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RESEARCH PAPER · ACS Applied Materials & Interfaces · 2024

Supported Platinum Nanoparticles Catalyzed Carbon–Carbon Bond Cleavage of Polyolefins: Role of the Oxide Support Acidity

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Supported Platinum Nanoparticles Catalyzed Carbon–Carbon Bond Cleavage of Polyolefins: Role of the Oxide Support AcidityOriginalInfluence of Autoclave Liner on Polyethylene Hydrogenolysis Selectivity7Catalytic chemical recycling and upcycling of polyolefin plastics28Catalytic Upcycling of Polyolefins317The role of size and structure of catalytic active sites in polyolefin hydrogenolysis12Reshaping catalysis beyond the conventional0Cross-Linked Polyolefins: Opportunities for Fostering Circularity Throughout the Materials Lifecycle29Natural abundance 195Pt-13C correlation NMR spectroscopy on surfaces enabled by fast MAS dynamic nuclear polarization5Elucidating the effect of nanocube support morphology on the hydrogenolysis of polypropylene over Ni/CeO 2 catalysts7Enhancing liquified petroleum gas selectivity through hierarchical porosity in MWW-type MCM-49 zeolite for polyethylene hydrocracking0Techno-economic and life cycle analyses of the synthesis of a platinum–strontium titanate catalyst14Tandem Catalysis for Plastic Depolymerization: In Situ Hydrogen Generation via Methanol Aqueous Phase Reforming for Sustainable Polyethylene Hydrogenolysis2Tandem Catalysis for Plastic Depolymerization: In Situ Hydrogen Generation via Methanol Aqueous Phase Reforming for Sustainable Polyethylene Hydrogenolysis27Predicting a generalized mechanism of branched alkane hydrogenolysis on Ru, Ir, and Pt surfaces relevant to polymer upcycling applications3A Broad-Spectrum Catalyst for Aliphatic Polymer Breakdown4Methods for Carbon Mass Closure in Polyolefin Hydrocracking6High-Temperature Size Exclusion Chromatography for Advanced Recycling: Systematic Errors in Analysis of Polyethylene─Alkane Mixtures0Polymer Upcycling by Catalytic Hydrogenolysis: The Role of Polyolefin Short-Chain Branching3Synergy Effects in a Bimetallic Ru ─ Pt Alloy Catalyst for Low‐H 2 ‐Pressure Hydrogenolysis of Low‐Density Polyethylene4Large-Mesopore Catalysts Synthesized via Calcination and Hydrothermal Treatment of Zinc-Meso-Y Zeolite Composites0Surface and Interface Properties of Metal Species for Waste Plastic Hydroconversion7Data-Driven Discovery of Bimetallic Nanoparticles Catalysts for the Hydrogenolysis of Polyethylene3Acidified montmorillonite (MMT)-supported ultrafine Ru nanoparticles for polyethylene plastic upcycling0An integrated techno-economic analysis and life cycle assessment of lube oil production from post-use polypropylene and comparison with conventional base oils0A semi-flow reactor design diverts catalytic hydrogenolysis of polyolefins to metastable kinetic products1Heterogeneous Transfer Dehydrogenation for Catalytic Upcycling of Polyethylene0Techno-economic analysis and life cycle assessment for the catalytic hydrogenolysis and hydrocracking of polyethylene6Low-Temperature Pyrolysis of Aliphatic Polymers Using a Fluorinated Amorphous Silica–Alumina: Cooperative Reactivity between a Redox-Active Radical and an Aluminum Lewis Site0

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  1. Influence of Autoclave Liner on Polyethylene Hydrogenolysis Selectivity

    ACS Sustainable Resource Management · 2024-06-10

    Makenna L. Pennel, Yile Jiang, Matteo Cargnello

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  2. Catalytic chemical recycling and upcycling of polyolefin plastics

    Giant · 2024-06-14

    Yingzi Tan, Yidan Cheng, Jiaming Xu, Haobing Wang

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  3. Catalytic Upcycling of Polyolefins

    Chemical Reviews · 2024-08-16

    Jia‐Kai Sun, Jinhu Dong, Lijun Gao, Yu‐Quan Zhao, Hyunjin Moon, Susannah L. Scott

