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RESEARCH PAPER · Angewandte Chemie International Edition · 2021

LiZn(OH)CO3: A Deep‐Ultraviolet Nonlinear Optical Hydroxycarbonate Designed from a Diamond‐like Structure

Xiaomeng Liu, Lei Kang, Pifu Gong, Zheshuai Lin

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LiZn(OH)CO3: A Deep‐Ultraviolet Nonlinear Optical Hydroxycarbonate Designed from a Diamond‐like StructureOriginalBa 2 [FeF 4 (IO 3 ) 2 ]IO 3 : a promising nonlinear optical material achieved by chemical-tailoring-induced structure evolution8Co-crystal AX·(H 3 C 3 N 3 O 3 ) (A = Na, Rb, Cs; X = Br, I): a series of strongly anisotropic alkali halide cyanurates with a planar structural motif and large birefringence13Zn(NH 3 )CO 3 : a “three-in-one” UV nonlinear optical crystal built by a polar molecule bonding strategy18Mg 2 In 3 Si 2 P 7 : A Quaternary Diamond-like Phosphide Infrared Nonlinear Optical Material Derived from ZnGeP 2130AZn4(OH)4(C3N3O3)2 (A = Mg, Zn): Two Zn-Based Cyanurate Crystals with Various Cation Coordination and Large Birefringence22A General Principle for DUV NLO Materials: π‐Conjugated Confinement Enlarges Band Gap**175A General Principle for DUV NLO Materials: π‐Conjugated Confinement Enlarges Band Gap**27Achieving Short‐Wavelength Phase‐Matching Second Harmonic Generation in Boron‐Rich Borosulfate with Planar [BO3] Units102Achieving Short‐Wavelength Phase‐Matching Second Harmonic Generation in Boron‐Rich Borosulfate with Planar [BO3] Units9Strong SHG Responses in a Beryllium‐Free Deep‐UV‐Transparent Hydroxyborate via Covalent Bond Modification89Strong SHG Responses in a Beryllium‐Free Deep‐UV‐Transparent Hydroxyborate via Covalent Bond Modification9A Lead Mixed Halide with Three Different Coordinated Anions and Strong Second‐Harmonic Generation Response10A New Nonlinear Optical Material with N(CN)2− Anion2The Electronic Structural and Defect-Induced Absorption Properties of a Ca2B10O14F6 Crystal1Ca-cluster-constructed deep-ultraviolet nonlinear-optical crystal Na2Ca17Al2(PO4)14 with strong NLO response11NaSb3O2(SO4)3·H2O: A New Alkali-Metal Antimony(III) Sulfate with a Unique Sb6O20H4 Unit and Moderate Birefringence19AZn 2 (BO 3 )Si 2 O 5 (A = Rb, Cs): first examples of KBe 2 BO 3 F 2 structure type in the borosilicate family exhibiting a deep-ultraviolet cutoff edge25Guanidinium Fluorooxoborates as Efficient Metal-free Short-Wavelength Nonlinear Optical Crystals140Hierarchical Modulation of Optical Anisotropy Driven by Metal Cation Polyhedra in Fluorooxoborates MIIB4O6F2 (MII=Be, Mg, Pb, Zn, Cd)6An excellent lead oxyiodide with a strong second-harmonic generation response and a large birefringence induced by the oriented arrangement of highly distorted [PbO 4 I 2 ] polyhedra13APb 2 (C 7 H 3 NO 4 ) 2 I (A = K, Rb, Cs): rare stable nonlinear optical crystals with second-harmonic generation response and highly distorted lead core coordination polyhedra2Hexameric poly-fluoroberyllophosphate Na 4 Be 2 PO 4 F 5 with moderate birefringence and deep-ultraviolet transmission as a potential zero-order-waveplate crystal17KPb 3 ( o -C 5 H 4 NCOO) 2 Cl 5 : a brand-new stable lead chloride with good comprehensive nonlinear optical performance5Large optical anisotropy-oriented construction of a carbonate-nitrate chloride compound as a potential ultraviolet birefringent material44Rbcl·(H2seo3)2: A New Salt-Inclusion Selenite as a Promising Uv Birefringent Material0Review of Heteroleptic Tetrahedra as Birefringent or Nonlinear Optical