electronic Structures of New Barium Fluoromolybdates0Rapid fluorination using polyvinylidene-difluoride (PVDF) for the synthesis of oxyfluoride Bi2VO5F1−x0Syntheses, crystal structures, and electronic structures of new barium fluoromolybdates1Bonding-type-driven structural transformation toward novel fluoroiodosulfates: Achieving non-centrosymmetry and enhanced optical properties in K2(IO3F)SO30

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  1. The selectivity of diglycolamide (TODGA) and bis-triazine-bipyridine (BTBP) ligands in actinide/lanthanide complexation and solvent extraction separation – a theoretical approach

    Dalton Transactions · 2014-11-20

    Jerzy Narbutt, Artur Wodyński, Magdalena Pecul

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  2. Synthetic strategies for new vanadium oxyfluorides containing novel building blocks: structures of V( iv ) and V( v ) containing Sr 4 V 3 O 5 F 13 , Pb 7 V 4 O 8 F 18 , Pb 2 VO 2 F 5 , and Pb 2 VOF 6

    CrystEngComm · 2015-01-01

    Jeongho Yeon, Justin B. Felder, Mark D. Smith, Gregory W. Morrison, Hans‐Conrad zur Loye

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  3. Preparation, nonlinear optical properties, and theoretical analysis of the non-centrosymmetric bismuth oxyfluoride, Bi 7 F 11 O 5

    Journal of Alloys and Compounds · 2015-11-06

    Wei Hu, Pai Shan, Tongqing Sun, Hongde Liu, Jianming Zhang, Xuanwen Liu, Yongfa Kong, Jingjun Xu

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  4. Design of noncentrosymmetric perovskites from centric and acentric basic building units

    Journal of Materials Chemistry C · 2016-01-01

    Joshua Young, Parth Lalkiya, James M. Rondinelli

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  5. Ferroelastic and Ferroelectric Phase Transitions in Fluoro- and Oxyfluorometallates

    Elsevier eBooks · 2016-01-01

    Igor N. Flerov, М. В. Горев, Мaxim S. Моlokeev, N. M. Laptash

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  6. Synthesis, Bonding, and Reactivity of Vanadium(IV) Oxido–Fluorido Compounds with Neutral Chelate Ligands of the General Formula cis-[VIV(═O)(F)(LN–N)2]+

    Inorganic Chemistry · 2016-01-21

    Stamatis S. Passadis, Constantinos G. Tsiafoulis, Chryssoula Drouza, Athanassios C. Tsipis, Haralampos N. Miras, Anastasios D. Keramidas, Themistoklis A. Kabanos

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  7. Thermal properties and phase transition in the fluoride, (NH4)3SnF7

    Journal of Solid State Chemistry · 2016-02-20

    A. V. Kartashev, М. В. Горев, Evgeniy V. Bogdanov, Igor N. Flerov, N. M. Laptash

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  8. On the identification of oxygen and fluorine atoms in disordered inorganic oxyfluoride compounds

    Journal of Structural Chemistry · 2016-03-01

    N. M. Laptash, Anatoly A. Udovenko

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  9. Synthesis and characterization of new fluoride-containing manganese vanadates A2Mn2V2O7F2 (A=Rb, Cs) and Mn2VO4F

    Journal of Solid State Chemistry · 2016-05-10

    Liurukara Duminda Sanjeewa, Michael A. McGuire, Tiffany M. Smith Pellizzeri, Colin D. McMillen, Vasile Ovidiu Garlea, Daniel R. Willett, George D. Chumanov, Joseph W. Kolis

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  10. Temperature-Independent, Large Dielectric Constant Induced by Vacancy and Partial Anion Order in the Oxyfluoride Pyrochlore Pb2Ti2O6−δF2δ

    Chemistry of Materials · 2016-07-18

    Kengo Oka, Hajime Hojo, Masaki Azuma, Katsuyoshi Oh‐ishi

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  11. Directed Lifting of Inversion Symmetry in Ruddlesden–Popper Oxide–Fluorides: Toward Ferroelectric and Multiferroic Behavior

    Chemistry of Materials · 2016-10-28

    Ronghuan Zhang, Mark S. Senn, Michael A. Hayward

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  12. Syntheses and characterizations of multinuclear, chain and layer silver(I) complexes assembled from bispyridine analogues of pyridinyl-hexahydropyrimidine

    Journal of Solid State Chemistry · 2017-04-30

    Ying-Hui Xiao, Jing Huang, Zhao‐Peng Deng, Li‐Hua Huo, Shan Gao

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  13. Effect of Deuteration on the Thermodynamic Properties of Dioxotetrafluoromolybdate(VI), (NH4)2MoO2F4

    Inorganic Chemistry · 2017-05-11

    Evgeniy V. Bogdanov, Evgeniy I. Pogoreltsev, М. В. Горев, Igor N. Flerov

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  14. Orientational disorder and phase transitions in ammonium oxofluorovanadates, (NH4)3VOF5 and (NH4)3VO2F4

    Acta Crystallographica Section B Structural Science Crystal Engineering and Materials · 2017-11-15

    Anatoly A. Udovenko, Evgeny I. Pogoreltsev, Yuri Marchenko, N. M. Laptash

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  15. Two halide-containing cesium manganese vanadates: synthesis, characterization, and magnetic properties

    Dalton Transactions · 2018-01-01

    Tiffany M. Smith Pellizzeri, Michael A. McGuire, Colin D. McMillen, Yimei Wen, George D. Chumanov, Joseph W. Kolis

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  16. Structural Diversity from Anion Order in Heteroanionic Materials

