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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2024

Strategically designed anisotropic organic–inorganic metal halides (OIMHs) with superior balance between bandgap and birefringence

Mingchang Wang, Huaiyu Wu, Miao‐Bin Xu, Jiajia Li, Ke‐Zhao Du, Jin Chen

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Strategically designed anisotropic organic–inorganic metal halides (OIMHs) with superior balance between bandgap and birefringenceOriginalExploring ultra-high optical anisotropy in polyiodides7A novel metal-free crystal demonstrating superior birefringence attributed to the synergistic interaction of dual π-conjugated units8Optimizing the Hydrogen-Bond Network Drives Cadmium Ce(IV) Fluoride Hydrate with Significantly Enhanced Optical Anisotropy8Low‐Dimensional Organic–Inorganic Hybrid Metal Halide with Large Optical Anisotropy9Design and DFT-Supported Characterization of a New Manganese(II)-Based Hybrid Material for Optoelectronic Applications4Organic Halogen Substitution-Driven Halogen Bonding Induces Polar 3D Supramolecular Framework and Second-Harmonic-Generation Response7Ligand-Directed Hydrogen Bond Symmetry Regulates Ultraviolet Absorption in Organic–Inorganic Metal Halides0Counterion engineering in open-framework crystals: dual enhancement of birefringence and UV transparency in Cd–oxalate framework via cation substitution0Cd[C(NH 2 ) 2 O] 2 Cl 2 : A Urea-Based Open-Framework Crystal with Concurrent Short UV Cutoff Edge and Large Birefringence1Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications5Steric‐Guided Coordination Engineering Enables Significantly Optimized Optical Anisotropy via Sulfur‐Driven [C 5 H 5 NS] Birefringence‐Active Groups0Local Aromatic Overlap Microregulation Enables Birefringence Enhancement in Isocompositional Hybrid Antimony Halides1

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  1. Exploring ultra-high optical anisotropy in polyiodides

    Inorganic Chemistry Frontiers · 2025-01-01

    Mingye Han, Hongbo Huang, Siyu Li, Xiao Yan, Bingbing Zhang, Ying Wang

    Read original paper ↗ ·

  2. A novel metal-free crystal demonstrating superior birefringence attributed to the synergistic interaction of dual π-conjugated units

    Science China Materials · 2025-07-07

    Die-Xue Yang, Ru‐Ling Tang, Yi‐Lei Lv, Bing-Wei Miao, Wenlong Liu, Sheng‐Ping Guo

    Read original paper ↗ ·

  3. Optimizing the Hydrogen-Bond Network Drives Cadmium Ce(IV) Fluoride Hydrate with Significantly Enhanced Optical Anisotropy

    Inorganic Chemistry · 2025-07-25

    Wen-Ye Gao, Siyu Ma, Bing-Wei Miao, Wenfeng Zhou, Wenlong Liu, Ru‐Ling Tang

    Read original paper ↗ ·

  4. Low‐Dimensional Organic–Inorganic Hybrid Metal Halide with Large Optical Anisotropy

    Advanced Optical Materials · 2025-08-05

    Siyu Li, Yakun Zhang, Dongxue Sun, Baoli Gao, Bingbing Zhang, Daqing Yang, Ying Wang

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  5. Design and DFT-Supported Characterization of a New Manganese(II)-Based Hybrid Material for Optoelectronic Applications

    Journal of Electronic Materials · 2025-08-24

    Zghouma El hadj Amar, Teyeb Mohamed Mahmoud, Dah Memoune, Ali Ben Ahmed

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  6. Organic Halogen Substitution-Driven Halogen Bonding Induces Polar 3D Supramolecular Framework and Second-Harmonic-Generation Response

    Inorganic Chemistry · 2025-09-17

    Mingchang Wang, Jiajia Li, Yan Chen, Ke‐Zhao Du, Jin Chen

    Read original paper ↗ ·

  7. Ligand-Directed Hydrogen Bond Symmetry Regulates Ultraviolet Absorption in Organic–Inorganic Metal Halides

    Crystal Growth & Design · 2025-12-12

    Qi Zhang, Hanlin Zhang, Hong-Jing Fan, Qingyi Liu, Jiexin Li, Shanji Guo, Lingyun Li, Yan Yu

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  8. Counterion engineering in open-framework crystals: dual enhancement of birefringence and UV transparency in Cd–oxalate framework via cation substitution

    CrystEngComm · 2026-01-01

    Chenyuan Ma, Jingyi Xie, Zhi Fang, Meihong Duan

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  9. Cd[C(NH 2 ) 2 O] 2 Cl 2 : A Urea-Based Open-Framework Crystal with Concurrent Short UV Cutoff Edge and Large Birefringence

    Inorganic Chemistry · 2026-03-03

    Chenyuan Ma, Xin-Mei Zeng, Jia-Tong Li, Xing-Yu Bi, Zhi Gang Fang, Meihong Duan

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  10. Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications

    Inorganic Chemistry · 2026-04-15

    Peng-Fei Li, Y Wang, Naifeng Zhuang, Jiannian Yao, Yu‐Wu Zhong

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  11. Steric‐Guided Coordination Engineering Enables Significantly Optimized Optical Anisotropy via Sulfur‐Driven [C 5 H 5 NS] Birefringence‐Active Groups

    Small · 2026-08-14

    Jiachen Lu, Chong‐An Chen, Wei Zeng, Kang Min Ok

    Read original paper ↗ ·

  12. Local Aromatic Overlap Microregulation Enables Birefringence Enhancement in Isocompositional Hybrid Antimony Halides

    Crystal Growth & Design · 2026-08-21

    Jia-Wei Li, Zi-Feng Cao, Jun-Pu Wang, Wen-Pei Jia, Zi-Lin Yang, Yongyan Xu, Kai Zhang, Song-Xue Luo, Hui-Li Zheng, Jian-Qiang Zhao

    Read original paper ↗ ·
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