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RESEARCH PAPER · Chemical Science · 2024

Exploring a new short-wavelength nonlinear optical fluoride material featuring unprecedented polar cis -[Zr 6 F 34 ] 10− clusters

Mei Yan, Ru‐Ling Tang, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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Exploring a new short-wavelength nonlinear optical fluoride material featuring unprecedented polar cis -[Zr 6 F 34 ] 10− clustersOriginalEquivalent cation-tuning to realize a new Ce( iv ) fluoride with excellent comprehensive nonlinear optical performances12KBa 3 M 2 F 14 Cl (M = Zr, Hf): novel short-wavelength mixed metal halides with the largest second-harmonic generation responses contributed by mixed functional moieties37Pb 2 (SeO 3 )(SiF 6 ): the first selenite fluorosilicate with a wide bandgap and large birefringence achieved through perfluorinated group modification45Salt-inclusion chalcogenides with d-orbital components: unveiling remarkable nonlinear optical properties and dual-band photoluminescence10Wide band gap selenide infrared nonlinear optical materials A II Mg 6 Ga 6 Se 16 with strong SHG responses and high laser-induced damage thresholds31Centrosymmetric CaBaMF8 and Noncentrosymmetric Li2CaMF8 (M = Zr, Hf): Dimension Variation and Nonlinear Optical Activity Resulting from an Isovalent Cation Substitution-Oriented Design17Complexity of the KNa2ZrF7, KNa2HfF7, and KNa2(Hf,Zr)F7 compounds4Three types of promising functional building units for designing metal halide nonlinear optical crystals20Centric Sc(HPO3)(H2PO3)(H2O) and Acentric Sc(H2PO3)3: Two Ultraviolet Scandium Phosphite Optical Crystals12A Universal Design Strategy Achieving Large Birefringence and Short Phase‐Matching Capability of Optical Materials via Dissimilating Non‐π‐Conjugated Units6From CaBaM2F12 to K2BaM2F12 (M = Zr, Hf): Heterovalent Cation-Substitution-Induced Symmetry Break and Nonlinear-Optical Activity11Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites56Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals66Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals8KSb2F7·2KNO3: Unveiling the peak birefringence in inorganic antimony oxysalts10From Pb6(HPO3)(H2PO3)Cl9 to Pb6(HPO3)2Br8(H2O)·H2O: Halogen Regulation to Achieve Inorganic Metal Phosphite Halide Nonlinear Optical Material with Unprecedented Pb-Centered Polyhedral Units13(C5H12N2S)Hg(NO3)2: A Mercury Nitrate Nonlinear Optical Crystal Motivated by Heteroatom Coordination Strategy9A DFT study of the second-order nonlinear optical properties of [22]smaragdyrin-BF2-NiII porphyrin fused hybrids4From HgGa2(SeO3)4 to Hg2Ga(SeO3)2F: The first HgI-based selenite birefringent crystal triggered by linear groups and fluoride ions29Strategically designed anisotropic organic–inorganic metal halides (OIMHs) with superior balance between bandgap and birefringence12A π-conjugated organic molecule-modified strategy to achieve high-performance metal nitrate birefringent crystals9CdF(C 6 H 4 NO 2 )(H 2 O): a UV nonlinear optical material with unprecedented SHG and birefringence via π-conjugated rings and a unique “Warren truss structure”11Greatly enhancing birefringence of fluorosilicates through the synergetic effect of functional units13Hg 2 (SeO 3 )(TeO 3 ): a novel tellurite–selenite birefringent crystal achieved by assembling multiple functional groups11Significant enhancement in the birefringence of metal phosphite halides via the introduction of π-conjugated cations17(C6H10N2)ZnX4·H2O (X=Cl and Br): Excellent nonlinear optical properties and temperature induced photoluminescence for encryption23KHfF5: a new representative in the M I M IVF5 family0LiAgCe2F10(H2O)2: Focusing on the Cation Size Effect to Reasonably Design a Nonlinear Optical Hydrated Cerium(IV) Fluoride10Synthesis, characterization and theoretical calculations of a new rare-earth fluoride with a DUV cutoff edge1Planar [HgCl 3 ] and V‑Shaped [HgCl 2 ] Units Synergistically Creating a Prominent Halide Birefringent Crystal β ‐CsHg 2 Cl 5 with Wide‐Spectrum7Synthesis, structure and properties of a new nitrate halide optical material: Cs3Zn(NO3)Br40Optimizing the Hydrogen-Bond Network Drives Cadmium Ce(IV) Fluoride Hydrate with Significantly Enhanced Optical Anisotropy8Structure, thermal properties and phase transition in RbCdHfF7: experiments and lattice dynamics calculations0K5NaZr4F22(H2O)2: A Hydrated Zirconium Fluoride with a Second-Harmonic Generation Effect and a Short Ultraviolet Cutoff Edge Induced by Cosubstitution with Heterovalent Cations6Breaking the Deep‐UV Transparency/Optical Nonlinearity Trade‐Off: Three‐Parameter Optimization in Oxyfluorides by Tailoring d 0 ‐Metal Incorporation10Breaking the Deep‐UV Transparency/Optical Nonlinearity Trade‐Off: Three‐Parameter Optimization in Oxyfluorides by Tailoring d 0 ‐Metal Incorporation4Third-order nonlinear optical properties of covalently linked phenyl-bridged 3-pyrrolyl BODIPY–BODIPY complexes: a theoretical study0Integrating Fluorinated [BF 4 ] Anion With π‐Conjugated Six‐Membered Rings for Short‐Wavelength UV Frequency Conversion17Integrating Fluorinated [BF 4 ] Anion With π‐Conjugated Six‐Membered Rings for Short‐Wavelength UV Frequency Conversion2ZnGa(SeO 3 ) 2 F: a UV transparent birefringent crystal explored in M( ii )–IIIA–selenite–F systems2REV 3 (BO 3 ) 4 (RE = La–Nd): a series of rare earth vanadoborates exhibit large birefringence induced by distorted V III O 6 groups2Strategic Oxygen‐Substitution in Perfluorinated Ce(IV) Coordination Frameworks Triggers Dual‐Wavelength Nonlinear Optical Materials With Exceptional Performances3Strategic Oxygen‐Substitution in Perfluorinated Ce(IV) Coordination Frameworks Triggers Dual‐Wavelength Nonlinear Optical Materials With Exceptional Performances32Deep-Ultraviolet Transparent Zr/Hf Fluorides with Second-Harmonic Generation Effects Induced by Alkali-Metal Modulation2Reversed Quantum‐Well Engineering Unlocks Large Ultraviolet Chiral Nonlinear Optical Response in a Water‐Resistant 2D Hybrid Fluorozirconate0Reversed Quantum‐Well Engineering Unlocks Large Ultraviolet Chiral Nonlinear Optical Response in a Water‐Resistant 2D Hybrid Fluorozirconate0Non-π-conjugated tetrahedra-based optical crystals: The improvement of the linear and nonlinear optical properties by the combination of trigonal pyramidal [XO3] (X = I, Se, Te) units1Multidimensional Cation Modulation toward Phase-Matchable Nonlinear Optical Fluorides with Short UV Cutoff Edges0