    Chemistry of Materials · 2018-04-30

    Nenian Charles, Richard J. Saballos, James M. Rondinelli

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  17. A Stable, Narrow-Gap Oxyfluoride Photocatalyst for Visible-Light Hydrogen Evolution and Carbon Dioxide Reduction

    Journal of the American Chemical Society · 2018-05-07

    Ryo Kuriki, Tom Ichibha, Kenta Hongo, Daling Lu, Ryo Maezono, Hiroshi Kageyama, Osamu Ishitani, Kengo Oka, Kazuhiko Maeda

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  18. Variable Asymmetric Chains in Transition Metal Oxyfluorides: Structure–Second-Harmonic-Generation Property Relationships

    Inorganic Chemistry · 2018-05-15

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  19. A series of oxyfluoride chains containing asymmetric basic building units of both early- and late-transition metal cations

    Journal of Solid State Chemistry · 2018-08-20

    Belal Ahmed, Hongil Jo, Sung Won Yoon, Kwang‐Yong Choi, Kang Min Ok

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  20. PbCdF(SeO 3 )(NO 3 ): A Nonlinear Optical Material Produced by Synergistic Effect of Four Functional Units

    Inorganic Chemistry · 2018-08-30

    Yun‐Xiang Ma, Chun‐Li Hu, Bingxuan Li, Fang Kong, Jiang‐Gao Mao

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  21. Reactivity of VOF3 with N-Heterocyclic Carbene and Imidazolium Fluoride: Analysis of Ligand–VOF3 Bonding with Evidence of a Minute π Back-Donation of Fluoride

    Inorganic Chemistry · 2018-10-24

    Žiga Zupanek, Melita Tramšek, Anton Kokalj, Gašper Tavčar

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  22. Rb 3 SbF 3 (NO 3 ) 3 : an excellent antimony nitrate nonlinear optical material with a strong second harmonic generation response fabricated by a rational multi-component design

    Dalton Transactions · 2019-01-01

    Lei Wang, Fei Yang, Xiaoyu Zhao, Ling Huang, Daojiang Gao, Jian Bi, Xin Wang, Guohong Zou

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  23. RbSbSO 4 Cl 2 : an excellent sulfate nonlinear optical material generated due to the synergistic effect of three asymmetric chromophores

    Journal of Materials Chemistry C · 2019-01-01

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  24. Effect of Deuteration on Phase Transitions in Vanadium Dioxotetrafluoride

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  25. Variable Chains Found in Mixed Transition Metal Oxyfluorides with Heterocyclic Ligands

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  26. Mixed Transition Metal (Oxy)fluoride Paramagnet Chains: Synthesis, Structure, and Characterization

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  27. Designing excellent mid-infrared nonlinear optical materials with fluorooxo-functional group of d0 transition metal oxyfluorides

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  28. Influence of structure-directing polyhedra and heterocyclic ligands on the chain structures and O/F ordering in a series of zinc vanadium oxyfluorides

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  29. An Exceptional Peroxide Birefringent Material Resulting from d–π Interactions

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  30. An Exceptional Peroxide Birefringent Material Resulting from d–π Interactions

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  31. Crystal structure and Hirshfeld surface analysis of 4,4′-(propane-1,3-diyl)bis(4H-1,2,4-triazol-1-ium) pentafluoridooxidovanadate(V)

    Acta Crystallographica Section E Crystallographic Communications · 2020-05-01

    Ganna A. Senchyk, A.B. Lysenko, Harald Krautscheid, K.V. Domasevitch

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  32. Synthesis of NaMoO3F and Na5W3O9F5 with Morphological Controllability in Non-Aqueous Solvents

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  33. Zero-Dimensional Organic-Inorganic Hybrid Material with Ultra-Narrow-Red Emission at Room Temperature

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  34. Mn4+ doped zero-dimensional organic-inorganic hybrid material with narrow-red emission

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  35. Symmetry-Dependent Intermolecular π–π Stacking Directed by Hydrogen Bonding in Racemic Copper-Phenanthroline Compounds

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  36. Distinctive modulation of optical anisotropy by halogens in α/β-Cd–P–X (X = Cl, Br, and I)

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  37. Order and Disorder: Toward the Thermodynamically Stable α-BaMoO2F4 from the Metastable Polymorph

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  38. Strong Hydrogen Bond in the Crystal Structure Design of CuNbOF 5·4H 2O

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  39. Designing new polar materials

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  40. Novel layered heterobimetallic fluorides with large optical band gaps

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  41. Introducing a New d0 Sc3+ Asymmetric Ion for Functional Materials: Large Birefringence Enhancement by ScO6 in Ba3Sc2(BO3)4

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  42. Regulated room temperature phosphorescence from zero-dimensional organometallic halide hybrids for anti-counterfeiting and encryption

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  43. Strong hydrogen bond in the crystal structure design of CuNbOF5·4H2O

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  44. Beyond π–π Stacking: Understanding Inversion Symmetry Breaking in Crystalline Racemates

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  45. The Role of Chemical Pressure in the Formation of the Structure and Barocaloric Properties of Complex Fluorides and Oxyfluorides

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  46. The Role of Chemical Pressure in the Formation of the Structure and Barocaloric Properties of Complex Fluorides and Oxyfluorides

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  47. NaVSeO 5 : synergistic combinations to synthesize excellent birefringent materials

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  48. Dual-Anion Strategy Induces Dual Enhancement Toward Ultrashort Phase-Matching Wavelength in Deep-UV Transparent d0 Transition Metal Oxyfluorides

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  49. Chiral Metal Self‐Assemblies of Zirconium‐Tetrahedra and Their Second Harmonic Generation Activity

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  50. Chiral Metal Self‐Assemblies of Zirconium‐Tetrahedra and Their Second Harmonic Generation Activity

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