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RESEARCH PAPER · Inorganic Chemistry · 2025

K5NaZr4F22(H2O)2: A Hydrated Zirconium Fluoride with a Second-Harmonic Generation Effect and a Short Ultraviolet Cutoff Edge Induced by Cosubstitution with Heterovalent Cations

Bing-Wei Miao, Guo-Ren Zhu, Ling Wang, Wenfeng Zhou, Wenlong Liu, Ru‐Ling Tang

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K5NaZr4F22(H2O)2: A Hydrated Zirconium Fluoride with a Second-Harmonic Generation Effect and a Short Ultraviolet Cutoff Edge Induced by Cosubstitution with Heterovalent CationsOriginalIsovalent cation substitution strategy for enhancing nonlinear optical properties of iodate-selenate materials0BiCe(SO 4 ) 3 (H 2 O) 3 : a non-centrosymmetric bismuth cerium( iii ) sulfate with second-order nonlinear optical activity arising from strategic heterovalent cationic substitution0From Ba[Sn(IO 3 ) 6 ] to Ba[Sn(IO 3 ) 4 F 2 ]: fluoride-ion-driven enhancement of birefringence and band gap1K 2 ZrSi 2 O 7 with a Wide Transmission Range and Enhanced Birefringence Induced by the d 0 -TM Zr-Based Units2Deep-Ultraviolet Transparent Zr/Hf Fluorides with Second-Harmonic Generation Effects Induced by Alkali-Metal Modulation2Multidimensional Cation Modulation toward Phase-Matchable Nonlinear Optical Fluorides with Short UV Cutoff Edges0

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  1. Isovalent cation substitution strategy for enhancing nonlinear optical properties of iodate-selenate materials

    Journal of Alloys and Compounds · 2025-12-31

    Yinglei Han, Tongqing Sun, Hongde Liu, Dahuai Zheng, Shiguo Liu, Yongfa Kong, Jingjun Xu

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  2. BiCe(SO 4 ) 3 (H 2 O) 3 : a non-centrosymmetric bismuth cerium( iii ) sulfate with second-order nonlinear optical activity arising from strategic heterovalent cationic substitution

    Chemical Communications · 2026-01-01

    Zheng-Yu Yang, C. Z. Chen, Bing-Wei Miao, Yi‐Lei Lv, Wenfeng Zhou, Ming‐Yang Cao, Ru‐Ling Tang

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  3. From Ba[Sn(IO 3 ) 6 ] to Ba[Sn(IO 3 ) 4 F 2 ]: fluoride-ion-driven enhancement of birefringence and band gap

    Inorganic Chemistry Frontiers · 2026-01-01

    Xue-Ying Zhang, Peng-Fei Chen, Bing‐Ping Yang, Jiang‐Gao Mao

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  4. K 2 ZrSi 2 O 7 with a Wide Transmission Range and Enhanced Birefringence Induced by the d 0 -TM Zr-Based Units

    Inorganic Chemistry · 2026-05-28

    Xueqing Liu, Xinyue Shi, Yuan Fang, Yipeng Pang, Degao Zhong, Bing Teng, Y Huang, Zhoubin Lin, Shijia Sun

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  5. Deep-Ultraviolet Transparent Zr/Hf Fluorides with Second-Harmonic Generation Effects Induced by Alkali-Metal Modulation

    Inorganic Chemistry · 2026-06-26

    Ling Wang, Mei Yan, Min Li, Zheng-Yu Yang, X X Li, Wenfeng Zhou, Ru‐Ling Tang

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  6. Multidimensional Cation Modulation toward Phase-Matchable Nonlinear Optical Fluorides with Short UV Cutoff Edges

    Inorganic Chemistry · 2026-08-22

    Ling Wang, Mei Yan, Bing-Wei Miao, Guo-Ren Zhu, Min Li, Wenfeng Zhou, Ru‐Ling Tang

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