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48 direct citing papers saved.

  1. Equivalent cation-tuning to realize a new Ce( iv ) fluoride with excellent comprehensive nonlinear optical performances

    Inorganic Chemistry Frontiers · 2024-01-01

    Beibei Zhang, Wen‐Ye Gao, Wei Lin Xu, L. Ma, Wenlong Liu, Ru‐Ling Tang, Sheng‐Ping Guo

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  2. KBa 3 M 2 F 14 Cl (M = Zr, Hf): novel short-wavelength mixed metal halides with the largest second-harmonic generation responses contributed by mixed functional moieties

    Chemical Science · 2024-01-01

    Mei Yan, Chun‐Li Hu, Ru‐Ling Tang, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  3. Pb 2 (SeO 3 )(SiF 6 ): the first selenite fluorosilicate with a wide bandgap and large birefringence achieved through perfluorinated group modification

    Chemical Science · 2024-01-01

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  4. Salt-inclusion chalcogenides with d-orbital components: unveiling remarkable nonlinear optical properties and dual-band photoluminescence

    Chemical Science · 2024-01-01

    Shao‐Min Pei, Ming‐Shu Zhang, Fan Wu, Yan Guo, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  5. Wide band gap selenide infrared nonlinear optical materials A II Mg 6 Ga 6 Se 16 with strong SHG responses and high laser-induced damage thresholds

    Chemical Science · 2024-01-01

    Linan Wang, Dongdong Chu, Zhihua Yang, Junjie Li, Shilie Pan

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  6. Centrosymmetric CaBaMF8 and Noncentrosymmetric Li2CaMF8 (M = Zr, Hf): Dimension Variation and Nonlinear Optical Activity Resulting from an Isovalent Cation Substitution-Oriented Design

