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RESEARCH PAPER · Journal of the American Chemical Society · 2015

Beryllium-Free Rb3Al3B3O10F with Reinforced Interlayer Bonding as a Deep-Ultraviolet Nonlinear Optical Crystal

Sangen Zhao, Pifu Gong, Siyang Luo, Sijie Liu, Lina Li, Muhammad Adnan Asghar, Tariq Mehmood Khan, Maochun Hong, Zheshuai Lin, Junhua Luo

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Beryllium-Free Rb3Al3B3O10F with Reinforced Interlayer Bonding as a Deep-Ultraviolet Nonlinear Optical CrystalOriginalBa 7 (BO 3 ) 3 GeO 4 X (X = Cl, Br): borogermanate halides with rigid GeO 4 tetrahedra and flexible XBa 6 octahedra11New isoformula borates with similar structures and different properties – Acentric nonlinear optical KGd[B6O10(OH)2] and centrosymmetric KHo[B6O10(OH)2]6ChemInform Abstract: Beryllium‐Free Rb3Al3B3O10F with Reinforced Interlayer Bonding as a Deep‐Ultraviolet Nonlinear Optical Crystal.2Linear optical and thermo-physical properties of polar K3B6O10Cl crystal21First-Principles Evaluation of the Alkali and/or Alkaline Earth Beryllium Borates in Deep Ultraviolet Nonlinear Optical Applications130Structural Modulation of Anionic Group Architectures by Cations to Optimize SHG Effects: A Facile Route to New NLO Materials in the ATCO3F (A = K, Rb; T = Zn, Cd) Series114First-Principles Design of a Deep-Ultraviolet Nonlinear-Optical Crystal from KBe2BO3F2 to NH4Be2BO3F2106Preparation, nonlinear optical properties, and theoretical analysis of the non-centrosymmetric bismuth oxyfluoride, Bi 7 F 11 O 525Sm3S3BO3: The First Sulfide Borate without S–O and B–S Bonds46The mechanism for the nonlinear optical properties in La9Na3B8O27, La2Na3B3O9and La2CaB10O19:ab initiostudies13Li 3 AlSiO 5 : the first aluminosilicate as a potential deep-ultraviolet nonlinear optical crystal with the quaternary diamond-like structure54Versatile Coordination Mode of LiNaB8O13 and α- and β-LiKB8O13 via the Flexible Assembly of Four-Connected B5O10 and B3O7 Groups19Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials340“XA 6 ” octahedra influencing the arrangement of anionic groups and optical properties in inverse-perovskite [B 6 O 10 ]XA 3 (X = Cl, Br; A = alkali metal)19AMgPO 4 ·6H 2 O (A = Rb, Cs): strong SHG responses originated from orderly PO 4 groups59An effective strategy to achieve deeper coherent light for LiB 3 O 529Frequency-Doubling Oxide Fluorides, Borate Fluorides, and Fluorooxoborates9M 2 Ca 3 B 16 O 28 (M = Rb, Cs): structures analogous to SBBO with three-dimensional open-framework layers10Three new phosphates with isolated P 2 O 7 units: noncentrosymmetric Cs 2 Ba 3 (P 2 O 7 ) 2 and centrosymmetric Cs 2 BaP 2 O 7 and LiCsBaP 2 O 768Two novel pillared-layer lanthanide borates built by Ln@B 12 O 28/29 ring clusters and dicarboxylate linkers (Ln = Pr, Nd)26Supramolecular Interactions Induced Chirality Transmission, Second Harmonic Generation Responses, and Photoluminescent Property of a Pair of Enantiomers from in Situ [2 + 3] Cycloaddition Synthesis18NaBa4(GaB4O9)2X3 (X = Cl, Br) with NLO-Active GaO4 Tetrahedral Unit: Experimental and ab Initio Studies25Designing a Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material without a Structural Instability Problem255Crystal growth and optical characteristics of beryllium-free polyphosphate, KLa(PO3)4, a possible deep-ultraviolet nonlinear optical crystal101Unusual Sequential Reversible Phase Transitions Containing Switchable Dielectric Behaviors in Cyclopentyl Ammonium 18-Crown-6 Perchlorate110A