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RESEARCH PAPER · Inorganic Chemistry · 2022

[C(NH2)3]2Zn(CO3)2: A Guanidinium-Templated Ultraviolet Nonlinear Optical Material

Zhiyong Bai, Lehui Liu, Zhoubin Lin, Kang Min Ok

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[C(NH2)3]2Zn(CO3)2: A Guanidinium-Templated Ultraviolet Nonlinear Optical MaterialOriginalA pair of ionic 1D Cu( ii ) chain enantiomers simultaneously displaying large second- and third-harmonic generation responses12Hydroxyfluorooxoborate (NH 4 )[C(NH 2 ) 3 ][B 3 O 3 F 4 (OH)] for exploring the effects of cation substitution on structure and optical properties26KRb 2 (NO 3 ) 2 Cl: a new birefringent crystal exhibiting a perovskite-related framework and a short cutoff edge6Two pairs of chiral Yb III enantiomers presenting distinct NIR luminescence and circularly polarized luminescence performances with giant differences in second-harmonic generation responses20Introduction of the [B–O/F] Units Enhances the Band Gap and Birefringence from Na6Mg3B10O18F6 to K3NaB10O16F211Quadruple‐Bidentate Nitrate‐Ligated A 2 Hg(NO 3 ) 4 (A=K, Rb): Strong Second‐Harmonic Generation and Sufficient Birefringence59Quadruple‐Bidentate Nitrate‐Ligated A 2 Hg(NO 3 ) 4 (A=K, Rb): Strong Second‐Harmonic Generation and Sufficient Birefringence2α- and β-(C4H5N2O)(IO3)·HIO3: Two SHG Materials Based on Organic–Inorganic Hybrid Iodates14(CN3H6)[FeIIFeIII(SO4)3(H2O)3]: A Framework Iron Sulfate with a Mixed S = 2 and S = 5/2 Honeycomb Lattice3Discovery of excellent ultraviolet nonlinear optical materials in chlorates and bromates with highly stereochemically active lone pairs12Research progress in optical materials with cationic organic planar π-conjugated groups containing CN bonds34Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering61Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering4Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances17Electron density distribution in bis(guanidinium) disodium hypodiphosphate heptahydrate, (CH 6 N 3 ) 2 Na 2 (P 2 O 6 )·7H 2 O1[C 2 N 4 H 7 O][NH 2 SO 3 ]: High‐Performance Ultraviolet Nonlinear Optical Crystal with Ditrigon Coupled Guanylurea Group9[C 2 N 4 H 7 O][NH 2 SO 3 ]: High‐Performance Ultraviolet Nonlinear Optical Crystal with Ditrigon Coupled Guanylurea Group48Strongly Polar [H2PO3]− Induced π-Conjugated Group Arrangement for Balanced UV Nonlinear Optical Performance3Synergistic Design of UV Nonlinear Optical Crystals: Harnessing Flexible π-Conjugated Anions and Guanidinium Cations for Enhanced Performance4Na2(C6H4NO3)2·H2O: A promising ultraviolet nonlinear optical crystal with strong second-harmonic generation effect and large birefringence1

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  1. A pair of ionic 1D Cu( ii ) chain enantiomers simultaneously displaying large second- and third-harmonic generation responses

    Dalton Transactions · 2023-01-01

    Xiaodi Du, Congli Gao, Zhiqiang Zhang, Bing Su, Xi-Li Li

    Read original paper ↗ ·

  2. Hydroxyfluorooxoborate (NH 4 )[C(NH 2 ) 3 ][B 3 O 3 F 4 (OH)] for exploring the effects of cation substitution on structure and optical properties

    Chemical Communications · 2023-01-01

    Ziqi Chen, Fuming Li, Zhihua Yang, Shilie Pan, Miriding Mutailipu

    Read original paper ↗ ·

  3. KRb 2 (NO 3 ) 2 Cl: a new birefringent crystal exhibiting a perovskite-related framework and a short cutoff edge

    Dalton Transactions · 2023-01-01

    Zhiyuan Zhang, Die Xu, Zhencheng Wu, Mei Hu, Xin Su, Yineng Huang

    Read original paper ↗ ·

  4. Two pairs of chiral Yb III enantiomers presenting distinct NIR luminescence and circularly polarized luminescence performances with giant differences in second-harmonic generation responses

    Dalton Transactions · 2023-01-01

    Xiaodi Du, Zhiqiang Zhang, Congli Gao, Fengcai Li, Xi-Li Li

    Read original paper ↗ ·

  5. Introduction of the [B–O/F] Units Enhances the Band Gap and Birefringence from Na6Mg3B10O18F6 to K3NaB10O16F2

    Inorganic Chemistry · 2023-07-26

    Bingliang Cheng, Wenjuan Ma, Abudukadi Tudi, Changyou Liu, Xifa Long, Yun Mo Yang

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  6. Quadruple‐Bidentate Nitrate‐Ligated A 2 Hg(NO 3 ) 4 (A=K, Rb): Strong Second‐Harmonic Generation and Sufficient Birefringence

    Angewandte Chemie International Edition · 2023-08-02

    Qi Lu, Xingxing Jiang, Kaining Duanmu, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