    Inorganic Chemistry · 2024-03-06

    Mei Yan, Ru‐Ling Tang, Wei Xu, Wenlong Liu, Sheng‐Ping Guo

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  7. Complexity of the KNa2ZrF7, KNa2HfF7, and KNa2(Hf,Zr)F7 compounds

    Journal of Solid State Chemistry · 2024-03-11

    Oksana Matselko, Morgane Poupon, Erika Samoľová, Zuzana Vasková, Blanka Kubíková, Zuzana Netriová, Matej Mičušík, Miroslav Boča

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  8. Three types of promising functional building units for designing metal halide nonlinear optical crystals

    Chinese Journal of Structural Chemistry · 2024-04-01

    Jiajing Wu, Ru‐Ling Tang, Sheng‐Ping Guo

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  9. Centric Sc(HPO3)(H2PO3)(H2O) and Acentric Sc(H2PO3)3: Two Ultraviolet Scandium Phosphite Optical Crystals

    Inorganic Chemistry · 2024-04-11

    Liang Ma, Yi‐Lei Lv, Xiao-Fang Ao, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  10. A Universal Design Strategy Achieving Large Birefringence and Short Phase‐Matching Capability of Optical Materials via Dissimilating Non‐π‐Conjugated Units

    Advanced Optical Materials · 2024-04-18

    Huan Zhou, Shan Shu, Abudukadi Tudi, Wenqi Jin, Shilie Pan, Zhihua Yang

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  11. From CaBaM2F12 to K2BaM2F12 (M = Zr, Hf): Heterovalent Cation-Substitution-Induced Symmetry Break and Nonlinear-Optical Activity

    Inorganic Chemistry · 2024-06-04

    Mei Yan, Ru‐Ling Tang, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  12. Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites

    Coordination Chemistry Reviews · 2024-06-15

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  13. Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals

    Angewandte Chemie International Edition · 2024-06-26

    Yang Li, Kang Min Ok

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  14. Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals

    Angewandte Chemie · 2024-06-26

    Yang Li, Kang Min Ok

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  15. KSb2F7·2KNO3: Unveiling the peak birefringence in inorganic antimony oxysalts

    Chinese Chemical Letters · 2024-06-26

    Qin Lin Wang, Han Luo, Luli Wang, Ling Huang, Liling Cao, Xuehua Dong, Guohong Zou

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  16. From Pb6(HPO3)(H2PO3)Cl9 to Pb6(HPO3)2Br8(H2O)·H2O: Halogen Regulation to Achieve Inorganic Metal Phosphite Halide Nonlinear Optical Material with Unprecedented Pb-Centered Polyhedral Units

    Inorganic Chemistry · 2024-07-08

    Ru‐Ling Tang, Liang Ma, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo

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  17. (C5H12N2S)Hg(NO3)2: A Mercury Nitrate Nonlinear Optical Crystal Motivated by Heteroatom Coordination Strategy

    Inorganic Chemistry · 2024-07-31

    Yi‐Lei Lv, Liang Ma, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  18. A DFT study of the second-order nonlinear optical properties of [22]smaragdyrin-BF2-NiII porphyrin fused hybrids

    Computational and Theoretical Chemistry · 2024-10-02

    Tingting Liu, Yan Yan, Yu Yang, Na Hou

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  19. From HgGa2(SeO3)4 to Hg2Ga(SeO3)2F: The first HgI-based selenite birefringent crystal triggered by linear groups and fluoride ions

    Chinese Chemical Letters · 2024-11-03

    Pengfei Li, Chun‐Li Hu, Bo Zhang, Jiang‐Gao Mao, Fang Kong

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  20. Strategically designed anisotropic organic–inorganic metal halides (OIMHs) with superior balance between bandgap and birefringence

    Inorganic Chemistry Frontiers · 2024-12-16

    Mingchang Wang, Huaiyu Wu, Miao‐Bin Xu, Jiajia Li, Ke‐Zhao Du, Jin Chen

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  21. A π-conjugated organic molecule-modified strategy to achieve high-performance metal nitrate birefringent crystals

    Inorganic Chemistry Frontiers · 2025-01-01

    Yi‐Lei Lv, Liang Ma, Guo-Ren Zhu, Bing-Wei Miao, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  22. CdF(C 6 H 4 NO 2 )(H 2 O): a UV nonlinear optical material with unprecedented SHG and birefringence via π-conjugated rings and a unique “Warren truss structure”

