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RESEARCH PAPER · Chemical Engineering Journal · 2025

(C6H10N2)ZnX4·H2O (X=Cl and Br): Excellent nonlinear optical properties and temperature induced photoluminescence for encryption

Chuanying Shen, Chenyi Zhang, Chenyi Zhang, Qiwei Xing, Defu Sun, Kui Wu, Bingbing Zhang, Jiyang Wang, Jiyang Wang, Duanliang Wang

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(C6H10N2)ZnX4·H2O (X=Cl and Br): Excellent nonlinear optical properties and temperature induced photoluminescence for encryptionOriginal(C 14 H 14 N 2 )MCl 4 (M = Zn, Cd): two hybrid metal halides exhibiting strong second harmonic generation responses, large birefringence, and broadband photoluminescence12Significant enhancement in the birefringence of metal phosphite halides via the introduction of π-conjugated cations17Multifunctional Cd‐based Hybrid with Large Birefringence Achieving Excellent Second Harmonic Generation and Reversible Temperature‐Activated Fluorescence for Anti‐counterfeiting16Decoupling the SHG‐Birefringence Trade‐off in UV NLO Materials via Triple‐Control Coordination Engineering: Achieving Synergistic Performance Optimization88Decoupling the SHG‐Birefringence Trade‐off in UV NLO Materials via Triple‐Control Coordination Engineering: Achieving Synergistic Performance Optimization13Halogen-Engineered Copper-Based Materials with Multicolor Emission for Dual-Functional Anticounterfeiting and LED Applications9Designing hybrid zinc-based ultraviolet nonlinear optical crystal with strong NLO response and dual-color luminescence via the integration of two different SHG-active genes6Bromine for iodine: Unlocking short-wavelength UV phase matching in nonlinear optical metal halides6Designing Hybrid Sb-Based Nonlinear Optical Crystals with Large Birefringence by Combining the Lone Pair and π-Conjugated Genes10Achieving Dual-Color Luminescence via Halogen Regulation in Copper-Based Halides for Anticounterfeiting30D Zinc OIMHs with Pyridine Vapor‐Activated NIR Fluorescence Emission Behavior for Gas Sensing2Investigation of the growth, linear optical, and nonlinear optical (NLO) characteristics of 1-methyl-2-[2-(3,4,5-Trimethoxy-phenyl)-vinyl]-pyridinium+anthraquinone-2-sulfonate−dihydrate (TMAS) organic single crystal3Organic Halogen Substitution-Driven Halogen Bonding Induces Polar 3D Supramolecular Framework and Second-Harmonic-Generation Response7Tunable dual-emission in a hybrid [Ph3PH]2[ZnI4] system: The role of {ZnI…HP} interactions and proton transfer in 3ILCT/3L(X + M)CT phosphorescence1Enhanced Photoluminescence in Hybrid Manganese Halides via Halogen Regulation for LED Applications10The modulation of structural polarity facilitating the gradient enhancement of second harmonic generation effects in hybrid metal halides5Hybrid Cd 2+ -Based Halide Birefringent Crystals Achieving Tunable Dual-Color Emission for Multifunctional LED and Anticounterfeiting Applications2C 6 H 7 NCl·X (X = Cl, Br): Outstanding Multifunctional Nonlinear Optical and Birefringent Crystals Enabled by Incorporation of π‐Conjugated Moieties2Halogen Anion-Mediated Substitution of Nitrate: Toward Polar Materials with Intense Second-Harmonic Generation Effects3A Strategy for Enhancing the Optical Anisotropy of Phosphates via Tetrahedral Unit Modification0Designing Novel Solar‐Blind Ultraviolet Nonlinear Optical Crystals Based on Local Proton Distribution Complementary Effect0Designing Novel Solar‐Blind Ultraviolet Nonlinear Optical Crystals Based on Local Proton Distribution Complementary Effect0Assembly of dual π-conjugated units toward enhanced birefringence in a 2D organic sulfonate crystal0

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23 direct citing papers saved.

