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RESEARCH PAPER · Angewandte Chemie · 2013

Cs2B4SiO9: A Deep‐Ultraviolet Nonlinear Optical Crystal

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Cs2B4SiO9: A Deep‐Ultraviolet Nonlinear Optical CrystalOriginalPb2TiOF(SeO3)2Cl and Pb2NbO2(SeO3)2Cl: small changes in structure induced a very large SHG enhancement117Sr3BeB6O13: A New Borate in the SrO/BeO/B2O3 System with Novel Tri-Six-Membered Ring (BeB6O15)10– Building Block22Cs2GeB4O9: a New Second-Order Nonlinear-Optical Crystal139Synthesis and Structure of KPbBP 2 O 8 – A Congruent Melting Borophosphate with Nonlinear Optical Properties35ChemInform Abstract: Cs2B4SiO9: A Deep‐Ultraviolet Nonlinear Optical Crystal.0Effect of Rigid Units on the Symmetry of the Framework: Design and Synthesis of Centrosymmetric NaBa4(B5O9)2F2Cl and Noncentrosymmetric NaBa4(AlB4O9)2Br350Synthesis, crystal structure, optical properties and theoretical calculations of a new potassium lead pentaborate, KPbB5O92Preparation, Structure, and Second‐order Nonlinear Optical Properties of a Borate‐Carboxylic Acid Compound: NH4B[ d‐ (+)‐C4H4O5]2·H2O3Noncentrosymmetric Cubic CsCdBO3 with Bichromophore23Pb 4 Zn 2 B 10 O 21 : a congruently melting lead zinc borate with a novel [B 10 O 24 ] anionic group and an interesting [Pb 4 O 12 ] ∞ chain29Sr 4 B 10 O 18 (OH) 2 ·2H 2 O: a new UV nonlinear optical material with a [B 10 O 23 ] 16− building block53SrGe2B2O8 and Sr3Ge2B6O16: Novel Strontium Borogermanates with Three-Dimensional and Layered Anionic Architectures50Pb3B6O11F2: the first non-centrosymmetric lead borate fluoride with a large second harmonic generation response61Crystal growth and calculation of the electronic band structure and density of states of Li3Cs2B5O1013Deep-Ultraviolet Nonlinear Optical Crystals: Ba3P3O10X (X = Cl, Br)462A new alkaline beryllium borate KBe 4 B 3 O 9 with ribbon alveolate [Be 2 BO 5 ] ∞ layers and the structural evolution of ABe 4 B 3 O 9 (A = K, Rb and Cs)12A new polymorph of Cd 3 B 2 O 6 : synthesis, crystal structure and phase transformation18Ba 2 B 10 O 17 : a new centrosymmetric alkaline-earth metal borate with a deep-UV cut-off edge50Ba4(BO3)3(SiO4)·Ba3X (X = Cl, Br): new salt-inclusion borosilicate halides as potential deep UV nonlinear optical materials58BaPbSi 2 O 6 ·BaSO 4 : the first mixed anionic compound synthesized via BaSO 4 salt-inclusion8Ca 3 Be 6 B 5 O 16 F: the first alkaline-earth beryllium borate with fluorine anions11Growth and properties of a noncentrosymmetric polyphosphate CsLa(PO 3 ) 4 crystal with deep-ultraviolet transparency101Sodium–rare earth carbonates with shorite structure and large second harmonic generation response44SrBeB2O5: Growth, crystal structure and optical properties13Nonplanar Donor–Acceptor Chiral Molecules with Large Second-Order Optical Nonlinearities: 1,1,4,4-Tetracyanobuta-1,3-diene Derivatives22ReBe2B5O11 (Re = Y, Gd): Rare-Earth Beryllium Borates as Deep-Ultraviolet Nonlinear-Optical Materials50A New Cesium Pentaborate with New B10O19 Building Blocks13Three New Alkaline Beryllium Borates LiBeBO3, Li6Be3B4O12, and Li8Be5B6O18 in the Ternary Phase Diagrams Li2O–BeO–B2O314A Nitrate Nonlinear Optical Crystal Pb16(OH)16(NO3)16 with a Large Second-Harmonic Generation Response57KSbB2O6 and