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RESEARCH PAPER · Inorganic Chemistry · 2024

Centrosymmetric CaBaMF8 and Noncentrosymmetric Li2CaMF8 (M = Zr, Hf): Dimension Variation and Nonlinear Optical Activity Resulting from an Isovalent Cation Substitution-Oriented Design

Mei Yan, Ru‐Ling Tang, Wei Xu, Wenlong Liu, Sheng‐Ping Guo

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Centrosymmetric CaBaMF8 and Noncentrosymmetric Li2CaMF8 (M = Zr, Hf): Dimension Variation and Nonlinear Optical Activity Resulting from an Isovalent Cation Substitution-Oriented DesignOriginalChemical modulation of A I RE III C IV QVI4 family compounds for band gap and optical anisotropy enhancement16Equivalent cation-tuning to realize a new Ce( iv ) fluoride with excellent comprehensive nonlinear optical performances12KBa 3 M 2 F 14 Cl (M = Zr, Hf): novel short-wavelength mixed metal halides with the largest second-harmonic generation responses contributed by mixed functional moieties37Hg16O12(NO3)6F2(H2O): A Mercury-Rich Nitrate Oxyfluoride with Diverse Triple-Coordinated Mercury-Based Units That Exhibits an Unparalleled [(Hg16O12F2(H2O))6+]∞ Cationic Framework and a Large Birefringence12Three types of promising functional building units for designing metal halide nonlinear optical crystals20From CaBaM2F12 to K2BaM2F12 (M = Zr, Hf): Heterovalent Cation-Substitution-Induced Symmetry Break and Nonlinear-Optical Activity11Greatly enhancing birefringence of fluorosilicates through the synergetic effect of functional units13LiAgCe2F10(H2O)2: Focusing on the Cation Size Effect to Reasonably Design a Nonlinear Optical Hydrated Cerium(IV) Fluoride10From Centrosymmetric Ca3Ge2O3S4 to Noncentrosymmetric Ca3Ge2O4Se3: A Nonlinear Optical Ca-Based Oxyselenide5Patterning and Dynamics of Structured Surfaces in Metal/Covalent Organic Frameworks and Polymer Chemistry5Structure, thermal properties and phase transition in RbCdHfF7: experiments and lattice dynamics calculations0K5NaZr4F22(H2O)2: A Hydrated Zirconium Fluoride with a Second-Harmonic Generation Effect and a Short Ultraviolet Cutoff Edge Induced by Cosubstitution with Heterovalent Cations6Breaking the Deep‐UV Transparency/Optical Nonlinearity Trade‐Off: Three‐Parameter Optimization in Oxyfluorides by Tailoring d 0 ‐Metal Incorporation10Breaking the Deep‐UV Transparency/Optical Nonlinearity Trade‐Off: Three‐Parameter Optimization in Oxyfluorides by Tailoring d 0 ‐Metal Incorporation4Li 3 GaTe 4 O 11 : small ion-driven orientation of TeO n units in a tunnel-structured tellurite1KNa2(Hf,Zr)F7 and KNa2HfF7: isostructural fluorides with phase-matchable second-harmonic generation0Deep-Ultraviolet Transparent Zr/Hf Fluorides with Second-Harmonic Generation Effects Induced by Alkali-Metal Modulation2

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17 direct citing papers saved.

  1. Chemical modulation of A I RE III C IV QVI4 family compounds for band gap and optical anisotropy enhancement

    Inorganic Chemistry Frontiers · 2024-01-01

    Hongshan Wang, Xueting Pan, Shilie Pan, Junjie Li

    Read original paper ↗ ·

  2. Equivalent cation-tuning to realize a new Ce( iv ) fluoride with excellent comprehensive nonlinear optical performances

    Inorganic Chemistry Frontiers · 2024-01-01

    Beibei Zhang, Wen‐Ye Gao, Wei Lin Xu, L. Ma, Wenlong Liu, Ru‐Ling Tang, Sheng‐Ping Guo

    Read original paper ↗ ·

  3. KBa 3 M 2 F 14 Cl (M = Zr, Hf): novel short-wavelength mixed metal halides with the largest second-harmonic generation responses contributed by mixed functional moieties

    Chemical Science · 2024-01-01

    Mei Yan, Chun‐Li Hu, Ru‐Ling Tang, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  4. Hg16O12(NO3)6F2(H2O): A Mercury-Rich Nitrate Oxyfluoride with Diverse Triple-Coordinated Mercury-Based Units That Exhibits an Unparalleled [(Hg16O12F2(H2O))6+]∞ Cationic Framework and a Large Birefringence

    Inorganic Chemistry · 2024-03-28

    Yi‐Lei Lv, Wei Xu, Wen‐Dong Yao, Miao‐Bin Xu, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