Deep-Ultraviolet Nonlinear Optical Crystal: Strontium Beryllium Borate Fluoride with Planar Be(O/F)3 Groups49A New Deep-Ultraviolet Transparent Orthophosphate LiCs 2 PO 4 with Large Second Harmonic Generation Response384Deep Ultraviolet Nonlinear Optical Materials644DFT Based Theoretical Study about the Contributions of Fluorine to Nonlinear Optical Properties in Borate Fluoride Crystals27K3B3O4(OH)4·2H2O: A UV Nonlinear Optical Crystal with Isolated [B3O4(OH)4]3– Anion Groups21Growth, Properties, and Theoretical Analysis of KBa2(PO3)5 Single Crystal51Deep-Ultraviolet Transparent Cs 2 LiPO 4 Exhibits an Unprecedented Second Harmonic Generation160Effects of the Orientation of [B5O11]7– Fundamental Building Blocks on Layered Structures Based on the Pentaborates31Predicting Global Minimum in Complex Beryllium Borate System for Deep-ultraviolet Functional Optical Applications29Strong Nonlinear-Optical Response in the Pyrophosphate CsLiCdP2O7 with a Short Cutoff Edge69SrNO3(OH)·H2O: A new member in strontium nitrate hydrate family with an ultraviolet cut-off edge7Multiple Fluorine-Substituted Phosphate Germanium Fluorides and Their Thermal Stabilities5LiRb 2 LaB 2 O 6 : a new rare-earth borate with a MOF-5-like topological structure and a short UV cut-off edge14Cooperation of Three Chromophores Generates the Water‐Resistant Nitrate Nonlinear Optical Material Bi3TeO6OH(NO3)2113Cooperation of Three Chromophores Generates the Water‐Resistant Nitrate Nonlinear Optical Material Bi3TeO6OH(NO3)220Ba n+2 Zn n (BO 3 ) n (B 2 O 5 )F n (n = 1, 2): new members of the zincoborate fluoride series with two kinds of isolated B–O units33BaBe2BO3F3: A KBBF-Type Deep-Ultraviolet Nonlinear Optical Material with Reinforced [Be2BO3F2]∞ Layers and Short Phase-Matching Wavelength80Na2B6O9F2: A Fluoroborate with Short Cutoff Edge and Deep-Ultraviolet Birefringent Property Prepared by an Open High-Temperature Solution Method106A promising lead-free fluoride carbonate SHG material designed from a theoretical perspective16ACaBO 3 (A = Cs, Rb): two new cubic borates with isolated BO 3 groups24BaCu 2 M IV Q 4 (M IV = Si, Ge, and Sn; Q = S, Se): synthesis, crystal structures, optical performances and theoretical calculations54Explorations of new UV nonlinear optical materials in the Na 2 CO 3 –CaCO 3 system37KB(PO 4 )F: a novel acentric deep-ultraviolet material43Li 2 CdGeSe 4 and Li 2 CdSnSe 4 : biaxial nonlinear optical materials with strong infrared second-order responses and laser-induced damage thresholds influenced by photoluminescence54Reversible structural phase transition, ferroelectric and switchable dielectric properties of an adduct molecule of hexamethylenetetramine ferrocene carboxylic acid23Structural diversities induced by cation sizes in a series of fluorogermanophosphates: A 2 [GeF 2 (HPO 4 ) 2 ] (A = Na, K, Rb, NH 4 , and Cs)4Syntheses, crystal structures and characterization of three alkaline metal borates7The activity of lone pair contributing to SHG response in bismuth borates: a combination investigation from experiment and DFT calculation28The structural diversity of halogen-centered secondary building units: two new mixed-metal borate halides with deep-ultraviolet cut-off edges16Theoretical investigation on the balance between large band gap and strong SHG response in BMO 4 (M = P and As) crystals22Theoretical perspectives on the structure, electronic, and optical properties of titanosilicates Li 2 M 4 [(TiO)Si 4 O 12 ] (M = K + , Rb + )13Two deep-ultraviolet nonlinear optical alkaline-earth metal