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RESEARCH PAPER · Inorganic Chemistry · 2022

Two Indium Iodate–Nitrates with Large Birefringence Induced by Hybrid Anionic Functional Groups and Their Favorable Arrangements

Yu Huang, Ting-Kun Jiang, Bing‐Ping Yang, Chun‐Li Hu, Zhi Gang Fang, Jiang‐Gao Mao

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Two Indium Iodate–Nitrates with Large Birefringence Induced by Hybrid Anionic Functional Groups and Their Favorable ArrangementsOriginalIndium( iii )/2-benzoylpyridine chemistry: interesting indium( iii ) bromide-assisted transformations of the ligand3Rbcl·(H2seo3)2: A New Salt-Inclusion Selenite as a Promising Uv Birefringent Material0Noncentrosymmetric (C3H7N6)6(H2PO4)4(HPO4)·4H2O and Centrosymmetric (C3H7N6)2SO4·2H2O: Exploration of Acentric Structure by Combining Planar and Tetrahedral Motifs via Hydrogen Bonds37A new birefringent material, HfF2(IO3)2, with a large birefringence and improved overall performances achieved by the integration of functional groups19RbCl·(H2SeO3)2: A Salt-Inclusion Selenite Featuring Short UV Cut-Off Edge and Large Birefringence15[M(OH) 2 ] 3 (IO 3 )(SeO 4 )·H 2 O (M = Ga and In): metal iodate–selenate nonlinear optical materials with a hexagonal tungsten oxide-type topology20Dramatically improved optical anisotropy by realizing stereochemically active lone pairs in a sulfate system, K 2 SO 4 ·HIO 323[C(NH2)2NHNO2][C(NH2)3](NO3)2: A Mixed Organic Cationic Hybrid Nitrate with an Unprecedented Nonlinear-Optical-Active Unit30A Polar Tetragonal Tungsten Bronze with Colossal Second‐Harmonic Generation18Ce(IO3)3F and Ce(IO3)2(NO3): Two Mixed-Anion Cerium Iodates with Good Nonlinear Optical and Birefringent Properties14K 2 RbB 8 PO 16 : A Borophosphate with Moderate Birefringence and Deep-Ultraviolet Transmission10C(NH2)3Cd(C2O4)Cl(H2O)·H2O and BaCd(C2O4)1.5Cl(H2O)2: Two Oxalate Chlorides Obtained by Chemical Scissors Strategy Exhibiting Low-Dimensional Structural Networks and Balanced Overall Optical Properties14Designing excellent UV birefringent materials through the synergistic interaction of two highly distorted functional groups23Explorations of highly birefringent materials in the vanadium oxyfluoride–iodate system by fluoride ion modulation8Designing Optical Anisotropy: Silver-Aminoalkylpyridine Nitrate Complexes with Tunable Structures3(C 8 H 7 N 2 O 2 ) 2 [Bi 2 Br 8 ]·2H 2 O and (C 8 H 7 N 2 O 2 ) 6 [Bi 2 Cl 10 ]Cl 2 ·2H 2 O: Exploring Birefringent Crystals in Hybrid Halide Systems5(C10N2H10)(HI2O6)(HIO3)(IO3): A Birefringent Material Featuring Large π-Conjugated Organic Cation and Two Types of Iodate Anions2SbO(OH)2(IO3): The First Polar Sb5+‐Iodate with a Strong Second‐Harmonic Generation Response and a Wide Bandgap8“All-four-in-one”: a novel mercury tellurite–nitrate Hg 3 (TeO 3 )(Te 3 O 7 )(NO 3 ) 2 exhibiting exceptional optical anisotropy29Design of borate-squarate hybrid crystals with large birefringence by synergistic assembly of planar π-conjugated groups0From Ba[Sn(IO 3 ) 6 ] to Ba[Sn(IO 3 ) 4 F 2 ]: fluoride-ion-driven enhancement of birefringence and band gap1Halogen-ion-driven polymorphs for high-performance nonlinear optical crystalline materials3

