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RESEARCH PAPER · Inorganic Chemistry · 2024

From CaBaM2F12 to K2BaM2F12 (M = Zr, Hf): Heterovalent Cation-Substitution-Induced Symmetry Break and Nonlinear-Optical Activity

Mei Yan, Ru‐Ling Tang, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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From CaBaM2F12 to K2BaM2F12 (M = Zr, Hf): Heterovalent Cation-Substitution-Induced Symmetry Break and Nonlinear-Optical ActivityOriginalEquivalent cation-tuning to realize a new Ce( iv ) fluoride with excellent comprehensive nonlinear optical performances12Breaking Symmetry for SHG Response: Lanthanide Acetate Crystals via Water Molecule Regulation Strategy5CdF(C 6 H 4 NO 2 )(H 2 O): a UV nonlinear optical material with unprecedented SHG and birefringence via π-conjugated rings and a unique “Warren truss structure”11Greatly enhancing birefringence of fluorosilicates through the synergetic effect of functional units13Synthesis, characterization and theoretical calculations of a new rare-earth fluoride with a DUV cutoff edge1Structure, thermal properties and phase transition in RbCdHfF7: experiments and lattice dynamics calculations0K5NaZr4F22(H2O)2: A Hydrated Zirconium Fluoride with a Second-Harmonic Generation Effect and a Short Ultraviolet Cutoff Edge Induced by Cosubstitution with Heterovalent Cations6Chiral calcium thiocyanate hybrids: amino acid-enabled structural diversity and second-harmonic generation0KNa2(Hf,Zr)F7 and KNa2HfF7: isostructural fluorides with phase-matchable second-harmonic generation0Deep-Ultraviolet Transparent Zr/Hf Fluorides with Second-Harmonic Generation Effects Induced by Alkali-Metal Modulation2Multidimensional Cation Modulation toward Phase-Matchable Nonlinear Optical Fluorides with Short UV Cutoff Edges0

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  1. Equivalent cation-tuning to realize a new Ce( iv ) fluoride with excellent comprehensive nonlinear optical performances

    Inorganic Chemistry Frontiers · 2024-01-01

    Beibei Zhang, Wen‐Ye Gao, Wei Lin Xu, L. Ma, Wenlong Liu, Ru‐Ling Tang, Sheng‐Ping Guo

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  2. Breaking Symmetry for SHG Response: Lanthanide Acetate Crystals via Water Molecule Regulation Strategy

    Inorganic Chemistry · 2024-10-24

    Yaolong Zhu, Yong Tao, Can Yang, Yuwei Kang, Xuefei Wang, Jie Gou, Yi Xiong, Qi Wu

    Read original paper ↗ ·

  3. CdF(C 6 H 4 NO 2 )(H 2 O): a UV nonlinear optical material with unprecedented SHG and birefringence via π-conjugated rings and a unique “Warren truss structure”

    Inorganic Chemistry Frontiers · 2025-01-01

    Jie Gou, Yaolong Zhu, Xin Su, Can Hui Yang, YunJie Wang, Qingwen Zhu, Yi Xiong, Qi Wu

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  4. Greatly enhancing birefringence of fluorosilicates through the synergetic effect of functional units

    Inorganic Chemistry Frontiers · 2025-01-01

    Liang Ma, Yi‐Lei Lv, Bing-Wei Miao, Guo-Ren Zhu, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  5. Synthesis, characterization and theoretical calculations of a new rare-earth fluoride with a DUV cutoff edge

    Journal of Molecular Structure · 2025-04-08

    Xiaotian Ma, Shaohua Liu, Xifa Long, Yun Mo Yang

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  6. Structure, thermal properties and phase transition in RbCdHfF7: experiments and lattice dynamics calculations

    Solid State Sciences · 2025-08-12

    Evgeniy V. Bogdanov, Мaxim S. Моlokeev, М. В. Горев, A. V. Kartashev, Maxim S. Pavlovskiy, Evgeniy I. Pogoreltsev, N. M. Laptash, Igor N. Flerov

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  7. K5NaZr4F22(H2O)2: A Hydrated Zirconium Fluoride with a Second-Harmonic Generation Effect and a Short Ultraviolet Cutoff Edge Induced by Cosubstitution with Heterovalent Cations

    Inorganic Chemistry · 2025-08-27

    Bing-Wei Miao, Guo-Ren Zhu, Ling Wang, Wenfeng Zhou, Wenlong Liu, Ru‐Ling Tang

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  8. Chiral calcium thiocyanate hybrids: amino acid-enabled structural diversity and second-harmonic generation

    Chemical Communications · 2026-01-01

    Xuemei Wen, Yingjie Wang, Guohong Zou, Zhien Lin, Kang Min Ok

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  9. KNa2(Hf,Zr)F7 and KNa2HfF7: isostructural fluorides with phase-matchable second-harmonic generation

    Materials Today Chemistry · 2026-03-31

    Oksana Matselko, Zuzana Vasková, Zuzana Netriová, Jaroslav Rusnák, Mei Yan, Ru‐Ling Tang, Sheng-Ping Guo, Sanam Bashir, Eva Scholtzová, Aydar I. Rakhmatullin, Róbert Klement, Miroslav Boča

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  10. Deep-Ultraviolet Transparent Zr/Hf Fluorides with Second-Harmonic Generation Effects Induced by Alkali-Metal Modulation

    Inorganic Chemistry · 2026-06-26

    Ling Wang, Mei Yan, Min Li, Zheng-Yu Yang, X X Li, Wenfeng Zhou, Ru‐Ling Tang

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  11. Multidimensional Cation Modulation toward Phase-Matchable Nonlinear Optical Fluorides with Short UV Cutoff Edges

    Inorganic Chemistry · 2026-08-22

    Ling Wang, Mei Yan, Bing-Wei Miao, Guo-Ren Zhu, Min Li, Wenfeng Zhou, Ru‐Ling Tang

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