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RESEARCH PAPER · Angewandte Chemie · 2021

A General Principle for DUV NLO Materials: π‐Conjugated Confinement Enlarges Band Gap**

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A General Principle for DUV NLO Materials: π‐Conjugated Confinement Enlarges Band Gap**OriginalPromising Deep‐Ultraviolet Birefringent Materials via Rational Design and Assembly of Planar π‐Conjugated [B(OH)3] and [B3O3(OH)3] Functional Species6Promising Deep‐Ultraviolet Birefringent Materials via Rational Design and Assembly of Planar π‐Conjugated [B(OH)3] and [B3O3(OH)3] Functional Species83Chalcohalides: A Rising Type of Second‐Order Nonlinear Optical Materials28A High‐Performance Nonlinear Optical Crystal with a Building Block Containing Expanded π‐Delocalization95A High‐Performance Nonlinear Optical Crystal with a Building Block Containing Expanded π‐Delocalization5Aluminoborates as Nonlinear Optical Materials79Aluminoborates as Nonlinear Optical Materials14Atomic Structural Origin of Fictive Temperature Revealed by AZnP3O9 (A=K, Rb) Glasses3Atomic Structural Origin of Fictive Temperature Revealed by AZnP3O9 (A=K, Rb) Glasses2A Second‐Order Nonlinear Optical Material Consisting of Two π‐Conjugated Groups10Facile Synthesis, Spectroscopic and Nonlinear Optical Insights of Hydrazinyl-Based Functional Materials: Experimental and DFT Approach9Synthesis, characterization and exploration of optical non-linearity of secondary ketamine derivatives via DFT study7Research progress in optical materials with cationic organic planar π-conjugated groups containing CN bonds34Tetrahedra Modification of Phosphates for Optical Anisotropy Enhancement13Looking Back the Nonlinear Optical Crystals in a Functionalized Unit's Perspective109All-three-in-one: Pb2(H2PO4)2(C2O4) significantly enhanced birefringence in phosphate materials4(NH4)Na3Zn4(PO4)4:An open-framework zincophosphate exhibiting well-balanced optical and thermal performance1DFT exploration of the solvent-dependent electronic and nonlinear optical properties of naphthyridine-stilbene dyads1Achieving record-high birefringence in a 3D fluorozincoborate via coplanar alignment of π-conjugated [BO 3 ] units0CsB(OH) 4 (H 2 O) 2 and Na(NH 4 ) 2 B 10 O 16 OH(H 2 O): a hydroxylation modification strategy regulates the borate structures and optical properties0Synthesis and characterization of mixed carbonate and bicarbonate materials as candidates for deep-UV applications1Confinement π‐Conjugated Moiety Tailoring to Achieve Record Deep‐UV Nonlinearity in Sulfates0(C 5 H 7 N 2 ) (C 8 H 4 O 4 ) PbBr: Jahn–Teller Distortion‐Induced Tilting of π‐Conjugated Planes Resolving the Second‐Order Polarizability–Structural Anisotropy Conflicts1Anion Size‐Dependent Conformational Folding of Guanidinopropionate: Enabling Tunable Birefringence and Balanced Second‐Harmonic Generation Performance0Zn(C 2 H 4 NO 2 ) 2 (SO 2 CH 3 NH 2 ) 2 and Zn(C 2 H 4 NO 2 ) 2 [SO 2 (NH 2 ) 2 ]: Regulation of Unique ZnO(C 2 H 4 NO 2 ) 2 Units by Polar Tetrahedrons for Balanced UV Nonlinear Optical Performance0Deep-Ultraviolet Transparent Zr/Hf Fluorides with Second-Harmonic Generation Effects Induced by Alkali-Metal Modulation2

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  1. Promising Deep‐Ultraviolet Birefringent Materials via Rational Design and Assembly of Planar π‐Conjugated [B(OH)3] and [B3O3(OH)3] Functional Species

    Angewandte Chemie · 2022-04-29

    Jiahao Jiao, Meng Cheng, Rong Yang, Yuchen Yan, Min Zhang, Fangfang Zhang, Zhihua Yang, Shilie Pan