BaSb2B4O12: Novel Boroantimonates with 3D Anionic Architectures Composed of 1D Chains of SbO6 Octahedra and B2O5 Groups36Linear and Nonlinear Optical Properties of K3B6O10Br Single Crystal: Experiment and Calculation81Beryllium-free Li4Sr(BO3)2 for deep-ultraviolet nonlinear optical applications463PbCd 2 B 6 O 12 and EuZnB 5 O 10 : syntheses, crystal structures and characterizations of two new mixed metal borates43Na4La2(CO3)5 and CsNa5Ca5(CO3)8: Two New Carbonates as UV Nonlinear Optical Materials65Optical Nonlinearity in Cu2CdSnS4 and α/β-Cu2ZnSiS4: Diamond-like Semiconductors with High Laser-Damage Thresholds87The interaction between cations and anionic groups inducing SHG enhancement in a series of apatite-like crystals: A first-principles study23The influence of hydrogen bonding on the nonlinear optical properties of a semiorganic material NH 4 B[ d -(+)-C 4 H 4 O 5 ] 2 ·H 2 O: a theoretical perspective23Ca3Na4LiBe4B10O24F: A New Beryllium Borate with a Unique Beryl Borate ∞2[Be8B16O40F2] Layer Intrabridged by [B12O24] Groups20An Acentric Calcium Borate Ca2[B5O9]·(OH)·H2O: Synthesis, Structure, and Nonliner Optical Property94Series of open-framework aluminoborates containing [B 5 O 10 ] clusters24An interpenetrated bioactive nonlinear optical MOF containing a coordinated quinolone-like drug and Zn( ii ) for pH-responsive release57Synthesis and structural characterization of a new rubidium borosulfate, Rb5BS4O1616Anomalous second-harmonic generation response in SrBPO 5 and BaBPO 542Ba 7 (BO 3 ) 3 GeO 4 X (X = Cl, Br): borogermanate halides with rigid GeO 4 tetrahedra and flexible XBa 6 octahedra11Evidence of “new hot spots” from determining the nonlinear optical behavior of materials: mechanistic studies of the vanadium borate crystal, Na 3 VO 2 B 6 O 1116Na 3 B 4 O 7 X (X = Cl, Br): two new borate halides with a 1D Na-X (X = Cl, Br) chain formed by the face-sharing XNa 6 octahedra14Synthesis, characterization and theoretical studies of nonlinear optical crystal Sr 2 B 5 O 9 (OH)·H 2 O29Synthesis, structures, and properties of two magnesium silicate fluorides Mg 5 (SiO 4 ) 2 F 2 and Mg 3 SiO 4 F 214Recent advances on second-order NLO materials based on metal iodates328Beryllium-Free Rb3Al3B3O10F with Reinforced Interlayer Bonding as a Deep-Ultraviolet Nonlinear Optical Crystal270Tailored Synthesis of a Nonlinear Optical Phosphate with a Short Absorption Edge242Tailored Synthesis of a Nonlinear Optical Phosphate with a Short Absorption Edge60Synthesis and Characterization of Mid-Infrared Transparency Compounds: Acentric BaHgS2 and Centric Ba8Hg4S5Se752Pb7O(OH)3(CO3)3(BO3): First Mixed Borate and Carbonate Nonlinear Optical Material Exhibiting Large Second-Harmonic Generation Response74The lone-pairs enhanced birefringence and SHG response: A DFT investigation on M2B5O9Cl (M=Sr, Ba, and Pb)47Femtosecond laser induced space-selective precipitation of a deep-ultraviolet nonlinear BaAlBO3F2 crystal in glass7Polar Polymorphism: α-, β-, and γ-Pb2Ba4Zn4B14O31–Synthesis, Characterization, and Nonlinear Optical Properties79Pb17O8Cl18: A Promising IR Nonlinear Optical Material with Large Laser Damage Threshold Synthesized in an Open System223Pb2Ba3(BO3)3Cl: A Material with Large SHG Enhancement Activated by Pb-Chelated BO3 Groups279First-Principles Evaluation