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RESEARCH PAPER · ACS Applied Polymer Materials · 2024

Cross-Linked Polyolefins: Opportunities for Fostering Circularity Throughout the Materials Lifecycle

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Cross-Linked Polyolefins: Opportunities for Fostering Circularity Throughout the Materials LifecycleOriginalCircular Cross-Linked Polyethylene Enabled by In-Chain Ketones11Reactive Processing of Polyethylene with Azidotriazine: From Modified Thermoplastics to Injection Moldable Covalent Adaptable Networks7Repurposing Post‐Consumer Polyethylene to Access Cross‐Linked Polyethylene with Reprocessability, Recyclability, and Tunable Properties18Repurposing Post‐Consumer Polyethylene to Access Cross‐Linked Polyethylene with Reprocessability, Recyclability, and Tunable Properties2Mechanical Recycling of Crosslinked High-Density Polyethylene (xHDPE)8Degradation technologies for condensation polymers mediated by organic catalysts10Electric-Field-Assisted Crystal and Dielectric Properties of Polyethylene Blends6Effect of ultraviolet radiation aging on the optical properties of Si-XLPE insulation1Fully Recyclable and Remarkably Robust Cross-Linked Polyethylene Networks via Direct Free-Radical Copolymerization with Disulfide Dynamic Covalent Bonds19Understanding Non-isothermal Crystallization Behaviors of Polyethylene-Derived Vitrimers11Catalyst-Free Ethylene Vinyl Acetate Copolymer (EVA) Vitrimer Based on Titanate Exchange through a One-Step, Green, and Scalable Reactive Blending Approach3Catalyst Influence on the Crystallization Behaviors and Mechanical Properties of Polyethylene Vitrimers10Enhanced Recoverability and Recycling of Resistant Waste Crosslinked Polyethylene via FeTiO3 Catalyst-Assisted Slow Pyrolysis4Recent developments in recycling technologies for polymeric plastics8Creep-resistant, extrudable, and recyclable polyolefin covalent adaptable networks incorporating azine cross-links via reactive processing3Fabrication of dynamically cross-linked polyethylene with boronate ester bonds via a thiol–ene click reaction: thermal stability and reprocessability0Iterative Layer Folding: Decoupling Mixing and Crosslinking for Scorch Free Incorporation of Peroxides into Polyethylene0Sustainable insulating materials for power systems5Impact of Network Architecture and Cross-Link Aggregation on the Crystallization Behavior of a Polypropylene-Based Thermoset Polyurethane2Activation entropy of degradation of cross-linked polymer in catalyzed and uncatalyzed slow pyrolysis1Precision-Engineered Silane Distribution in Polyolefins Governs Cross-Linking Kinetics0Mechanical recycling of cross-linked polyethylene foam scrap wastes – Development of a mechanical recycling process and life cycle assessment0Polyvinyl chloride (PVC): modification, properties, industrial and diverse applications1Covalent adaptable networks act as macromolecular compatibilizers: Insights from polypropylene/polyethylene blends0Chemically and Mechanically Recyclable Polyolefins Incorporating Covalent Adaptable Networks0Potential of Thermoset Polyolefins for FRP Concrete Reinforcing Bars0Acyclic Hydrocarbon α , ω ‐Dienes: From Biomass and Plastic Upcycling to Carbocycles, Precision Polymers, and Cross‐Linked Elastomers0Reversible Cross-Linking of Ketone-Functionalized Polyethylenes through the Formation of Acetals0

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  1. Circular Cross-Linked Polyethylene Enabled by In-Chain Ketones

    ACS Macro Letters · 2024-11-15

    Tobias O. Morgen, Stefan Mecking

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  2. Reactive Processing of Polyethylene with Azidotriazine: From Modified Thermoplastics to Injection Moldable Covalent Adaptable Networks

    ACS Applied Polymer Materials · 2025-01-31

    Huidi Sun, Thomas Vialon, Clément Guibert, Sandra Casale, Renaud Nicolaÿ, Nathan J. Van Zee