    Inorganic Chemistry Frontiers · 2025-01-01

    Jie Gou, Yaolong Zhu, Xin Su, Can Hui Yang, YunJie Wang, Qingwen Zhu, Yi Xiong, Qi Wu

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  23. Greatly enhancing birefringence of fluorosilicates through the synergetic effect of functional units

    Inorganic Chemistry Frontiers · 2025-01-01

    Liang Ma, Yi‐Lei Lv, Bing-Wei Miao, Guo-Ren Zhu, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  24. Hg 2 (SeO 3 )(TeO 3 ): a novel tellurite–selenite birefringent crystal achieved by assembling multiple functional groups

    Journal of Materials Chemistry C · 2025-01-01

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  25. Significant enhancement in the birefringence of metal phosphite halides via the introduction of π-conjugated cations

    Chemical Science · 2025-01-01

    Ru‐Ling Tang, Yue Wang, Yi‐Lei Lv, Bing-Wei Miao, Wenlong Liu, Sheng‐Ping Guo

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  26. (C6H10N2)ZnX4·H2O (X=Cl and Br): Excellent nonlinear optical properties and temperature induced photoluminescence for encryption

    Chemical Engineering Journal · 2025-03-09

    Chuanying Shen, Chenyi Zhang, Chenyi Zhang, Qiwei Xing, Defu Sun, Kui Wu, Bingbing Zhang, Jiyang Wang, Jiyang Wang, Duanliang Wang

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  27. KHfF5: a new representative in the M I M IVF5 family

    Acta Crystallographica Section C Structural Chemistry · 2025-03-14

    O. P. Grigorieva, В. А. Тафеенко, Peter S. Berdonosov, В. А. Долгих

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  28. LiAgCe2F10(H2O)2: Focusing on the Cation Size Effect to Reasonably Design a Nonlinear Optical Hydrated Cerium(IV) Fluoride

    Inorganic Chemistry · 2025-03-24

    Wen-Ye Gao, Yi‐Lei Lv, Siyu Ma, Cheng Chen, Wenlong Liu, Ru‐Ling Tang

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  29. Synthesis, characterization and theoretical calculations of a new rare-earth fluoride with a DUV cutoff edge

    Journal of Molecular Structure · 2025-04-08

    Xiaotian Ma, Shaohua Liu, Xifa Long, Yun Mo Yang

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  30. Planar [HgCl 3 ] and V‑Shaped [HgCl 2 ] Units Synergistically Creating a Prominent Halide Birefringent Crystal β ‐CsHg 2 Cl 5 with Wide‐Spectrum

    Advanced Optical Materials · 2025-06-03

    Yi‐Lei Lv, Ru‐Ling Tang, Cheng Chen, Liang Ma, Wenlong Liu, Sheng‐Ping Guo

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  31. Synthesis, structure and properties of a new nitrate halide optical material: Cs3Zn(NO3)Br4

    Journal of Solid State Chemistry · 2025-07-03

    Yueling Sun, Jian-Cheng Qiao, An-Hua Gong

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  32. Optimizing the Hydrogen-Bond Network Drives Cadmium Ce(IV) Fluoride Hydrate with Significantly Enhanced Optical Anisotropy

    Inorganic Chemistry · 2025-07-25

    Wen-Ye Gao, Siyu Ma, Bing-Wei Miao, Wenfeng Zhou, Wenlong Liu, Ru‐Ling Tang

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  33. Structure, thermal properties and phase transition in RbCdHfF7: experiments and lattice dynamics calculations

    Solid State Sciences · 2025-08-12

    Evgeniy V. Bogdanov, Мaxim S. Моlokeev, М. В. Горев, A. V. Kartashev, Maxim S. Pavlovskiy, Evgeniy I. Pogoreltsev, N. M. Laptash, Igor N. Flerov

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  34. K5NaZr4F22(H2O)2: A Hydrated Zirconium Fluoride with a Second-Harmonic Generation Effect and a Short Ultraviolet Cutoff Edge Induced by Cosubstitution with Heterovalent Cations

    Inorganic Chemistry · 2025-08-27

    Bing-Wei Miao, Guo-Ren Zhu, Ling Wang, Wenfeng Zhou, Wenlong Liu, Ru‐Ling Tang

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  35. Breaking the Deep‐UV Transparency/Optical Nonlinearity Trade‐Off: Three‐Parameter Optimization in Oxyfluorides by Tailoring d 0 ‐Metal Incorporation

