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RESEARCH PAPER · Chemistry of Materials · 2015

Polar Polymorphism: α-, β-, and γ-Pb2Ba4Zn4B14O31–Synthesis, Characterization, and Nonlinear Optical Properties

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Polar Polymorphism: α-, β-, and γ-Pb2Ba4Zn4B14O31–Synthesis, Characterization, and Nonlinear Optical PropertiesOriginalChemInform Abstract: Polar Polymorphism: α‐, β‐, and γ‐Pb2Ba4Zn4B14 O31 — Synthesis, Characterization, and Nonlinear Optical Properties.0K2Pb3(CO3)3F2 and KCdCO3F: Novel Fluoride Carbonates with Layered and 3D Framework Structures42Versatile Coordination Mode of LiNaB8O13 and α- and β-LiKB8O13 via the Flexible Assembly of Four-Connected B5O10 and B3O7 Groups19M 2 Ca 3 B 16 O 28 (M = Rb, Cs): structures analogous to SBBO with three-dimensional open-framework layers10Nonlinear optical response mechanism of noncentrosymmetric lead borate Pb 6 [B 4 O 7 (OH) 2 ] 3 with three crystallographically independent [B 4 O 7 (OH) 2 ] 4− chains8Pb 2 Bi 2 GaB 3 O 11 , a new congruent-melting galloborate containing two types of asymmetric cations with a moderate birefringence5Three new phosphates with isolated P 2 O 7 units: noncentrosymmetric Cs 2 Ba 3 (P 2 O 7 ) 2 and centrosymmetric Cs 2 BaP 2 O 7 and LiCsBaP 2 O 768Design and Syntheses of Three Novel Carbonate Halides: Cs 3 Pb 2 (CO 3 ) 3 I, KBa 2 (CO 3 ) 2 F, and RbBa 2 (CO 3 ) 2 F29Effect of the [Ba 2 BO 3 F] ∞ Layer on the Band Gap: Synthesis, Characterization, and Theoretical Studies of BaZn 2 B 2 O 6 · n Ba 2 BO 3 F ( n = 0, 1, 2)21LiSc(SeO3)2·xH2O (0 ≤ x ≤ 1): New Selenites Revealing Water Molecule-Driven Extremely High Temperature Single-Crystal-to-Single-Crystal Transformations16Synthesis, Characterization, and Theoretical Studies of (Pb4O)Pb2B6O14: A New Lead(II) Borate with Isolated Oxygen-Centered Pb4O Tetrahedra and Large Second Harmonic Generation Response41Ba n+2 Zn n (BO 3 ) n (B 2 O 5 )F n (n = 1, 2): new members of the zincoborate fluoride series with two kinds of isolated B–O units33Controlling the structure and morphology of zinc borate by adjusting the reaction temperature and pH value: formation mechanisms and luminescent properties17Mixed-Metal Carbonate Fluorides as Deep-Ultraviolet Nonlinear Optical Materials259New lead( ii ) borates in the PbO/PbF 2 /H 3 BO 3 ternary phase diagram: syntheses and structures of β-Pb 6 B 10 O 21 and Pb 4 B 8 O 164ScMO(BO 3 ) (M = Ca and Cd): new Sc-based oxyborates featuring interesting edge-sharing sandwich-like chains and UV cut-off edges17Two deep-ultraviolet nonlinear optical alkaline-earth metal borates based on different types of oxoboron clusters56K3MB5O10 (M = Zn and Cd) with d10 configuration: Efficient and reusable catalysts for dehalogenation of halophenols31Synthesis, characterization and determination of standard molar enthalpies of formation of two zinc borates with higher ratio of ZnO/B2O3 by solution calorimetry6Novel borate supramolecular frameworks constructed from isolated B4/B5 clusters and 1-D B17-based chains8Enhanced nonlinear optical activity and Ca2+-conductivity in Са10.5-Pb (VO4)7 ferroelectrics23Flexible coordination of Pb atoms and variable zinc–borate frameworks to construct three Pb 5 Zn 4 B 6 O 18 polymorphs8PbTeGeO 6 : polar rosiaite-type germanate featuring a two dimensional layered structure24Unusual high-temperature reversible phase transition containing