of the Alkali and/or Alkaline Earth Beryllium Borates in Deep Ultraviolet Nonlinear Optical Applications130Electro-optic Coefficient Enhancement of AlxGa1–xN via Multiple Field Modulations14RbMgCO3F: A New Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material342Effect of the tetrahedral groups on the optical properties of LaBRO5 (R = Si and Ge): A first-principles study11K2Pb3(CO3)3F2 and KCdCO3F: Novel Fluoride Carbonates with Layered and 3D Framework Structures42Structure and thermal behavior of a nickel complex based on a V-shaped bis(4-(1H-imidazol-1-yl)phenyl)amine ligand3Li 3 AlSiO 5 : the first aluminosilicate as a potential deep-ultraviolet nonlinear optical crystal with the quaternary diamond-like structure55Versatile Coordination Mode of LiNaB8O13 and α- and β-LiKB8O13 via the Flexible Assembly of Four-Connected B5O10 and B3O7 Groups19Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials341A series of inorganic–organic hybrid cadmium borates with novel Cd-centred [Cd@B 14 O 20 (OH) 6 ] 2− clusters27Active performance of tetrahedral groups to SHG response: theoretical interpretations of Ge/Si-containing borate crystals3An effective strategy to achieve deeper coherent light for LiB 3 O 529BaCdSnS 4 and Ba 3 CdSn 2 S 8 : syntheses, structures, and non-linear optical and photoluminescence properties98Crystal and electronic structures, and optical and magnetic properties of novel rare-earth sulfide borates RE 3 S 3 BO 3 (RE = Sm, Gd)18Hierarchized band gap and enhanced optical responses of trivalent rare-earth metal nitrates due to (d–p)π conjugation interactions22Hydrogen bond-assisted crystallization: structure, growth and characterization of a new mixed-anion transition metal fluoride Na 3 NH 4 (TiF 6 )(SO 4 )·H 2 O6KPb 2 (PO 3 ) 5 : a novel nonlinear optical lead polyphosphate with a short deep-UV cutoff edge109Li 3 Cs 2 M 2 B 3 P 6 O 24 (M = Pb, Sr): borophosphates with double six-membered ring of [BP 2 O 8 ] 3−22Nonlinear optical response mechanism of noncentrosymmetric lead borate Pb 6 [B 4 O 7 (OH) 2 ] 3 with three crystallographically independent [B 4 O 7 (OH) 2 ] 4− chains8Design and Syntheses of Three Novel Carbonate Halides: Cs 3 Pb 2 (CO 3 ) 3 I, KBa 2 (CO 3 ) 2 F, and RbBa 2 (CO 3 ) 2 F29NaBa4(GaB4O9)2X3 (X = Cl, Br) with NLO-Active GaO4 Tetrahedral Unit: Experimental and ab Initio Studies25Designing a Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material without a Structural Instability Problem255Structure modulations in nonlinear optical (NLO) materials Cs2TB4O9(T= Ge, Si)14Molecular Engineering as an Approach To Design a New Beryllium-Free Fluoride Carbonate as a Deep-Ultraviolet Nonlinear Optical Material101Electronic, Crystal Chemistry, and Nonlinear Optical Property Relationships in the Dugganite A3B3CD2O14 Family147Effect of the [Ba 2 BO 3 F] ∞ Layer on the Band Gap: Synthesis, Characterization, and Theoretical Studies of BaZn 2 B 2 O 6 · n Ba 2 BO 3 F ( n = 0, 1, 2)21Crystal growth and optical characteristics of beryllium-free polyphosphate, KLa(PO3)4, a possible deep-ultraviolet nonlinear optical crystal101Trigonal Planar [HgSe3]4– Unit: A New Kind of Basic Functional Group in IR Nonlinear Optical Materials with Large Susceptibility and Physicochemical Stability198Top-Seeded Solution Crystal