    Read original paper ↗ ·

  5. Three types of promising functional building units for designing metal halide nonlinear optical crystals

    Chinese Journal of Structural Chemistry · 2024-04-01

    Jiajing Wu, Ru‐Ling Tang, Sheng‐Ping Guo

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  6. From CaBaM2F12 to K2BaM2F12 (M = Zr, Hf): Heterovalent Cation-Substitution-Induced Symmetry Break and Nonlinear-Optical Activity

    Inorganic Chemistry · 2024-06-04

    Mei Yan, Ru‐Ling Tang, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

    Read original paper ↗ ·

  7. Greatly enhancing birefringence of fluorosilicates through the synergetic effect of functional units

    Inorganic Chemistry Frontiers · 2025-01-01

    Liang Ma, Yi‐Lei Lv, Bing-Wei Miao, Guo-Ren Zhu, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

    Read original paper ↗ ·

  8. LiAgCe2F10(H2O)2: Focusing on the Cation Size Effect to Reasonably Design a Nonlinear Optical Hydrated Cerium(IV) Fluoride

    Inorganic Chemistry · 2025-03-24

    Wen-Ye Gao, Yi‐Lei Lv, Siyu Ma, Cheng Chen, Wenlong Liu, Ru‐Ling Tang

    Read original paper ↗ ·

  9. From Centrosymmetric Ca3Ge2O3S4 to Noncentrosymmetric Ca3Ge2O4Se3: A Nonlinear Optical Ca-Based Oxyselenide

    Inorganic Chemistry · 2025-07-09

    Rui Xiao, Wen‐Dong Yao, Wenhao Xing, Chunlan Tang, Wenwen Jiang, Sheng‐Ping Guo, Wenlong Yin

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  10. Patterning and Dynamics of Structured Surfaces in Metal/Covalent Organic Frameworks and Polymer Chemistry

    Topics in Current Chemistry · 2025-08-11

    Brij Mohan, Hongli Wen, Virender Virender, Neera Raghav, Rakesh Kumar Gupta, Wei Sun

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  11. Structure, thermal properties and phase transition in RbCdHfF7: experiments and lattice dynamics calculations

    Solid State Sciences · 2025-08-12

    Evgeniy V. Bogdanov, Мaxim S. Моlokeev, М. В. Горев, A. V. Kartashev, Maxim S. Pavlovskiy, Evgeniy I. Pogoreltsev, N. M. Laptash, Igor N. Flerov

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  12. K5NaZr4F22(H2O)2: A Hydrated Zirconium Fluoride with a Second-Harmonic Generation Effect and a Short Ultraviolet Cutoff Edge Induced by Cosubstitution with Heterovalent Cations

    Inorganic Chemistry · 2025-08-27

    Bing-Wei Miao, Guo-Ren Zhu, Ling Wang, Wenfeng Zhou, Wenlong Liu, Ru‐Ling Tang

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  13. Breaking the Deep‐UV Transparency/Optical Nonlinearity Trade‐Off: Three‐Parameter Optimization in Oxyfluorides by Tailoring d 0 ‐Metal Incorporation

    Angewandte Chemie International Edition · 2025-09-16

    Xiaotian Zhang, Xingxing Jiang, Hui Gao, Kaining Duanmu, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  14. Breaking the Deep‐UV Transparency/Optical Nonlinearity Trade‐Off: Three‐Parameter Optimization in Oxyfluorides by Tailoring d 0 ‐Metal Incorporation

    Angewandte Chemie · 2025-09-16

    Xiaotian T. Zhang, Xingxing Jiang, Hui Ming Gao, Kaining Duanmu, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  15. Li 3 GaTe 4 O 11 : small ion-driven orientation of TeO n units in a tunnel-structured tellurite

    Dalton Transactions · 2026-01-01

    Jingfang Zhou, Pifu Gong, Chang Gao, Mingjun Xia, Jing Yu, Hongxia Zhang, Qian Wu

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  16. KNa2(Hf,Zr)F7 and KNa2HfF7: isostructural fluorides with phase-matchable second-harmonic generation

    Materials Today Chemistry · 2026-03-31

    Oksana Matselko, Zuzana Vasková, Zuzana Netriová, Jaroslav Rusnák, Mei Yan, Ru‐Ling Tang, Sheng-Ping Guo, Sanam Bashir, Eva Scholtzová, Aydar I. Rakhmatullin, Róbert Klement, Miroslav Boča

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  17. Deep-Ultraviolet Transparent Zr/Hf Fluorides with Second-Harmonic Generation Effects Induced by Alkali-Metal Modulation

    Inorganic Chemistry · 2026-06-26

    Ling Wang, Mei Yan, Min Li, Zheng-Yu Yang, X X Li, Wenfeng Zhou, Ru‐Ling Tang

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