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  2. Promising Deep‐Ultraviolet Birefringent Materials via Rational Design and Assembly of Planar π‐Conjugated [B(OH)3] and [B3O3(OH)3] Functional Species

    Angewandte Chemie International Edition · 2022-04-29

    Jiahao Jiao, Meng Cheng, Rong Yang, Yuchen Yan, Min Zhang, Fangfang Zhang, Zhihua Yang, Shilie Pan

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  3. Chalcohalides: A Rising Type of Second‐Order Nonlinear Optical Materials

    European Journal of Inorganic Chemistry · 2022-10-05

    Jun Li, Shanshan Han, Sheng‐Ping Guo

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  4. A High‐Performance Nonlinear Optical Crystal with a Building Block Containing Expanded π‐Delocalization

    Angewandte Chemie International Edition · 2022-11-07

    Yanqiang Li, Weiqi Huang, Zhou Yang, Xianyu Song, Jieyu Zheng, Han Wang, Yipeng Song, Minjuan Li, Junhua Luo, Sangen Zhao

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  5. A High‐Performance Nonlinear Optical Crystal with a Building Block Containing Expanded π‐Delocalization

    Angewandte Chemie · 2022-11-07

    Yanqiang Li, Weiqi Huang, Zhou Yang, Xianyu Song, Jieyu Zheng, Han Wang, Yipeng Song, Minjuan Li, Junhua Luo, Sangen Zhao

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  6. Aluminoborates as Nonlinear Optical Materials

    Angewandte Chemie International Edition · 2022-12-13

    Jiahao Jiao, Min Zhang, Shilie Pan

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  7. Aluminoborates as Nonlinear Optical Materials

    Angewandte Chemie · 2022-12-13

    Jiahao Jiao, Min Zhang, Shilie Pan

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  8. Atomic Structural Origin of Fictive Temperature Revealed by AZnP3O9 (A=K, Rb) Glasses

    Angewandte Chemie International Edition · 2023-02-01

    Di Xu, Xin Liu, Ji Wang, Qianqian Liu, Rong Fu, He Lin, Ling Chen, Li‐Min Wang, Li‐Ming Wu

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  9. Atomic Structural Origin of Fictive Temperature Revealed by AZnP3O9 (A=K, Rb) Glasses

    Angewandte Chemie · 2023-02-01

    Di Xu, Xin Liu, Ji Wang, Qianqian Liu, Rong Fu, He Lin, Ling Chen, Li‐Min Wang, Li‐Ming Wu

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  10. A Second‐Order Nonlinear Optical Material Consisting of Two π‐Conjugated Groups

    ChemPlusChem · 2023-03-01

    Minjuan Li, Ziyi Wang, Belal Ahmed, Yanqiang Li, Han Wang, Yipeng Song, Xianyu Song, Xiaojun Kuang, Junhua Luo, Sangen Zhao

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  11. Facile Synthesis, Spectroscopic and Nonlinear Optical Insights of Hydrazinyl-Based Functional Materials: Experimental and DFT Approach

    Polycyclic aromatic compounds · 2023-07-26

    Hasnain Mehmood, Tashfeen Akhtar, Muhammad Haroon, Muhammad Khalid, Simon Woodward, Iqra Shafiq, Ataualpa Albert Carmo Braga, Norah Saad Alhokbany

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  12. Synthesis, characterization and exploration of optical non-linearity of secondary ketamine derivatives via DFT study

    Optical and Quantum Electronics · 2023-10-07

    Muhammad Khalid, Rifat Jawaria, Shahbaz Allah Ditta, Iqra Shafiq, Ataualpa Albert Carmo Braga, Saad M. Alshehri, Muhammad Adnan Asghar

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  13. Research progress in optical materials with cationic organic planar π-conjugated groups containing CN bonds

    Inorganic Chemistry Frontiers · 2024-01-01

    Hangwei Jia, Xueling Hou, Shilie Pan

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  14. Tetrahedra Modification of Phosphates for Optical Anisotropy Enhancement

    Advanced Optical Materials · 2024-08-29

    Haotian Qiu, Ran An, Junjie Li, Zhihua Yang, Shilie Pan, Miriding Mutailipu

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  15. Looking Back the Nonlinear Optical Crystals in a Functionalized Unit's Perspective