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  3. Repurposing Post‐Consumer Polyethylene to Access Cross‐Linked Polyethylene with Reprocessability, Recyclability, and Tunable Properties

    Angewandte Chemie International Edition · 2025-02-26

    Kun Liu, Yucheng Zhao, Anna M. Wolff, Katherine L. Harry, Emma M. Rettner, Joel Miscall, Nicholas A. Rorrer, Garret M. Miyake

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  4. Repurposing Post‐Consumer Polyethylene to Access Cross‐Linked Polyethylene with Reprocessability, Recyclability, and Tunable Properties

    Angewandte Chemie · 2025-02-26

    Kun Liu, Yucheng Zhao, Anna M. Wolff, Katherine L. Harry, Emma M. Rettner, Joel Miscall, Nicholas A. Rorrer, Garret M. Miyake

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  5. Mechanical Recycling of Crosslinked High-Density Polyethylene (xHDPE)

    Processes · 2025-03-10

    Hibal Ahmad, Denis Rodrigue

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  6. Degradation technologies for condensation polymers mediated by organic catalysts

    Polymer Journal · 2025-06-18

    Kazuki Fukushima

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  7. Electric-Field-Assisted Crystal and Dielectric Properties of Polyethylene Blends

    Crystal Growth & Design · 2025-07-04

    Yongjun Li, Yongsen Han, Shanshan Wang, Di Jin, Zhonghua Li

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  8. Effect of ultraviolet radiation aging on the optical properties of Si-XLPE insulation

    Engineering Research Express · 2025-07-16

    Saadiya Afeissa, Larbi Boukezzi, I W Omrani, Lakhdar Bessissa

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  9. Fully Recyclable and Remarkably Robust Cross-Linked Polyethylene Networks via Direct Free-Radical Copolymerization with Disulfide Dynamic Covalent Bonds

    Journal of the American Chemical Society · 2025-07-24

    Logan M. Fenimore, Mathew J. Suazo, Sarah M. Mitchell, Hadi Mohammadi, Kimberly Miller McLoughlin, Cassandra Gallaschun, Patryk Sewruk, Markus Busch, John M. Torkelson

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  10. Understanding Non-isothermal Crystallization Behaviors of Polyethylene-Derived Vitrimers

    Macromolecules · 2025-08-20

    Sara Valdez, Zhe Qiang

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  11. Catalyst-Free Ethylene Vinyl Acetate Copolymer (EVA) Vitrimer Based on Titanate Exchange through a One-Step, Green, and Scalable Reactive Blending Approach

    ACS Applied Polymer Materials · 2025-10-22

    Siyu Guo, Xuanwei Zhang, Xiaopei Li, Yongjie Zhang

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  12. Catalyst Influence on the Crystallization Behaviors and Mechanical Properties of Polyethylene Vitrimers

    Macromolecules · 2025-10-27

    Sara Valdez, Zhe Qiang

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  13. Enhanced Recoverability and Recycling of Resistant Waste Crosslinked Polyethylene via FeTiO3 Catalyst-Assisted Slow Pyrolysis

    Recycling · 2025-10-31

    Pavel Straka, Olga Bičáková, Jaroslav Cihlář

    Read original paper ↗ ·
  14. Recent developments in recycling technologies for polymeric plastics

    Polymer Chemistry · 2025-12-29

    Zhihao Wang, En Fang, Liangyu Chen, Zhiqiang Fan, Shaofei Song

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  15. Creep-resistant, extrudable, and recyclable polyolefin covalent adaptable networks incorporating azine cross-links via reactive processing

    Polymer Chemistry · 2026-01-01

    Mathew J. Suazo, Stephanie M. Barbon, Hayley A. Brown, Evelyn Auyeung, Colin Li Pi Shan, Pi Shan, John M. Torkelson

    Read original paper ↗ ·
  16. Fabrication of dynamically cross-linked polyethylene with boronate ester bonds via a thiol–ene click reaction: thermal stability and reprocessability

