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RESEARCH PAPER · Chem · 2023

Bifunctional tandem catalytic upcycling of polyethylene to surfactant-range alkylaromatics

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Bifunctional tandem catalytic upcycling of polyethylene to surfactant-range alkylaromaticsOriginalQuantitative analyses of products and rates in polyethylene depolymerization and upcycling11A Supported Ziegler-Type Organohafnium Site Metabolizes Polypropylene8End-of-Life Plastics Management: A Review7Precise activation of C–C bonds for recycling and upcycling of plastics81Valorisation of Plastic Waste via Catalytic Hydrocracking: a Technological Survey4Depolymerization of waste polyethylene to linear alkenes via sequential dehydrogenation and metathesis19Catalytic Hydrogenolysis of Polyethylene Under Reactive Separation46Population Balance Equations for Reactive Separation in Polymer Upcycling20Upcycling Waste Plastics with a C–C Backbone by Heterogeneous Catalysis45Upgrading waste plastics to value-added aromatics30Supported Platinum Nanoparticles Catalyzed Carbon–Carbon Bond Cleavage of Polyolefins: Role of the Oxide Support Acidity27Chloride and Hydride Transfer as Keys to Catalytic Upcycling of Polyethylene into Liquid Alkanes3Chloride and Hydride Transfer as Keys to Catalytic Upcycling of Polyethylene into Liquid Alkanes29CO2-facilitated upcycling of polyolefin plastics to aromatics at low temperature56The Overlooked Potential of Sulfated Zirconia: Reexamining Solid Superacidity Toward the Controlled Depolymerization of Polyolefins11Coupled conversion of polyethylene and carbon dioxide catalyzed by a zeolite–metal oxide system50Hydrogenolysis of Poly(Ethylene‐co‐Vinyl Alcohol) and Related Polymer Blends over Ruthenium Heterogeneous Catalysts7Micelles Cascade Assembly to Tandem Porous Catalyst for Waste Plastics Upcycling3Micelles Cascade Assembly to Tandem Porous Catalyst for Waste Plastics Upcycling50Brønsted-acid sites induced photocatalytic cracking of low-polarity polyethylene plastics17Positioning dynamic polymeric materials within the modern polymer economy: From application to recycling and circularity10Efficient Photolytic Breakdown of Waste Polystyrene Foam Using an “All-in-One” Photo-HAT Reagent at Ambient Conditions21Chemical upcycling of high-density polyethylene into upcycled waxes as rheology modifiers and paper coating materials12Driving selective upcycling of mixed polyethylene waste with table salt11Recent advances in polyolefin plastic waste upcycling via mild heterogeneous catalysis route from catalyst development to process design25Plastic upgrading via catalytic pyrolysis with combined metal-modified gallium-based HZSM-5 and MCM-4110Unlocking opportunities: Supported metal catalysts for the chemical upcycling of waste plastics26Catalytic Upcycling of Polyolefins316Polyolefin waste to light olefins with ethylene and base-metal heterogeneous catalysts151Selective Upcycling of Polyolefins into High-Value Nitrogenated Chemicals80Cross-Linked Polyolefins: Opportunities for Fostering Circularity Throughout the Materials Lifecycle28One-pot synthesis of Ir subnanosized clusters supported on MWW nanosheets as effective catalysts for C-C bond hydrogenolysis2Influence of Trace Metal in Plastics on Catalyst Activity and Reusability during Polyolefins Upcycling with Polyoxometalates2Upcycling of polyolefins into detergents2Room-temperature co-upcycling of polyvinyl chloride and polypropylene50Polyethylene hydrogenolysis by dilute RuPt alloy to achieve H2-pressure-independent low methane selectivity70Kinetic Models for Polymer Upcycling by Tag-and-Cut Strategies6Heterogeneous catalysis strategies for polyolefin plastic upcycling: co-reactant-assisted and direct transformation under mild conditions15Base-Metal Heterogeneous Catalysts for Upgrading Plastics to Light Olefins3Bimetallic NiFe/Al 2 O 3 catalyst for efficient hydrogenolysis of polyethylene into aviation fuel range alkanes12Upgrading of waste polyolefins with non-noble metal catalysts21Ruthenium‐Catalyzed Deconstruction of Polyolefins: A Strategy to Up‐cycle Waste Polyethylene to Value‐Added Alkene1Ruthenium‐Catalyzed Deconstruction of Polyolefins: A Strategy to Up‐cycle Waste Polyethylene to Value‐Added Alkene20Anionic Surfactants from Reactive Separation of Hydrocarbons Derived from Polyethylene Upcycling8Investigating the Role of Acid Sites in the Hydrocracking of Polyethylene-EVOH Multilayer Film Waste over Pt/BEA Catalyst7Advances and Challenges in Low‐Temperature Upcycling of Waste Polyolefins via Tandem Catalysis25Advances and Challenges in Low‐Temperature Upcycling of Waste Polyolefins via Tandem Catalysis2Cold plasma-assisted co-conversion of polyolefin wastes and CO2 into aromatics over hierarchical Ga/ZSM-5 catalyst24Polyethylene Upcycling to Liquid Alkanes in Molten Salts under Neat and External Hydrogen Source-Free Conditions17Engineering porous Beta zeolite-encapsulated nickel catalyst for waste polyolefins