  1. (C 14 H 14 N 2 )MCl 4 (M = Zn, Cd): two hybrid metal halides exhibiting strong second harmonic generation responses, large birefringence, and broadband photoluminescence

    Inorganic Chemistry Frontiers · 2025-01-01

    Xinhui Li, Pifu Gong, Mingxing Chen, Shujuan Zhuang, Man Qi, Wenqiang Wang, Xinfang Wang, Zhen Jia, Mingjun Xia

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  2. Significant enhancement in the birefringence of metal phosphite halides via the introduction of π-conjugated cations

    Chemical Science · 2025-01-01

    Ru‐Ling Tang, Yue Wang, Yi‐Lei Lv, Bing-Wei Miao, Wenlong Liu, Sheng‐Ping Guo

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  3. Multifunctional Cd‐based Hybrid with Large Birefringence Achieving Excellent Second Harmonic Generation and Reversible Temperature‐Activated Fluorescence for Anti‐counterfeiting

    Advanced Optical Materials · 2025-05-21

    Duanliang Wang, Qiwei Xing, Defu Sun, Chuanrui Zhu, Kui Wu, Bingbing Zhang, Guangxia Liu, Jiyang Wang, Chuanying Shen

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  4. Decoupling the SHG‐Birefringence Trade‐off in UV NLO Materials via Triple‐Control Coordination Engineering: Achieving Synergistic Performance Optimization

    Angewandte Chemie International Edition · 2025-05-22

    Yaolong Zhu, Jie Gou, Can Yang, Qingwen Zhu, Yi Xiong, Qi Wu

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  5. Decoupling the SHG‐Birefringence Trade‐off in UV NLO Materials via Triple‐Control Coordination Engineering: Achieving Synergistic Performance Optimization

    Angewandte Chemie · 2025-05-22

    Yaolong Zhu, Jie Gou, Can Yang, Qingwen Zhu, Yi Xiong, Qi Wu

    Read original paper ↗ ·

  6. Halogen-Engineered Copper-Based Materials with Multicolor Emission for Dual-Functional Anticounterfeiting and LED Applications

    ACS Applied Materials & Interfaces · 2025-07-22

    Chenyi Zhang, Duanliang Wang, Chuanrui Zhu, Xiao‐Wu Lei, Lingqiang Meng, Chuanying Shen

    Read original paper ↗ ·

  7. Designing hybrid zinc-based ultraviolet nonlinear optical crystal with strong NLO response and dual-color luminescence via the integration of two different SHG-active genes

    Materials Today Chemistry · 2025-07-24

    Kang Yang, Duanliang Wang, Chuanrui Zhu, Kui Wu, Guangxia Liu, Jiyang Wang, Chuanying Shen

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  8. Bromine for iodine: Unlocking short-wavelength UV phase matching in nonlinear optical metal halides

    Chinese Chemical Letters · 2025-07-27

    Mingchang Wang, Zhi Rong Lin, Jiajia Li, Jia-Min Lian, Yunxia Hu, Yan Chen, Ke‐Zhao Du, Jin Chen

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  9. Designing Hybrid Sb-Based Nonlinear Optical Crystals with Large Birefringence by Combining the Lone Pair and π-Conjugated Genes

    Inorganic Chemistry · 2025-07-28

    Kang Yang, Duanliang Wang, Fangcong Liu, Chuanrui Zhu, Qiyao Wang, Kui Wu, Jiyang Wang, Chuanying Shen

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  10. Achieving Dual-Color Luminescence via Halogen Regulation in Copper-Based Halides for Anticounterfeiting

    Inorganic Chemistry · 2025-08-20

    Chenyi Zhang, Chuanrui Zhu, Baopeng Shan, Jiaxi Ding, Xiao‐Wu Lei, Longyun Xu, Chuanying Shen

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  11. 0D Zinc OIMHs with Pyridine Vapor‐Activated NIR Fluorescence Emission Behavior for Gas Sensing

    Advanced Functional Materials · 2025-08-28

    Yunming Liu, Linlin Chen, Xiangdi Huang, Peng Liu, Zhigang Ma, Yanxiong Liu, Yu‐Chen Zhang, Liyan Zheng, Qiue Cao

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  12. Investigation of the growth, linear optical, and nonlinear optical (NLO) characteristics of 1-methyl-2-[2-(3,4,5-Trimethoxy-phenyl)-vinyl]-pyridinium+anthraquinone-2-sulfonate−dihydrate (TMAS) organic single crystal