    Polymer Chemistry · 2026-01-01

    Tianhao Nan, Yuxin Liang, Guangbi Gong, Bo Liu, Dongmei Cui

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  17. Iterative Layer Folding: Decoupling Mixing and Crosslinking for Scorch Free Incorporation of Peroxides into Polyethylene

    SSRN Electronic Journal · 2026-01-01

    Michail Maricanov, Robert David Ludwig Jerusalem, Joerg Christian Tiller, Frank Katzenberg

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  18. Sustainable insulating materials for power systems

    Nature Reviews Electrical Engineering · 2026-01-09

    Yi Li, Jie Ying Chen, ShengYao Shi, Qi Kang, Ju Tang, Xiaoxing Zhang, Song Xiao, Xingyi Huang

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  19. Impact of Network Architecture and Cross-Link Aggregation on the Crystallization Behavior of a Polypropylene-Based Thermoset Polyurethane

    Macromolecules · 2026-01-14

    Ronard Herrera Monegro, Josiah Hanson, Ioannis Mountziaris, Ramanan Krishnamoorti, Megan L. Robertson

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  20. Activation entropy of degradation of cross-linked polymer in catalyzed and uncatalyzed slow pyrolysis

    Next Materials · 2026-02-16

    Pavel Straka

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  21. Precision-Engineered Silane Distribution in Polyolefins Governs Cross-Linking Kinetics

    Macromolecules · 2026-02-27

    Jie Li, Jin Dong, Xinghao Fan, K Liu, Zhujun Huang, Chao He, Yabin Sun, Saurav S. Sengupta, Liangliang Zhu, Xiangcheng Pan

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  22. Mechanical recycling of cross-linked polyethylene foam scrap wastes – Development of a mechanical recycling process and life cycle assessment

    Cleaner Waste Systems · 2026-05-14

    Sahra M. Pogrzeba, Marina Mudersbach, Hans‐Josef Endres, Madina Shamsuyeva

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  23. Polyvinyl chloride (PVC): modification, properties, industrial and diverse applications

    Journal of Materials Science Materials in Engineering · 2026-05-19

    Great Iruoghene Edo, Ali B. M. Ali, Ayomide Chike Ahamefula, Maryam Rabiu Aliyu, Joseph Oghenewogaga Owheruo, Agatha Ngukuran Jikah, Ufuoma Augustina Igbuku, Emad A. Yousif, Ephraim Evi Alex Oghroro, Ibiyinka Fuwape, Arthur Efeoghene Athan Essaghah, Dina S. Ahmed, Ahmed A. Alamiery, Huzaifa Umar

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  24. Covalent adaptable networks act as macromolecular compatibilizers: Insights from polypropylene/polyethylene blends

    European Polymer Journal · 2026-06-26

    Yuanchu Gao, Hui Niu

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  25. Chemically and Mechanically Recyclable Polyolefins Incorporating Covalent Adaptable Networks

    Macromolecular Rapid Communications · 2026-07-01

    Andrii Tiiara, Bernadine Daichendt, Sergiy Minko, Olga Kuksenok, Igor A. Luzinov

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  26. Potential of Thermoset Polyolefins for FRP Concrete Reinforcing Bars

    Polymer Composites · 2026-07-07

    Osama Omar, Farzaneh Mahmoudi, Leonidas G. Bachas, Francisco De Caso, Brahim Benmokrane, Antonio Nanni

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  27. Acyclic Hydrocarbon α , ω ‐Dienes: From Biomass and Plastic Upcycling to Carbocycles, Precision Polymers, and Cross‐Linked Elastomers

    ChemSusChem · 2026-07-11

    Rosa Villaccio, Giuseppe Leone

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  28. Reversible Cross-Linking of Ketone-Functionalized Polyethylenes through the Formation of Acetals

    ACS Applied Polymer Materials · 2026-09-29

    Robin Lemmens, Tristan De Rijck, Jules Henrotte, Rodrigo de Oliveira Silva, Dimitrios Sakellariou, Anton Ginzburg, Dirk E De Vos

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