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RESEARCH PAPER · Inorganic Chemistry · 2014

Syntheses of Two Vanadium Oxide–Fluoride Materials That Differ in Phase Matchability

Martin D. Donakowski, Romain Gautier, Hongcheng Lu, T. Thao Tran, Jacqueline Cantwell, P. Shiv Halasyamani, Kenneth Reinhard Poeppelmeier

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Syntheses of Two Vanadium Oxide–Fluoride Materials That Differ in Phase MatchabilityOriginalBorate Fluoride and Fluoroborate in Alkali-Metal Borate Prepared by an Open High-Temperature Solution Method50BaBi(SeO 3 ) 2 Cl: a new polar material showing high second-harmonic generation efficiency enhanced by constructive alignment of chloride ions36Synthetic strategies for new vanadium oxyfluorides containing novel building blocks: structures of V( iv ) and V( v ) containing Sr 4 V 3 O 5 F 13 , Pb 7 V 4 O 8 F 18 , Pb 2 VO 2 F 5 , and Pb 2 VOF 617ChemInform Abstract: Syntheses of Two Vanadium Oxide—Fluoride Materials that Differ in Phase Matchability.0K2Pb3(CO3)3F2 and KCdCO3F: Novel Fluoride Carbonates with Layered and 3D Framework Structures42KPb 2 (PO 3 ) 5 : a novel nonlinear optical lead polyphosphate with a short deep-UV cutoff edge109Three new phosphates with isolated P 2 O 7 units: noncentrosymmetric Cs 2 Ba 3 (P 2 O 7 ) 2 and centrosymmetric Cs 2 BaP 2 O 7 and LiCsBaP 2 O 768Synthesis, Bonding, and Reactivity of Vanadium(IV) Oxido–Fluorido Compounds with Neutral Chelate Ligands of the General Formula cis-[VIV(═O)(F)(LN–N)2]+7Synthesis, Characterization, and Theoretical Studies of (Pb4O)Pb2B6O14: A New Lead(II) Borate with Isolated Oxygen-Centered Pb4O Tetrahedra and Large Second Harmonic Generation Response42A New Deep-Ultraviolet Transparent Orthophosphate LiCs 2 PO 4 with Large Second Harmonic Generation Response386Syntheses, characterization and theoretical studies of three apatite-type phosphates MPb4(PO4)3 (M = K, Rb, Cs)17Infrared SHG Materials CsM3Se6 (M = Ga/Sn, In/Sn): Phase Matchability Controlled by Dipole Moment of the Asymmetric Building Unit102Compositional phase diagram and microscopic mechanism of Ba 1−x Ca x Zr y Ti 1−y O 3 relaxor ferroelectrics30Nature of phase transitions in ammonium oxofluorovanadates, a vibrational spectroscopy study of (NH4)3VO2F4 and (NH4)3VOF57New Intermediate Polymorph of 1-Fluoro-adamantane and Its Second-Order-like Transition toward the Low Temperature Phase20DFT-Based Comparative Study about the Influence of Fluorine and Hydroxyl Anions on Opto-Electric Properties of Borate Crystals: Choice for Better Anion13Design and Synthesis of a Series of Novel Mixed Borate and Carbonate Halides21Orientational disorder and phase transitions in ammonium oxofluorovanadates, (NH4)3VOF5 and (NH4)3VO2F41Morphology-controlled epitaxial vanadium dioxide low-dimensional structures: the delicate effects on the phase transition behaviors8Surface-step-terrace tuned second-order nonlinear optical coefficients of epitaxial ferroelectric BaTiO 3 films17Polymorphisme, dynamique et transitions de phases dans les dérivés de l'adamantane0Non-centrosymmetric BaNaP3O9 with a short deep-ultraviolet cutoff edge14Function of Tetrahedral ZnS3O Building Blocks in the Formation of SrZn2S2O: A Phase Matchable Polar Oxysulfide with a Large Second Harmonic Generation Response83Structural insights into three phosphates with distinct polyanionic configurations20Heteroanionic Materials by Design: Progress Toward Targeted Properties236Vanadium oxide thin films on quartz and Al6061 with reduced phase transition temperature and low solar absorptance for advanced thermal control application in space6Ba(B 2 OF 3 (OH) 2 ) 2 with well-ordered OH/F anions and a unique B 2 OF 3 (OH) 2 dimer29Recent advances of oxyfluorides for nonlinear optical applications69Interplay between Oxo and Fluoro in Vanadium Oxyfluorides for Centrosymmetric and Non-Centrosymmetric Structure Formation4Recyclable Oxofluorovanadate‐Catalyzed Formylation of Amines by Reductive Functionalization of CO2 with Hydrosilanes19Second-Harmonic-Generation-Active Oxyhalides: CuSb2O3X (X = Cl, Br)17Phase Matchability Transformation in the Infrared Nonlinear Optical Materials with Diamond‐Like Frameworks63Metal oxyhalides: an emerging family of nonlinear optical materials125Phase matching achieved by isomorphous substitution in IR nonlinear optical material Ba 2 SnSSi 2 O 7 with an undiscovered [SnO 4 S] functional motif47New quinary cesium vanadium (IV) fluorophosphates, CsVOF(PO3F) and CsV2O2F(PO3F)2·H2O3Isoreticular Design of KTiOPO 4 -Like Deep-Ultraviolet Transparent Materials Exhibiting Strong Second-Harmonic Generation69From Ba3Nb2O2F12(H2O)2 to Ba0.5NbO2F2(H2O): Achieving Balanced Nonlinear Optical Performance by O/F Ratio Regulation18K2(H2O)WO3F2: A new nonlinear optical material with remarkable second-harmonic generation response and enhanced laser damage threshold9Beyond π–π Stacking: Understanding Inversion Symmetry Breaking in Crystalline Racemates27K 3 Mo 2 O 5.6 F 3.4 and K 3 V 2 O 3.3 F 5.7 – exploring transition metal cation valence and anion distribution in oxyfluorides0Construction of Ideal One-Dimensional Spin Chains by Topochemical Dehydration/Rehydration Route13Low-temperature synthesis, crystal structure, and ionic mobility in KTiOPO4-structured RbVOPO42Chiral Metal Self‐Assemblies of Zirconium‐Tetrahedra and Their Second Harmonic Generation Activity6Chiral Metal Self‐Assemblies of Zirconium‐Tetrahedra and Their Second Harmonic Generation Activity0Superconducting VF with unusual delocalized electrons under high pressure0Recent achievements of d0 transition-metal-based oxyfluorides: Crystal chemistry and application in second-order NLO materials10