borates based on different types of oxoboron clusters56Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect238Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect71M4Mg4(P2O7)3 (M = K, Rb): Structural Engineering of Pyrophosphates for Nonlinear Optical Applications238Borate-Based Ultraviolet and Deep-Ultraviolet Nonlinear Optical Crystals58Li2HgMS4 (M = Si, Ge, Sn): New Quaternary Diamond-Like Semiconductors for Infrared Laser Frequency Conversion64Studies on nonlinear optical ammonium pentaborate crystals27Na8MB21O36 (M = Rb and Cs): Noncentrosymmetric Borates with Unprecedented [B21O36]9– Fundamental Building Blocks36Design and Synthesis of a Series of Novel Mixed Borate and Carbonate Halides21A New KBBF-Family Nonlinear Optical Material with Strong Interlayer Bonding51Structural Insights into Borates with an Anion‐Templated Open‐Framework Configuration: Asymmetric K2BaB16O26 versus Centrosymmetric K3CsB20O32 and Na2M2NB18O30 (M=Rb, Cs; N=Ba, Pb)26Structurally stable borate as a UV nonlinear optical material20Homologous Series of 2D Chalcogenides Cs–Ag–Bi–Q (Q = S, Se) with Ion-Exchange Properties27Synthesis and characterization of two lead-containing metal chalcogenides: Ba5Pb2Sn3S13 and Ba6PbSn3Se137Rational Design of Deep-Ultraviolet Nonlinear Optical Materials in Fluorooxoborates: Toward Optimal Planar Configuration157Synthesis, Structure, and Properties of Nonlinear Optical Crystal Na2SiF622LiGaGe2S6: A Chalcogenide with Good Infrared Nonlinear Optical Performance and Low Melting Point56K2[B3O3(OH)5]: A new deep-UV nonlinear optical crystal with isolated [B3O3(OH)5]2- anionic groups31Chemical Cosubstitution-Oriented Design of Rare-Earth Borates as Potential Ultraviolet Nonlinear Optical Materials267Noncentrosymmetric Cubic Cyanurate K6Cd3(C3N3O3)4 Containing Isolated Planar π-Conjugated (C3N3O3)3– Groups59Crystal Growth and Optical Properties of Beryllium-Free Nonlinear Optical Crystal K3Ba3Li2Al4B6O20F35A beryllium-free deep-UV nonlinear optical material CsNaMgP 2 O 7 with honeycomb-like topological layers53BaLiZn 3 (BO 3 ) 3 : a new member of the KBe 2 BO 3 F 2 family possessing dense BO 3 triangles and the smallest interlayer distance16Cs 3 VO(O 2 ) 2 CO 3 : an exceptionally thermostable carbonatoperoxovanadate with an extremely large second-harmonic generation response129Design and synthesis of a nonlinear optical material BaAl 4 S 7 with a wide band gap inspired from SrB 4 O 763Influence of A-site cations on germanium iodates as mid-IR nonlinear optical materials: A 2 Ge(IO 3 ) 6 (A = Li, K, Rb and Cs) and BaGe(IO 3 ) 6 ·H 2 O43Ion-induced structural and optical performance evolution in LBO-like crystals: experimental and theoretical investigation13Oxyhalides: prospecting ore for optical functional materials with large laser damage thresholds76Pb 3 (SeO 3 )Br 4 : a new nonlinear optical material with enhanced SHG response designed via an ion-substitution strategy36Perfect balance harmony in Ba 2 NO 3 (OH) 3 : a beryllium-free nitrate as a UV nonlinear optical material184RbSe 3 B 2 O 9 (OH) and CsSe 3 B 2 O 9 (OH): one dimensional boroselenite-based anionic frameworks with second harmonic generation properties15Synthesis, structure and nonlinear optical properties of solution-processed Bi 2 TeO 5 nanocrystals20Non-Centrosymmetric RbNaMgP 2 O 7 with Unprecedented Thermo-Induced Enhancement of Second Harmonic Generation239High-Temperature, High-Pressure Hydrothermal Synthesis, Crystal Structure, Thermal Stability, and Solid State NMR Spectroscopy of an Aluminum