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  4. The role of size and structure of catalytic active sites in polyolefin hydrogenolysis

    Chem Catalysis · 2024-08-20

    Jueun Kim, Simin Sun, Donghyeon Kim, Byung Gwan Park, Hojeong Lee, Wenyu Huang, Kwangjin An

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  5. Reshaping catalysis beyond the conventional

    Nature Catalysis · 2024-08-27

    Amani M. Ebrahim

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  6. Cross-Linked Polyolefins: Opportunities for Fostering Circularity Throughout the Materials Lifecycle

    ACS Applied Polymer Materials · 2024-09-20

    Alison J. Shapiro, Paul J. Brigandi, Maria Moubarak, Saurav S. Sengupta, Thomas H. III Epps

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  7. Natural abundance 195Pt-13C correlation NMR spectroscopy on surfaces enabled by fast MAS dynamic nuclear polarization

    Journal of Magnetic Resonance Open · 2024-10-09

    Zhuoran Wang, Thomas C. Robinson, Domenico Gioffrè, Rochlitz Lukas, David Gajan, Aaron J. Rossini, Christophe Copéret, Anne S. J. Lesage

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  8. Elucidating the effect of nanocube support morphology on the hydrogenolysis of polypropylene over Ni/CeO 2 catalysts

    Journal of Materials Chemistry A · 2024-12-10

    Donald R. Inns, Megan Carr, Mounib Bahri, Ajay Tomer, Troy D. Manning, Nigel D. Browning, Simon A. Kondrat, John B. Claridge, Alexandros P. Katsoulidis, Matthew J. Rosseinsky

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  9. Enhancing liquified petroleum gas selectivity through hierarchical porosity in MWW-type MCM-49 zeolite for polyethylene hydrocracking

    Catalysis Science & Technology · 2025-01-01

    Ruoyan Bai, Juhong Nie, Roudan Lian, Jian Zhang, Maolin Zhang

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  10. Techno-economic and life cycle analyses of the synthesis of a platinum–strontium titanate catalyst

    Catalysis Science & Technology · 2025-01-01

    Sultana Ferdous, Ulises R. Gracida-Alvarez, Magali S. Ferrandon, Massimiliano Delferro, Pahola Thathiana Benavides, Meltem Urgun‐Demirtas

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  11. Tandem Catalysis for Plastic Depolymerization: In Situ Hydrogen Generation via Methanol Aqueous Phase Reforming for Sustainable Polyethylene Hydrogenolysis

    Angewandte Chemie · 2025-01-22

    Junsung Lee, Taeeun Kwon, Ki Hyuk Kang, Wangyun Won, Insoo Ro

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  12. Tandem Catalysis for Plastic Depolymerization: In Situ Hydrogen Generation via Methanol Aqueous Phase Reforming for Sustainable Polyethylene Hydrogenolysis

    Angewandte Chemie International Edition · 2025-01-22

    Junsung Lee, Taeeun Kwon, Ki Hyuk Kang, Wangyun Won, Insoo Ro

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  13. Predicting a generalized mechanism of branched alkane hydrogenolysis on Ru, Ir, and Pt surfaces relevant to polymer upcycling applications

    Journal of Catalysis · 2025-05-08

    Andy Simonson, Lydia Thies, David D. Hibbitts

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  14. A Broad-Spectrum Catalyst for Aliphatic Polymer Breakdown

    Journal of the American Chemical Society · 2025-05-13

    Jiaxin Gao, Frédéric A. Perras, Matthew P. Conley

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  15. Methods for Carbon Mass Closure in Polyolefin Hydrocracking

    JACS Au · 2025-07-24

    Anna E. Brenner, Griffin Drake, Gregg T. Beckham, Yuriy Román‐Leshkov

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  16. High-Temperature Size Exclusion Chromatography for Advanced Recycling: Systematic Errors in Analysis of Polyethylene─Alkane Mixtures

    ACS Applied Polymer Materials · 2025-08-01

    Mason D. Jones, Christine W. Barker, Fawaz Motolani, Rakesh Patter, S. Michael Kilbey, Bert D. Chandler, Brian K. Long, Bryan D. Vogt

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  17. Polymer Upcycling by Catalytic Hydrogenolysis: The Role of Polyolefin Short-Chain Branching