    Read original paper ↗ ·

  7. Quadruple‐Bidentate Nitrate‐Ligated A 2 Hg(NO 3 ) 4 (A=K, Rb): Strong Second‐Harmonic Generation and Sufficient Birefringence

    Angewandte Chemie · 2023-08-02

    Qi Lu, Xingxing Jiang, Kaining Duanmu, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

    Read original paper ↗ ·

  8. α- and β-(C4H5N2O)(IO3)·HIO3: Two SHG Materials Based on Organic–Inorganic Hybrid Iodates

    Inorganic Chemistry · 2023-08-11

    Qianqian Chen, Chun‐Li Hu, Mingzhi Zhang, Bingxuan Li, Jiang‐Gao Mao

    Read original paper ↗ ·

  9. (CN3H6)[FeIIFeIII(SO4)3(H2O)3]: A Framework Iron Sulfate with a Mixed S = 2 and S = 5/2 Honeycomb Lattice

    Inorganic Chemistry · 2023-10-16

    Victoria A. Ginga, Oleg I. Siidra, Alexander A. Tsirlin, A. Setzer, Dmitri O. Charkin, M. Börner, Veronika R. Abdulina, Semen A. Ivanov, Darya A. Gorbachevskaya, Nikita Zolotov

    Read original paper ↗ ·

  10. Discovery of excellent ultraviolet nonlinear optical materials in chlorates and bromates with highly stereochemically active lone pairs

    Inorganic Chemistry Frontiers · 2024-01-01

    Chun‐Li Hu, Qianqian Chen, Fang Kong, Jiang‐Gao Mao

    Read original paper ↗ ·

  11. Research progress in optical materials with cationic organic planar π-conjugated groups containing CN bonds

    Inorganic Chemistry Frontiers · 2024-01-01

    Hangwei Jia, Xueling Hou, Shilie Pan

    Read original paper ↗ ·

  12. Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering

    Angewandte Chemie International Edition · 2024-08-15

    Huan Zhou, Meng Cheng, Dongdong Chu, Xu Liu, Ran An, Shilie Pan, Shilie Pan, Zhihua Yang

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  13. Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering

    Angewandte Chemie · 2024-08-15

    Huan Zhou, Meng Cheng, Dongdong Chu, Xu Liu, Ran An, Shilie Pan, Zhihua Yang

    Read original paper ↗ ·

  14. Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances

    Small · 2024-12-23

    Junben Huang, Ailijiang Abudurusuli, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  15. Electron density distribution in bis(guanidinium) disodium hypodiphosphate heptahydrate, (CH 6 N 3 ) 2 Na 2 (P 2 O 6 )·7H 2 O

    Acta Crystallographica Section B Structural Science Crystal Engineering and Materials · 2025-01-05

    Przemysław Starynowicz, Katarzyna Anna Ślepokura, P. Kurowska, Vasyl Kinzhybalo

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  16. [C 2 N 4 H 7 O][NH 2 SO 3 ]: High‐Performance Ultraviolet Nonlinear Optical Crystal with Ditrigon Coupled Guanylurea Group

    Angewandte Chemie · 2025-02-11

    Xin Wen, Yuchen Yan, Jingyao Lu, Xuemei Shi, Piao Tang, Jindong Chen, Guangsai Yang, Guang Peng, Haohai Yu, Huaijin Zhang, Zhanggui Hu, Jiyang Wang, Ning Ye

    Read original paper ↗ ·

  17. [C 2 N 4 H 7 O][NH 2 SO 3 ]: High‐Performance Ultraviolet Nonlinear Optical Crystal with Ditrigon Coupled Guanylurea Group

    Angewandte Chemie International Edition · 2025-02-11

    Xin Wen, Yuchen Yan, Jingyao Lu, Xuemei Shi, Piao Tang, Jindong Chen, Guangsai Yang, Guang Peng, Haohai Yu, Huaijin Zhang, Zhanggui Hu, Jiyang Wang, Ning Ye

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  18. Strongly Polar [H2PO3]− Induced π-Conjugated Group Arrangement for Balanced UV Nonlinear Optical Performance

    Inorganic Chemistry · 2025-08-07

    Xin Wen, Guang Peng, Jingyao Lu, Yuchen Yan, Huili Zhang, Huili Zhang, Dequan Kong, Haohai Yu, Huaijin Zhang, Huaijin Zhang, Ning Ye

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  19. Synergistic Design of UV Nonlinear Optical Crystals: Harnessing Flexible π-Conjugated Anions and Guanidinium Cations for Enhanced Performance

    Inorganic Chemistry · 2025-08-22

    Cheng Hu, Yujie Fan, Chensheng Lin, Yunxia Song, Chao Wang, Tao Yan, Min Luo

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  20. Na2(C6H4NO3)2·H2O: A promising ultraviolet nonlinear optical crystal with strong second-harmonic generation effect and large birefringence

    Chinese Journal of Structural Chemistry · 2025-12-23

    Xuan Pang, Leyan Nian, Yongzhang Wang, Chunmei Huang

    Read original paper ↗ ·
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