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  1. Indium( iii )/2-benzoylpyridine chemistry: interesting indium( iii ) bromide-assisted transformations of the ligand

    Dalton Transactions · 2022-01-01

    Christina Stamou, Zoi G. Lada, Christos T. Chasapis, Dionissios A. Papaioannou, Pierre Dechambenoit, Spyros P. Perlepes

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  2. Rbcl·(H2seo3)2: A New Salt-Inclusion Selenite as a Promising Uv Birefringent Material

    SSRN Electronic Journal · 2022-01-01

    Huan Wang, Lili Liu, Zhaowei Hu, Junbo Wang, Mengmeng Zhu, Jiayue Xu

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  3. Noncentrosymmetric (C3H7N6)6(H2PO4)4(HPO4)·4H2O and Centrosymmetric (C3H7N6)2SO4·2H2O: Exploration of Acentric Structure by Combining Planar and Tetrahedral Motifs via Hydrogen Bonds

    Inorganic Chemistry · 2022-06-16

    Shu‐Fang Li, Liang Hu, Yao Ma, Fei‐Fei Mao, Jie Zheng, Xiu‐Du Zhang, Dong Yan

    Read original paper ↗ ·

  4. A new birefringent material, HfF2(IO3)2, with a large birefringence and improved overall performances achieved by the integration of functional groups

    Scripta Materialia · 2022-10-10

    Yu Huang, Zhi Gang Fang, Bing‐Ping Yang, Xueying Zhang, Jiang‐Gao Mao

    Read original paper ↗ ·

  5. RbCl·(H2SeO3)2: A Salt-Inclusion Selenite Featuring Short UV Cut-Off Edge and Large Birefringence

    Inorganic Chemistry · 2022-12-23

    Huan Wang, Lili Liu, Zhaowei Hu, Junbo Wang, Mengmeng Zhu, Yu Meng, Jiayue Xu

    Read original paper ↗ ·

  6. [M(OH) 2 ] 3 (IO 3 )(SeO 4 )·H 2 O (M = Ga and In): metal iodate–selenate nonlinear optical materials with a hexagonal tungsten oxide-type topology

    Inorganic Chemistry Frontiers · 2023-01-01

    Qianqian Chen, Chun‐Li Hu, Bingxuan Li, Jiang‐Gao Mao

    Read original paper ↗ ·

  7. Dramatically improved optical anisotropy by realizing stereochemically active lone pairs in a sulfate system, K 2 SO 4 ·HIO 3

    Inorganic Chemistry Frontiers · 2023-01-01

    Zhiyong Bai, Kang Min Ok

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  8. [C(NH2)2NHNO2][C(NH2)3](NO3)2: A Mixed Organic Cationic Hybrid Nitrate with an Unprecedented Nonlinear-Optical-Active Unit

    Inorganic Chemistry · 2023-03-14

    Dong Yan, Meng-Meng Ren, Qian Liu, Fei‐Fei Mao, Yu Ma, Ru‐Ling Tang, Hongbo Huang, Bingbing Zhang, Xiu‐Du Zhang, Shu‐Fang Li

    Read original paper ↗ ·

  9. A Polar Tetragonal Tungsten Bronze with Colossal Second‐Harmonic Generation

    Advanced Science · 2023-04-23

    Yunseung Kuk, Seong Bin Bae, Sang Mo Yang, Kang Min Ok

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  10. Ce(IO3)3F and Ce(IO3)2(NO3): Two Mixed-Anion Cerium Iodates with Good Nonlinear Optical and Birefringent Properties

    Inorganic Chemistry · 2023-09-07

    Nan Ma, Yu Hong Huang, Chun‐Li Hu, Mingzhi Zhang, Bingxuan Li, Jiang‐Gao Mao

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  11. K 2 RbB 8 PO 16 : A Borophosphate with Moderate Birefringence and Deep-Ultraviolet Transmission