upcycling26Synthesis and Tunable Properties of Chemically Recyclable Multiblock Copolymers via Tandem Olefin Metathesis Polymerizations6Co-recycling of plastics and other waste materials70Synergistic Catalysis for Recycling and Upcycling of Plastics35Methanolysis of mixed plastics catalyzed by ionic liquid: PET depolymerization and recycling of PP/PE8Coordinating cracking and hydrogenation of polyethylene waste via acid-metal site isolation for selective hydrocarbon production10Ambient solar thermal catalysis for polyolefin upcycling using copper encapsulated in silicon nanosheets and chloroaluminate ionic liquid32Polyethylene Hydrogenolysis over Ru Supported on Mesoporous MFI Zeolite: Effects of Mesoporosity and External Acid Sites16A Minimalist Design for a Dual-Catalyst System for High-Efficiency Conversion of Waste Plastics into Liquid Fuel Products27Mechanistic alteration of polyethylene oxidation via heterogenous catalysis for enhanced fatty di-carboxylic acid yields6Catalysis for the Energy Transition8Noble Metal‐Free Low‐Temperature Aromatization of Polyethylene Waste for High‐Quality Fuel Production8Noble Metal‐Free Low‐Temperature Aromatization of Polyethylene Waste for High‐Quality Fuel Production3Efficient conversion of polyethylene to light olefins by self-confined cracking and reforming22Circular economy strategies for converting waste plastics into surfactants6Plasma catalytic hydrogenolysis of polyethylene to gasoline-range fuels over Sm/USY catalysts10Advancing chemical recycling for waste plastic conversion1Plasma Catalysis for Plastic Waste Conversion into Value‐Added Products: Advancements and Perspectives11Upcycling of waste plastics, end-of-life tire rubber, and bio-derived oils for circular asphalt pavements: A Systematic review2A highly efficient and recyclable bone char for catalytic pyrolysis of polypropylene4Chemical recycling of polyolefin wastes: recent advances and insights into recycling routes0From inert carbon chains to closed-loop recycling: emerging polyolefin chemistry enabled by telechelic (macro)monomers0Advances in converting waste plastics into energy to bolster the circular economy1Supported Organoiridium-Pincer Catalysts for the Nonoxidative Dehydrogenation of High-Density Polyethylene1Research progress in metal-zeolite bifunctional systems for upcycling of waste polyolefins3Solar-driven upcycling of plastic waste using plasmonic black gold4Catalytic transfer reductive conversion of plastic wastes into fuel and chemicals0Acid sites in hydrogen-involved polyolefin upcycling: mechanistic insights and design principles0A semi-flow reactor design diverts catalytic hydrogenolysis of polyolefins to metastable kinetic products1Rational design of bifunctional catalysts for hydrocracking of polyethylene waste plastics to narrow-distributed liquid fuels4Upcycling of Vulcanized Rubber via Controlled Backbone Cleavage and Functionalization11Heterogeneous Transfer Dehydrogenation for Catalytic Upcycling of Polyethylene0Unraveling the Single-Site Origin of Strong Brønsted Acidity in Fluorinated γ-Al 2 O 35Catalytic Upcycling of Polyolefins and Polystyrene: Integrating Active Site Design With Mass Transfer Considerations4Oxygen-mediated tandem polyethylene upcycling for selective aromatic synthesis0Site-selective dehydrogenation and protonation synergy for efficient polyolefin upcycling into aromatics0Polymer and plastic waste recycling: Challenges and prospects towards a circular economy3Conversion of polyethylene to monoaromatics via a tandem catalytic strategy1Phosphorus-modified plate-like ZSM-5 for oriented regulation of product distribution in catalytic plastic cracking0Hydrocracking of LDPE to liquid fuel over HY zeolite supported Ni catalyst: synergistic effect among metal, porosity and acidity1Direct Alkane–Benzene Coupling Reactions with Bifunctional Zeolite-Encapsulated Metal Catalysts with Subnanoscale Intimacy0Boosting aromatic production from catalytic pyrolysis of polyethylene by Co-feeding CO2 over Zn-modified HZSM-5 zeolite1Selective hydrogenolysis of waste polyolefins to aviation fuel over a Co‑modified Ni/SiO2 catalyst1Synergistic effect of oxygen vacancies and acid sites promotes aqueous-phase photothermal co-catalytic oxidation of polystyrene to benzoic acid0Coupling Polyolefin Conversion and Methanol Reduction for C 9 –C 10 Alkylaromatic Production1Coupling Polyolefin Conversion and Methanol Reduction for C 9 –C 10 Alkylaromatic Production0Elucidating the Spatiotemporal Reaction Mechanism of Polyethylene Aromatization over ZSM-5 Zeolites1Comprehensive quantitative analysis of polyolefin hydrogenolysis toward plastic waste management0Catalyst Control of Alkylbenzene Molecular Architecture in Tandem Catalytic Hydrogenolysis-Aromatization of Polyethylene0TRAPDOR NMR Reveals How Surface Fluorination Changes the Conformation of Polyethylene Adsorbed on γ-Alumina0Upcycling of polymer waste into high value energy products0In Situ Hydrogen Utilization in Plastic Waste Recycling and Upcycling0

