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RESEARCH PAPER · Inorganic Chemistry · 2015

Pb7O(OH)3(CO3)3(BO3): First Mixed Borate and Carbonate Nonlinear Optical Material Exhibiting Large Second-Harmonic Generation Response

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Pb7O(OH)3(CO3)3(BO3): First Mixed Borate and Carbonate Nonlinear Optical Material Exhibiting Large Second-Harmonic Generation ResponseOriginalChemInform Abstract: Pb7O(OH)3(CO3)3(BO3): First Mixed Borate and Carbonate Nonlinear Optical Material Exhibiting Large Second‐Harmonic Generation Response.0Series of SHG Materials Based on Lanthanide Borate–Acetate Mixed Anion Compounds39K2Pb3(CO3)3F2 and KCdCO3F: Novel Fluoride Carbonates with Layered and 3D Framework Structures42Beyond Single-Wavelength SHG Measurements: Spectrally-Resolved SHG Studies of Tetraphosphonate Ester Coordination Polymers31Hydrogen bond-assisted crystallization: structure, growth and characterization of a new mixed-anion transition metal fluoride Na 3 NH 4 (TiF 6 )(SO 4 )·H 2 O6Influence of an oxygen vacancy on the electronic structure of the asymmetric mixed borate–carbonate Pb 7 O(OH) 3 (CO 3 ) 3 (BO 3 )3KPb 2 (PO 3 ) 5 : a novel nonlinear optical lead polyphosphate with a short deep-UV cutoff edge109LiSc(SeO3)2·xH2O (0 ≤ x ≤ 1): New Selenites Revealing Water Molecule-Driven Extremely High Temperature Single-Crystal-to-Single-Crystal Transformations16Structural and physical systematization of the nonlinear-optical borate crystals1A new nonlinear optical silicate carbonate K2Ca[Si2O5](CO3) with a hybrid structure of kalsilite and soda-like layered fragments2Syntheses, characterization and theoretical studies of three apatite-type phosphates MPb4(PO4)3 (M = K, Rb, Cs)17Revealing the electronic structure and optical properties of K6[Mo4O8F10] novel molybdenum oxyfluoride materials2Positive and negative contribution to birefringence in a family of carbonates: A Born effective charges analysis36SrNO3(OH)·H2O: A new member in strontium nitrate hydrate family with an ultraviolet cut-off edge7A Polar Titanium–Organic Chain with a Very Large Second-Harmonic-Generation Response5Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures601Lithium borate Li 3 B 5 O 8 (OH) 2 with large second harmonic generation and a high damage threshold in the deep-ultraviolet spectral range16Noncentrosymmetric (NCS) solid solutions: elucidating the structure–nonlinear optical (NLO) property relationship and beyond21Role of spin–orbit interaction on the nonlinear optical response of CsPbCO 3 F using DFT35The influence of oxygen vacancies on the linear and nonlinear optical properties of Pb 7 O(OH) 3 (CO 3 ) 3 (BO 3 )41Two haloid borate crystals with large nonlinear optical response32Comparative Interrelationship of the Structural, Nonlinear-Optical and Other Acentric Properties for Oxide, Borate and Carbonate Crystals16Molecular Construction Using (C3N3O3)3– Anions: Analysis and Prospect for Inorganic Metal Cyanurates Nonlinear Optical Materials152Design and Synthesis of a Series of Novel Mixed Borate and Carbonate Halides21Novel borate CsZn2B3O7 single crystal with large efficient second harmonic generation in deep-ultraviolet spectral range43Pb@Pb8 Basket-like-Cluster-Based Lead Tellurate–Nitrate Kleinman-Forbidden Nonlinear-Optical Crystal: Pb9Te2O13(OH)(NO3)326Acentric La3(IO3)8(OH) and La(IO3)2(NO3): Partial Substitution of Iodate Anions in La(IO3)3 by Hydroxide or Nitrate Anion55A novel photocatalytic water splitting solar-to-hydrogen energy conversion: Non-centro-symmetric borate CsZn2B3O7 photocatalyst21New silicate-germanate Cs2Pb2[(Si0.6Ge0.4)2O7] from the series A2Pb2[B2O7], A = K, Cs, B = Si, Ge with the umbrella-like [PbO3]4- group9Novel report on SHG efficiency, Z-scan, laser damage threshold, photoluminescence, dielectric and surface microscopic studies of hybrid inorganic ammonium zinc sulphate hydrate single crystal55The role of cations in second-order nonlinear optical materials based on π-conjugated [BO 3 ] 3− groups195Syntheses, Crystal Structures and Properties of Two Novel Mixed Anion Hybrids with Formulas of Pb 6 O 2 (BO 3 ) 2 (C 2 O 4 ) and Pb 4 (CO 3 ) 2 (C 2 O 4 )(OH) 21Hydrogen Bonding Assisted Construction of Graphite-like Deep-UV Optical Materials with Two Types of Parallel π-Conjugated Units22Second-order nonlinear optical crystals with mixed anions250High-Temperature, High-Pressure Hydrothermal Synthesis of Ba3[B6O10(OH)2](CO3) and Ba6[B12O21(OH)2](CO3)2, Two Barium Borate Carbonates with 2D Layer and 3D Framework Structures16Ca 2 