Growth, Morphology, Optical and Thermal Properties of Ba3(ZnB5O10)PO442Deep‐Ultraviolet Nonlinear Optics in a Borate Framework with 21‐Ring Channels109A Deep-Ultraviolet Nonlinear Optical Crystal: Strontium Beryllium Borate Fluoride with Planar Be(O/F)3 Groups49A New Deep-Ultraviolet Transparent Orthophosphate LiCs 2 PO 4 with Large Second Harmonic Generation Response386Deep Ultraviolet Nonlinear Optical Materials647Titanosilicates with Strong Phase-Matched Second Harmonic Generation Responses77K3B3O4(OH)4·2H2O: A UV Nonlinear Optical Crystal with Isolated [B3O4(OH)4]3– Anion Groups21Syntheses, characterization and theoretical studies of three apatite-type phosphates MPb4(PO4)3 (M = K, Rb, Cs)17Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation381Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation129Growth, Properties, and Theoretical Analysis of KBa2(PO3)5 Single Crystal51Influence of Synthetic Conditions on Chemistry and Structural Properties of Alkaline Earth Uranyl Borates23Effects of the Orientation of [B5O11]7– Fundamental Building Blocks on Layered Structures Based on the Pentaborates31The Indium Borate In19B34O74(OH)11 with T2 Supertetrahedra27Cooperation of Three Chromophores Generates the Water‐Resistant Nitrate Nonlinear Optical Material Bi3TeO6OH(NO3)2113Cooperation of Three Chromophores Generates the Water‐Resistant Nitrate Nonlinear Optical Material Bi3TeO6OH(NO3)220Mixed-Metal Carbonate Fluorides as Deep-Ultraviolet Nonlinear Optical Materials258A new phase-matchable nonlinear optical silicate: Rb 2 ZnSi 3 O 826A promising lead-free fluoride carbonate SHG material designed from a theoretical perspective16Characterization and optimization of the growth conditions of a novel Cs 2 TeW 3 O 12 piezoelectric crystal5Experimental and ab initio studies of Cd 5 (BO 3 ) 3 Cl: the first cadmium borate chlorine NLO material with isolated BO 3 groups21Li 2 CdGeSe 4 and Li 2 CdSnSe 4 : biaxial nonlinear optical materials with strong infrared second-order responses and laser-induced damage thresholds influenced by photoluminescence55Li 3 Ge 3 Se 6 : the first ternary lithium germanium selenide with interesting ∞ [Ge 6 Se 12 ] n chains constructed by ethane-like [Ge 2 Se 6 ] 6− clusters8Solvent-controlled syntheses of mixed-alkali-metal borates exhibiting UV nonlinear optical properties23Two Phosphates: Noncentrosymmetric Cs6Mg6(PO3)18 and Centrosymmetric Cs2MgZn2(P2O7)256Structural Modulation of Nitrate Group with Cations to Affect SHG Responses in RE(OH)2NO3 (RE = La, Y, and Gd): New Polar Materials with Large NLO Effect after Adjusting pH Values of Reaction Systems151Synthesis and crystal structure of the rare earth borogermanate EuGeBO 55Preparation, crystal structure, vibrational and electronic properties of Cd4Si2O7F25Top-Seeded Solution Crystal Growth and Linear and Nonlinear Optical Properties of Ba 4 B 11 O 20 F42M4Mg4(P2O7)3 (M = K, Rb): Structural Engineering of Pyrophosphates for Nonlinear Optical Applications240Beryllium‐Free β‐Rb2Al2B2O7 as a Possible Deep‐Ultraviolet Nonlinear Optical Material Replacement for KBe2BO3F2185Beryllium‐Free β‐Rb2Al2B2O7 as a Possible Deep‐Ultraviolet Nonlinear Optical Material Replacement for KBe2BO3F278Fluorooxoborates: Beryllium‐Free Deep‐Ultraviolet Nonlinear Optical Materials without Layered