dielectric and nonlinear optical switches in host–guest supramolecular crown ether clathrates35Effect of Element Substitution on Structural Transformation and Optical Performances in I2BaMIVQ4 (I = Li, Na, Cu, and Ag; MIV = Si, Ge, and Sn; Q = S and Se)63A Series of Rare-Earth Borates K 7 MRE 2 B 15 O 30 (M = Zn, Cd, Pb; RE = Sc, Y, Gd, Lu) with Large Second Harmonic Generation Responses103Li3.366Mg0.317B2O5: The first pyroborate in the Li2O-MgO-B2O3 system1Syntheses, Crystal Structures and Properties of Two Novel Mixed Anion Hybrids with Formulas of Pb 6 O 2 (BO 3 ) 2 (C 2 O 4 ) and Pb 4 (CO 3 ) 2 (C 2 O 4 )(OH) 21Non-centrosymmetric BaNaP3O9 with a short deep-ultraviolet cutoff edge14Assisting the Effective Design of Polar Iodates with Early Transition-Metal Oxide Fluoride Anions206Polymorphic Smooth Interfaces Formation Based on the Biphasic BaTeMo2O9 Using Top Multi-Seeded Growth9Two new mixed metal borates with the large birefringence in borates system confirmed by a disordered crystal optical calculation method6Centrosymmetric (NH4)2SbCl(SO4)2 and Non-centrosymmetric (NH4)SbCl2(SO4): Synergistic Effect of Hydrogen-Bonding Interactions and Lone-Pair Cations on the Framework Structures and Macroscopic Centricities89Li2BaSc(BO3)2F and LiBa2Pb(BO3)2F with Layered Structures featuring Special Li−O/F Configurations11Two Lanthanide Borate Chlorides LnB4O6(OH)2Cl (Ln = La, Ce) with Wide Ultraviolet Transmission Windows and Large Second-Harmonic Generation Responses25[C5H12N]SnCl3: A Tin Halide Organic–Inorganic Hybrid as an Above‐Room‐Temperature Solid‐State Nonlinear Optical Switch56Ba 3 B 10 O 17 F 2 ·0.1KF: the first mixed alkali/alkaline-earth metal fluorooxoborate with unprecedented double-layered B–O/F anionic arrangement17Band structure engineering of boron–oxygen-based materials for efficient charge separation12Structural insights into three phosphates with distinct polyanionic configurations20A New Cadmium‐Based Pb2Cd3(PO4)2(P2O7) with Two Types of Isolated P–O Groups18Crystallographic Investigations into the Polar Polymorphism of BaTeW2O9: Phase Transformation, Controlled Crystallization, and Linear and Nonlinear Optical Properties26Ba4M(CO3)2(BO3)2 (M=Ba, Sr): two borate-carbonates synthesized by open high temperature solution method29Thermoluminescence spectra of Tm doped ZnB2O4 phosphor prepared via a wet-chemical synthesis19K9[B4O5(OH)4]3(CO3)X·7H2O (X = Cl, Br): Syntheses, Characterizations, and Theoretical Studies of Noncentrosymmetric Halogen Borate–Carbonates with Short UV Cutoff Edges16Research and Development of Zincoborates: Crystal Growth, Structural Chemistry and Physicochemical Properties20Pb 3 Ba 3 Zn 6 (BO 3 ) 8 and α-BaZn 2 (BO 3 ) 2 : new members of the zincoborates containing two different dimensional Zn–O units8Al8(BO3)4(B2O5)F8: A F-Containing Aluminum Borate Featuring Two Types of Isolated B–O Groups12Crystal structure, theoretical studies and luminescent properties of a new borate Na 3 GdB 8 O 15 with one-dimensional broad-banded anionic framework13Synthesis, characterization and crystal structure of a new mixed alkali and alkaline-earth metal borate Rb 9 Ba 24 (BO 3 ) 196α-, β-Pb4B2O7 and α-, β-Pb4B6O13: Polymorphism drives changes in structure and performance15Infrared Nonlinear Optical Polymorphs α- and β-SrCu 2 SnS 4 Exhibiting Large Second Harmonic Generation Responses with Requisite Phase-Matching Behavior44The