GeB 2 O 7 and Ca 1.78 Cd 0.22 GeB 2 O 7 : two acentric borogermanates with a melilite-like structure and short ultraviolet cutoff edge14Lone pair effects on ternary infrared nonlinear optical materials19Sr[B(OH) 4 ](IO 3 ) and Li 4 Sr 5 [B 12 O 22 (OH) 4 ](IO 3 ) 2 : two unprecedented metal borate-iodates showing a subtle balance of enlarged band gap and birefringence34Ba4M(CO3)2(BO3)2 (M=Ba, Sr): two borate-carbonates synthesized by open high temperature solution method29Growth of NH4H2PO4 crystal in urea environment to optimize linear-nonlinear optical traits for photonic device applications21Structure–Property Correlation Studies of Potassium 4,4′-Bis(dinitromethyl)-3,3′-azofurazanate: A Noncentrosymmetric Primary Explosive14Cs2Bi2O(Ge2O7) (CBGO): A Larger SHG Effect Induced by Synergistic Polarizations of BiO5 Polyhedra and GeO4 Tetrahedra73Cs2Bi2O(Ge2O7) (CBGO): A Larger SHG Effect Induced by Synergistic Polarizations of BiO5 Polyhedra and GeO4 Tetrahedra18Noncentrosymmetric Sulfide Oxide MZnSO (M = Ca or Sr) with Strongly Polar Structure as Novel Nonlinear Crystals43Sr 5 TeO 2 (BO 3 ) 4 and NaSr 5 (BO 3 )(SiO 4 ) 2 : two inorganic metal borate derivatives with diverse zero dimensional anions21Mg3Pt(BO3)2O2: The first platinum borate from the flux technique13NaRb3B6O9(OH)3(HCO3): A Borate-Bicarbonate Nonlinear Optical Material18NaK 15 [B 4 O 5 (OH) 4 ] 6 (NO 2 ) 2 (CO 3 )·7H 2 O: assembly of an unprecedented mixed anion inorganic compound via a facile hydrothermal route4Growth and optimization of optical traits of copper sulphate crystal exploiting L-ascorbic acid for photonic device applications16Ba3(BO3)(CO3)F: The First Borate Carbonate Fluoride Synthesized by the High‐Temperature Solution Method19Synthesis of two 3D supramoleculars and their fluorescent sensing for nitroaromatic compounds/Fe3+ ions in aqueous medium8A melamine-based organic–inorganic hybrid material revealing excellent optical performance and moderate thermal stability75K 2 Pb(H 2 C 3 N 3 O 3 ) 4 (H 2 O) 4 : a potential UV nonlinear optical material with large birefringence50M3B6O10NO3 (M = K, Rb): Two New Alkali Metal Borate‐Nitrates with Noncentrosymmetric Structures20Bi2[B2(SeO3)6]: A Metal Boroselenite with a Unique Zero-Dimensional [B2(SeO3)6]6– Anionic Group and Large Birefringence31High-Performance Second-Harmonic-Generation (SHG) Materials: New Developments and New Strategies323Sr5(CO3)2(BO3)2: A new family member of isostructural mixed borate and carbonate Ba4M(BO3)2(CO3)2 (M = Ba, Sr) with isolated BO3 and CO3 groups7Ba 2 B 5 O 8 (OH) 2 (NO 3 )·3H 2 O: the design of an alkaline earth metal borate-nitrate optimized from a hydroxylic borate4Two lead borate-nitrates with anion-centered [OPb 4 ] tetrahedra and two types of π-conjugated planar units showing large birefringence20Noncentrosymmetric (C3H7N6)6(H2PO4)4(HPO4)·4H2O and Centrosymmetric (C3H7N6)2SO4·2H2O: Exploration of Acentric Structure by Combining Planar and Tetrahedral Motifs via Hydrogen Bonds37La2B3O4(OH)3(SO4)2: A new rare-earth borate-sulfate with second-harmonic generation response5Na 2 (C 4 O 4 )(H 3 BO 3 )(H 2 O) 4 ·H 3 BO 3 : the first borate-squarate with strong SHG response obtained by superior synergy11An effective pathway to design and synthesize UV birefringent crystals via rational assembly of π-conjugated [CO 3 ] 2− and [NO 3 ] − triangles32Two Carboxylate-Cyanurates with Strong Optical Anisotropy and Large Band Gaps6Synthesis and characterization of pure and l-proline doped copper sulphate single crystals6Nonlinear optical inorganic sulfates: The improvement of the phase matching ability driven by the structural modulation41Sr(NO 3 )(NH 2 SO 3 )·H 2 O: First Nitrate Sulfamate Revealing Remarkable Second Harmonic Generation and Optimized Birefringence25Crystal chemistry and thermal behavior of B-, S- and Na-bearing spurrite1Crystal structure and electronic structure calculations of a novel organic triphosphate complex: excellent electrochemical properties with ultra-efficient lithium storage capacity1M6[Cd2(CO3)2(B12O18)(OH)6] (M = K, Rb): Borate–Carbonates with Two CdCO3 Embedded in a Cyclic Oxoboron Anion10Two Mixed Alkali Metal Isocyanurates with Wide Band Gap and Giant Birefringence2Looking Back the Nonlinear Optical Crystals in a Functionalized Unit's Perspective109Tuning birefringence in alkaline-earth metal oxyhalides through diverse mixed-cation coordination architectures1Effects of pressure on structural, electronic and optical properties of noncentrosymmetric monoclinic Na3Sr(PO4)(CO3) with discrete [PO4] and [CO3] units0