Growth894Fluorooxoborates: Beryllium‐Free Deep‐Ultraviolet Nonlinear Optical Materials without Layered Growth99Borates—Crystal Structures of Prospective Nonlinear Optical Materials: High Anisotropy of the Thermal Expansion Caused by Anharmonic Atomic Vibrations76Borate-Based Ultraviolet and Deep-Ultraviolet Nonlinear Optical Crystals58First-Principles Assisted Prediction of the Nonlinear Optical Behavior of Mg3B7O13Cl Crystal6Synthesis, structure and electronic calculation of alkali metals borate Li2Na[B5O8(OH)2]7Li2HgMS4 (M = Si, Ge, Sn): New Quaternary Diamond-Like Semiconductors for Infrared Laser Frequency Conversion64Extending Unique 1D Borate Chains to 3D Frameworks by Introducing Metallic Nodes44Synthesis and structural characterization of Li3K3Y7(BO3)919Crystal Growth and Linear and Nonlinear Optical Properties of KIO 3 ·Te(OH) 615Synthesis and characterization of a new beryllium-free deep-ultraviolet nonlinear optical material: Na2GdCO3F331Improvement of second-harmonic generation induced by structural distortions in Nb doped YCa9(VO4)7 crystals13Synthesis and characterization of two lead-containing metal chalcogenides: Ba5Pb2Sn3S13 and Ba6PbSn3Se137Flux Exploration, Growth, and Optical Spectroscopic Properties of Large Size LaBSiO5 and Eu3+-Substituted LaBSiO5 Crystals16LiGaGe2S6: A Chalcogenide with Good Infrared Nonlinear Optical Performance and Low Melting Point56A novel mixed-metal borate with large [B12O18(OH)6]6- motif: Synthesis, structure and property5K2[B3O3(OH)5]: A new deep-UV nonlinear optical crystal with isolated [B3O3(OH)5]2- anionic groups31Synthesis and Study of the First Zeolitic Uranium Borate22RE (SO 4 )[B(OH) 4 ](H 2 O), RE (SO 4 )[B(OH) 4 ](H 2 O) 2 , and RE (SO 4 )[B(OH) 4 ](H 2 O)·H 2 O: Rare-Earth Borate-Sulfates Featuring Three Types of Layered Structures20Design and synthesis of a nonlinear optical material BaAl 4 S 7 with a wide band gap inspired from SrB 4 O 763Pb 2 BO 3 Br: a novel nonlinear optical lead borate bromine with a KBBF-type structure exhibiting strong nonlinear optical response113The first investigation of europium silicate melilite for second-order nonlinear optical application: experimental and theoretical studies29A Joint Strategy To Evaluate the Microscopic Origin of the Second-Harmonic-Generation Response in Nonpolar ABCO3F Compounds32From AgGaS2 to Li2ZnSiS4: Realizing Impressive High Laser Damage Threshold Together with Large Second-Harmonic Generation Response134Non-Centrosymmetric RbNaMgP 2 O 7 with Unprecedented Thermo-Induced Enhancement of Second Harmonic Generation240High-Temperature, High-Pressure Hydrothermal Synthesis, Crystal Structure, Thermal Stability, and Solid State NMR Spectroscopy of an Aluminum Borate, Ba[AlB4O8(OH)]10Pb8M(BO3)6 (M = Mg, Ca): Two new borates with large birefringence activated by the ∞[Pb8B6O18]2- double layers6A Series of Rare-Earth Borates K 7 MRE 2 B 15 O 30 (M = Zn, Cd, Pb; RE = Sc, Y, Gd, Lu) with Large Second Harmonic Generation Responses103Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals256CsSiB3O7: A Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material Discovered by the Combination of Electron Diffraction and First-Principles Calculations58Crystal structures and theoretical studies of polyphosphate LiZnP3O9 for nonlinear optical applications19