Borate, Ba[AlB4O8(OH)]10LiNa4B15O25: Featuring Unprecedented B15O30 Fundamental Building Block and Deep-UV Cutoff Edge20Pb2BO3I: A Borate Iodide with the Largest Second‐Harmonic Generation (SHG) Response in the KBe2BO3F2 (KBBF) Family of Nonlinear Optical (NLO) Materials237Pb2BO3I: A Borate Iodide with the Largest Second‐Harmonic Generation (SHG) Response in the KBe2BO3F2 (KBBF) Family of Nonlinear Optical (NLO) Materials24M2B10O14F6 (M = Ca, Sr): Two Noncentrosymmetric Alkaline Earth Fluorooxoborates as Promising Next-Generation Deep-Ultraviolet Nonlinear Optical Materials356Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals257Engineered Photocatalytic Material Membrane Assemblies for Removing Nitrate from Water33Crystal structures and theoretical studies of polyphosphate LiZnP3O9 for nonlinear optical applications18The role of cations in second-order nonlinear optical materials based on π-conjugated [BO 3 ] 3− groups195Deep‐Ultraviolet Nonlinear Optical Crystal Cs2Al2(B3O6)2O: A Benign Member of the Sr2Be2(BO3)2O Family with [Al2(B3O6)2O]2− Double Layers70Polar Fluorooxoborate, NaB4O6F: A Promising Material for Ionic Conduction and Nonlinear Optics494Polar Fluorooxoborate, NaB4O6F: A Promising Material for Ionic Conduction and Nonlinear Optics67Crystal packing, high-temperature phase transition, second-order nonlinear optical and biological activities in a hybrid material: [(S) C7H16N2][CuBr4]12NH4Be2BO3F2 and γ‐Be2BO3F: Overcoming the Layering Habit in KBe2BO3F2 for the Next‐Generation Deep‐Ultraviolet Nonlinear Optical Materials280NH4Be2BO3F2 and γ‐Be2BO3F: Overcoming the Layering Habit in KBe2BO3F2 for the Next‐Generation Deep‐Ultraviolet Nonlinear Optical Materials68Li3.366Mg0.317B2O5: The first pyroborate in the Li2O-MgO-B2O3 system1Hydrogen Bonding Assisted Construction of Graphite-like Deep-UV Optical Materials with Two Types of Parallel π-Conjugated Units22Fluorooxoborates: Ushering in a New Era of Deep Ultraviolet Nonlinear Optical Materials102Mo6+ Cation Enrichment of the Structure Chemistry of Iodates: Syntheses, Structures, and Calculations of Ba(MoO2)2(IO3)4O, Ba3[(MoO2)2(IO3)4O(OH)4]·2H2O, and Sr[(MoO2)6(IO4)2O4]·H2O24Second-order nonlinear optical crystals with mixed anions250Removal of A-Site Alkali and Alkaline Earth Metal Cations in KBe2BO3F2-Type Layered Structures To Enhance the Deep-Ultraviolet Nonlinear Optical Capability46Mg 3 B 7 O 13 Cl: A New Quasi‐Phase Matching Crystal in the Deep‐Ultraviolet Region56Why Some Noncentrosymmetric Borates Do Not Make Good Nonlinear Optical Materials: A Case Study with K3B5O8(OH)222Two new mixed metal borates with the large birefringence in borates system confirmed by a disordered crystal optical calculation method6Li2BaSc(BO3)2F and LiBa2Pb(BO3)2F with Layered Structures featuring Special Li−O/F Configurations11The Rubidium Barium Borate Resulting from B7O15 Fundamental Building Block Exhibits DUV Cutoff Edge17A UV Transmittable NLO crystal Hydrofluoric Acid Mixed Sulphamic acid (FASA) : Synthesis, Growth and Characterization0Y2(CO3)3·H2O and (NH4)2Ca2Y4(CO3)9·H2O: Partial Aliovalent Cation Substitution Enabling Evolution from Centrosymmetry to Noncentrosymmetry for Nonlinear Optical Response37A 2 SrM IV S 4 (A = Li, Na; M IV = Ge, Sn) concurrently exhibiting wide bandgaps and good nonlinear optical responses as new potential infrared nonlinear optical materials78An energy band engineering design to enlarge the band gap of KTiOPO 4 (KTP)-type sulfates via aliovalent substitution66Ba 3 Ca 4 (BO 3 ) 3 (SiO 4 )Cl: a new