Non-Concentration-Quenching Phosphor Ca3Eu2B4O12 for WLED Application176A review on phase transition and structure-performance relationship of second-order nonlinear optical polymorphs107Borates: A Rich Source for Optical Materials1089Sb6O7(SO4)2: A Promising Ultraviolet Nonlinear Optical Material with an Enhanced Second‐Harmonic‐Generation Response Activated by SbIII Lone‐Pair Stereoactivity62BaB 4 O 5 F 4 with reversible phase transition featuring unprecedented fundamental building blocks of [B 16 O 21 F 16 ] in the α -phase and [B 4 O 6 F 4 ] in the β -phase19New Polymorphism for Ba3Zn2(BO3)3F with Two Polymorphs Exhibiting Anomalous Phase Transition2Different mechanism of stereochemical activity and birefringence in post-transition metal halides: A first-principles investigation1Newly emerging borate-based nonlinear optical materials for organic pollutant degradation: A review33Polar polymorphism: β-Ca2[B5O8(OH)]2[B(OH)3]·H2O—synthesis, structure and nonlinear optical property11The First Mixed Calcium Zinc Borate with a Flexible [B8O17] Fundamental Building Block and Short UV Cutoff Edge7An Effective Strategy for Designing Nonlinear Optical Crystals by Combining the Structure‐Directing Property of Oxyfluorides with Chemical Substitution73An Effective Strategy for Designing Nonlinear Optical Crystals by Combining the Structure‐Directing Property of Oxyfluorides with Chemical Substitution10Finding a Series of BaBOF3 Fluorooxoborate Polymorphs with Tunable Symmetries: A Simple but Flexible Case37Designing A New Infrared Nonlinear Optical Material, β‐BaGa 2 Se 4 Inspired by the Phase Transition of the BaB 2 O 4 (BBO) Crystal75Designing A New Infrared Nonlinear Optical Material, β‐BaGa2Se4 Inspired by the Phase Transition of the BaB2O4 (BBO) Crystal13Ba 2 [WO 3 F(IO 3 )][WO 3 F 2 ]: the first polar fluorinated tungsten iodate featuring a direct W–O–I bond7Li 6.58 Na 7.43 Sr 4 (B 9 O 18 )(B 12 O 24 )Cl: unprecedented combination of the largest two highly polymerized isolated B–O clusters with novel isolated B 9 O 18 FBB18Tellurate polymorphs with high-performance nonlinear optical switch property and wide mid-IR transparency19α-LiMB 9 O 15 (M = Sr, Pb): flexible [B 3 O 7 ] units leading to the low temperature phase of β-LiMB 9 O 15 (M = Sr, Pb)11Novel Dy incorporated Ca3Y2B4O12 phosphor: Insights into the structure, broadband emission, photoluminescence and cathodoluminescence characteristics21Polymorphism of LiCdBO3: Crystal structures, phase transitions and optical characterizations10Ba1.09Pb0.91Be2(BO3)2F2: The First Pb-Containing Beryllium Borate Fluoride with Trigonal Prismatic PbO6 and 2D [Be3B3O6F3]∞ Layers7Solvent-Mediated Separation and Reversible Transformation of 1D Supramolecular Polymorphs Built from [W10O32]4– Templated 48-Nuclei Silver(I) Cluster85Designing a Strong Second-Harmonic Generation Polar Iodate by the Structure-Directing Properties of the “Tumbler-like” [Zn(IO3)(I2O5(OH))] Polyanions20Sr2[B5O8(OH)]2 ⋅ [B(OH)3] ⋅ H2O: A Strontium Borate That Shows Deep‐Ultraviolet‐Transparent Nonlinear Optical Properties17From β-KB3O4F2 to α-KB3O4F2: Phase Transition-Directed Great Changes in Structure and Optical Anisotropy4Highly stable and reversible birefringence switching triggered by thermally stimulated phase transition1Rational design of a high-efficiency lead halide organic-inorganic hybrid nonlinear optical switch via molecular engineering5