Motifs17Ba6(CuxZy)Sn4S16 (Z = Mg, Mn, Zn, Cd, In, Bi, Sn): High Chemical Flexibility Resulting in Good Nonlinear-Optical Properties12Chiral Ligand‐Driven Systematic Synthesis of Coordination Polymers with Non‐centrosymmetric Structures12The dependence of crystal structure and ultraviolet nonlinear optical property of KBe2BO3F2 by density functional theory and π-conjugate confinement2Two Indium Iodate–Nitrates with Large Birefringence Induced by Hybrid Anionic Functional Groups and Their Favorable Arrangements22Finding the First Squarates Nonlinear Optical Crystal NaHC4O4·H2O with Strong Second Harmonic Generation and Giant Birefringence56Uncovering a Vital Band Gap Mechanism of Pnictides49Noncentrosymmetric Rare-Earth Borate Fluoride La2B5O9F3: A New Ultraviolet Nonlinear Optical Crystal with Enhanced Linear and Nonlinear Performance48An Optimized KBe2BO3F2‐Like Structure: The Unity of Deep‐Ultraviolet Transparency, Nonlinear Optical Property, and Ferroelectricity22(NH4)3B11PO19F3: a deep-UV nonlinear optical crystal with unique [B5PO10F]∞ layers142Two Metal Phosphate Nonlinear Optical Materials Simultaneously Exhibiting Ultraviolet Transparence and a Large Birefringence50AgGaSe2-Inspired Nonlinear Optical Materials: Tetrel Selenides of Alkali Metals and Mercury34Deep-ultraviolet nonlinear optical crystals: concept development and materials discovery181Cation-anion synergetic interactions achieving tunable birefringence in quasi-one-dimensional antimony(III) fluoride oxalates58Directional Construction of New Nonlinear Optical Bifunctional Units through Molecular Engineering Design Inspired by the B 3 O 7 -Typed Configuration23[C(NH2)3]2Zn(CO3)2: A Guanidinium-Templated Ultraviolet Nonlinear Optical Material20Difluoro(oxalato)borates as Short-Wavelength Optical Crystals with Bifunctional [BF 2 C 2 O 4 ] Units38Mixed-Anion-Oriented Design of LnMGa3S6O (Ln = La, Pr, and Nd; M = Ca and Sr) Nonlinear Optical Oxysulfides with Targeted Property Balance56NaB3O4F(OH): A Hydroxyfluorooxoborate with One-Dimensional Chain Featuring Large Birefringence and Short Ultraviolet Cutoff Edge5Design of novel deep-UV nonlinear optical materials with one-dimensional functional module [BO2]∞ chain and fluorine-driven short phase-matching43Achieving Large Second Harmonic Generation Effects via Optimal Planar Alignment of Triangular Units64CaBO2F: A novel deep-UV structural template with high nonlinear optical performance induced by electron delocalization25RbCl·(H2SeO3)2: A Salt-Inclusion Selenite Featuring Short UV Cut-Off Edge and Large Birefringence15Deep-ultraviolet nonlinear-optical crystal BaNa2[PO3(OH)]2 with large birefringence and strong second-harmonic-generation response8Enhancing birefringence of non-π-conjugated sulfate systems through rare-earth metal-centered polyhedra10K 5 [B 3 O 3 F 4 (OH)] 2 (NO 3 ): the first hydroxyfluorooxoborate-nitrate with a short ultraviolet cutoff edge and large birefringence18Nitrides: a promising class of nonlinear optical material candidates9Recent progress in borate-based short-wavelength nonlinear optical crystals with boron–oxygen skeleton modification28The Kurtz–Perry Powder Technique Revisited: A Study of the Effect of Reference Selection on Powder Second-Harmonic Generation Response20A Rare‐Earth Selenite with Unexpectedly Well‐Balanced Ultraviolet Nonlinear Optical Functionality, Sc(HSeO 3 ) 331Recent advances of inorganic phosphates with UV/DUV cutoff edge and large second harmonic response7Two Mixed-Alkali-Metal Selenates as Short-Wave Ultraviolet