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RESEARCH PAPER · Chinese Chemical Letters · 2024

From HgGa2(SeO3)4 to Hg2Ga(SeO3)2F: The first HgI-based selenite birefringent crystal triggered by linear groups and fluoride ions

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From HgGa2(SeO3)4 to Hg2Ga(SeO3)2F: The first HgI-based selenite birefringent crystal triggered by linear groups and fluoride ionsOriginalDesigning a Heteroleptic Tetrahedral Group with an Ultrahigh Polarizability Anisotropy by Optimizing the Bonding Electrons Activity and Their Distribution14Hg 2 (HTe 2 O 5 )(PO 4 ): a novel phosphate crystal with enhanced birefringence enabled by the synergistic modification of multiple functional groups12Hg 2 (SeO 3 )(TeO 3 ): a novel tellurite–selenite birefringent crystal achieved by assembling multiple functional groups11Hg[CS(NH 2 ) 2 ] 4 (SiF 6 ): a fluorosilicate crystal with large birefringence achieved via multi-functional group modification6K 2 Na(I 3 O 8 ) 3 : a promising mid-infrared birefringent material with two different structures of octaoxotriiodate( v ) polyanions1A Wide Band Gap Germanate with the Largest Second Harmonic Generation Response Created by Hypoxic Strategy22A Wide Band Gap Germanate with the Largest Second Harmonic Generation Response Created by Hypoxic Strategy6From Holodirected to Hemidirected Coordination Activated by Oxygenation Strategy: A Facile Route to Long Wave Infrared Birefringent Crystal4From Holodirected to Hemidirected Coordination Activated by Oxygenation Strategy: A Facile Route to Long Wave Infrared Birefringent Crystal29Na[B3IO7(OH)] and Na2[B4IO9](IO3): Explorations of Boroiodates with Strong Second Harmonic Generation Response and Large Birefringence55Hg3(TeO3)2(NO3)2 and Hg3(Te2O5)2(NO3)2: The First Two Hg‐Based Tellurite Nitrate Unit‐Mixed Crystals with Large Optical Anisotropy16Giant Birefringence Enabled by the Highly Anisotropic Linear IX 2 − (X = Cl, Br) Building Blocks6Giant Birefringence Enabled by the Highly Anisotropic Linear IX 2 − (X = Cl, Br) Building Blocks33Unveiling the potential of rare-earth XCuSeO (X = Dy, Sm) oxychalcogenides for high-performance UV shielding and photovoltaics2La2Zn3(SeO3)6: A UV Selenite Crystal with Second-Harmonic Generation and Large Birefringence13Engineering optical anisotropy in paramagnetic organic crystals: Dichroism of nitronyl nitroxide radicals0Temperature dependence of polarizability, order parameters and dielectric properties of a nematic liquid crystals0Ag3In3(SeO3)3(SO4)F4: A Sulfate Selenite Nonlinear Optical Material with a Wide Bandgap3Crystal growth and opto-electrical properties of Ag6.5P0.5Si0.5S5I solid-state ionic conductor2ZnGa(SeO 3 ) 2 F: a UV transparent birefringent crystal explored in M( ii )–IIIA–selenite–F systems2[Cd 4 P 2 ][I 3 ] and [Cd 2 P][CdCl 3 ]: two Millon's phase phosphides exhibiting wide band gaps and large birefringence0A mercury-based selenite with wide bandgap and moderate birefringence via cation substitution and partial fluorination1From centrosymmetric (C 4 H 8 N 5 )(SbF 4 ) to polar (C 4 H 7 N 4 O)(SbF 4 ): a new UV nonlinear optical material achieved by functional group modulation8Pyrazinamide–IBr: an organic–inorganic hybrid crystal exhibiting giant optical anisotropy0SnCl 2 [SC(NH 2 ) 2 ]: lone-pair and hydrogen-bonding triggered chromophore assembling for dual optical optimization0Syntheses, structures and optical properties of two new cadmium antimonites: Cs 4 Cd(SbF 5 ) 3 (H 2 O) 2 and Cd[Sb 7 O 10 (OH)](SO 4 )0Cd[C(NH 2 ) 2 O] 2 Cl 2 : A Urea-Based Open-Framework Crystal with Concurrent Short UV Cutoff Edge and Large Birefringence1Magnetic Copper Selenite-Sulfate Cu 3 O 2 (HSeO 3 )(HSO 4 )(H 2 O) with T26-Type Non-Archimedean Lattice Featuring a Robust 1/3-Magnetization Plateau2Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications5

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  1. Designing a Heteroleptic Tetrahedral Group with an Ultrahigh Polarizability Anisotropy by Optimizing the Bonding Electrons Activity and Their Distribution

    Laser & Photonics Review · 2024-12-12

    Hongyuan Sha, Dongling Yang, Qinghe Li, Lilin Yang, Zujian Wang, Rongbing Su, Chao He, Bin Su, Xiaoming Yang, Xifa Long