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  1. ChemInform Abstract: Polar Polymorphism: α‐, β‐, and γ‐Pb2Ba4Zn4B14 O31 — Synthesis, Characterization, and Nonlinear Optical Properties.

    ChemInform · 2015-09-01

    Hongwei Yu, Hongping Wu, Qun Jing, Zhihua Yang, P. Shiv Halasyamani, Shilie Pan

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  2. K2Pb3(CO3)3F2 and KCdCO3F: Novel Fluoride Carbonates with Layered and 3D Framework Structures

    Inorganic Chemistry · 2015-10-21

    Yuan Hua Lin, Chun‐Li Hu, Jiang‐Gao Mao

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  3. Versatile Coordination Mode of LiNaB8O13 and α- and β-LiKB8O13 via the Flexible Assembly of Four-Connected B5O10 and B3O7 Groups

    Inorganic Chemistry · 2015-12-21

    Donghai An, Qingrong Kong, Min Zhang, Yun Mo Yang, Danni Li, Zhihua Yang, Shilie Pan, Huimin Chen, Zhi Su, Yi Sun, Miriding Mutailipu

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  4. M 2 Ca 3 B 16 O 28 (M = Rb, Cs): structures analogous to SBBO with three-dimensional open-framework layers

    RSC Advances · 2016-01-01

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  5. Nonlinear optical response mechanism of noncentrosymmetric lead borate Pb 6 [B 4 O 7 (OH) 2 ] 3 with three crystallographically independent [B 4 O 7 (OH) 2 ] 4− chains

    RSC Advances · 2016-01-01

    Xuefei Wang, Fangfang Zhang, Bing‐Hua Lei, Zhihua Yang, Shilie Pan

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  6. Pb 2 Bi 2 GaB 3 O 11 , a new congruent-melting galloborate containing two types of asymmetric cations with a moderate birefringence

    Dalton Transactions · 2016-01-01

    Lili Liu, Yun Mo Yang, Linping Li, Zhihua Yang, Shilie Pan

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  7. Three new phosphates with isolated P 2 O 7 units: noncentrosymmetric Cs 2 Ba 3 (P 2 O 7 ) 2 and centrosymmetric Cs 2 BaP 2 O 7 and LiCsBaP 2 O 7

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  8. Design and Syntheses of Three Novel Carbonate Halides: Cs 3 Pb 2 (CO 3 ) 3 I, KBa 2 (CO 3 ) 2 F, and RbBa 2 (CO 3 ) 2 F

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  9. Effect of the [Ba 2 BO 3 F] ∞ Layer on the Band Gap: Synthesis, Characterization, and Theoretical Studies of BaZn 2 B 2 O 6 · n Ba 2 BO 3 F ( n = 0, 1, 2)

    Inorganic Chemistry · 2016-04-27

    Hongping Wu, Xin Su, Shujuan Han, Zhihua Yang, Shilie Pan

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  10. LiSc(SeO3)2·xH2O (0 ≤ x ≤ 1): New Selenites Revealing Water Molecule-Driven Extremely High Temperature Single-Crystal-to-Single-Crystal Transformations

    Crystal Growth & Design · 2016-05-04

    Seung Yoon Song, Kang Min Ok

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  11. Synthesis, Characterization, and Theoretical Studies of (Pb4O)Pb2B6O14: A New Lead(II) Borate with Isolated Oxygen-Centered Pb4O Tetrahedra and Large Second Harmonic Generation Response

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    Fangfang Zhang, Fangyuan Zhang, Bing‐Hua Lei, Zhihua Yang, Shilie Pan

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  12. Ba n+2 Zn n (BO 3 ) n (B 2 O 5 )F n (n = 1, 2): new members of the zincoborate fluoride series with two kinds of isolated B–O units

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  13. Controlling the structure and morphology of zinc borate by adjusting the reaction temperature and pH value: formation mechanisms and luminescent properties

    RSC Advances · 2016-12-21

    Pan Liang, Tuoheti Zuolaguli, Zhi‐Hong Liu

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  14. Mixed-Metal Carbonate Fluorides as Deep-Ultraviolet Nonlinear Optical Materials

    Journal of the American Chemical Society · 2016-12-24

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  15. New lead( ii ) borates in the PbO/PbF 2 /H 3 BO 3 ternary phase diagram: syntheses and structures of β-Pb 6 B 10 O 21 and Pb 4 B 8 O 16

    New Journal of Chemistry · 2017-01-01

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  16. ScMO(BO 3 ) (M = Ca and Cd): new Sc-based oxyborates featuring interesting edge-sharing sandwich-like chains and UV cut-off edges

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  17. Two deep-ultraviolet nonlinear optical alkaline-earth metal borates based on different types of oxoboron clusters

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  18. K3MB5O10 (M = Zn and Cd) with d10 configuration: Efficient and reusable catalysts for dehalogenation of halophenols

    Applied Catalysis B: Environmental · 2017-01-06

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  19. Synthesis, characterization and determination of standard molar enthalpies of formation of two zinc borates with higher ratio of ZnO/B2O3 by solution calorimetry

    Journal of Thermal Analysis and Calorimetry · 2017-03-14

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  20. Novel borate supramolecular frameworks constructed from isolated B4/B5 clusters and 1-D B17-based chains

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  21. Enhanced nonlinear optical activity and Ca2+-conductivity in Са10.5-Pb (VO4)7 ferroelectrics

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  22. Flexible coordination of Pb atoms and variable zinc–borate frameworks to construct three Pb 5 Zn 4 B 6 O 18 polymorphs

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  23. PbTeGeO 6 : polar rosiaite-type germanate featuring a two dimensional layered structure

