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RESEARCH PAPER · Light Science & Applications · 2022

Deep-ultraviolet nonlinear optical crystals: concept development and materials discovery

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Deep-ultraviolet nonlinear optical crystals: concept development and materials discoveryOriginalHalogen regulation triggers structural transformation from centrosymmetric to noncentrosymmetric switches in tin phosphate halides Sn 2 PO 4 X (X = F, Cl)47Oxychalcogenides as Promising Ultraviolet Nonlinear Optical Candidates: Experimental and Theoretical Studies of AEGeOS2(AE = Sr and Ba)24Local Polarity-Induced Assembly of Second-Order Nonlinear Optical Materials128AeMg6Ga6S16 (Ae = Ca, Sr, Ba): The First Double Alkaline‐Earth Metal Chalcogenides with Excellent Performances29Soliton dynamics in a piecewise gas-filled hollow-core fiber for efficient dispersive wave emission in the vacuum-ultraviolet range4M(NH2SO3)2·xH2O (M = Ca, Pb, x = 0, 1, 4): Effect of Hydrogen Bonding on Structural Transformations and Second Harmonic Generation of Metal Sulfamates26Rb 3 B 11 P 2 O 23 : Materials Design of a New Chemically Benign Deep-Ultraviolet Nonlinear Optical Material58Achieving broadband ultraviolet to mid-infrared transparency in germanate-based nonlinear optical crystals Cs 3 REGe 3 O 9 (RE = Y, Gd)16An overview of Mg-based IR nonlinear optical materials22Breaking the bottleneck of simultaneously wide band gap and large nonlinear optical coefficient by a “pore reconstruction” strategy in a salt-inclusion chalcogenide26Evaluating refractive index and birefringence of nonlinear optical crystals: Classical methods and new developments45Open honeycomb frameworks of sulphides AHg 4 Ga 5 S 12 (A = Rb, Cs) exhibiting infrared nonlinear optical properties12Recent advances on the synthesis of Sb(III)-based inorganic ultraviolet nonlinear optical materials47SbI3·3S8: A Novel Promising Inorganic Adducts Crystal for Second Harmonic Generation5Scheme for the excitation of thorium-229 nuclei based on electronic bridge excitation17Recent advances in non-π-conjugated nonlinear optical sulfates with deep-UV absorption edge53[K2PbX][Ga7S12] (X = Cl, Br, I): The First Lead‐Containing Cationic Moieties with Ultrahigh Second‐Harmonic Generation and Band Gaps Exceeding the Criterion of 2.33 eV46The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO 3 ) 2 and Y 3 F(SeO 3 ) 485The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO3)2 and Y3F(SeO3)47Nonlinear optical crystals KPb3(3-C5H4NCOO)2Br5 and KPb3(3-C5H4NCOO)2Cl3Br2 with new Pb-centered nitrogen-halide polyhedrons obtained by the halide anionic substitution4Cs 3 [(BOP) 2 (B 3 O 7 ) 3 ]: A Deep-Ultraviolet Nonlinear Optical Crystal Designed by Optimizing Matching of Cation and Anion Groups169Recent advances in IR nonlinear optical chalcogenides with well-balanced comprehensive performance56Special Issue on the 120th Anniversary of Shandong University0Hg3(SeO3)2(SO4): A UV Nonlinear Optical Mercury Selenite Sulfate Constructed by Neat [Hg6O8(SeO3)4]∞ Layers and SO4 Tetrahedra27Spatial Frequency Manipulation of a Quartz Crystal for Phase‐Matched Second‐Harmonic Vacuum Ultraviolet Generation16Recent Progress in Crystalline Borates with Edge-Sharing BO4 Tetrahedra21Improved Birefringence Activated by Tetrahedra Decorated with a Single Linear Unit38Improved Birefringence Activated by Tetrahedra Decorated with a Single Linear Unit1A study on livelihood capital, social