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  2. A Supported Ziegler-Type Organohafnium Site Metabolizes Polypropylene

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  3. End-of-Life Plastics Management: A Review

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  5. Valorisation of Plastic Waste via Catalytic Hydrocracking: a Technological Survey

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  7. Catalytic Hydrogenolysis of Polyethylene Under Reactive Separation

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  8. Population Balance Equations for Reactive Separation in Polymer Upcycling

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  9. Upcycling Waste Plastics with a C–C Backbone by Heterogeneous Catalysis

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  10. Upgrading waste plastics to value-added aromatics

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  14. CO2-facilitated upcycling of polyolefin plastics to aromatics at low temperature

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  15. The Overlooked Potential of Sulfated Zirconia: Reexamining Solid Superacidity Toward the Controlled Depolymerization of Polyolefins

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  16. Coupled conversion of polyethylene and carbon dioxide catalyzed by a zeolite–metal oxide system

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  17. Hydrogenolysis of Poly(Ethylene‐co‐Vinyl Alcohol) and Related Polymer Blends over Ruthenium Heterogeneous Catalysts

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  18. Micelles Cascade Assembly to Tandem Porous Catalyst for Waste Plastics Upcycling

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  19. Micelles Cascade Assembly to Tandem Porous Catalyst for Waste Plastics Upcycling

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  20. Brønsted-acid sites induced photocatalytic cracking of low-polarity polyethylene plastics

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  22. Efficient Photolytic Breakdown of Waste Polystyrene Foam Using an “All-in-One” Photo-HAT Reagent at Ambient Conditions

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  33. Influence of Trace Metal in Plastics on Catalyst Activity and Reusability during Polyolefins Upcycling with Polyoxometalates

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  34. Upcycling of polyolefins into detergents

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  35. Room-temperature co-upcycling of polyvinyl chloride and polypropylene

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  36. Polyethylene hydrogenolysis by dilute RuPt alloy to achieve H2-pressure-independent low methane selectivity

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  37. Kinetic Models for Polymer Upcycling by Tag-and-Cut Strategies

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  39. Base-Metal Heterogeneous Catalysts for Upgrading Plastics to Light Olefins

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  42. Ruthenium‐Catalyzed Deconstruction of Polyolefins: A Strategy to Up‐cycle Waste Polyethylene to Value‐Added Alkene

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  50. Engineering porous Beta zeolite-encapsulated nickel catalyst for waste polyolefins upcycling

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