    Journal of Molecular Structure · 2025-09-06

    Raji Vinayagamoorthy, Anand Sekar, L. Poornima, Ravi Shanker Babu, M. Usha Rani

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  13. Organic Halogen Substitution-Driven Halogen Bonding Induces Polar 3D Supramolecular Framework and Second-Harmonic-Generation Response

    Inorganic Chemistry · 2025-09-17

    Mingchang Wang, Jiajia Li, Yan Chen, Ke‐Zhao Du, Jin Chen

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  14. Tunable dual-emission in a hybrid [Ph3PH]2[ZnI4] system: The role of {ZnI…HP} interactions and proton transfer in 3ILCT/3L(X + M)CT phosphorescence

    Journal of Photochemistry and Photobiology A Chemistry · 2025-11-04

    Alexey S. Berezin

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  15. Enhanced Photoluminescence in Hybrid Manganese Halides via Halogen Regulation for LED Applications

    Inorganic Chemistry · 2025-12-09

    Chuanying Shen, Jie Liu, Zhengao Xie, Xun-Wang Yan, Chuanrui Zhu, Xiao‐Wu Lei, Duanliang Wang

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  16. The modulation of structural polarity facilitating the gradient enhancement of second harmonic generation effects in hybrid metal halides

    Science China Chemistry · 2026-01-04

    Ru‐Ling Tang, Die-Xue Yang, Jian-Dong Guo, C. Z. Chen, Wenlong Liu, Sheng‐Ping Guo

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  17. Hybrid Cd 2+ -Based Halide Birefringent Crystals Achieving Tunable Dual-Color Emission for Multifunctional LED and Anticounterfeiting Applications

    ACS Applied Materials & Interfaces · 2026-01-14

    Duanliang Wang, Qiwei Xing, Zhengao Xie, Xunwang Yan, Chuanrui Zhu, Bingbing Zhang, Xiao‐Wu Lei, Chuanying Shen

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  18. C 6 H 7 NCl·X (X = Cl, Br): Outstanding Multifunctional Nonlinear Optical and Birefringent Crystals Enabled by Incorporation of π‐Conjugated Moieties

    Advanced Optical Materials · 2026-02-28

    Chuanying Shen, Jiaxi Ding, Zhengao Xie, Kang Yang, Xunwang Yan, Bingbing Zhang, Kui Wu, Jiyang Wang, Duanliang Wang

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  19. Halogen Anion-Mediated Substitution of Nitrate: Toward Polar Materials with Intense Second-Harmonic Generation Effects

    Inorganic Chemistry · 2026-03-09

    Zheng-Yu Yang, Ming-Yang Cao, Liang Ma, Bing-Wei Miao, Xing-Yu Li, Wenfeng Zhou, Ru‐Ling Tang

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  20. A Strategy for Enhancing the Optical Anisotropy of Phosphates via Tetrahedral Unit Modification

    Crystal Growth & Design · 2026-06-26

    Bao Jiang, Hongheng Chen, Lei Wu, Xueyin Fu, Maierhaba Abudoureheman, Yi Huang, Ailijiang Abudurusuli, Qun Jing, Xue Yu, Zhaohui Chen

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  21. Designing Novel Solar‐Blind Ultraviolet Nonlinear Optical Crystals Based on Local Proton Distribution Complementary Effect

    Angewandte Chemie International Edition · 2026-08-11

    Hongyuan Sha, Dongling Yang, Lilin Yang, Fan Xiao, Xiaoming Yang, Lingfei Lv, Chao He, Zhihua Yang, Fangfang Zhang, Zujian Wang, Xifa Long

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  22. Designing Novel Solar‐Blind Ultraviolet Nonlinear Optical Crystals Based on Local Proton Distribution Complementary Effect

    Angewandte Chemie · 2026-08-11

    Hongyuan Sha, Dongling Yang, Lilin Yang, Fan Xiao, Xiaoming Yang, Lingfei Lv, Chao He, Zhihua Yang, Fangfang Zhang, Zujian Wang, Xifa Long

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  23. Assembly of dual π-conjugated units toward enhanced birefringence in a 2D organic sulfonate crystal

    Science China Chemistry · 2026-09-15

    Longyun Xu, Hanjing Huang, Conggang Li, Huijian Zhao, Conghe Liu, Kaidong Xu, Jina Wang, Ning Ye, Zhanggui Hu

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