adaptation, and life satisfaction—empirical analysis based on ecological migration in the Kalajun world natural heritage site4The Strategy to Improve the Phase Matching Ability in Tetrahedron‐Based Deep‐Ultraviolet Nonlinear Optical Crystals21Cs4Zn5P6S18I2: the Largest Birefringence in Chalcohalide Achieved by Highly Polarizable Nonlinear Optical Functional Motifs21Optimization strategies for comprehensive performance of organic second-order nonlinear optical materials1Nonlinear Metal–Organic Framework Crystals for Efficient Multicolor Coherent Optical Emission39Wide band gaps in nonlinear optical materials AMgAgGa6S11 (A = K, Rb) achieved by the incorporation of dual s-block elements in Ag-based sulfide11Deep-ultraviolet (DUV) nonlinear optical (NLO) crystals: An application in photonic technologies29ACd 4 Ga 5 Te 12 (A = K, Rb, Cs): Tellurides with a Strong Nonlinear Optical Response and Purple Emission24A methodical investigation on the growth and characterization of a third-order nonlinear optical novel co-crystal of 8-hydroxyquinolinium phthalate: X-ray, Hirshfeld surface, optical, mechanical, thermal and DFT analysis13High-efficiency 261-nm continuous-wave laser by single-blue-laser-diode-pumped Pr3+:LiYF4 crystal18(SO3CF3)−: A Non‐π‐Conjugated Motif for Nonlinear Optical Crystals Transparent into the Deep‐Ultraviolet Region23Nitride Wide-Bandgap Semiconductors for UV Nonlinear Optics3New Organic Nonlinear Optical Pyridinium-Based Hydrate Crystals: Trimethoxy-Induced Noncentrosymmetric Alignment6Birefringent Dispersion Optimization to Achieve Superior Nonlinear Optical Phase Matching in Deeper Solar‐Blind UV Band from KH 2 PO 4 to BeH 3 PO 516Advances in Solid-State Nonlinear Optical Materials: From Fundamentals to Applications61Secondary‐Bond‐Driven Construction of a Polar Material Exhibiting Strong Broad‐Spectrum Second‐Harmonic Generation and Large Birefringence9Secondary‐Bond‐Driven Construction of a Polar Material Exhibiting Strong Broad‐Spectrum Second‐Harmonic Generation and Large Birefringence41A-site cation manipulation of exemplary second harmonic generation response and optical anisotropy in rare-earth borates18Form-controlled synthesis of a polymorphic nonlinear optical crystal CsMgPO 4 ·6H 2 O3Galloborates as ultraviolet nonlinear optical crystals: advances and perspectives8Generation of 160 nm vacuum ultraviolet light at 82 MHz in a KBBF crystal by the fifth-harmonic of a Ti:sapphire laser2新型深紫外非线性光学晶体研究进展(特邀)9Hierarchical van der Waals Assemblies to Boost Deep‐Ultraviolet Nonlinear‐Optical Capabilities in Boron Phosphate8Toward the ultraviolet (UV) or deep-UV nonlinear optical crystals: The combination of π-conjugated planar [XY3] and tetrahedral [XY4]80Continuous-wave second-harmonic generation in the far-UVC pumped by a blue laser diode14The local state of hydrogen atoms and proton transfer in the crystal structure of natural berborite, Be2(BO3)(OH)‧H2O: Low-temperature single crystal X-ray analysis, IR and 1H NMR spectroscopy, and crystal chemistry and structural complexity of beryllium borates8Monolithic PMN-39PT nanograting-assisted second harmonic generation enhancement1Record Second-Harmonic Generation and Birefringence in an Ultraviolet Antimonate by Bond Engineering157Solvent effects and self-assembled aggregation modulate nonlinear optical effects in indocyanine green-like dyes5Sr2[B5O8(OH)]2 ⋅ [B(OH)3] ⋅ H2O: A Strontium Borate That Shows Deep‐Ultraviolet‐Transparent Nonlinear Optical Properties17Theoretical