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  1. ChemInform Abstract: Pb7O(OH)3(CO3)3(BO3): First Mixed Borate and Carbonate Nonlinear Optical Material Exhibiting Large Second‐Harmonic Generation Response.

    ChemInform · 2015-06-01

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  2. Series of SHG Materials Based on Lanthanide Borate–Acetate Mixed Anion Compounds

    Inorganic Chemistry · 2015-07-21

    Hui Yang, Chun‐Li Hu, Xiang Xu, Jiang‐Gao Mao

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  3. K2Pb3(CO3)3F2 and KCdCO3F: Novel Fluoride Carbonates with Layered and 3D Framework Structures

    Inorganic Chemistry · 2015-10-21

    Yuan Hua Lin, Chun‐Li Hu, Jiang‐Gao Mao

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  4. Beyond Single-Wavelength SHG Measurements: Spectrally-Resolved SHG Studies of Tetraphosphonate Ester Coordination Polymers

    Inorganic Chemistry · 2015-10-22

    Jan K. Zaręba, Michał J. Białek, Jan Janczak, Marcin Nyk, Jerzy Zoń, Marek J. Samoc

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  5. Hydrogen bond-assisted crystallization: structure, growth and characterization of a new mixed-anion transition metal fluoride Na 3 NH 4 (TiF 6 )(SO 4 )·H 2 O

    New Journal of Chemistry · 2016-01-01

    Dongdong Xu, Fangfang Zhang, Yanzhou Sun, Zhihua Yang, Xiaoyu Dong, Shilie Pan

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  6. Influence of an oxygen vacancy on the electronic structure of the asymmetric mixed borate–carbonate Pb 7 O(OH) 3 (CO 3 ) 3 (BO 3 )

    RSC Advances · 2016-01-01

    A.H. Reshak, S. Auluck

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  7. KPb 2 (PO 3 ) 5 : a novel nonlinear optical lead polyphosphate with a short deep-UV cutoff edge