Nonlinear-Optical Materials10Target‐Driven Design of Deep‐UV Nonlinear Optical Materials via Interpretable Machine Learning125Elucidating the structure-nonlinear optical property relationship of Te2O4(OH)26AKTeO2(CO3) (A = Li, Na): The First Carbonatotellurites Featuring a Zero-Dimensional [Te2C2O10]4– Cluster and a Wide Band Gap5Recent progress of newly developed functional building units and corresponding nonlinear optical materials14“Cation Activation”: An Effective Strategy for the Enhancement of Birefringence36Design of the Ionic Organic Nonlinear Optical Material NH 4 [LiC 3 H(CH 3 )O 4 ] with Ultrawide Band Gap and Moderate Birefringence79Design of the Ionic Organic Nonlinear Optical Material NH 4 [LiC 3 H(CH 3 )O 4 ] with Ultrawide Band Gap and Moderate Birefringence9Hg3(SeO3)2(SO4): A UV Nonlinear Optical Mercury Selenite Sulfate Constructed by Neat [Hg6O8(SeO3)4]∞ Layers and SO4 Tetrahedra27Design Principles for Noncentrosymmetric Materials23Fluorooxoborate Promoting the Exploration of Short-Wavelength Linear and Nonlinear Optical Crystals with Expected Properties and Versatile Structures27The Strategy to Improve the Phase Matching Ability in Tetrahedron‐Based Deep‐Ultraviolet Nonlinear Optical Crystals21Crystal structure of K6[Zn(CO3)4]0Centrosymmetric Rb2Sb(C2O4)2.5(H2O)3 and Noncentrosymmetric RbSb2(C2O4)F5: Two Antimony (III) Oxalates as UV Optical Materials20Quadruple‐Bidentate Nitrate‐Ligated A 2 Hg(NO 3 ) 4 (A=K, Rb): Strong Second‐Harmonic Generation and Sufficient Birefringence59Quadruple‐Bidentate Nitrate‐Ligated A 2 Hg(NO 3 ) 4 (A=K, Rb): Strong Second‐Harmonic Generation and Sufficient Birefringence2Enlargement of Bandgap and Birefringence in Nonlinear Optical Alkali‐Metal Sulfate Crystals by the Substitution of Asymmetrical Non‐π‐Conjugated Cation8Sr(NH2SO3)(NO3)·H2O: An Ultraviolet Nonlinear Optical Material Exhibiting Strong Second-Harmonic Generation Response and Sufficient Birefringence10New Functional Groups Design toward High Performance Ultraviolet Nonlinear Optical Materials95Na 10 Zn(NO 3 ) 4 (SO 3 S) 4 : a nonlinear optical crystal combining inorganic π-conjugated and non-π-conjugated heteroanion groups8A Ferroelectric Nonlinear Optical Crystal for Deep‐UV Quasi‐Phase‐Matching51A2Hgx(SeO3)y (A = K, Rb, Cs): Three Alkali Metal Mercury Selenites Featuring Unique 1D [HgOm(SeO3)n]∞ Chains13Rational Design of the Alkali Metal Sn‐Based Mixed Halides with Large Birefringence and Wide Transparent Range44Secondary‐Bond‐Driven Construction of a Polar Material Exhibiting Strong Broad‐Spectrum Second‐Harmonic Generation and Large Birefringence9Secondary‐Bond‐Driven Construction of a Polar Material Exhibiting Strong Broad‐Spectrum Second‐Harmonic Generation and Large Birefringence41A bifunctional primitive strategy induces enhancements of large second harmonic generation and wide UV transmittance in rare-earth borates containing [B 5 O 10 ] groups22Crystal clear: unveiling giant birefringence in organic–inorganic cocrystals33Exploration of silver borates with diverse low-dimensional anion frameworks by introducing monovalent heteroanions6Exploring a new short-wavelength nonlinear optical fluoride material featuring unprecedented polar cis -[Zr 6 F 34 ] 10− clusters48Fully tricoordinated assembly unveils a pioneering nonlinear optical crystal (SbTeO 3 )(NO 3 )25Hydrogen bonding bolstered head-to-tail ligation of functional chromophores in a 0D SbF 3 ·glycine adduct for a short-wave ultraviolet nonlinear optical material32KBa 3 M 2 F 14 Cl (M = Zr, Hf): novel short-wavelength mixed metal halides with the largest second-harmonic generation responses contributed by mixed functional moieties37Shooting short-wavelength nonlinear optical materials with targeted balance performances in hydroxyborates through first-principles high-throughput screening4Hierarchical van der Waals Assemblies to Boost Deep‐Ultraviolet Nonlinear‐Optical Capabilities in Boron Phosphate8Synthesis and Characterization of Metal Iso-cyamelurate K0.5In0.5(H2C6N7O3)2·9H2O with Large Birefringence8Synthesis, structures and properties of two new nitrate optical materials: Rb3ZnNO3Cl4 and Rb5Na(NO3)4Cl24Giant Optical Anisotropy in a Covalent Molybdenum Tellurite via Oxyanion Polymerization43AYSO4F2 (A = K, Rb): [YO4F4] Polyhedra Enhancement of Birefringence in Non-π-Conjugated Sulfate Systems9Record Second-Harmonic Generation and Birefringence in an Ultraviolet Antimonate by Bond Engineering157A perspective on deep-ultraviolet nonlinear optical materials13Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals66Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals8KSb2F7·2KNO3: Unveiling the peak birefringence in inorganic antimony oxysalts10Fluorine-driven materials design of novel deep-ultraviolet nonlinear optical crystal materials: Research progress and challenges6Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66Bi(SO4)F·H2O and Bi(SO4)(NO3)·3H2O: Chemical Substitution-Induced Birefringence Enhancement in Bismuth Sulfates6Gradual Increase in Birefringence of Antimony Oxalates through Precise Tuning of the Sb3+/[C2O4]2– Ratio7NaK5La2(SO4)6: Enhanced Birefringence of Multiple-Alkali Metal Sulfate Systems via Rare Earth Metal-Centered Polyhedra5(C5H12N2S)Hg(NO3)2: A Mercury Nitrate Nonlinear Optical Crystal Motivated by Heteroatom Coordination Strategy9Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering61Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering4Ba2ScBSi2O9: A Mixed-Coordination Borosilicate with a Low B/Si Ratio Exhibiting Enhanced Second Harmonic Generation Response7C6N7(NH2)3·H3PO4: Strong Second Harmonic Generation and Giant Birefringence Benefiting from Amino Substitution Strategy24Breaking Symmetry for SHG Response: Lanthanide Acetate Crystals via Water Molecule Regulation Strategy5LaAgSiS4: Increasing Optical Birefringence in Rare Earth Chalcogenide by Addition of Planar [AgS3] Groups5Elucidating the Photo‐Induced Electronic Structure and Mechanisms of ZnAl‐Layered Double Hydroxide: A DFT Study0Two α‐SiO 2 ‐Related Deep‐Ultraviolet Phase‐Matchable Optical Nonlinear Beryllium Silicate Crystals Na 2 BeSiO 4 and Li 2 BeSiO 4 with Enhanced SHG Effect10From HgGa2(SeO3)4 to Hg2Ga(SeO3)2F: The first HgI-based selenite birefringent crystal triggered by linear groups and fluoride ions29Chiral-driven formation of hybrid cyanurates with large birefringence2Two l -Proline Cadmium Thiocyanates with Moderate Second-Harmonic-Generation Responses and Large Birefringences13Birefringence Disparity Induced by Synergistic Effects of Stereochemically Active Lone Pairs19Rational design of a series of non-centrosymmetric antiperovskite and double antiperovskite borate fluorides13Cationic Coordination Modification Drives Birefringence and Nonlinear Effect Double Lifting in Sulfate4Deep ultraviolet transparent borophosphates LiAB 2 P 2 O 9 (A = NH 4 , K) and LiNaB 2 P 2 O 8 (OH) 2 ·H 2 O exhibiting a moderate second-harmonic generation response4“All-four-in-one”: a novel mercury tellurite–nitrate Hg 3 (TeO 3 )(Te 3 O 7 )(NO 3 ) 2 exhibiting