    Angewandte Chemie International Edition · 2025-09-16

    Xiaotian Zhang, Xingxing Jiang, Hui Gao, Kaining Duanmu, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  36. Breaking the Deep‐UV Transparency/Optical Nonlinearity Trade‐Off: Three‐Parameter Optimization in Oxyfluorides by Tailoring d 0 ‐Metal Incorporation

    Angewandte Chemie · 2025-09-16

    Xiaotian T. Zhang, Xingxing Jiang, Hui Ming Gao, Kaining Duanmu, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  37. Third-order nonlinear optical properties of covalently linked phenyl-bridged 3-pyrrolyl BODIPY–BODIPY complexes: a theoretical study

    Theoretical Chemistry Accounts · 2025-11-14

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  38. Integrating Fluorinated [BF 4 ] Anion With π‐Conjugated Six‐Membered Rings for Short‐Wavelength UV Frequency Conversion

    Angewandte Chemie International Edition · 2025-11-26

    Xiangyu Long, Fuming Li, Haotian Qiu, Xueling Hou, Juanjuan Lu, Junjie Li, Zhihua Yang, Jinhui Cao, Shilie Pan, Miriding Mutailipu

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  39. Integrating Fluorinated [BF 4 ] Anion With π‐Conjugated Six‐Membered Rings for Short‐Wavelength UV Frequency Conversion

    Angewandte Chemie · 2025-11-26

    Xiangyu Long, Fuming Li, Haotian Qiu, Xueling Hou, Juanjuan Lu, Junjie Li, Zhihua Yang, Jinhui Cao, Shilie Pan, Miriding Mutailipu

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  40. ZnGa(SeO 3 ) 2 F: a UV transparent birefringent crystal explored in M( ii )–IIIA–selenite–F systems

    Inorganic Chemistry Frontiers · 2025-12-20

    Tian-Tian He, C Hu, Ya-Ping Gong, Jiang‐Gao Mao, Fang Kong

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  41. REV 3 (BO 3 ) 4 (RE = La–Nd): a series of rare earth vanadoborates exhibit large birefringence induced by distorted V III O 6 groups

    Chemical Communications · 2026-01-01

    Yu-Long Wei, Wen-Dong Yao, Yi‐Lei Lv, Liang Ma, Ru‐Ling Tang

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  42. Strategic Oxygen‐Substitution in Perfluorinated Ce(IV) Coordination Frameworks Triggers Dual‐Wavelength Nonlinear Optical Materials With Exceptional Performances

    Angewandte Chemie · 2026-01-16

    Ru‐Ling Tang, Wen‐Ye Gao, Guo-Ren Zhu, Yang Chi, Liang Ma, Wenlong Liu, Sheng‐Ping Guo

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  43. Strategic Oxygen‐Substitution in Perfluorinated Ce(IV) Coordination Frameworks Triggers Dual‐Wavelength Nonlinear Optical Materials With Exceptional Performances

    Angewandte Chemie International Edition · 2026-01-16

    Ru‐Ling Tang, Wen‐Ye Gao, Guo-Ren Zhu, Yang Chi, Liang Ma, Wenlong Liu, Sheng‐Ping Guo

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  44. Deep-Ultraviolet Transparent Zr/Hf Fluorides with Second-Harmonic Generation Effects Induced by Alkali-Metal Modulation

    Inorganic Chemistry · 2026-06-26

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  45. Reversed Quantum‐Well Engineering Unlocks Large Ultraviolet Chiral Nonlinear Optical Response in a Water‐Resistant 2D Hybrid Fluorozirconate

    Angewandte Chemie International Edition · 2026-08-05

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  46. Reversed Quantum‐Well Engineering Unlocks Large Ultraviolet Chiral Nonlinear Optical Response in a Water‐Resistant 2D Hybrid Fluorozirconate

    Angewandte Chemie · 2026-08-05

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  47. Non-π-conjugated tetrahedra-based optical crystals: The improvement of the linear and nonlinear optical properties by the combination of trigonal pyramidal [XO3] (X = I, Se, Te) units

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  48. Multidimensional Cation Modulation toward Phase-Matchable Nonlinear Optical Fluorides with Short UV Cutoff Edges

    Inorganic Chemistry · 2026-08-22

    Ling Wang, Mei Yan, Bing-Wei Miao, Guo-Ren Zhu, Min Li, Wenfeng Zhou, Ru‐Ling Tang

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