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RESEARCH PAPER · Inorganic Chemistry · 2025

LiAgCe2F10(H2O)2: Focusing on the Cation Size Effect to Reasonably Design a Nonlinear Optical Hydrated Cerium(IV) Fluoride

Wen-Ye Gao, Yi‐Lei Lv, Siyu Ma, Cheng Chen, Wenlong Liu, Ru‐Ling Tang

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LiAgCe2F10(H2O)2: Focusing on the Cation Size Effect to Reasonably Design a Nonlinear Optical Hydrated Cerium(IV) FluorideOriginal(C 14 H 14 N 2 )MCl 4 (M = Zn, Cd): two hybrid metal halides exhibiting strong second harmonic generation responses, large birefringence, and broadband photoluminescence12Optimizing the Hydrogen-Bond Network Drives Cadmium Ce(IV) Fluoride Hydrate with Significantly Enhanced Optical Anisotropy8K5NaZr4F22(H2O)2: A Hydrated Zirconium Fluoride with a Second-Harmonic Generation Effect and a Short Ultraviolet Cutoff Edge Induced by Cosubstitution with Heterovalent Cations6K 2 GdB 3 O 6 F 2 : A Promising Short-Wave UV Birefringent Crystal via Optimized Assembly of π-Conjugated [B 3 O 6 ] Groups8BiCe(SO 4 ) 3 (H 2 O) 3 : a non-centrosymmetric bismuth cerium( iii ) sulfate with second-order nonlinear optical activity arising from strategic heterovalent cationic substitution0REV 3 (BO 3 ) 4 (RE = La–Nd): a series of rare earth vanadoborates exhibit large birefringence induced by distorted V III O 6 groups2Strategic Oxygen‐Substitution in Perfluorinated Ce(IV) Coordination Frameworks Triggers Dual‐Wavelength Nonlinear Optical Materials With Exceptional Performances3Strategic Oxygen‐Substitution in Perfluorinated Ce(IV) Coordination Frameworks Triggers Dual‐Wavelength Nonlinear Optical Materials With Exceptional Performances33Research advances in rare-earth nonlinear optical crystalline materials in 20251A new cerium(III)-based sulfate material: Crystal structure, thermal behavior and photoluminescence properties0

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  1. (C 14 H 14 N 2 )MCl 4 (M = Zn, Cd): two hybrid metal halides exhibiting strong second harmonic generation responses, large birefringence, and broadband photoluminescence

    Inorganic Chemistry Frontiers · 2025-01-01

    Xinhui Li, Pifu Gong, Mingxing Chen, Shujuan Zhuang, Man Qi, Wenqiang Wang, Xinfang Wang, Zhen Jia, Mingjun Xia

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  2. Optimizing the Hydrogen-Bond Network Drives Cadmium Ce(IV) Fluoride Hydrate with Significantly Enhanced Optical Anisotropy

    Inorganic Chemistry · 2025-07-25

    Wen-Ye Gao, Siyu Ma, Bing-Wei Miao, Wenfeng Zhou, Wenlong Liu, Ru‐Ling Tang

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  3. K5NaZr4F22(H2O)2: A Hydrated Zirconium Fluoride with a Second-Harmonic Generation Effect and a Short Ultraviolet Cutoff Edge Induced by Cosubstitution with Heterovalent Cations

    Inorganic Chemistry · 2025-08-27

    Bing-Wei Miao, Guo-Ren Zhu, Ling Wang, Wenfeng Zhou, Wenlong Liu, Ru‐Ling Tang

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  4. K 2 GdB 3 O 6 F 2 : A Promising Short-Wave UV Birefringent Crystal via Optimized Assembly of π-Conjugated [B 3 O 6 ] Groups

    Inorganic Chemistry · 2025-10-14

    Mengru Liu, Huijian Zhao, Xianghao Kong, Ning Ye, Zhanggui Hu, Conggang Li

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  5. BiCe(SO 4 ) 3 (H 2 O) 3 : a non-centrosymmetric bismuth cerium( iii ) sulfate with second-order nonlinear optical activity arising from strategic heterovalent cationic substitution

    Chemical Communications · 2026-01-01

    Zheng-Yu Yang, C. Z. Chen, Bing-Wei Miao, Yi‐Lei Lv, Wenfeng Zhou, Ming‐Yang Cao, Ru‐Ling Tang

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  6. REV 3 (BO 3 ) 4 (RE = La–Nd): a series of rare earth vanadoborates exhibit large birefringence induced by distorted V III O 6 groups

    Chemical Communications · 2026-01-01

    Yu-Long Wei, Wen-Dong Yao, Yi‐Lei Lv, Liang Ma, Ru‐Ling Tang

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  7. Strategic Oxygen‐Substitution in Perfluorinated Ce(IV) Coordination Frameworks Triggers Dual‐Wavelength Nonlinear Optical Materials With Exceptional Performances

    Angewandte Chemie · 2026-01-16

    Ru‐Ling Tang, Wen‐Ye Gao, Guo-Ren Zhu, Yang Chi, Liang Ma, Wenlong Liu, Sheng‐Ping Guo

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  8. Strategic Oxygen‐Substitution in Perfluorinated Ce(IV) Coordination Frameworks Triggers Dual‐Wavelength Nonlinear Optical Materials With Exceptional Performances

    Angewandte Chemie International Edition · 2026-01-16

    Ru‐Ling Tang, Wen‐Ye Gao, Guo-Ren Zhu, Yang Chi, Liang Ma, Wenlong Liu, Sheng‐Ping Guo

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  9. Research advances in rare-earth nonlinear optical crystalline materials in 2025

    Journal of Rare Earths · 2026-07-21

    Tiantian He, Dandan Zhou, Fang Kong, Jianggao Mao

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  10. A new cerium(III)-based sulfate material: Crystal structure, thermal behavior and photoluminescence properties

    Structural Chemistry · 2026-08-04

    Omar Kammoun, Chaima Zouari, Malek Rebei, Issam Jardak, Slim Elleuch, Thierry Roisnel, hanen CHAKER, Nabil Zouari

    Read original paper ↗ ·
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