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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2022

An excellent lead oxyiodide with a strong second-harmonic generation response and a large birefringence induced by the oriented arrangement of highly distorted [PbO 4 I 2 ] polyhedra

Ziqi Zhou, Ruibiao Fu, Hong‐Xin Tang, Zuju Ma, Xin‐Tao Wu

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An excellent lead oxyiodide with a strong second-harmonic generation response and a large birefringence induced by the oriented arrangement of highly distorted [PbO 4 I 2 ] polyhedraOriginalA potassium lead 2-methylmalonate-iodide nonlinear optical crystal with strong second-harmonic generation response and large birefringence2Substitution of apical iodide ligands in octahedral molybdenum cluster complexes by N-donor molecules: Synthesis and investigation of [{Mo6I8}(L)I5]– and cis-[{Mo6I8}(L)2I4] (L = CH3CN or 1,2,4-triazole)6Na 2 CeF 6 : A Highly Laser Damage‐Tolerant Double Perovskite Type Ce(IV) Fluoride Exhibiting Strong Second‐Harmonic Generation Effect30Design of alkali lead oxybromides with a strong second-harmonic generation response and large birefringence1Strategically designed anisotropic organic–inorganic metal halides (OIMHs) with superior balance between bandgap and birefringence133Pb 8 O 7 I 2 ·2CsI: the salt-inclusion strategy enriches the structural chemistry in lead oxyhalides1(CH5N3S)2Pb5Br10 and (CH5N3S)Pb2Br4: Two Nonlinear Optical Lead Thiosemicarbazide Bromides with Diverse Pb-Centered Building Units10Reversal Enhancement of Birefringence by Stereochemically Active Lone Pairs in Sn(II)-Based Mixed Halides0Chiral Lead-Oxyiodide Nonlinear Optical Crystals Constructed on l -Malate Groups5Stable lead succinate-iodides with strong second-harmonic generation response and large birefringence0(C 5 H 7 N 2 ) (C 8 H 4 O 4 ) PbBr: Jahn–Teller Distortion‐Induced Tilting of π‐Conjugated Planes Resolving the Second‐Order Polarizability–Structural Anisotropy Conflicts14(C 5 H 7 N 2 ) (C 8 H 4 O 4 ) PbBr: Jahn–Teller Distortion‐Induced Tilting of π‐Conjugated Planes Resolving the Second‐Order Polarizability–Structural Anisotropy Conflicts1The Parallel Coplanar Alignment of Planar Non‐π‐Conjugated [Pb 3 Br 3 ] Rings for a Stable Ultraviolet Nonlinear Optical Crystal0

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  1. A potassium lead 2-methylmalonate-iodide nonlinear optical crystal with strong second-harmonic generation response and large birefringence

    Scripta Materialia · 2023-10-14

    Shuangcheng Li, Zilong Geng, Ruibiao Fu, Zuju Ma, Xin‐Tao Wu

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  2. Substitution of apical iodide ligands in octahedral molybdenum cluster complexes by N-donor molecules: Synthesis and investigation of [{Mo6I8}(L)I5]– and cis-[{Mo6I8}(L)2I4] (L = CH3CN or 1,2,4-triazole)

    Polyhedron · 2023-11-08

    Anton A. Ulantikov, K.D. Podolets, Taisiya Sergeevna Sukhikh, Yuri V. Mironov, Konstantin A. Brylev, Yakov Maksumovich Gayfulin

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  3. Na 2 CeF 6 : A Highly Laser Damage‐Tolerant Double Perovskite Type Ce(IV) Fluoride Exhibiting Strong Second‐Harmonic Generation Effect

    Small · 2023-12-05

    Ru‐Ling Tang, Wei Xu, Xin Lian, Yue‐Qi Wei, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo

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  4. Design of alkali lead oxybromides with a strong second-harmonic generation response and large birefringence

    Journal of Materials Chemistry C · 2024-01-01

    Jialin Zeng, Shuangcheng Li, Ya-Hui Zhu, Zilong Geng, Yiting Luo, Ruibiao Fu, Zuju Ma

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  5. Strategically designed anisotropic organic–inorganic metal halides (OIMHs) with superior balance between bandgap and birefringence

    Inorganic Chemistry Frontiers · 2024-12-16

    Mingchang Wang, Huaiyu Wu, Miao‐Bin Xu, Jiajia Li, Ke‐Zhao Du, Jin Chen

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  6. 3Pb 8 O 7 I 2 ·2CsI: the salt-inclusion strategy enriches the structural chemistry in lead oxyhalides

    Dalton Transactions · 2025-01-01

    Mayinuer Maimaiti, Yuchen Yan, Jiang Wu, Tingwen Han, Jing Xie, Min Zhang

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  7. (CH5N3S)2Pb5Br10 and (CH5N3S)Pb2Br4: Two Nonlinear Optical Lead Thiosemicarbazide Bromides with Diverse Pb-Centered Building Units

    Inorganic Chemistry · 2025-05-20

    Ru‐Ling Tang, Yue‐Qi Wei, Yi‐Lei Lv, Bing-Wei Miao, Cheng Chen, Wenlong Liu

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  8. Reversal Enhancement of Birefringence by Stereochemically Active Lone Pairs in Sn(II)-Based Mixed Halides

    Crystal Growth & Design · 2025-07-11

    Xu Liu, Abudukadi Tudi, Junben Huang, Juanjuan Lu, Zhaofeng Wu

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  9. Chiral Lead-Oxyiodide Nonlinear Optical Crystals Constructed on l -Malate Groups

    Inorganic Chemistry · 2025-12-08

    Yiting Luo, Shuangcheng Li, Jialin Zeng, Senfu Lei, Zilong Geng, Yulu Wu, Wenjing Yang, Ruibiao Fu, Zuju Ma

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  10. Stable lead succinate-iodides with strong second-harmonic generation response and large birefringence

    Inorganic Chemistry Frontiers · 2026-01-01

    Yulu Wu, Jialin Zeng, Rui Biao Fu, Wen Jing Yang, Zilong Geng, Senfu Lei, Yiting Luo, Xiaofan Tong, Zuju Ma

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  11. (C 5 H 7 N 2 ) (C 8 H 4 O 4 ) PbBr: Jahn–Teller Distortion‐Induced Tilting of π‐Conjugated Planes Resolving the Second‐Order Polarizability–Structural Anisotropy Conflicts

    Angewandte Chemie International Edition · 2026-03-28

    Ming‐Yan Yu, Can Yang, Yun‐Jie Wang, Xin Su, Jian Cui, Yao‐Long Zhu, Qing‐Wen Zhu, Qi Wu, Li‐Ming Wu, Ling Chen

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  12. (C 5 H 7 N 2 ) (C 8 H 4 O 4 ) PbBr: Jahn–Teller Distortion‐Induced Tilting of π‐Conjugated Planes Resolving the Second‐Order Polarizability–Structural Anisotropy Conflicts

    Angewandte Chemie · 2026-03-28

    Ming‐Yan Yu, Can Yang, Yun‐Jie Wang, Xin Su, Jian Cui, Yao‐Long Zhu, Qing‐Wen Zhu, Qi Wu, Li‐Ming Wu, Ling Chen

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  13. The Parallel Coplanar Alignment of Planar Non‐π‐Conjugated [Pb 3 Br 3 ] Rings for a Stable Ultraviolet Nonlinear Optical Crystal

    Advanced Optical Materials · 2026-08-27

    Xiaofan Tong, Zuju Ma, Yulu Wu, Ruibiao Fu, Wenjing Yang, Jiacheng Chen, Qian Zeng

    Read original paper ↗ ·
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