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  2. Hg 2 (HTe 2 O 5 )(PO 4 ): a novel phosphate crystal with enhanced birefringence enabled by the synergistic modification of multiple functional groups

    Inorganic Chemistry Frontiers · 2025-01-01

    Pengfei Li, Chun‐Li Hu, Bo Zhang, Jiang‐Gao Mao, Fang Kong

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  3. Hg 2 (SeO 3 )(TeO 3 ): a novel tellurite–selenite birefringent crystal achieved by assembling multiple functional groups

    Journal of Materials Chemistry C · 2025-01-01

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  4. Hg[CS(NH 2 ) 2 ] 4 (SiF 6 ): a fluorosilicate crystal with large birefringence achieved via multi-functional group modification

    Dalton Transactions · 2025-01-01

    Pengfei Li, Xinlei Liu, Si-Qi Zhou, Mingchang Wang, Jingjing Wu, Yu‐Wu Zhong, Jiannian Yao

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  5. K 2 Na(I 3 O 8 ) 3 : a promising mid-infrared birefringent material with two different structures of octaoxotriiodate( v ) polyanions

    New Journal of Chemistry · 2025-01-01

    Min-Quan Lin, Meng-Fan Duan, Jiang-Gao Mao, Bing‐Ping Yang

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  6. A Wide Band Gap Germanate with the Largest Second Harmonic Generation Response Created by Hypoxic Strategy

    Angewandte Chemie International Edition · 2025-02-11

    Qi‐Chang Song, Chun‐Li Hu, Fang Kong, Fang Kong, Jiang‐Gao Mao

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  7. A Wide Band Gap Germanate with the Largest Second Harmonic Generation Response Created by Hypoxic Strategy

    Angewandte Chemie · 2025-02-11

    Qi‐Chang Song, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  8. From Holodirected to Hemidirected Coordination Activated by Oxygenation Strategy: A Facile Route to Long Wave Infrared Birefringent Crystal

    Angewandte Chemie · 2025-02-22

    Xinyang Li, Xiyue Cheng, Chun‐Li Hu, Bingxuan Li, Zhengyang Zhou, Jian‐Han Zhang, Shuiquan Deng, Jiang‐Gao Mao, Fang Kong

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  9. From Holodirected to Hemidirected Coordination Activated by Oxygenation Strategy: A Facile Route to Long Wave Infrared Birefringent Crystal

    Angewandte Chemie International Edition · 2025-02-22

    Xin‐Yang Li, Xiyue Cheng, Chun‐Li Hu, Bingxuan Li, Zhengyang Zhou, Jian‐Han Zhang, Shuiquan Deng, Jiang‐Gao Mao, Fang Kong

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  10. Na[B3IO7(OH)] and Na2[B4IO9](IO3): Explorations of Boroiodates with Strong Second Harmonic Generation Response and Large Birefringence

    Journal of the American Chemical Society · 2025-04-07

    Ya-Lan Deng, Chun‐Li Hu, Xiang Xu, Mingzhi Zhang, Jiang‐Gao Mao

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  11. Hg3(TeO3)2(NO3)2 and Hg3(Te2O5)2(NO3)2: The First Two Hg‐Based Tellurite Nitrate Unit‐Mixed Crystals with Large Optical Anisotropy

    Laser & Photonics Review · 2025-04-10

    Piao Tang, Xin Wen, Yuchen Yan, Cao Xue, Jindong Chen, Chensheng Lin, Min Luo, Ning Ye, Guang Peng

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  12. Giant Birefringence Enabled by the Highly Anisotropic Linear IX 2 − (X = Cl, Br) Building Blocks

    Angewandte Chemie · 2025-04-16

    Chong‐An Chen, Yang Li, Hongbo Huang, Congcong Jin, Bingbing Zhang, Kang Min Ok

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  13. Giant Birefringence Enabled by the Highly Anisotropic Linear IX 2 − (X = Cl, Br) Building Blocks

    Angewandte Chemie International Edition · 2025-04-16

    Chong‐An Chen, Yang Li, Hongbo Huang, Congcong Jin, Bingbing Zhang, Kang Min Ok

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  14. Unveiling the potential of rare-earth XCuSeO (X = Dy, Sm) oxychalcogenides for high-performance UV shielding and photovoltaics

    Journal of Solid State Chemistry · 2025-04-24

    Banat Gul, Mohannad Mahmoud Ali Al-Hmoud, Muhammad Salman Khan, Siti Maisarah Aziz

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  15. La2Zn3(SeO3)6: A UV Selenite Crystal with Second-Harmonic Generation and Large Birefringence

    Inorganic Chemistry · 2025-05-01

    Pengfei Li, Xiaoxue Wang, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  16. Engineering optical anisotropy in paramagnetic organic crystals: Dichroism of nitronyl nitroxide radicals

