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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2025

CdF(C 6 H 4 NO 2 )(H 2 O): a UV nonlinear optical material with unprecedented SHG and birefringence via π-conjugated rings and a unique “Warren truss structure”

Jie Gou, Yaolong Zhu, Xin Su, Can Hui Yang, YunJie Wang, Qingwen Zhu, Yi Xiong, Qi Wu

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CdF(C 6 H 4 NO 2 )(H 2 O): a UV nonlinear optical material with unprecedented SHG and birefringence via π-conjugated rings and a unique “Warren truss structure”Original(C 14 H 14 N 2 )MCl 4 (M = Zn, Cd): two hybrid metal halides exhibiting strong second harmonic generation responses, large birefringence, and broadband photoluminescence12Strong second-harmonic generation response in an organic–inorganic hybrid antimony bromide1Optimizing the Hydrogen-Bond Network Drives Cadmium Ce(IV) Fluoride Hydrate with Significantly Enhanced Optical Anisotropy8Designing Hybrid Sb-Based Nonlinear Optical Crystals with Large Birefringence by Combining the Lone Pair and π-Conjugated Genes10Shape‐Topology‐Driven Design of Deep Ultraviolet Nonlinear Optical Crystals: Engineering [CH 3 PO 3 ]–Metal‐Oxo Layered Frameworks for Enhanced SHG, DUV Transparency3The modulation of structural polarity facilitating the gradient enhancement of second harmonic generation effects in hybrid metal halides5[CdCl 2 (4-Aminopyridine) 2 ] n : Synergistic Enhancement of Second-Harmonic Generation and Birefringence Enabled by a π-Conjugated Ligand for UV Nonlinear Optics5Hydrogen‐Bond‐Modulated Alignment of Iminodiacetic Acid Cations for Achieving Ultraviolet Second Harmonic Generation6Halogen Anion-Mediated Substitution of Nitrate: Toward Polar Materials with Intense Second-Harmonic Generation Effects3KNa2(Hf,Zr)F7 and KNa2HfF7: isostructural fluorides with phase-matchable second-harmonic generation0Coordination-Mode-Modulated Symmetry Breaking for Nonlinear Optical Crystals0

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  1. (C 14 H 14 N 2 )MCl 4 (M = Zn, Cd): two hybrid metal halides exhibiting strong second harmonic generation responses, large birefringence, and broadband photoluminescence

    Inorganic Chemistry Frontiers · 2025-01-01

    Xinhui Li, Pifu Gong, Mingxing Chen, Shujuan Zhuang, Man Qi, Wenqiang Wang, Xinfang Wang, Zhen Jia, Mingjun Xia

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  2. Strong second-harmonic generation response in an organic–inorganic hybrid antimony bromide

    Dalton Transactions · 2025-01-01

    Xuemei Wen, Gangji Yi, Qinglan Zhong, Caihong Guo, Hongmei Zeng, Guohong Zou, Zhien Lin

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  3. Optimizing the Hydrogen-Bond Network Drives Cadmium Ce(IV) Fluoride Hydrate with Significantly Enhanced Optical Anisotropy

    Inorganic Chemistry · 2025-07-25

    Wen-Ye Gao, Siyu Ma, Bing-Wei Miao, Wenfeng Zhou, Wenlong Liu, Ru‐Ling Tang

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  4. Designing Hybrid Sb-Based Nonlinear Optical Crystals with Large Birefringence by Combining the Lone Pair and π-Conjugated Genes

    Inorganic Chemistry · 2025-07-28

    Kang Yang, Duanliang Wang, Fangcong Liu, Chuanrui Zhu, Qiyao Wang, Kui Wu, Jiyang Wang, Chuanying Shen

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  5. Shape‐Topology‐Driven Design of Deep Ultraviolet Nonlinear Optical Crystals: Engineering [CH 3 PO 3 ]–Metal‐Oxo Layered Frameworks for Enhanced SHG, DUV Transparency

    Laser & Photonics Review · 2025-11-03

    Cheng Hu, Lingli Wu, Chensheng Lin, Yujie Fan, Chao Wang, Huixin Fan, Tao Yan, Min Luo

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  6. The modulation of structural polarity facilitating the gradient enhancement of second harmonic generation effects in hybrid metal halides

    Science China Chemistry · 2026-01-04

    Ru‐Ling Tang, Die-Xue Yang, Jian-Dong Guo, C. Z. Chen, Wenlong Liu, Sheng‐Ping Guo

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  7. [CdCl 2 (4-Aminopyridine) 2 ] n : Synergistic Enhancement of Second-Harmonic Generation and Birefringence Enabled by a π-Conjugated Ligand for UV Nonlinear Optics

    Inorganic Chemistry · 2026-01-06

    Qingwen Zhu, Jie Gou, Yunjie Wang, Yaolong Zhu, Qi Wu

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  8. Hydrogen‐Bond‐Modulated Alignment of Iminodiacetic Acid Cations for Achieving Ultraviolet Second Harmonic Generation

    Advanced Optical Materials · 2026-01-09

    Limin Duan, Xiaomin Zhang, Yan Chun Xiao, Daqing Yang, Y. Y. Wang, Bingbing Zhang

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  9. Halogen Anion-Mediated Substitution of Nitrate: Toward Polar Materials with Intense Second-Harmonic Generation Effects

    Inorganic Chemistry · 2026-03-09

    Zheng-Yu Yang, Ming-Yang Cao, Liang Ma, Bing-Wei Miao, Xing-Yu Li, Wenfeng Zhou, Ru‐Ling Tang

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  10. KNa2(Hf,Zr)F7 and KNa2HfF7: isostructural fluorides with phase-matchable second-harmonic generation

    Materials Today Chemistry · 2026-03-31

    Oksana Matselko, Zuzana Vasková, Zuzana Netriová, Jaroslav Rusnák, Mei Yan, Ru‐Ling Tang, Sheng-Ping Guo, Sanam Bashir, Eva Scholtzová, Aydar I. Rakhmatullin, Róbert Klement, Miroslav Boča

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  11. Coordination-Mode-Modulated Symmetry Breaking for Nonlinear Optical Crystals

    Inorganic Chemistry · 2026-08-24

    Lan Wang, Zhen Qin, Shu‐Fang Li, Xin-Ran Hao, Chu Chu, Bingbing Zhang, Dong Yan

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