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  1. Borate Fluoride and Fluoroborate in Alkali-Metal Borate Prepared by an Open High-Temperature Solution Method

    Inorganic Chemistry · 2014-12-01

    Hongping Wu, Hongwei Yu, Qiang Bian, Zhihua Yang, Shujuan Han, Shilie Pan

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  2. BaBi(SeO 3 ) 2 Cl: a new polar material showing high second-harmonic generation efficiency enhanced by constructive alignment of chloride ions

    Journal of Materials Chemistry C · 2015-01-01

    Lei Geng, Qiang Li, Chang‐Yu Meng, Kai Dai, Hong‐Yan Lu, Chensheng Lin, Wen‐Dan Cheng

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  3. Synthetic strategies for new vanadium oxyfluorides containing novel building blocks: structures of V( iv ) and V( v ) containing Sr 4 V 3 O 5 F 13 , Pb 7 V 4 O 8 F 18 , Pb 2 VO 2 F 5 , and Pb 2 VOF 6

    CrystEngComm · 2015-01-01

    Jeongho Yeon, Justin B. Felder, Mark D. Smith, Gregory W. Morrison, Hans‐Conrad zur Loye

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  4. ChemInform Abstract: Syntheses of Two Vanadium Oxide—Fluoride Materials that Differ in Phase Matchability.