Understanding of Nonlinear Optical Properties in Solids: A Perspective27A perspective on deep-ultraviolet nonlinear optical materials13Optical second harmonic generation in anisotropic multilayers with complete multireflection of linear and nonlinear waves using ♯SHAARP.ml package12Frequency converting and digital modulation of light derived from lanthanide for signal encoding and logic computing9Nonlinear optical, dielectric, and piezoelectric properties of hexagonal fluorocarbonates ABCO3F (A: K, Rb, Cs; B: Mg, Ca, Sr, Zn, Cd, Pb) from first principles3An Unprecedented [BO2]‐Based Deep‐Ultraviolet Transparent Nonlinear Optical Crystal by Superhalogen Substitution33An Unprecedented [BO2]‐Based Deep‐Ultraviolet Transparent Nonlinear Optical Crystal by Superhalogen Substitution1Optical Phenomena in Molecule-Based Magnetic Materials154Assembly of π‐Conjugated [B 3 O 6 ] Units by Mer‐Isomer [YO 3 F 3 ] Octahedra to Design a UV Nonlinear Optical Material, Cs 2 YB 3 O 6 F 211Assembly of π‐Conjugated [B3O6] Units by Mer‐Isomer [YO3F3] Octahedra to Design a UV Nonlinear Optical Material, Cs2YB3O6F297M6[Cd2(CO3)2(B12O18)(OH)6] (M = K, Rb): Borate–Carbonates with Two CdCO3 Embedded in a Cyclic Oxoboron Anion10Theoretical insight on structure, electronic, and optical properties of two d 0–d 10 electron transition-metal oxyhalides SHG materials2Second Harmonic Generation in β-K2TeW3O12: An Acentric Crystal Designed from Centric Phase via Pressure Modulation4Direct Band Gap Semiconductor Zn 1− x Be x Oxide Maquettes as Magnetic‐Field‐Induced Harmonics: A Comprehensive Design Benchmarking1Second-harmonic generation tensors from high-throughput density-functional perturbation theory15Growth, spectroscopic, thermal and laser frequency doubling properties of CTGAS crystal2Tuning the 5 d State of Pr 3+ in Oxyhalides for Efficient Deep Ultraviolet Upconversion19Enhancement of growth perfection and optical transmission in rhodamine B-doped KDP single crystal for photonic applications8C6N7(NH2)3·H3PO4: Strong Second Harmonic Generation and Giant Birefringence Benefiting from Amino Substitution Strategy24Wide‐Bandgap RBa3(B3O6)3 (R = Nd, Sm, Tb, Dy, and Er) Single Crystals for Ultraviolet Nonlinear Optics6Enhanced Second-Harmonic Generation in Thin-Film Lithium Niobate Circular Bragg Nanocavity23Exploiting Deep‐Ultraviolet Nonlinear Optical Material Rb 2 ScB 3 O 6 F 2 Originated from Congruously Oriented [B 3 O 6 ] Groups61Exploiting Deep‐Ultraviolet Nonlinear Optical Material Rb 2 ScB 3 O 6 F 2 Originated from Congruously Oriented [B 3 O 6 ] Groups4K0.9Rb2.1B8PO16: Design and Synthesis of a Deep-Ultraviolet Nonlinear Optical Crystal with Balanced Performance Derived from π-Conjugated and Non-π-Conjugated Groups11Toward Strong UV–Vis–NIR Second-Harmonic Generation by Dimensionality Engineering of Zinc Thiocyanates32High-power picosecond UV and deep-UV laser sources delivering powers of 30 W at 355 nm, 10 W at 266 nm, and 5 W at 213 nm15Breaking Symmetry for SHG Response: Lanthanide Acetate Crystals via Water Molecule Regulation Strategy5Extremely Downsized Materials: Ball-Milling-Enabled Universal Production and Size-Reduction-Induced Performance Enhancement17Broadband nonlinear Bragg diffraction from self-assembled structures in potassium tantalate niobate crystals3Enhanced Second‐Harmonic Generation in Quadratically Nonlinear Weyl Semimetal NbAs for Broadband Photodetection Applications10Functional assembly and modification of nonlinear optical