non-centrosymmetric complex alkaline-earth metal borosilicate chloride with a deep-ultraviolet cut-off edge19K 2 SrP 4 O 12 : a deep-UV transparent cyclophosphate as a nonlinear optical crystal79Pb 10 O 4 (BO 3 ) 3 I 3 : a new noncentrosymmetric oxyborate iodide synthesized by the straightforward hydrothermal method6Sn 2 B 7 O 12 F with a 2∞[B 14 O 24 ] 6− layer constructed from the unprecedented [B 7 O 16 ] 11− fundamental building block18Sr[B(OH) 4 ](IO 3 ) and Li 4 Sr 5 [B 12 O 22 (OH) 4 ](IO 3 ) 2 : two unprecedented metal borate-iodates showing a subtle balance of enlarged band gap and birefringence34Synthesis, crystal structures, second harmonic generation response and temperature phase transitions of two noncentrosymmetric Cu(II)-hybrid halides compounds: [(R)-C7H16N2][CuX4] (X = Cl or Br)24Formation Mechanism of a Polyanonic Framework from Layer to Chain Explored by Adjusting Time, Temperature, and pH: Preparation and Characterization of Metal-Complex-Templated 1D Borate and 2D Nickel Borate13Two Non-π-Conjugated Deep-UV Nonlinear Optical Sulfates268CsSbF 2 SO 4 : An Excellent Ultraviolet Nonlinear Optical Sulfate with a KTiOPO 4 (KTP)‐type Structure87CsSbF2SO4: An Excellent Ultraviolet Nonlinear Optical Sulfate with a KTiOPO4 (KTP)‐type Structure432New cadmium-selenium-oxyhalides: Noncentrosymmetric Cd5(SeO3)4Cl2(H2O) and centrosymmetric Cd2(SeO3)F2, Cd2(SeO3)(OH)Br17Designing Three Fluorooxoborates with a Wide Transmittance Window by Anionic Group Substitution15NaCa5BO3(SiO4)2 with Interesting Isolated [BO3] and [SiO4] Units in Alkali- and Alkaline-Earth-Metal Borosilicates14Rational Design and Synthesis of a Deep-Ultraviolet Nonlinear Optical Fluorinated Orthophosphate: BaZn(PO4)F16Two Polar Molybdenum(VI) Iodates(V) with Large Second-Harmonic Generation Responses67Synthesis, Characterization and Optical Properties of Two Metal Borates Containing Two Types of Oxoboron Clusters2Deep-Ultraviolet Mixed-Alkali-Metal Borates with Induced Enlarged Birefringence Derived from the Structure Rearrangement of the LiB3O545β‐CsB9O14: A Triple‐Layered Borate with Edge‐Sharing BO4 Tetrahedra Exhibiting a Short Cutoff Edge and a Large Birefringence30Experiment and First-Principles Calculations of A2Mg2TeB2O10 (A = Pb, Ba): Influences of the Cosubstitution on the Structure Transformation and Optical Properties21Research and Development of Zincoborates: Crystal Growth, Structural Chemistry and Physicochemical Properties20Nontoxic KBBF Family Member Zn2BO3(OH): Balance between Beneficial Layered Structure and Layer Tendency81[NH4]12[(MoO2)2O(HPO4)2]4[PO4]Cl·0.5H2O: A mixed phosphomolybdate with nonlinear optical properties4KMg(H 2 O)PO 4 : A Deep-Ultraviolet Transparent Nonlinear Optical Material Derived from KTiOPO 483CsAlB 3 O 6 F: a beryllium-free deep-ultraviolet nonlinear optical material with enhanced thermal stability153Structural Origin of Thermally Induced Second Harmonic Generation Enhancement in RbNaMgP2O721A new family of quaternary thiosilicates SrA 2 SiS 4 (A = Li, Na, Cu) as promising infrared nonlinear optical crystals48NaRb3B6O9(OH)3(HCO3): A Borate-Bicarbonate Nonlinear Optical Material18From BaAl 2 (BO 3 ) 2 O to SnAl 2 (BO 3 ) 2 F 2 : structure transformation based on ion regulation3Nd3+ and Pr3+ doped anti-zeolite matrix-LiBa12(BO3)7F4: Crystal structures, luminescence properties11Rb 3 BaTeB 7 O 15 : a novel [B 7 O 16 ] fundamental building block in a new telluroborate with [TeO 3 ] polyhedra11Second-order nonlinear optical materials with a benzene-like conjugated π system49