    ChemInform · 2015-03-26

    Martin D. Donakowski, Romain Gautier, Hongcheng Lu, T. Thao Tran, Jacqueline Cantwell, P. Shiv Halasyamani, Kenneth Reinhard Poeppelmeier

    Read original paper ↗ ·

  5. K2Pb3(CO3)3F2 and KCdCO3F: Novel Fluoride Carbonates with Layered and 3D Framework Structures

    Inorganic Chemistry · 2015-10-21

    Yuan Hua Lin, Chun‐Li Hu, Jiang‐Gao Mao

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  6. KPb 2 (PO 3 ) 5 : a novel nonlinear optical lead polyphosphate with a short deep-UV cutoff edge

    Journal of Materials Chemistry C · 2016-01-01

    Maierhaba Abudoureheman, Shujuan Han, Bing‐Hua Lei, Zhihua Yang, Xifa Long, Shilie Pan

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  7. Three new phosphates with isolated P 2 O 7 units: noncentrosymmetric Cs 2 Ba 3 (P 2 O 7 ) 2 and centrosymmetric Cs 2 BaP 2 O 7 and LiCsBaP 2 O 7

    Dalton Transactions · 2016-01-01

    Lin Li, Shujuan Han, Bing‐Hua Lei, Ying Wang, Hongyi Li, Zhihua Yang, Shilie Pan

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  8. Synthesis, Bonding, and Reactivity of Vanadium(IV) Oxido–Fluorido Compounds with Neutral Chelate Ligands of the General Formula cis-[VIV(═O)(F)(LN–N)2]+

    Inorganic Chemistry · 2016-01-21

    Stamatis S. Passadis, Constantinos G. Tsiafoulis, Chryssoula Drouza, Athanassios C. Tsipis, Haralampos N. Miras, Anastasios D. Keramidas, Themistoklis A. Kabanos

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  9. Synthesis, Characterization, and Theoretical Studies of (Pb4O)Pb2B6O14: A New Lead(II) Borate with Isolated Oxygen-Centered Pb4O Tetrahedra and Large Second Harmonic Generation Response

    The Journal of Physical Chemistry C · 2016-05-23

    Fangfang Zhang, Fangyuan Zhang, Bing‐Hua Lei, Zhihua Yang, Shilie Pan

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  10. A New Deep-Ultraviolet Transparent Orthophosphate LiCs 2 PO 4 with Large Second Harmonic Generation Response

    Journal of the American Chemical Society · 2016-07-12

    Lin Li, Ying Wang, Bing‐Hua Lei, Shujuan Han, Zhihua Yang, Kenneth Reinhard Poeppelmeier, Shilie Pan

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  11. Syntheses, characterization and theoretical studies of three apatite-type phosphates MPb4(PO4)3 (M = K, Rb, Cs)

    Journal of Alloys and Compounds · 2016-08-20

    Maierhaba Abudoureheman, Shujuan Han, Xiaoyu Dong, Bing‐Hua Lei, Ying Wang, Zhihua Yang, Xifa Long, Shilie Pan

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  12. Infrared SHG Materials CsM3Se6 (M = Ga/Sn, In/Sn): Phase Matchability Controlled by Dipole Moment of the Asymmetric Building Unit

    Chemistry of Materials · 2016-12-26

    Hua Lin, Ling Chen, Ju‐Song Yu, Hong Chen, Li‐Ming Wu

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  13. Compositional phase diagram and microscopic mechanism of Ba 1−x Ca x Zr y Ti 1−y O 3 relaxor ferroelectrics

    Physical Chemistry Chemical Physics · 2017-01-01

    Shiyu Liu, Shiyu Liu, Yang Meng, Shiyang Liu, Shiyang Liu, Dejun Li, Yaping Li, Yingdi Liu, Y.G. Shen, Sanwu Wang

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  14. Nature of phase transitions in ammonium oxofluorovanadates, a vibrational spectroscopy study of (NH4)3VO2F4 and (NH4)3VOF5

    Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · 2017-01-09

    Yu. V. Gerasimova, Aleksandr S. Oreshonkov, N. M. Laptash, Alexander N. Vtyurin, А. С. Крылов, N. P. Shestakov, A.A. Ershov, A. G. Kocharova

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  15. New Intermediate Polymorph of 1-Fluoro-adamantane and Its Second-Order-like Transition toward the Low Temperature Phase

    Crystal Growth & Design · 2017-04-18

    Lina Yuan, Simon Clevers, Antoine Burel, P. Négrier, Marı́a Barrio, Bacem Ben Hassine, Denise Mondieig, Valérie Dupray, J. Ll. Tamarit, Gérard Coquerel

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  16. DFT-Based Comparative Study about the Influence of Fluorine and Hydroxyl Anions on Opto-Electric Properties of Borate Crystals: Choice for Better Anion

