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RESEARCH PAPER · Inorganic Chemistry · 2021

AZn4(OH)4(C3N3O3)2 (A = Mg, Zn): Two Zn-Based Cyanurate Crystals with Various Cation Coordination and Large Birefringence

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AZn4(OH)4(C3N3O3)2 (A = Mg, Zn): Two Zn-Based Cyanurate Crystals with Various Cation Coordination and Large BirefringenceOriginalTwo metal-free cyanurate crystals with a large optical birefringence resulting from the combination of π-conjugated units17[C(NH 2 ) 3 ] 2 S 2 O 8 : combining delocalized and localized π-conjugate units to achieve strong optical anisotropy21(C3N6H7)2SbF5·H2O Exhibiting Strong Optical Anisotropy from the Optimal Arrangement of π-Conjugated (C3N6H7)+ Groups31Naphthalene-Like Unit That Induces Strong Optical Anisotropy in C10H8NO2Br and C10H8NO2Br·H2O12Alkali-metal isocyanurate Cs 3 (H 2 C 3 N 3 O 3 ) 3 (H 3 C 3 N 3 O 3 )·3H 2 O: synthesis and characterization0Crystal clear: unveiling giant birefringence in organic–inorganic cocrystals33C9H7NBrX (X = Cl, Br, NO3): Three Excellent Birefringent Crystals with Distinct Optical Anisotropy Regulated by Anions34Zn(C6H4NO2)2·4H2O: A Solar-Blind Birefringent Crystal5Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals66Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals8Na(C2H10N2)2[Zn3(PO4)2(H0.5PO4)]2: A Short-Wave Ultraviolet Open-Framework Zincophosphate Exhibiting Substantial Optical Dispersion Ability4CO2 adsorption on a new gel - grown mesoporous Zinc complex of 1, 3, 5 -triazinane-2, 4, 6 – trione1(C 7 H 3 NO 4 ) 2 Sb 2 F 2 ·2H 2 O: a pyridine-based compound shows large optical anisotropy4Recent progress in structural design strategies of high-birefringence optical crystals54Enhancing Birefringence via a Planar‐Conformation‐Locking Strategy3Hydrogen‐Bond‐Driven Metal‐Free Crystal (C 6 H 7 N 2 O)(NH 2 SO 3 ) with Giant Birefringence and Solar‐Blind Ultraviolet Transmission0Syntheses, structures and optical properties of two new cadmium antimonites: Cs 4 Cd(SbF 5 ) 3 (H 2 O) 2 and Cd[Sb 7 O 10 (OH)](SO 4 )0The condensation of π-conjugated units: a new paradigm for designing high-performance optical crystals4Unit Symmetry‐Breaking and Layered Linear Ordering Enabling Superior Short‐Wave Ultraviolet Birefringent Crystal8Unit Symmetry‐Breaking and Layered Linear Ordering Enabling Superior Short‐Wave Ultraviolet Birefringent Crystal2Chromium cyanurate-based robust resistive switching device emulating synaptic plasticity for neuromorphic application1Interlayer Electronic Decoupling Unlocks Giant Birefringence in π‐Conjugated Metal‐Organic Frameworks0

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  1. Two metal-free cyanurate crystals with a large optical birefringence resulting from the combination of π-conjugated units

    Dalton Transactions · 2021-01-01

    Xiaomeng Liu, Lei Kang, Ruixin Guo, Zheshuai Lin

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  2. [C(NH 2 ) 3 ] 2 S 2 O 8 : combining delocalized and localized π-conjugate units to achieve strong optical anisotropy

    Inorganic Chemistry Frontiers · 2022-01-01

    Man Zhang, Bingbing Zhang, Daqing Yang, Ying Wang

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  3. (C3N6H7)2SbF5·H2O Exhibiting Strong Optical Anisotropy from the Optimal Arrangement of π-Conjugated (C3N6H7)+ Groups

    Inorganic Chemistry · 2022-08-31

    Yaoguo Shen, Bo Wen Chen, Hao Chen, Junhua Luo

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  4. Naphthalene-Like Unit That Induces Strong Optical Anisotropy in C10H8NO2Br and C10H8NO2Br·H2O

    Inorganic Chemistry · 2023-05-19

    Yaoguo Shen, Yingwu Zhou, Xiaoling Xue, Guofa Dong

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  5. Alkali-metal isocyanurate Cs 3 (H 2 C 3 N 3 O 3 ) 3 (H 3 C 3 N 3 O 3 )·3H 2 O: synthesis and characterization

    CrystEngComm · 2024-01-01

    Xinyue Wang, Dandan Wang, Yujie Liu, Jinhui Wang

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  6. Crystal clear: unveiling giant birefringence in organic–inorganic cocrystals