    Inorganic Chemistry · 2023-12-15

    Jianyi Zuo, Qiuyuan Feng, Hong Lei Du

    Read original paper ↗ ·

  12. C(NH2)3Cd(C2O4)Cl(H2O)·H2O and BaCd(C2O4)1.5Cl(H2O)2: Two Oxalate Chlorides Obtained by Chemical Scissors Strategy Exhibiting Low-Dimensional Structural Networks and Balanced Overall Optical Properties

    Inorganic Chemistry · 2023-12-19

    Wei Xu, Liang Ma, Yi‐Lei Lv, Siyu Ma, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

    Read original paper ↗ ·

  13. Designing excellent UV birefringent materials through the synergistic interaction of two highly distorted functional groups

    Inorganic Chemistry Frontiers · 2024-01-01

    Xiaoyan Zhou, Xiang Mao, Pu Zhang, Xuehua Dong, Ling Huang, Liling Cao, Daojiang Gao, Guohong Zou

    Read original paper ↗ ·

  14. Explorations of highly birefringent materials in the vanadium oxyfluoride–iodate system by fluoride ion modulation

    Journal of Materials Chemistry C · 2024-01-01

    Yu Huang, Xueying Zhang, Sangen Zhao, Jiang‐Gao Mao, Bing‐Ping Yang

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  15. Designing Optical Anisotropy: Silver-Aminoalkylpyridine Nitrate Complexes with Tunable Structures

    Inorganic Chemistry · 2024-01-23

    Myung‐Ho Choi, Yang Li, Kang Min Ok

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  16. (C 8 H 7 N 2 O 2 ) 2 [Bi 2 Br 8 ]·2H 2 O and (C 8 H 7 N 2 O 2 ) 6 [Bi 2 Cl 10 ]Cl 2 ·2H 2 O: Exploring Birefringent Crystals in Hybrid Halide Systems

    Inorganic Chemistry · 2024-05-10

    Mingliang Ding, Qiong Sen Wu, Yaoguo Shen, Jinquan Hong, Guofa Dong, Liang Ma

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  17. (C10N2H10)(HI2O6)(HIO3)(IO3): A Birefringent Material Featuring Large π-Conjugated Organic Cation and Two Types of Iodate Anions

    Inorganic Chemistry · 2024-10-19

    Yuhang Wang, De-Xuan Jiang, De‐Xuan Liu, Fu-Ying Li, He Zhao, Jie Pan, Qi Wei, Li Wei, Guo‐Yu Yang

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  18. SbO(OH)2(IO3): The First Polar Sb5+‐Iodate with a Strong Second‐Harmonic Generation Response and a Wide Bandgap

    Small · 2024-10-27

    Mengya Ji, Yilin Li, Chun‐Li Hu, Jin Chen, Bingxuan Li, Jiang‐Gao Mao

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  19. “All-four-in-one”: a novel mercury tellurite–nitrate Hg 3 (TeO 3 )(Te 3 O 7 )(NO 3 ) 2 exhibiting exceptional optical anisotropy

    Chemical Science · 2025-01-01

    Ru‐Ling Tang, Yi‐Lei Lv, Liang Ma, Bing-Wei Miao, Wenlong Liu, Sheng‐Ping Guo

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  20. Design of borate-squarate hybrid crystals with large birefringence by synergistic assembly of planar π-conjugated groups

    Dalton Transactions · 2026-01-01

    Haowen Li, X Y Wang, Hui Chai, Fangfang Zhang

    Read original paper ↗ ·

  21. From Ba[Sn(IO 3 ) 6 ] to Ba[Sn(IO 3 ) 4 F 2 ]: fluoride-ion-driven enhancement of birefringence and band gap

    Inorganic Chemistry Frontiers · 2026-01-01

    Xue-Ying Zhang, Peng-Fei Chen, Bing‐Ping Yang, Jiang‐Gao Mao

    Read original paper ↗ ·

  22. Halogen-ion-driven polymorphs for high-performance nonlinear optical crystalline materials

    Chemical Science · 2026-01-01

    Yuwei Kang, Can Hui Yang, Yunjie Wang, Qi Wu

    Read original paper ↗ ·
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