fundamental motifs in phosphates27Dual quasi-bound state enhanced second harmonic generation in lithium niobate metasurfaces2Growth, optical, thermal and dielectric characterization of NLO active L-Tryptophan tris (4-nitrophenol) single crystals2Cationic Coordination Modification Drives Birefringence and Nonlinear Effect Double Lifting in Sulfate4Deep ultraviolet transparent borophosphates LiAB 2 P 2 O 9 (A = NH 4 , K) and LiNaB 2 P 2 O 8 (OH) 2 ·H 2 O exhibiting a moderate second-harmonic generation response4Crystalline salt synthesis from p-dimethylaminobenzaldehyde and o-phenylenediamine, single crystal XRD study along with computational investigation10A new structure type of the Na3Yb(BO3)2: Synthesis, crystal structure, thermal behavior, ionic conductivity, and spectroscopy2Accelerating the discovery of high-performance nonlinear optical materials using active learning and high-throughput screening11Advances in Graphene-Based Nanostructures for Multimodal Bioimaging0Designing a novel perovskite-type KCd(NH 2 SO 3 ) 3 with deep-ultraviolet transparency and strong second-harmonic generation response2Different p-block elements induce C 3 [111] octahedral distortion in titanium to generate an intense nonlinear effect14Harnessing the dual role of DMSO in the synthesis of SbOCl·DMSO: an excellent nonlinear optical crystal with unique 1D spiral chain10Tunable chiroptical activity and second-harmonic generation in chiral one-dimensional perovskites2基于共线三倍频与近场干涉技术的飞秒紫外脉冲产生与相位同步系统设计与研制(特邀)0大尺寸RbLi(HC3N3O3)·2H2O晶体生长和光学性能研究(特邀)2层状结构深紫外非线性光学晶体研究进展(特邀)2激光聚变驱动器频率转换技术研究进展(特邀)0Pb 4 O 3 I 2 : A Lead Oxyhalide IR Optical Crystal with an Unprecedented 1 ∞ [O 3 Pb 4 ] Chain Featuring a Wide Transmittance Range and Large Birefringence3Strong Second‐Harmonic Generation Responses in Salt‐Inclusion Oxychalcogenides Enabled by the Highly Distorted Polyhedra with Mixed‐Anions4Insights into the optoelectronic, quantum chemical, NBO and dynamic nonlinear optical properties of meso-BODIPY dyes3Investigation of the Nonlinear Optical Properties of Silk Fibroin (SF) Using the Z-Scan Method5Proposal and theoretical investigation of 229Th-doped nonlinear optical crystals for compact solid-state clocks6Potassium Tetraiodatoiodate(III) Iodate(V): A Nonlinear Optical Crystal with Exceptional Second‐Harmonic Generation and Full‐Wavelength Phase Matching19Potassium Tetraiodatoiodate(III) Iodate(V): A Nonlinear Optical Crystal with Exceptional Second‐Harmonic Generation and Full‐Wavelength Phase Matching0Methyl substitution induced noncentrosymmetric alignment: a new thiazolium-based nonlinear optical crystal of HDT-N1S2All-three-in-one: Pb2(H2PO4)2(C2O4) significantly enhanced birefringence in phosphate materials4Na3RE(PO4)2 with a Glaserite-Like Structure: The Effect of Cation on Structural Evolution2Finding a Novel Borate Ferroelectric with Random Domain Structures for Deep‐UV Quasi‐Phase‐Matching22Symmetry Breaking via Anion-Molecule Synergy: Fluorine and Crystalline Water Directed Construction of Noncentrosymmetric Sr(IO2F2)2·2H2O0Design and Synthesis of a Deep-Ultraviolet Nonlinear Optical Crystal KRb3B6Ge3O17 Composed of [B3O8] Units and [GeO4] Tetrahedra6A Promising Short-Wave UV NLO Crystal with an Optimized KBBF-like Structure and Well-Balanced Properties Achieved via a Chemical Substitution Strategy6Borosilicates as deep-ultraviolet transparent nonlinear optical crystals: Structural motifs, performance limits and future directions9Structure-property relationships in