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  2. Sr3BeB6O13: A New Borate in the SrO/BeO/B2O3 System with Novel Tri-Six-Membered Ring (BeB6O15)10– Building Block

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  3. Cs2GeB4O9: a New Second-Order Nonlinear-Optical Crystal

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  4. Synthesis and Structure of KPbBP 2 O 8 – A Congruent Melting Borophosphate with Nonlinear Optical Properties

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  5. ChemInform Abstract: Cs2B4SiO9: A Deep‐Ultraviolet Nonlinear Optical Crystal.

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  6. Effect of Rigid Units on the Symmetry of the Framework: Design and Synthesis of Centrosymmetric NaBa4(B5O9)2F2Cl and Noncentrosymmetric NaBa4(AlB4O9)2Br3

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  7. Synthesis, crystal structure, optical properties and theoretical calculations of a new potassium lead pentaborate, KPbB5O9

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  8. Preparation, Structure, and Second‐order Nonlinear Optical Properties of a Borate‐Carboxylic Acid Compound: NH4B[ d‐ (+)‐C4H4O5]2·H2O

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  9. Noncentrosymmetric Cubic CsCdBO3 with Bichromophore

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  10. Pb 4 Zn 2 B 10 O 21 : a congruently melting lead zinc borate with a novel [B 10 O 24 ] anionic group and an interesting [Pb 4 O 12 ] ∞ chain

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  11. Sr 4 B 10 O 18 (OH) 2 ·2H 2 O: a new UV nonlinear optical material with a [B 10 O 23 ] 16− building block

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  12. SrGe2B2O8 and Sr3Ge2B6O16: Novel Strontium Borogermanates with Three-Dimensional and Layered Anionic Architectures

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  13. Pb3B6O11F2: the first non-centrosymmetric lead borate fluoride with a large second harmonic generation response

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  14. Crystal growth and calculation of the electronic band structure and density of states of Li3Cs2B5O10

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  15. Deep-Ultraviolet Nonlinear Optical Crystals: Ba3P3O10X (X = Cl, Br)

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  16. A new alkaline beryllium borate KBe 4 B 3 O 9 with ribbon alveolate [Be 2 BO 5 ] ∞ layers and the structural evolution of ABe 4 B 3 O 9 (A = K, Rb and Cs)

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  17. A new polymorph of Cd 3 B 2 O 6 : synthesis, crystal structure and phase transformation

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  18. Ba 2 B 10 O 17 : a new centrosymmetric alkaline-earth metal borate with a deep-UV cut-off edge

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  19. Ba4(BO3)3(SiO4)·Ba3X (X = Cl, Br): new salt-inclusion borosilicate halides as potential deep UV nonlinear optical materials

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  20. BaPbSi 2 O 6 ·BaSO 4 : the first mixed anionic compound synthesized via BaSO 4 salt-inclusion

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  21. Ca 3 Be 6 B 5 O 16 F: the first alkaline-earth beryllium borate with fluorine anions

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  22. Growth and properties of a noncentrosymmetric polyphosphate CsLa(PO 3 ) 4 crystal with deep-ultraviolet transparency

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  23. Sodium–rare earth carbonates with shorite structure and large second harmonic generation response

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  24. SrBeB2O5: Growth, crystal structure and optical properties

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  25. Nonplanar Donor–Acceptor Chiral Molecules with Large Second-Order Optical Nonlinearities: 1,1,4,4-Tetracyanobuta-1,3-diene Derivatives

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  26. ReBe2B5O11 (Re = Y, Gd): Rare-Earth Beryllium Borates as Deep-Ultraviolet Nonlinear-Optical Materials

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  27. A New Cesium Pentaborate with New B10O19 Building Blocks

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  28. Three New Alkaline Beryllium Borates LiBeBO3, Li6Be3B4O12, and Li8Be5B6O18 in the Ternary Phase Diagrams Li2O–BeO–B2O3

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  29. A Nitrate Nonlinear Optical Crystal Pb16(OH)16(NO3)16 with a Large Second-Harmonic Generation Response

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  30. KSbB2O6 and BaSb2B4O12: Novel Boroantimonates with 3D Anionic Architectures Composed of 1D Chains of SbO6 Octahedra and B2O5 Groups

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  31. Linear and Nonlinear Optical Properties of K3B6O10Br Single Crystal: Experiment and Calculation

    The Journal of Physical Chemistry C · 2014-05-12

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  32. Beryllium-free Li4Sr(BO3)2 for deep-ultraviolet nonlinear optical applications

    Nature Communications · 2014-05-29

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  33. PbCd 2 B 6 O 12 and EuZnB 5 O 10 : syntheses, crystal structures and characterizations of two new mixed metal borates

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  34. Na4La2(CO3)5 and CsNa5Ca5(CO3)8: Two New Carbonates as UV Nonlinear Optical Materials

    Inorganic Chemistry · 2014-07-16

    Min Luo, Genxiang Wang, Chensheng Lin, Ning Ye, Yuqiao Zhou, Wendan Cheng

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