    Chemical Science · 2024-01-01

    Yang Li, Kang Min Ok

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  7. C9H7NBrX (X = Cl, Br, NO3): Three Excellent Birefringent Crystals with Distinct Optical Anisotropy Regulated by Anions

    Small · 2024-05-10

    Yaoguo Shen, Mingliang Ding, Gang Chen, Yingjie Luo, Sangen Zhao, Junhua Luo

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  8. Zn(C6H4NO2)2·4H2O: A Solar-Blind Birefringent Crystal

    Crystal Growth & Design · 2024-05-14

    Yaoguo Shen, Yu Wang, Zixiang Chen, Wencheng Lu

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  9. Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals

    Angewandte Chemie International Edition · 2024-06-26

    Yang Li, Kang Min Ok

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  10. Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals

    Angewandte Chemie · 2024-06-26

    Yang Li, Kang Min Ok

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  11. Na(C2H10N2)2[Zn3(PO4)2(H0.5PO4)]2: A Short-Wave Ultraviolet Open-Framework Zincophosphate Exhibiting Substantial Optical Dispersion Ability

    Inorganic Chemistry · 2024-09-25

    Zhi Gang Fang, Chao-Qian Li, Bing‐Ping Yang, Meihong Duan

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  12. CO2 adsorption on a new gel - grown mesoporous Zinc complex of 1, 3, 5 -triazinane-2, 4, 6 – trione

    Journal of Molecular Structure · 2024-12-05

    D. G. Arya, M. G. Darsana, B.R. Bijini

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  13. (C 7 H 3 NO 4 ) 2 Sb 2 F 2 ·2H 2 O: a pyridine-based compound shows large optical anisotropy

    Dalton Transactions · 2025-01-01

    Yaoguo Shen, Jiajia Xiong, Yiman Yang, Zhifeng Tang

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  14. Recent progress in structural design strategies of high-birefringence optical crystals

    Coordination Chemistry Reviews · 2025-05-08

    A-Lan Xu, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  15. Enhancing Birefringence via a Planar‐Conformation‐Locking Strategy

    Laser & Photonics Review · 2025-09-04

    Yaoguo Shen, Jiajia Xiong, Mengqing Wu, M.-R. Li, Yingwu Zhou, Yanjie Zhang

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  16. Hydrogen‐Bond‐Driven Metal‐Free Crystal (C 6 H 7 N 2 O)(NH 2 SO 3 ) with Giant Birefringence and Solar‐Blind Ultraviolet Transmission

    Advanced Optical Materials · 2025-12-10

    Zhenkai Cen, Z.-Y. Li, Guang Peng, Junbo Gong, Junbo Gong

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  17. Syntheses, structures and optical properties of two new cadmium antimonites: Cs 4 Cd(SbF 5 ) 3 (H 2 O) 2 and Cd[Sb 7 O 10 (OH)](SO 4 )

    Dalton Transactions · 2026-01-01

    Yi Yuan, Chun‐Li Hu, Dan-Dan Zhou, Jiang‐Gao Mao, Fang Kong

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  18. The condensation of π-conjugated units: a new paradigm for designing high-performance optical crystals

    Chemical Society Reviews · 2026-01-01

    Hangwei Jia, Bailin Chen, Fangfang Zhang, Xueling Hou, Shilie Pan

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  19. Unit Symmetry‐Breaking and Layered Linear Ordering Enabling Superior Short‐Wave Ultraviolet Birefringent Crystal

    Angewandte Chemie International Edition · 2026-01-14

    Xin Wen, Dequan Kong, Jingyao Lu, Jindong Chen, Haohai Yu, Huaijin Zhang, Zhanggui Hu, Jiyang Wang, Ning Ye, Guang Peng

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  20. Unit Symmetry‐Breaking and Layered Linear Ordering Enabling Superior Short‐Wave Ultraviolet Birefringent Crystal

    Angewandte Chemie · 2026-01-14

    Xin Wen, Dequan Kong, Jingyao Lu, Jindong Chen, Haohai Yu, Huaijin Zhang, Zhanggui Hu, Jiyang Wang, Ning Ye, Guang Peng

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  21. Chromium cyanurate-based robust resistive switching device emulating synaptic plasticity for neuromorphic application

    Synthetic Metals · 2026-04-07

    Udumu Mounika Reddy, Deepak Vishnu S. K, Ashish Varade, Ponnam Anjaneyulu, Shobith M Shanbogh, R. S. Vishwanath

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  22. Interlayer Electronic Decoupling Unlocks Giant Birefringence in π‐Conjugated Metal‐Organic Frameworks

    Advanced Materials · 2026-06-18

    Jia-Xiang Zhang, Xinyan Wu, Weishan Li, Haolin Zhong, Jinkun Guo, Qingsheng Zeng, Mao‐Yin Ran, Ze‐Fan Yao, Yu‐Qing Zheng, Qingqing Ji, Jin‐Hu Dou

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