    Journal of Materials Chemistry C · 2016-01-01

    Maierhaba Abudoureheman, Shujuan Han, Bing‐Hua Lei, Zhihua Yang, Xifa Long, Shilie Pan

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  8. LiSc(SeO3)2·xH2O (0 ≤ x ≤ 1): New Selenites Revealing Water Molecule-Driven Extremely High Temperature Single-Crystal-to-Single-Crystal Transformations

    Crystal Growth & Design · 2016-05-04

    Seung Yoon Song, Kang Min Ok

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  9. Structural and physical systematization of the nonlinear-optical borate crystals

    International Forum on Strategic Technology · 2016-06-01

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  10. A new nonlinear optical silicate carbonate K2Ca[Si2O5](CO3) with a hybrid structure of kalsilite and soda-like layered fragments

    Solid State Sciences · 2016-08-04

    Elena L. Belokoneva, Sergey Yu. Stefanovich, Anatoly S. Volkov, Olga V. Dimitrova

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  11. Syntheses, characterization and theoretical studies of three apatite-type phosphates MPb4(PO4)3 (M = K, Rb, Cs)

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  12. Revealing the electronic structure and optical properties of K6[Mo4O8F10] novel molybdenum oxyfluoride materials

    The Philosophical Magazine A Journal of Theoretical Experimental and Applied Physics · 2016-08-31

    A.H. Reshak

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  13. Positive and negative contribution to birefringence in a family of carbonates: A Born effective charges analysis

    Journal of Solid State Chemistry · 2016-09-09

    Qun Jing, Guang Yang, Juan Hou, Maozhu Sun, Haibin Cao

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  14. SrNO3(OH)·H2O: A new member in strontium nitrate hydrate family with an ultraviolet cut-off edge

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    Lili Liu, Yun Mo Yang, Linping Li, Zhihua Yang, Shilie Pan

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  15. A Polar Titanium–Organic Chain with a Very Large Second-Harmonic-Generation Response

    Inorganic Chemistry · 2016-11-10

    Bongsu Kim, Seung‐Jin Oh, Hongil Jo, Kang Min Ok

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  16. Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures

    Accounts of Chemical Research · 2016-11-14

    Kang Min Ok

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  17. Lithium borate Li 3 B 5 O 8 (OH) 2 with large second harmonic generation and a high damage threshold in the deep-ultraviolet spectral range

    Physical Chemistry Chemical Physics · 2017-01-01

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  18. Noncentrosymmetric (NCS) solid solutions: elucidating the structure–nonlinear optical (NLO) property relationship and beyond

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  19. Role of spin–orbit interaction on the nonlinear optical response of CsPbCO 3 F using DFT

    Physical Chemistry Chemical Physics · 2017-01-01

    E. Narsimha Rao, G. Vaitheeswaran, A.H. Reshak, S. Auluck

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  20. The influence of oxygen vacancies on the linear and nonlinear optical properties of Pb 7 O(OH) 3 (CO 3 ) 3 (BO 3 )

    RSC Advances · 2017-01-01

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  21. Two haloid borate crystals with large nonlinear optical response

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  22. Comparative Interrelationship of the Structural, Nonlinear-Optical and Other Acentric Properties for Oxide, Borate and Carbonate Crystals

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  23. Molecular Construction Using (C3N3O3)3– Anions: Analysis and Prospect for Inorganic Metal Cyanurates Nonlinear Optical Materials

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  24. Design and Synthesis of a Series of Novel Mixed Borate and Carbonate Halides

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  25. Novel borate CsZn2B3O7 single crystal with large efficient second harmonic generation in deep-ultraviolet spectral range

    Journal of Alloys and Compounds · 2017-06-12

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  26. Pb@Pb8 Basket-like-Cluster-Based Lead Tellurate–Nitrate Kleinman-Forbidden Nonlinear-Optical Crystal: Pb9Te2O13(OH)(NO3)3

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  27. Acentric La3(IO3)8(OH) and La(IO3)2(NO3): Partial Substitution of Iodate Anions in La(IO3)3 by Hydroxide or Nitrate Anion