exceptional optical anisotropy29“Three functions in one”: multifunctional rare-earth cyamelurates with magnetism, luminescence, and giant optical nonlinearity6A strongly birefringent sulfate crystal with a wide second-harmonic generation phase-matching range4A π-conjugated organic molecule-modified strategy to achieve high-performance metal nitrate birefringent crystals9Assembling 4f and 3d–4f clusters as single-molecule magnets by automatic fixation of atmospheric CO 25Deep-ultraviolet nonlinear-optical crystals LiBePO 4 and BeP 2 O 6 synthesized by ionic potential modulation towards uniform arrangement of PO 4 groups5Deep-ultraviolet sulfamate halides with halogen-centered secondary building units for enhanced optical anisotropy4Design and Synthesis of Vanadium-Based Infrared Nlo Crystal K4cdv5o15br Through Aliovalent Substitution with Strongly Polarized Active Units0Exploring Novel Mixed Metal Sulfate Hydrates with Short UV Cut-Off Edges0Realizing large birefringence via S-substitution and anisotropic arrangement optimization4层状结构深紫外非线性光学晶体研究进展（特邀）2Sr2Zn(C3N3O3)2: An Alkaline Earth and d10 Transition Metal Based Ultraviolet Cyanurate with Large Birefringence6Ln(HCOO) 3 (Ln = Y, Gd, Ce, and La) With Triangular Configuration Exhibits Excellent UV Nonlinear Optical Performance12[C 2 N 4 H 7 O][NH 2 SO 3 ]: High‐Performance Ultraviolet Nonlinear Optical Crystal with Ditrigon Coupled Guanylurea Group9[C 2 N 4 H 7 O][NH 2 SO 3 ]: High‐Performance Ultraviolet Nonlinear Optical Crystal with Ditrigon Coupled Guanylurea Group48Chiral-Unit-Oriented Design of Non-π-Conjugated Noncentrosymmetric Phosphates with Short Absorption Edges4Na3Y2F3P2O8 and K4Y3F5P4O14: [YOF] Polyhedra Inducing Birefringence Enhancement in Non-π-Conjugated Phosphate Systems3K3[HCO3]2F: a new deep-UV birefringent crystal exhibiting strong optical anisotropy17Series of New Alkali Metal Hafnium-Based Iodates A2Hf(IO3)6 (A = K, Rb, Cs) and Isomorphic Ba2Zn(IO3)6 with Large Birefringence1(3‐C6H10N2)ZnX4 (X = Cl and Br): Two Excellent UV Nonlinear Optical Crystals Designed by Combination of π‐conjugated and [ZnX4]2− Tetrahedral Units26Bridging the Interlayer Binding to Ordered π‐Conjugated Units for Constructing High‐Performing Light Polarization Crystals8Bridging the Interlayer Binding to Ordered π‐Conjugated Units for Constructing High‐Performing Light Polarization Crystals48Multifunctional Cd‐based Hybrid with Large Birefringence Achieving Excellent Second Harmonic Generation and Reversible Temperature‐Activated Fluorescence for Anti‐counterfeiting16A Promising Short-Wave UV NLO Crystal with an Optimized KBBF-like Structure and Well-Balanced Properties Achieved via a Chemical Substitution Strategy6Synthesis and Characterization of (H7C5N2)6(V10O28)·2H2O with Edge-Sharing VO6 Octahedra Exhibiting Large Birefringence2Reversal Enhancement of Birefringence by Stereochemically Active Lone Pairs in Sn(II)-Based Mixed Halides0Studies on Three 3D Bimetallic Tellurates: Including a Second-Order NLO Material with d10-Zn2+ and SOJT-Effect Te4+/Mo6+ Cations2Anion-Ordered [B3O5(OH)2] Induced by Crystal Water with Deep Ultraviolet Transparency and Large Birefringence in Boron-Rich Borophosphates4K5NaZr4F22(H2O)2: A Hydrated Zirconium Fluoride with a Second-Harmonic Generation Effect and a Short Ultraviolet Cutoff Edge Induced by Cosubstitution with Heterovalent Cations6KF·[SO 2 (NH 2 ) 2 ]: the First Deep‐Ultraviolet Transparent Sulfonamide Fluoride Nonlinear Optical Crystal with Novel Cairo Pentagonal Structure13