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  1. Ba 7 (BO 3 ) 3 GeO 4 X (X = Cl, Br): borogermanate halides with rigid GeO 4 tetrahedra and flexible XBa 6 octahedra

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  2. New isoformula borates with similar structures and different properties – Acentric nonlinear optical KGd[B6O10(OH)2] and centrosymmetric KHo[B6O10(OH)2]

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  3. ChemInform Abstract: Beryllium‐Free Rb3Al3B3O10F with Reinforced Interlayer Bonding as a Deep‐Ultraviolet Nonlinear Optical Crystal.

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  4. Linear optical and thermo-physical properties of polar K3B6O10Cl crystal

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  5. First-Principles Evaluation of the Alkali and/or Alkaline Earth Beryllium Borates in Deep Ultraviolet Nonlinear Optical Applications

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  10. The mechanism for the nonlinear optical properties in La9Na3B8O27, La2Na3B3O9and La2CaB10O19:ab initiostudies

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  11. Li 3 AlSiO 5 : the first aluminosilicate as a potential deep-ultraviolet nonlinear optical crystal with the quaternary diamond-like structure

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  12. Versatile Coordination Mode of LiNaB8O13 and α- and β-LiKB8O13 via the Flexible Assembly of Four-Connected B5O10 and B3O7 Groups

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  13. Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials

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  14. “XA 6 ” octahedra influencing the arrangement of anionic groups and optical properties in inverse-perovskite [B 6 O 10 ]XA 3 (X = Cl, Br; A = alkali metal)

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  15. AMgPO 4 ·6H 2 O (A = Rb, Cs): strong SHG responses originated from orderly PO 4 groups

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  16. An effective strategy to achieve deeper coherent light for LiB 3 O 5

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  18. M 2 Ca 3 B 16 O 28 (M = Rb, Cs): structures analogous to SBBO with three-dimensional open-framework layers

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  19. Three new phosphates with isolated P 2 O 7 units: noncentrosymmetric Cs 2 Ba 3 (P 2 O 7 ) 2 and centrosymmetric Cs 2 BaP 2 O 7 and LiCsBaP 2 O 7

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  20. Two novel pillared-layer lanthanide borates built by Ln@B 12 O 28/29 ring clusters and dicarboxylate linkers (Ln = Pr, Nd)

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  21. Supramolecular Interactions Induced Chirality Transmission, Second Harmonic Generation Responses, and Photoluminescent Property of a Pair of Enantiomers from in Situ [2 + 3] Cycloaddition Synthesis

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  22. NaBa4(GaB4O9)2X3 (X = Cl, Br) with NLO-Active GaO4 Tetrahedral Unit: Experimental and ab Initio Studies

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  23. Designing a Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material without a Structural Instability Problem