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  28. A novel photocatalytic water splitting solar-to-hydrogen energy conversion: Non-centro-symmetric borate CsZn2B3O7 photocatalyst

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  29. New silicate-germanate Cs2Pb2[(Si0.6Ge0.4)2O7] from the series A2Pb2[B2O7], A = K, Cs, B = Si, Ge with the umbrella-like [PbO3]4- group

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  30. Novel report on SHG efficiency, Z-scan, laser damage threshold, photoluminescence, dielectric and surface microscopic studies of hybrid inorganic ammonium zinc sulphate hydrate single crystal

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  31. The role of cations in second-order nonlinear optical materials based on π-conjugated [BO 3 ] 3− groups

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  32. Syntheses, Crystal Structures and Properties of Two Novel Mixed Anion Hybrids with Formulas of Pb 6 O 2 (BO 3 ) 2 (C 2 O 4 ) and Pb 4 (CO 3 ) 2 (C 2 O 4 )(OH) 2

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  33. Hydrogen Bonding Assisted Construction of Graphite-like Deep-UV Optical Materials with Two Types of Parallel π-Conjugated Units

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  34. Second-order nonlinear optical crystals with mixed anions

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  35. High-Temperature, High-Pressure Hydrothermal Synthesis of Ba3[B6O10(OH)2](CO3) and Ba6[B12O21(OH)2](CO3)2, Two Barium Borate Carbonates with 2D Layer and 3D Framework Structures

    Inorganic Chemistry · 2018-08-27

    Chun-Jui Liao, Yuh-Sheng Wen, Kwang‐Hwa Lii

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  36. Ca 2 GeB 2 O 7 and Ca 1.78 Cd 0.22 GeB 2 O 7 : two acentric borogermanates with a melilite-like structure and short ultraviolet cutoff edge

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  37. Lone pair effects on ternary infrared nonlinear optical materials

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  38. Sr[B(OH) 4 ](IO 3 ) and Li 4 Sr 5 [B 12 O 22 (OH) 4 ](IO 3 ) 2 : two unprecedented metal borate-iodates showing a subtle balance of enlarged band gap and birefringence

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  39. Ba4M(CO3)2(BO3)2 (M=Ba, Sr): two borate-carbonates synthesized by open high temperature solution method

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  40. Growth of NH4H2PO4 crystal in urea environment to optimize linear-nonlinear optical traits for photonic device applications

    Optik · 2019-03-14

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  41. Structure–Property Correlation Studies of Potassium 4,4′-Bis(dinitromethyl)-3,3′-azofurazanate: A Noncentrosymmetric Primary Explosive

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  42. Cs2Bi2O(Ge2O7) (CBGO): A Larger SHG Effect Induced by Synergistic Polarizations of BiO5 Polyhedra and GeO4 Tetrahedra

    Angewandte Chemie International Edition · 2019-08-26

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  43. Cs2Bi2O(Ge2O7) (CBGO): A Larger SHG Effect Induced by Synergistic Polarizations of BiO5 Polyhedra and GeO4 Tetrahedra

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  44. Noncentrosymmetric Sulfide Oxide MZnSO (M = Ca or Sr) with Strongly Polar Structure as Novel Nonlinear Crystals

    The Journal of Physical Chemistry C · 2019-10-18

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  45. Sr 5 TeO 2 (BO 3 ) 4 and NaSr 5 (BO 3 )(SiO 4 ) 2 : two inorganic metal borate derivatives with diverse zero dimensional anions

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  46. Mg3Pt(BO3)2O2: The first platinum borate from the flux technique

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  47. NaRb3B6O9(OH)3(HCO3): A Borate-Bicarbonate Nonlinear Optical Material

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  48. NaK 15 [B 4 O 5 (OH) 4 ] 6 (NO 2 ) 2 (CO 3 )·7H 2 O: assembly of an unprecedented mixed anion inorganic compound via a facile hydrothermal route

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  49. Growth and optimization of optical traits of copper sulphate crystal exploiting L-ascorbic acid for photonic device applications

    Chinese Journal of Physics · 2020-05-11

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  50. Ba3(BO3)(CO3)F: The First Borate Carbonate Fluoride Synthesized by the High‐Temperature Solution Method

    Chemistry - A European Journal · 2020-09-25

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