IR nonlinear optical chalcogenides with stereochemically active lone pairs29Origin of second harmonic generation in noncentrosymmetric crystal structures containing lone pair electrons5Progresses on 148 nm light sources for precision measurement of nuclear transition of 229m Th2Na6(SO4)2SiF6: A Stable Sulfate Fluosilicate with Wide Deep-Ultraviolet Transparency Window and Strong Second-Harmonic Generation Response4Unlocking Advanced UV NLO Crystals in Rare‐Earth Metal Borate Fluorides via [B 3 O 6 ]‐Mediated Structural Modulation18Ultraviolet Nonlinear Frequency Conversion of Solid‐State Lasers in 200–400 nm Spectral Region4Four zinc borates: From acentric chain to centric porous layer0Growth and Characterization of Novel SrB2O4 Crystals0First-principles study of carbon vacancy effects on the nonlinear optical and electronic properties of BC2N monolayers0The nonlinear optical characteristics of nickel and lanthanum phthalocyanine complexes possessing sulfonylphenoxy functionalities0Ce-centered polyhedral arrangement pattern and optical performance in Ce-based nonlinear optical materials3Reactive flux assisted metal oxide–boron–sulfur routine for syntheses of CsRESiS 4 (RE = Sm, Gd–Ho): featuring nonlinear optical activity and wide band gaps5Recent achievements of d0 transition-metal-based oxyfluorides: Crystal chemistry and application in second-order NLO materials10Ba 3 ZnB 5 PO 14 as a Multifunctional Host for New Colored Compounds, White‐Light Emission, and Turn‐Off Luminescence Sensing0Tailoring ordered structures with distorted [TeO 3 ] and aligned [ScO 6 ] motifs for balanced nonlinear optical properties in rare-earth tellurate crystals5Cation regulation achieves symmetry breaking: from centrosymmetric M 2 Cs 2 B 10 O 17 (M = Na, K) to noncentrosymmetric Na 3 CsB 10 O 172Chiral-Unit-Driven Short-Wave Ultraviolet Nonlinear Optical Acetates with Balanced Overall Optical Properties3Synthesis, structural, spectral, optical and magnetic analysis of magnesium thiosulfate hexahydrate crystal0Interrelation between the exponential absorption-optical band width and degree of crystalline perfection in nonlinear optical bulk single-crystals0Optical anisotropy in Mo–Te–O frameworks constructed from distorted MoO 6 and TeO 3 units0Phase transfer in dispersive four-wave mixing in gas-filled hollow capillary fibers0Strong second-harmonic generation and wide temperature range switching behavior coexisting in an ultrawide-bandgap selenate0高性能硫属化物红外非线性光学材料构效关系(特邀)0High Entropy Wide‐Bandgap Borates with Broadband Luminescence and Large Nonlinear Optical properties5Dual efficient X-ray scintillation and strong second harmonic generation in a single cubic alkane Cu4I4 cluster achieved through organic-inorganic synergistic effect5Sum-frequency generation of more than 50 W of deep-ultraviolet light at 266 nm in LBO crystals based on a spherical-aberration-compensated high-energy picosecond Nd:YVO 4 laser3Growth and comprehensive study of novel 2-p-nitrophenol-1H-benzo[d]imidazole single crystal: Structural, spectroscopic, and DFT insights1Advancements and Challenges in AlGaN and Phosphor-Based Deep Ultraviolet LEDs: Towards Broader Applications and Higher Efficiencies0Generation of subfemtosecond deep and vacuum UV pulses via two-photon Rabi oscillations in alkali-metal atoms or alkaline-earth-metal ions0Dimensionality Engineering of Fluorozirconium Phosphates for Deep-UV-Transparent Crystals with Enhanced Second-Harmonic Generation and Birefringence10