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  24. Crystal growth and optical characteristics of beryllium-free polyphosphate, KLa(PO3)4, a possible deep-ultraviolet nonlinear optical crystal

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  25. Unusual Sequential Reversible Phase Transitions Containing Switchable Dielectric Behaviors in Cyclopentyl Ammonium 18-Crown-6 Perchlorate

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  26. A Deep-Ultraviolet Nonlinear Optical Crystal: Strontium Beryllium Borate Fluoride with Planar Be(O/F)3 Groups

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  27. A New Deep-Ultraviolet Transparent Orthophosphate LiCs 2 PO 4 with Large Second Harmonic Generation Response

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  28. Deep Ultraviolet Nonlinear Optical Materials

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  29. DFT Based Theoretical Study about the Contributions of Fluorine to Nonlinear Optical Properties in Borate Fluoride Crystals

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  30. K3B3O4(OH)4·2H2O: A UV Nonlinear Optical Crystal with Isolated [B3O4(OH)4]3– Anion Groups

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  31. Growth, Properties, and Theoretical Analysis of KBa2(PO3)5 Single Crystal

    Crystal Growth & Design · 2016-09-07

    Pai Shan, Tongqing Sun, Hongde Liu, Shiguo Liu, Shaolin Chen, Xuanwen Liu, Yongfa Kong, Jingjun Xu

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  32. Deep-Ultraviolet Transparent Cs 2 LiPO 4 Exhibits an Unprecedented Second Harmonic Generation

    Chemistry of Materials · 2016-09-13

    Yaoguo Shen, Yi Jin Yang, Sangen Zhao, Bingqing Zhao, Zheshuai Lin, Chengmin Ji, Lina Li, Ping Fu, Maochun Hong, Junhua Luo

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  33. Effects of the Orientation of [B5O11]7– Fundamental Building Blocks on Layered Structures Based on the Pentaborates

    Inorganic Chemistry · 2016-09-26

    Miriding Mutailipu, Min Zhang, Xiaoyu Dong, Yanna Chen, Shilie Pan

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  34. Predicting Global Minimum in Complex Beryllium Borate System for Deep-ultraviolet Functional Optical Applications

    Scientific Reports · 2016-10-13

    Qiang Bian, Zhihua Yang, Ying Wang, Chao Cao, Shilie Pan

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  35. Strong Nonlinear-Optical Response in the Pyrophosphate CsLiCdP2O7 with a Short Cutoff Edge

    Inorganic Chemistry · 2016-10-31

    Yaoguo Shen, Sangen Zhao, Bingqing Zhao, Chengmin Ji, Lina Li, Zhihua Sun, Maochun Hong, Junhua Luo

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  36. SrNO3(OH)·H2O: A new member in strontium nitrate hydrate family with an ultraviolet cut-off edge

    Journal of Alloys and Compounds · 2016-11-03

    Lili Liu, Yun Mo Yang, Linping Li, Zhihua Yang, Shilie Pan

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  37. Multiple Fluorine-Substituted Phosphate Germanium Fluorides and Their Thermal Stabilities

    Inorganic Chemistry · 2016-11-18

    Xia Huang, Biao Liu, Rong‐Chuan Zhuang, Yuanming Pan, Jin‐Xiao Mi, Ya‐Xi Huang

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  38. LiRb 2 LaB 2 O 6 : a new rare-earth borate with a MOF-5-like topological structure and a short UV cut-off edge

    Dalton Transactions · 2016-11-28

    Dongdong Xu, Fangfang Zhang, Yanzhou Sun, Zhihua Yang, Bing‐Hua Lei, Lili Liu, Shilie Pan

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  39. Cooperation of Three Chromophores Generates the Water‐Resistant Nitrate Nonlinear Optical Material Bi3TeO6OH(NO3)2

    Angewandte Chemie International Edition · 2016-11-30

    Sangen Zhao, Yi Jin Yang, Yaoguo Shen, Bingqing Zhao, Lina Li, Chengmin Ji, Zhenyue Wu, Daqiang Yuan, Zheshuai Lin, Maochun Hong, Junhua Luo