    Chinese Journal of Structural Chemistry · 2025-06-19

    Matvey K. Shurikov, Yuliana Kolesnikova, Darya E. Votkina, Pavel A. Abramov⧫, Taisiya Sergeevna Sukhikh, Г.В. Романенко, Sergey L. Veber, Dmitry E. Gorbunov, Nina P. Gritsan, Giuseppe Resnati, E.V. Tretyakov, Vadim Yu. Kukushkin, Павел Сергеевич Постников, Pavel V. Petunin

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  17. Temperature dependence of polarizability, order parameters and dielectric properties of a nematic liquid crystals

    Next Materials · 2025-06-21

    Surendra Kumar, Manoj Bhushan Pandey, Syed Salman Ahmad Warsi, Rajiv Manohar

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  18. Ag3In3(SeO3)3(SO4)F4: A Sulfate Selenite Nonlinear Optical Material with a Wide Bandgap

    Inorganic Chemistry · 2025-09-30

    Dandan Zhou, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  19. Crystal growth and opto-electrical properties of Ag6.5P0.5Si0.5S5I solid-state ionic conductor

    Materials Research Bulletin · 2025-10-30

    Artem I. Pogodin, I.O. Shender, М.М. Поп, M.J. Filep, Т.О. Malakhovska, Oleksandr Kokhan

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  20. ZnGa(SeO 3 ) 2 F: a UV transparent birefringent crystal explored in M( ii )–IIIA–selenite–F systems

    Inorganic Chemistry Frontiers · 2025-12-20

    Tian-Tian He, C Hu, Ya-Ping Gong, Jiang‐Gao Mao, Fang Kong

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  21. [Cd 4 P 2 ][I 3 ] and [Cd 2 P][CdCl 3 ]: two Millon's phase phosphides exhibiting wide band gaps and large birefringence

    Dalton Transactions · 2026-01-01

    Fupeng Wang, Guang Peng, Ning Ye, Jindong Chen

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  22. A mercury-based selenite with wide bandgap and moderate birefringence via cation substitution and partial fluorination

    Dalton Transactions · 2026-01-01

    Chen Zhu, Xiao-Min Wu, Xiao-Xue Wang, Si-Qi Zhou, Jing-Jing Wu, Xin-Lei Liu, You-Qian Wu, Jiannian Yao, Peng-Fei Li, Yu-Wu Zhong

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  23. From centrosymmetric (C 4 H 8 N 5 )(SbF 4 ) to polar (C 4 H 7 N 4 O)(SbF 4 ): a new UV nonlinear optical material achieved by functional group modulation

    Chemical Science · 2026-01-01

    Zhixiang Wang, Chun-Li Hu, Chuan‐Fu Sun, Jiang‐Gao Mao, Fang Kong

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  24. Pyrazinamide–IBr: an organic–inorganic hybrid crystal exhibiting giant optical anisotropy

    Dalton Transactions · 2026-01-01

    Meng-Fan Duan, Jiang‐Gao Mao, Bing‐Ping Yang

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  25. SnCl 2 [SC(NH 2 ) 2 ]: lone-pair and hydrogen-bonding triggered chromophore assembling for dual optical optimization

    Dalton Transactions · 2026-01-01

    Xing-Yu Bi, Yuting Gao, Chenyuan Ma, Zhi Gang Fang, Meihong Duan

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  26. Syntheses, structures and optical properties of two new cadmium antimonites: Cs 4 Cd(SbF 5 ) 3 (H 2 O) 2 and Cd[Sb 7 O 10 (OH)](SO 4 )

    Dalton Transactions · 2026-01-01

    Yi Yuan, Chun‐Li Hu, Dan-Dan Zhou, Jiang‐Gao Mao, Fang Kong

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  27. Cd[C(NH 2 ) 2 O] 2 Cl 2 : A Urea-Based Open-Framework Crystal with Concurrent Short UV Cutoff Edge and Large Birefringence

    Inorganic Chemistry · 2026-03-03

    Chenyuan Ma, Xin-Mei Zeng, Jia-Tong Li, Xing-Yu Bi, Zhi Gang Fang, Meihong Duan

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  28. Magnetic Copper Selenite-Sulfate Cu 3 O 2 (HSeO 3 )(HSO 4 )(H 2 O) with T26-Type Non-Archimedean Lattice Featuring a Robust 1/3-Magnetization Plateau

    Inorganic Chemistry · 2026-04-14

    Nian Shi, Yue Wang, Hui Li, Yun Lv, Hiroshi Takatsu, Hyun‐Joo Koo, Chao Dong, Reinhard Karl Kremer, J. F. Wang, Myung‐Hwan Whangbo, Hiroshi Kageyama, Hongcheng Lu

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  29. Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications

    Inorganic Chemistry · 2026-04-15

    Peng-Fei Li, Y Wang, Naifeng Zhuang, Jiannian Yao, Yu‐Wu Zhong

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