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  1. Ba 2 [FeF 4 (IO 3 ) 2 ]IO 3 : a promising nonlinear optical material achieved by chemical-tailoring-induced structure evolution

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  2. Co-crystal AX·(H 3 C 3 N 3 O 3 ) (A = Na, Rb, Cs; X = Br, I): a series of strongly anisotropic alkali halide cyanurates with a planar structural motif and large birefringence

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  3. Zn(NH 3 )CO 3 : a “three-in-one” UV nonlinear optical crystal built by a polar molecule bonding strategy

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  4. Mg 2 In 3 Si 2 P 7 : A Quaternary Diamond-like Phosphide Infrared Nonlinear Optical Material Derived from ZnGeP 2

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  5. AZn4(OH)4(C3N3O3)2 (A = Mg, Zn): Two Zn-Based Cyanurate Crystals with Various Cation Coordination and Large Birefringence

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  16. NaSb3O2(SO4)3·H2O: A New Alkali-Metal Antimony(III) Sulfate with a Unique Sb6O20H4 Unit and Moderate Birefringence

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  21. APb 2 (C 7 H 3 NO 4 ) 2 I (A = K, Rb, Cs): rare stable nonlinear optical crystals with second-harmonic generation response and highly distorted lead core coordination polyhedra

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  23. KPb 3 ( o -C 5 H 4 NCOO) 2 Cl 5 : a brand-new stable lead chloride with good comprehensive nonlinear optical performance

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  24. Large optical anisotropy-oriented construction of a carbonate-nitrate chloride compound as a potential ultraviolet birefringent material

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  28. Chiral Ligand‐Driven Systematic Synthesis of Coordination Polymers with Non‐centrosymmetric Structures

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  29. The dependence of crystal structure and ultraviolet nonlinear optical property of KBe2BO3F2 by density functional theory and π-conjugate confinement

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  30. Two Indium Iodate–Nitrates with Large Birefringence Induced by Hybrid Anionic Functional Groups and Their Favorable Arrangements

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  31. Finding the First Squarates Nonlinear Optical Crystal NaHC4O4·H2O with Strong Second Harmonic Generation and Giant Birefringence

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  32. Uncovering a Vital Band Gap Mechanism of Pnictides

    Advanced Science · 2022-03-31

    Jindong Chen, Qingchen Wu, Haotian Tian, Xiaotian Jiang, Feng Xu, Xin Lei Zhao, Zheshuai Lin, Min Luo, Ning Ye

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  33. Noncentrosymmetric Rare-Earth Borate Fluoride La2B5O9F3: A New Ultraviolet Nonlinear Optical Crystal with Enhanced Linear and Nonlinear Performance

    ACS Applied Materials & Interfaces · 2022-04-13

    Xuping Shi, Abudukadi Tudi, Meng Cheng, Fangfang Zhang, Zhihua Yang, Shujuan Han, Shilie Pan

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  34. An Optimized KBe2BO3F2‐Like Structure: The Unity of Deep‐Ultraviolet Transparency, Nonlinear Optical Property, and Ferroelectricity

    Advanced Optical Materials · 2022-05-02

    Hongyuan Sha, Junxin Xu, Zheyao Xiong, Zujian Wang, Rongbing Su, Chao He, Xiaoming Yang, Xifa Long, Ying Liu

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  35. (NH4)3B11PO19F3: a deep-UV nonlinear optical crystal with unique [B5PO10F]∞ layers

    National Science Review · 2022-06-10

    Bingliang Cheng, Zi‐Jian Li, Yu Chu, Abudukadi Tudi, Miriding Mutailipu, Fangfang Zhang, Zhihua Yang, Shilie Pan