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  40. Cooperation of Three Chromophores Generates the Water‐Resistant Nitrate Nonlinear Optical Material Bi3TeO6OH(NO3)2

    Angewandte Chemie · 2016-11-30

    Sangen Zhao, Yi Jin Yang, Yaoguo Shen, Bingqing Zhao, Lina Li, Chengmin Ji, Zhenyue Wu, Daqiang Yuan, Zheshuai Lin, Maochun Hong, Junhua Luo

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  41. Ba n+2 Zn n (BO 3 ) n (B 2 O 5 )F n (n = 1, 2): new members of the zincoborate fluoride series with two kinds of isolated B–O units

    Inorganic Chemistry Frontiers · 2016-12-01

    Miriding Mutailipu, Xin Su, Min Zhang, Zhihua Yang, Shilie Pan

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  42. BaBe2BO3F3: A KBBF-Type Deep-Ultraviolet Nonlinear Optical Material with Reinforced [Be2BO3F2]∞ Layers and Short Phase-Matching Wavelength

    Chemistry of Materials · 2016-12-05

    Shu Hai Guo, Xingxing Jiang, Lijuan Liu, Mingjun Xia, Zhi Gang Fang, Xiaoyang Wang, Zheshuai Lin, Chuangtian Chen

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  43. Na2B6O9F2: A Fluoroborate with Short Cutoff Edge and Deep-Ultraviolet Birefringent Property Prepared by an Open High-Temperature Solution Method

    Inorganic Chemistry · 2016-12-14

    Guoqiang Q. Shi, Fangfang Zhang, Bingbing Zhang, Dianwei Hou, Xinglong Chen, Zhihua Yang, Shilie Pan

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  44. A promising lead-free fluoride carbonate SHG material designed from a theoretical perspective

    Dalton Transactions · 2017-01-01

    Jinyu Hu, Zuju Ma, Rongjian Sa, Yongfan Zhang, Kechen Wu

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  45. ACaBO 3 (A = Cs, Rb): two new cubic borates with isolated BO 3 groups

    Dalton Transactions · 2017-01-01

    Ming Wen, Hongping Wu, Xin Su, Juanjuan Lu, Zhihua Yang, Xiaohong Wu, Shilie Pan

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  46. BaCu 2 M IV Q 4 (M IV = Si, Ge, and Sn; Q = S, Se): synthesis, crystal structures, optical performances and theoretical calculations

    RSC Advances · 2017-01-01

    Leyan Nian, Junben Huang, Kui Wu, Zhi Su, Zhihua Yang, Shilie Pan

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  47. Explorations of new UV nonlinear optical materials in the Na 2 CO 3 –CaCO 3 system

    Journal of Materials Chemistry C · 2017-01-01

    Yunxia Song, Min Luo, Dan Zhao, Guang Peng, Chensheng Lin, Ning Ye

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  48. KB(PO 4 )F: a novel acentric deep-ultraviolet material

    Dalton Transactions · 2017-01-01

    Jihong Jiang, Lin-Chuan Zhang, Ya‐Xi Huang, Zhimei Sun, Yuanming Pan, Jin‐Xiao Mi

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  49. Li 2 CdGeSe 4 and Li 2 CdSnSe 4 : biaxial nonlinear optical materials with strong infrared second-order responses and laser-induced damage thresholds influenced by photoluminescence

    Inorganic Chemistry Frontiers · 2017-01-01

    Jian‐Han Zhang, Daniel J. Clark, Ashley Weiland, Stanislav S. Stoyko, Yong Soo Kim, Joon Ik Jang, Jennifer A. Aitken

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  50. Reversible structural phase transition, ferroelectric and switchable dielectric properties of an adduct molecule of hexamethylenetetramine ferrocene carboxylic acid

    RSC Advances · 2017-01-01

    Yun‐Zhi Tang, Yi Liu, Ji‐Xing Gao, Changfeng Wang, Bin Wang, Yu‐Hui Tan, He‐Rui Wen

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