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  24. Unusual high-temperature reversible phase transition containing dielectric and nonlinear optical switches in host–guest supramolecular crown ether clathrates

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  26. A Series of Rare-Earth Borates K 7 MRE 2 B 15 O 30 (M = Zn, Cd, Pb; RE = Sc, Y, Gd, Lu) with Large Second Harmonic Generation Responses

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  27. Li3.366Mg0.317B2O5: The first pyroborate in the Li2O-MgO-B2O3 system

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  28. Syntheses, Crystal Structures and Properties of Two Novel Mixed Anion Hybrids with Formulas of Pb 6 O 2 (BO 3 ) 2 (C 2 O 4 ) and Pb 4 (CO 3 ) 2 (C 2 O 4 )(OH) 2

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  29. Non-centrosymmetric BaNaP3O9 with a short deep-ultraviolet cutoff edge

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  30. Assisting the Effective Design of Polar Iodates with Early Transition-Metal Oxide Fluoride Anions

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  31. Polymorphic Smooth Interfaces Formation Based on the Biphasic BaTeMo2O9 Using Top Multi-Seeded Growth

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  32. Two new mixed metal borates with the large birefringence in borates system confirmed by a disordered crystal optical calculation method

    Journal of Alloys and Compounds · 2018-09-01

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  33. Centrosymmetric (NH4)2SbCl(SO4)2 and Non-centrosymmetric (NH4)SbCl2(SO4): Synergistic Effect of Hydrogen-Bonding Interactions and Lone-Pair Cations on the Framework Structures and Macroscopic Centricities

    Crystal Growth & Design · 2018-09-11

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  34. Li2BaSc(BO3)2F and LiBa2Pb(BO3)2F with Layered Structures featuring Special Li−O/F Configurations

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  35. Two Lanthanide Borate Chlorides LnB4O6(OH)2Cl (Ln = La, Ce) with Wide Ultraviolet Transmission Windows and Large Second-Harmonic Generation Responses

    Inorganic Chemistry · 2018-11-14

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  36. [C5H12N]SnCl3: A Tin Halide Organic–Inorganic Hybrid as an Above‐Room‐Temperature Solid‐State Nonlinear Optical Switch

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  37. Ba 3 B 10 O 17 F 2 ·0.1KF: the first mixed alkali/alkaline-earth metal fluorooxoborate with unprecedented double-layered B–O/F anionic arrangement

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  38. Band structure engineering of boron–oxygen-based materials for efficient charge separation

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  39. Structural insights into three phosphates with distinct polyanionic configurations

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  40. A New Cadmium‐Based Pb2Cd3(PO4)2(P2O7) with Two Types of Isolated P–O Groups

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  41. Crystallographic Investigations into the Polar Polymorphism of BaTeW2O9: Phase Transformation, Controlled Crystallization, and Linear and Nonlinear Optical Properties

    Crystal Growth & Design · 2019-01-24

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  42. Ba4M(CO3)2(BO3)2 (M=Ba, Sr): two borate-carbonates synthesized by open high temperature solution method

    Science China Materials · 2019-01-29

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  43. Thermoluminescence spectra of Tm doped ZnB2O4 phosphor prepared via a wet-chemical synthesis

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  44. K9[B4O5(OH)4]3(CO3)X·7H2O (X = Cl, Br): Syntheses, Characterizations, and Theoretical Studies of Noncentrosymmetric Halogen Borate–Carbonates with Short UV Cutoff Edges

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  45. Research and Development of Zincoborates: Crystal Growth, Structural Chemistry and Physicochemical Properties

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  46. Pb 3 Ba 3 Zn 6 (BO 3 ) 8 and α-BaZn 2 (BO 3 ) 2 : new members of the zincoborates containing two different dimensional Zn–O units

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  47. Al8(BO3)4(B2O5)F8: A F-Containing Aluminum Borate Featuring Two Types of Isolated B–O Groups

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  48. Crystal structure, theoretical studies and luminescent properties of a new borate Na 3 GdB 8 O 15 with one-dimensional broad-banded anionic framework

    Dalton Transactions · 2020-01-01

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  49. Synthesis, characterization and crystal structure of a new mixed alkali and alkaline-earth metal borate Rb 9 Ba 24 (BO 3 ) 19

    New Journal of Chemistry · 2020-01-01

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  50. α-, β-Pb4B2O7 and α-, β-Pb4B6O13: Polymorphism drives changes in structure and performance

    Science China Materials · 2020-01-20

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