    ACS Catalysis · 2025-09-23

    Zachary M. Gdowski, Rishi Raj, Aditya Bhan, K. Andre Mkhoyan, Mahesh K. Mahanthappa, Frank S. Bates

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  18. Synergy Effects in a Bimetallic Ru ─ Pt Alloy Catalyst for Low‐H 2 ‐Pressure Hydrogenolysis of Low‐Density Polyethylene

    Chemistry - A European Journal · 2025-11-02

    Yukari Yamazaki, Xiongjie Jin, Weihan Sun, Satoshi Yamamoto, Katsutoshi Nomoto, Kohei Takahashi, Hiroki Miura, Tetsuya Shishido, Akira Nakayama, Kyoko Nozaki

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  19. Large-Mesopore Catalysts Synthesized via Calcination and Hydrothermal Treatment of Zinc-Meso-Y Zeolite Composites

    Chemistry of Materials · 2025-11-11

    Xuemin Li, Oleksandr O. Trybrat, Abraham Martinez, Jinyi Han, Kaustav Chaudhuri, Yi-Sheng Chen, Cong-Yan Chen, Michael Girgis, Joel E. Schmidt, Howard S. Lacheen, A. Kuperman, Son‐Jong Hwang, Alexander Katz

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  20. Surface and Interface Properties of Metal Species for Waste Plastic Hydroconversion

    ACS Catalysis · 2025-12-10

    Fan Yuan, Hongshun Ran, Tingxi Chen, Yaxuan Jing

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  21. Data-Driven Discovery of Bimetallic Nanoparticles Catalysts for the Hydrogenolysis of Polyethylene

    ACS Catalysis · 2025-12-19

    Carly Byron, Katherine McCullough, Jacklyn N. Hall, Salai Cheettu Ammal, Andreas Heyden, Jacob T. Bryant, Yiyu Wang, Kajol Tonk, Jianguo Wen, Arthur Jeremy Kropf, Wenyu Huang, Aaron David Sadow, Massimiliano Delferro, Magali S. Ferrandon

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  22. Acidified montmorillonite (MMT)-supported ultrafine Ru nanoparticles for polyethylene plastic upcycling

    Green Chemistry · 2026-01-01

    Ruoyan Bai, Roudan Lian, Jian Zhang, Maolin Zhang

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  23. An integrated techno-economic analysis and life cycle assessment of lube oil production from post-use polypropylene and comparison with conventional base oils

    RSC Sustainability · 2026-01-01

    Sultana Ferdous, Ulises R. Gracida-Alvarez, Pahola Thathiana Benavides, Meltem Urgun‐Demirtas

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  24. A semi-flow reactor design diverts catalytic hydrogenolysis of polyolefins to metastable kinetic products

    Applied Catalysis B: Environmental · 2026-02-10

    Yiyu Wang, Ruoyu Cui, Changhae Andrew Kim, Chao Meng, Mubarak Bello, Emma L. Fetters, Emerson G. Waltz, Long Qi, Andreas Heyden, Baron Peters, Wenyu Huang, Aaron David Sadow

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  25. Heterogeneous Transfer Dehydrogenation for Catalytic Upcycling of Polyethylene

    ChemSusChem · 2026-03-15

    Tim de la Croix, Nathalie Claes, Sara Bals, Dirk E De Vos

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  26. Techno-economic analysis and life cycle assessment for the catalytic hydrogenolysis and hydrocracking of polyethylene

    Joule · 2026-03-23

    Geetanjali Yadav, Taylor Uekert, Jason S. DesVeaux, Elisabeth C. Van Roijen, Julie E. Rorrer, Anna E. Brenner, Griffin Drake, Guido Zichittella, Nick Carlson, Yuriy Román‐Leshkov, Gregg T. Beckham

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  27. Low-Temperature Pyrolysis of Aliphatic Polymers Using a Fluorinated Amorphous Silica–Alumina: Cooperative Reactivity between a Redox-Active Radical and an Aluminum Lewis Site

    Journal of the American Chemical Society · 2026-04-27

    Jiaxin Gao, Avijit Mondal, Riley Pritchett, Paul H. Oyala, Matthew P. Conley

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