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RESEARCH PAPER · Chemical Science · 2025

Significant enhancement in the birefringence of metal phosphite halides via the introduction of π-conjugated cations

Ru‐Ling Tang, Yue Wang, Yi‐Lei Lv, Bing-Wei Miao, Wenlong Liu, Sheng‐Ping Guo

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Significant enhancement in the birefringence of metal phosphite halides via the introduction of π-conjugated cationsOriginalZnGa(SeO 3 ) 2 F: a UV transparent birefringent crystal explored in M( ii )–IIIA–selenite–F systems2Isovalent cation substitution strategy for enhancing nonlinear optical properties of iodate-selenate materials0A universal synthetic strategy for noncentrosymmetric lead oxyhalide frameworks with strong second-harmonic generation0Broadband infrared-transparent crystals enabled by heterologous isomorphic substitution0Crystal structures and optical properties of two layered lead halide phosphites Pb 3 (HPO 3 )Cl 4 ·H 2 O and Pb 3 (HPO 3 ) 2 Cl 2 ·H 2 O0Pyrazinamide–IBr: an organic–inorganic hybrid crystal exhibiting giant optical anisotropy0SnCl 2 [SC(NH 2 ) 2 ]: lone-pair and hydrogen-bonding triggered chromophore assembling for dual optical optimization0Hydrogen‐Bond‐Modulated Alignment of Iminodiacetic Acid Cations for Achieving Ultraviolet Second Harmonic Generation6Overcoming the Bandgap‐Birefringence Trade‐Off: Proton‐Transfer Engineering of High‐Performance Ultraviolet‐Transparent Organic Crystal5Halogen Anion-Mediated Substitution of Nitrate: Toward Polar Materials with Intense Second-Harmonic Generation Effects3K 3 Mg 2 [K 6 MgCl 3 ][Ga 20 S 36 ]: A Diamond-like Framework Based on Mixed-Type Supertetrahedra for Excellent Nonlinear Optical Property1Linear [ICl 2 ] Units Induced Giant Optical Anisotropy in AICl 2 (A = NH 4 , Rb): A Pathway to Advanced Birefringent Materials4(C 2 N 4 H 7 S)(H 2 PO 3 ): Optical Properties Study of a Metal‐Free Amidinothiourea Phosphite0Zn‐4‐Aminopyridine Coordination Compound as a Novel Saturable Absorber in Ho‐Doped Fiber Laser System0Steric‐Guided Coordination Engineering Enables Significantly Optimized Optical Anisotropy via Sulfur‐Driven [C 5 H 5 NS] Birefringence‐Active Groups0Coordination-Mode-Modulated Symmetry Breaking for Nonlinear Optical Crystals0Assembly of dual π-conjugated units toward enhanced birefringence in a 2D organic sulfonate crystal0

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17 direct citing papers saved.

  1. ZnGa(SeO 3 ) 2 F: a UV transparent birefringent crystal explored in M( ii )–IIIA–selenite–F systems

    Inorganic Chemistry Frontiers · 2025-12-20

    Tian-Tian He, C Hu, Ya-Ping Gong, Jiang‐Gao Mao, Fang Kong

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  2. Isovalent cation substitution strategy for enhancing nonlinear optical properties of iodate-selenate materials

    Journal of Alloys and Compounds · 2025-12-31

    Yinglei Han, Tongqing Sun, Hongde Liu, Dahuai Zheng, Shiguo Liu, Yongfa Kong, Jingjun Xu

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  3. A universal synthetic strategy for noncentrosymmetric lead oxyhalide frameworks with strong second-harmonic generation

    Chemical Science · 2026-01-01

    Chen Sun, Xingxing Jiang, Feiyuan Gong, Xiaotian T. Zhang, Chao Wu, Zheshuai Lin, Chi Zhang, Honghan Fei

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  4. Broadband infrared-transparent crystals enabled by heterologous isomorphic substitution

    Dalton Transactions · 2026-01-01

    B Yang, Ziqi Chen, Zhenjiang Lu, Juanjuan Lu

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  5. Crystal structures and optical properties of two layered lead halide phosphites Pb 3 (HPO 3 )Cl 4 ·H 2 O and Pb 3 (HPO 3 ) 2 Cl 2 ·H 2 O