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  1. Halogen regulation triggers structural transformation from centrosymmetric to noncentrosymmetric switches in tin phosphate halides Sn 2 PO 4 X (X = F, Cl)

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  2. Oxychalcogenides as Promising Ultraviolet Nonlinear Optical Candidates: Experimental and Theoretical Studies of AEGeOS2(AE = Sr and Ba)

    Inorganic Chemistry · 2022-09-21

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  3. Local Polarity-Induced Assembly of Second-Order Nonlinear Optical Materials

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  4. AeMg6Ga6S16 (Ae = Ca, Sr, Ba): The First Double Alkaline‐Earth Metal Chalcogenides with Excellent Performances

    Advanced Optical Materials · 2022-11-24

    Jiale Chen, Yu-Jie Zhang, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  5. Soliton dynamics in a piecewise gas-filled hollow-core fiber for efficient dispersive wave emission in the vacuum-ultraviolet range

    Physical Review A · 2022-11-28

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  6. M(NH2SO3)2·xH2O (M = Ca, Pb, x = 0, 1, 4): Effect of Hydrogen Bonding on Structural Transformations and Second Harmonic Generation of Metal Sulfamates

    Inorganic Chemistry · 2022-12-12

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  7. Rb 3 B 11 P 2 O 23 : Materials Design of a New Chemically Benign Deep-Ultraviolet Nonlinear Optical Material

    ACS Materials Letters · 2022-12-12

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  8. Achieving broadband ultraviolet to mid-infrared transparency in germanate-based nonlinear optical crystals Cs 3 REGe 3 O 9 (RE = Y, Gd)

    Inorganic Chemistry Frontiers · 2023-01-01

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  9. An overview of Mg-based IR nonlinear optical materials

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  10. Breaking the bottleneck of simultaneously wide band gap and large nonlinear optical coefficient by a “pore reconstruction” strategy in a salt-inclusion chalcogenide

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  11. Evaluating refractive index and birefringence of nonlinear optical crystals: Classical methods and new developments

    Chinese Journal of Structural Chemistry · 2023-01-01

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  12. Open honeycomb frameworks of sulphides AHg 4 Ga 5 S 12 (A = Rb, Cs) exhibiting infrared nonlinear optical properties

    Dalton Transactions · 2023-01-01

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  13. Recent advances on the synthesis of Sb(III)-based inorganic ultraviolet nonlinear optical materials

    Chinese Journal of Structural Chemistry · 2023-01-01

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  14. SbI3·3S8: A Novel Promising Inorganic Adducts Crystal for Second Harmonic Generation

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  15. Scheme for the excitation of thorium-229 nuclei based on electronic bridge excitation

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  16. Recent advances in non-π-conjugated nonlinear optical sulfates with deep-UV absorption edge

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  17. [K2PbX][Ga7S12] (X = Cl, Br, I): The First Lead‐Containing Cationic Moieties with Ultrahigh Second‐Harmonic Generation and Band Gaps Exceeding the Criterion of 2.33 eV

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  18. The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO 3 ) 2 and Y 3 F(SeO 3 ) 4

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  19. The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO3)2 and Y3F(SeO3)4

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  20. Nonlinear optical crystals KPb3(3-C5H4NCOO)2Br5 and KPb3(3-C5H4NCOO)2Cl3Br2 with new Pb-centered nitrogen-halide polyhedrons obtained by the halide anionic substitution

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  21. Cs 3 [(BOP) 2 (B 3 O 7 ) 3 ]: A Deep-Ultraviolet Nonlinear Optical Crystal Designed by Optimizing Matching of Cation and Anion Groups

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  22. Recent advances in IR nonlinear optical chalcogenides with well-balanced comprehensive performance

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  23. Special Issue on the 120th Anniversary of Shandong University

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  24. Hg3(SeO3)2(SO4): A UV Nonlinear Optical Mercury Selenite Sulfate Constructed by Neat [Hg6O8(SeO3)4]∞ Layers and SO4 Tetrahedra

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  25. Spatial Frequency Manipulation of a Quartz Crystal for Phase‐Matched Second‐Harmonic Vacuum Ultraviolet Generation

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  26. Recent Progress in Crystalline Borates with Edge-Sharing BO4 Tetrahedra

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  31. Cs4Zn5P6S18I2: the Largest Birefringence in Chalcohalide Achieved by Highly Polarizable Nonlinear Optical Functional Motifs

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  32. Optimization strategies for comprehensive performance of organic second-order nonlinear optical materials

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  33. Nonlinear Metal–Organic Framework Crystals for Efficient Multicolor Coherent Optical Emission

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  34. Wide band gaps in nonlinear optical materials AMgAgGa6S11 (A = K, Rb) achieved by the incorporation of dual s-block elements in Ag-based sulfide

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    Wen‐Fa Chen, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  35. Deep-ultraviolet (DUV) nonlinear optical (NLO) crystals: An application in photonic technologies

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  36. ACd 4 Ga 5 Te 12 (A = K, Rb, Cs): Tellurides with a Strong Nonlinear Optical Response and Purple Emission

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  37. A methodical investigation on the growth and characterization of a third-order nonlinear optical novel co-crystal of 8-hydroxyquinolinium phthalate: X-ray, Hirshfeld surface, optical, mechanical, thermal and DFT analysis

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  38. High-efficiency 261-nm continuous-wave laser by single-blue-laser-diode-pumped Pr3+:LiYF4 crystal

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