    Inorganic Chemistry · 2017-04-27

    Beenish Bashir, Bingbing Zhang, Ming‐Hsien Lee, Shilie Pan, Zhihua Yang

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  17. Design and Synthesis of a Series of Novel Mixed Borate and Carbonate Halides

    Chemistry - A European Journal · 2017-06-02

    Lili Liu, Yun Mo Yang, Junben Huang, Xiaoyu Dong, Zhihua Yang, Shilie Pan

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  18. Orientational disorder and phase transitions in ammonium oxofluorovanadates, (NH4)3VOF5 and (NH4)3VO2F4

    Acta Crystallographica Section B Structural Science Crystal Engineering and Materials · 2017-11-15

    Anatoly A. Udovenko, Evgeny I. Pogoreltsev, Yuri Marchenko, N. M. Laptash

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  19. Morphology-controlled epitaxial vanadium dioxide low-dimensional structures: the delicate effects on the phase transition behaviors

    Physical Chemistry Chemical Physics · 2018-01-01

    Weiming Xiong, Jian Shao, Yuxuan Zhang, Yun Chen, Xiaoyue Zhang, Weijin Chen, Yue Zheng

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  20. Surface-step-terrace tuned second-order nonlinear optical coefficients of epitaxial ferroelectric BaTiO 3 films

    Journal of Materials Chemistry C · 2018-01-01

    Yuan Zhang, Quan Guo, Shuaizhi Zheng, Xiangli Zhong, Gaokuo Zhong, Dongwen Zhang, Chuanlai Ren, Congbing Tan, Zhihui Lü, Yi Zhang, Yong Jian Tang, Jinbin Wang, Jianmin Yuan

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  21. Polymorphisme, dynamique et transitions de phases dans les dérivés de l'adamantane

    Unknown journal · 2018-06-03

    Bacem Ben Hassine

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  22. Non-centrosymmetric BaNaP3O9 with a short deep-ultraviolet cutoff edge

    Journal of Alloys and Compounds · 2018-06-07

    Xuefang Lu, Ronglan Wu, Qun Jing, Wenqiang Chen, Yunjing Shi, Xiaoyu Dong, Ming‐Hsien Lee, Zhaohui Chen

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  23. Function of Tetrahedral ZnS3O Building Blocks in the Formation of SrZn2S2O: A Phase Matchable Polar Oxysulfide with a Large Second Harmonic Generation Response

    Chemistry of Materials · 2018-08-22

    Yoshihiro Tsujimoto, Christian A. Juillerat, Weiguo Zhang, Kotaro Fujii, Masatomo Yashima, P. Shiv Halasyamani, Hans‐Conrad zur Loye

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  24. Structural insights into three phosphates with distinct polyanionic configurations

    Dalton Transactions · 2019-01-01

    Jun Sun, Hongping Wu, Miriding Mutailipu, Zhihua Yang, Shilie Pan

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  25. Heteroanionic Materials by Design: Progress Toward Targeted Properties

    Advanced Materials · 2019-03-12

    Jaye K. Harada, Nenian Charles, Kenneth Reinhard Poeppelmeier, James M. Rondinelli

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  26. Vanadium oxide thin films on quartz and Al6061 with reduced phase transition temperature and low solar absorptance for advanced thermal control application in space

    Ceramics International · 2019-04-22

    Dipta Mukherjee, Arjun Dey, Anoop Kumar Mukhopadhyay

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  27. Ba(B 2 OF 3 (OH) 2 ) 2 with well-ordered OH/F anions and a unique B 2 OF 3 (OH) 2 dimer

    Chemical Communications · 2020-01-01

    Minqiang Gai, Ying Wang, Tinghao Tong, Liying Wang, Zhihua Yang, Xin Hua Zhou, Shilie Pan

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  28. Recent advances of oxyfluorides for nonlinear optical applications

    Inorganic Chemistry Frontiers · 2021-01-01

    Shuo Bai, Dan Wang, Hongkun Liu, Ying Wang

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  29. Interplay between Oxo and Fluoro in Vanadium Oxyfluorides for Centrosymmetric and Non-Centrosymmetric Structure Formation