    Advanced Functional Materials · 2024-12-15

    Miriding Mutailipu, Junjie Li, Shilie Pan

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  16. All-three-in-one: Pb2(H2PO4)2(C2O4) significantly enhanced birefringence in phosphate materials

    Science China Chemistry · 2025-05-28

    Qingpeng Shao, Qingran Ding, Yanqiu Zhang, Weiqi Huang, Zihao Yu, Yipeng Song, Chengmin Ji, Ziyi Wang, Sangen Zhao, Junhua Luo

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  17. (NH4)Na3Zn4(PO4)4:An open-framework zincophosphate exhibiting well-balanced optical and thermal performance

    Journal of Molecular Structure · 2025-06-07

    Chen-Yuan Ma, Qiang Tu, Yu-Ming Pan, Pei De Han, Meihong Duan, Zhi Gang Fang

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  18. DFT exploration of the solvent-dependent electronic and nonlinear optical properties of naphthyridine-stilbene dyads

    Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · 2025-07-29

    P K Dhanya, Navjot Kaur, Renjith Raveendran Pillai

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  19. Achieving record-high birefringence in a 3D fluorozincoborate via coplanar alignment of π-conjugated [BO 3 ] units

    Inorganic Chemistry Frontiers · 2026-01-01

    Yucheng Hao, Qiuhui Zhang, Haoran Yu, Xikai Miu, Simin Cai, Xinnan Li, Fengshan Yu, Yuan Lin, Mingyang Cao

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  20. CsB(OH) 4 (H 2 O) 2 and Na(NH 4 ) 2 B 10 O 16 OH(H 2 O): a hydroxylation modification strategy regulates the borate structures and optical properties

    Dalton Transactions · 2026-01-01

    Kelibinuer Wulamu, Ziting Yan, Dongdong Chu, Juanjuan Lu, Yanhui Zhang, Hong Du

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  21. Synthesis and characterization of mixed carbonate and bicarbonate materials as candidates for deep-UV applications

    Chemical Communications · 2026-01-01

    Muhammad Mujahid Iqbal, Hussin Elkik, Changyou Liu, Aqsa Munawar, Zilong Chen, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  22. Confinement π‐Conjugated Moiety Tailoring to Achieve Record Deep‐UV Nonlinearity in Sulfates

    Angewandte Chemie · 2026-03-05

    Yujie Fan, Cheng Hu, Li Wu, Chensheng Lin, Chao Wang, Huixin Fan, Tao Yan, Min Luo

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  23. (C 5 H 7 N 2 ) (C 8 H 4 O 4 ) PbBr: Jahn–Teller Distortion‐Induced Tilting of π‐Conjugated Planes Resolving the Second‐Order Polarizability–Structural Anisotropy Conflicts

    Angewandte Chemie · 2026-03-28

    Ming‐Yan Yu, Can Yang, Yun‐Jie Wang, Xin Yan Su, Jian Cui, Yao‐Long Zhu, Qing‐Wen Zhu, Qi Wu, Li‐Ming Wu, Ling Chen

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  24. Anion Size‐Dependent Conformational Folding of Guanidinopropionate: Enabling Tunable Birefringence and Balanced Second‐Harmonic Generation Performance

    Angewandte Chemie · 2026-04-13

    Si‐Qian Jiang, Shuang Zhao, Yi‐Chang Yang, Jingyu Guo, Wenkai Zhao, Xuefei Wang, Li‐Ming Wu, Ling Chen

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  25. Zn(C 2 H 4 NO 2 ) 2 (SO 2 CH 3 NH 2 ) 2 and Zn(C 2 H 4 NO 2 ) 2 [SO 2 (NH 2 ) 2 ]: Regulation of Unique ZnO(C 2 H 4 NO 2 ) 2 Units by Polar Tetrahedrons for Balanced UV Nonlinear Optical Performance

    Advanced Science · 2026-05-08

    Cui Chenjie, Yuchen Yan, Xin Wen, Jindong Chen, Yi-Xiang Wang, Zhanggui Hu, Ning Ye, Guang Peng

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  26. Deep-Ultraviolet Transparent Zr/Hf Fluorides with Second-Harmonic Generation Effects Induced by Alkali-Metal Modulation

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