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  36. Two Metal Phosphate Nonlinear Optical Materials Simultaneously Exhibiting Ultraviolet Transparence and a Large Birefringence

    Chemistry of Materials · 2022-06-24

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  37. AgGaSe2-Inspired Nonlinear Optical Materials: Tetrel Selenides of Alkali Metals and Mercury

    Chemistry of Materials · 2022-06-26

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  38. Deep-ultraviolet nonlinear optical crystals: concept development and materials discovery

    Light Science & Applications · 2022-07-01

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  39. Cation-anion synergetic interactions achieving tunable birefringence in quasi-one-dimensional antimony(III) fluoride oxalates

    Science China Materials · 2022-07-05

    Die Zhang, Qiang Wang, Ting Zheng, Liling Cao, Kang Min Ok, Daojiang Gao, Jian Bi, Ling Huang, Guohong Zou

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  40. Directional Construction of New Nonlinear Optical Bifunctional Units through Molecular Engineering Design Inspired by the B 3 O 7 -Typed Configuration

    ACS Applied Materials & Interfaces · 2022-07-07

    Huixin Fan, Chensheng Lin, Fei Liang, Haotian Tian, Shijun Huang, Yuqiao Zhou, Shixian Ke, Bingxuan Li, Ning Ye, Min Luo

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  41. [C(NH2)3]2Zn(CO3)2: A Guanidinium-Templated Ultraviolet Nonlinear Optical Material

    Inorganic Chemistry · 2022-07-25

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  42. Difluoro(oxalato)borates as Short-Wavelength Optical Crystals with Bifunctional [BF 2 C 2 O 4 ] Units

    Chemistry of Materials · 2022-07-26

    Congcong Jin, Fuming Li, Xingqi Li, Juanjuan Lu, Zhihua Yang, Shilie Pan, Miriding Mutailipu

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  43. Mixed-Anion-Oriented Design of LnMGa3S6O (Ln = La, Pr, and Nd; M = Ca and Sr) Nonlinear Optical Oxysulfides with Targeted Property Balance

    ACS Applied Materials & Interfaces · 2022-08-11

    Jingjing Xu, Kui Wu, Yan Xiao, Bingbing Zhang, Haohai Yu, Huaijin Zhang

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  44. NaB3O4F(OH): A Hydroxyfluorooxoborate with One-Dimensional Chain Featuring Large Birefringence and Short Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2022-08-18

    Yu Dang, Dongdong Chu, Zhihua Yang, Hongsheng Shi, Shilie Pan

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  45. Design of novel deep-UV nonlinear optical materials with one-dimensional functional module [BO2]∞ chain and fluorine-driven short phase-matching

    Materials Today Physics · 2022-10-03

    Abudukadi Tudi, Congwei Xie, Shilie Pan, Zhihua Yang

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  46. Achieving Large Second Harmonic Generation Effects via Optimal Planar Alignment of Triangular Units

    Advanced Functional Materials · 2022-11-04

    Xinyu Li, Qi Wei, Chun‐Li Hu, Jie Pan, Bingxuan Li, Zhen‐Zhen Xue, Xiao‐Yu Li, Jinhua Li, Jiang‐Gao Mao, Guo‐Ming Wang

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  47. CaBO2F: A novel deep-UV structural template with high nonlinear optical performance induced by electron delocalization

    Science China Materials · 2022-11-09

    Chenchen Tu, Abudukadi Tudi, Wenqi Jin, Congwei Xie, Zhihua Yang

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  48. RbCl·(H2SeO3)2: A Salt-Inclusion Selenite Featuring Short UV Cut-Off Edge and Large Birefringence

    Inorganic Chemistry · 2022-12-23

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  49. Deep-ultraviolet nonlinear-optical crystal BaNa2[PO3(OH)]2 with large birefringence and strong second-harmonic-generation response

    Chinese Journal of Structural Chemistry · 2023-01-01

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  50. Enhancing birefringence of non-π-conjugated sulfate systems through rare-earth metal-centered polyhedra

    CrystEngComm · 2023-01-01

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