    Molecules · 2021-01-24

    Prashanth Sandineni, Hooman Yaghoobnejad Asl, Weiguo Zhang, P. Shiv Halasyamani, K. Ghosh, Amitava Choudhury

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  30. Recyclable Oxofluorovanadate‐Catalyzed Formylation of Amines by Reductive Functionalization of CO2 with Hydrosilanes

    ChemSusChem · 2021-02-15

    Shanxuan Wu, Zijun Huang, Xiaolin Jiang, Fachao Yan, Yuehui Li, Chenxia Du

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  31. Second-Harmonic-Generation-Active Oxyhalides: CuSb2O3X (X = Cl, Br)

    Inorganic Chemistry · 2021-12-15

    Mei Yang, Zhi‐Hui Shi, Wen‐Dong Yao, Sheng‐Ping Guo

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  32. Phase Matchability Transformation in the Infrared Nonlinear Optical Materials with Diamond‐Like Frameworks

    Advanced Optical Materials · 2021-12-30

    Man‐Man Chen, Shenghua Zhou, Wenbo Wei, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  33. Metal oxyhalides: an emerging family of nonlinear optical materials

    Chemical Science · 2022-01-01

    Xinglong Chen, Kang Min Ok

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  34. Phase matching achieved by isomorphous substitution in IR nonlinear optical material Ba 2 SnSSi 2 O 7 with an undiscovered [SnO 4 S] functional motif

    Materials Chemistry Frontiers · 2022-01-01

    Yong‐Fang Shi, Zuju Ma, Bingxuan Li, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  35. New quinary cesium vanadium (IV) fluorophosphates, CsVOF(PO3F) and CsV2O2F(PO3F)2·H2O

    Journal of Solid State Chemistry · 2022-06-05

    Xinan Zhang, Yanling Jin, Wenxuan Zhu, Dan Chen, Qingqing Huang, Yaping Li, Minfeng Lü

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  36. Isoreticular Design of KTiOPO 4 -Like Deep-Ultraviolet Transparent Materials Exhibiting Strong Second-Harmonic Generation

    Journal of the American Chemical Society · 2022-10-19

    Chunbo Jiang, Xingxing Jiang, Chao Wu, Zhipeng Huang, Zheshuai Lin, Mark Graeme Humphrey, Chi Zhang

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  37. From Ba3Nb2O2F12(H2O)2 to Ba0.5NbO2F2(H2O): Achieving Balanced Nonlinear Optical Performance by O/F Ratio Regulation

    Inorganic Chemistry · 2022-12-07

    Mei Yan, Ru‐Ling Tang, Wenlong Liu, Sheng‐Ping Guo

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  38. K2(H2O)WO3F2: A new nonlinear optical material with remarkable second-harmonic generation response and enhanced laser damage threshold

    Journal of Alloys and Compounds · 2023-02-14

    Hong‐Xin Tang, Ruibiao Fu, Zuju Ma, Xintao Wu

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  39. Beyond π–π Stacking: Understanding Inversion Symmetry Breaking in Crystalline Racemates

    Journal of the American Chemical Society · 2023-07-24

    Yiran Wang, Matthew Lander Nisbet, Kendall R. Kamp, Emily Hiralal, Romain Gautier, P. Shiv Halasyamani, Kenneth Reinhard Poeppelmeier

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  40. K 3 Mo 2 O 5.6 F 3.4 and K 3 V 2 O 3.3 F 5.7 – exploring transition metal cation valence and anion distribution in oxyfluorides

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  41. Construction of Ideal One-Dimensional Spin Chains by Topochemical Dehydration/Rehydration Route

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  42. Low-temperature synthesis, crystal structure, and ionic mobility in KTiOPO4-structured RbVOPO4

    Materials Research Bulletin · 2024-04-16

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  43. Chiral Metal Self‐Assemblies of Zirconium‐Tetrahedra and Their Second Harmonic Generation Activity

    Angewandte Chemie International Edition · 2024-10-29

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  44. Chiral Metal Self‐Assemblies of Zirconium‐Tetrahedra and Their Second Harmonic Generation Activity

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  45. Superconducting VF with unusual delocalized electrons under high pressure

    Physical Chemistry Chemical Physics · 2025-01-01

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  46. Recent achievements of d0 transition-metal-based oxyfluorides: Crystal chemistry and application in second-order NLO materials

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