    Dalton Transactions · 2026-01-01

    Zong-Jie Zhao, Yu-Zheng Yan, Jia-Jian Fu, Hongyan Wu, Jian‐Han Zhang

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  6. Pyrazinamide–IBr: an organic–inorganic hybrid crystal exhibiting giant optical anisotropy

    Dalton Transactions · 2026-01-01

    Meng-Fan Duan, Jiang‐Gao Mao, Bing‐Ping Yang

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  7. SnCl 2 [SC(NH 2 ) 2 ]: lone-pair and hydrogen-bonding triggered chromophore assembling for dual optical optimization

    Dalton Transactions · 2026-01-01

    Xing-Yu Bi, Yuting Gao, Chenyuan Ma, Zhi Gang Fang, Meihong Duan

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  8. Hydrogen‐Bond‐Modulated Alignment of Iminodiacetic Acid Cations for Achieving Ultraviolet Second Harmonic Generation

    Advanced Optical Materials · 2026-01-09

    Limin Duan, Xiaomin Zhang, Yan Chun Xiao, Daqing Yang, Y. Y. Wang, Bingbing Zhang

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  9. Overcoming the Bandgap‐Birefringence Trade‐Off: Proton‐Transfer Engineering of High‐Performance Ultraviolet‐Transparent Organic Crystal

    Angewandte Chemie · 2026-03-05

    Lin Qiu, Xing‐Yu Li, Bing-Wei Miao, Hongjian Yu, Wenlong Liu, Yifan Sun, Ru‐Ling Tang

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  10. Halogen Anion-Mediated Substitution of Nitrate: Toward Polar Materials with Intense Second-Harmonic Generation Effects

    Inorganic Chemistry · 2026-03-09

    Zheng-Yu Yang, Ming-Yang Cao, Liang Ma, Bing-Wei Miao, Xing-Yu Li, Wenfeng Zhou, Ru‐Ling Tang

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  11. K 3 Mg 2 [K 6 MgCl 3 ][Ga 20 S 36 ]: A Diamond-like Framework Based on Mixed-Type Supertetrahedra for Excellent Nonlinear Optical Property

    Chemistry of Materials · 2026-04-22

    Jun-Long Chen, Shao‐Min Pei, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo-Cong Guo

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  12. Linear [ICl 2 ] Units Induced Giant Optical Anisotropy in AICl 2 (A = NH 4 , Rb): A Pathway to Advanced Birefringent Materials

    Advanced Functional Materials · 2026-05-22

    Du Yinxia, C J Huang, Hongshan Wang, Linan Wang, Z Chen, Miriding Mutailipu, Shilie Pan, J F Li

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  13. (C 2 N 4 H 7 S)(H 2 PO 3 ): Optical Properties Study of a Metal‐Free Amidinothiourea Phosphite

    European Journal of Inorganic Chemistry · 2026-06-02

    Yueling Sun, An-Hua Gong

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  14. Zn‐4‐Aminopyridine Coordination Compound as a Novel Saturable Absorber in Ho‐Doped Fiber Laser System

    Annalen der Physik · 2026-08-01

    Khalil Kamaruzzaman, H. Ahmad, Norazriena Yusoff, Mousa I. Hussein, Shufeng Sun

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  15. Steric‐Guided Coordination Engineering Enables Significantly Optimized Optical Anisotropy via Sulfur‐Driven [C 5 H 5 NS] Birefringence‐Active Groups

    Small · 2026-08-14

    Jiachen Lu, Chong‐An Chen, Wei Zeng, Kang Min Ok

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  16. Coordination-Mode-Modulated Symmetry Breaking for Nonlinear Optical Crystals

    Inorganic Chemistry · 2026-08-24

    Lan Wang, Zhen Qin, Shu‐Fang Li, Xin-Ran Hao, Chu Chu, Bingbing Zhang, Dong Yan

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  17. Assembly of dual π-conjugated units toward enhanced birefringence in a 2D organic sulfonate crystal

    Science China Chemistry · 2026-09-15

    Longyun Xu, Hanjing Huang, Conggang Li, Huijian Zhao, Conghe Liu, Kaidong Xu, Jina Wang, Ning Ye, Zhanggui Hu

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