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RESEARCH PAPER · Chemistry of Materials · 2004

Asymmetric Cation Coordination in Oxide Materials: Influence of Lone-Pair Cations on the Intra-octahedral Distortion in d0 Transition Metals

P. Shiv Halasyamani

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Asymmetric Cation Coordination in Oxide Materials: Influence of Lone-Pair Cations on the Intra-octahedral Distortion in d0 Transition MetalsOriginalNew d0 Transition Metal Iodates: Synthesis, Structure, and Characterization of BaTi(IO3)6, LaTiO(IO3)5, Ba2VO2(IO3)4·(IO3), K2MoO2(IO3)4, and BaMoO2(IO3)4·H2O64Mixed-Metal Tellurites: Synthesis, Structure, and Characterization of Na1.4Nb3Te4.9O18 and NaNb3Te4O16126Directed Synthesis of Noncentrosymmetric Molybdates83Predicting morphotropic phase boundary locations and transition temperatures in Pb- and Bi-based perovskite solid solutions from crystal chemical data and first-principles calculations216Luminescent Lanthanide Selenites and Tellurites Decorated by MoO4 Tetrahedra or MoO6 Octahedra: Nd2MoSe2O10, Gd2MoSe3O12, La2MoTe3O12, and Nd2MoTe3O1253Unusual High‐Temperature Structural Behaviour in Ferroelectric Bi2WO6172Na2Te3Mo3O16: A New Molybdenum Tellurite with Second-Harmonic Generating and Pyroelectric Properties232Structure prediction of ordered and disordered multiple octahedral cation perovskites using SPuDS208Distortions in Octahedrally Coordinated d0 Transition Metal Oxides: A Continuous Symmetry Measures Approach404Directed Synthesis of Noncentrosymmetric Molybdates Using Composition Space Analysis72Structure and Bonding in SnWO4, PbWO4, and BiVO4: Lone Pairs vs Inert Pairs310Biosynthesis and biological activity of enniatins49Two New Noncentrosymmetric Polar Oxides: Synthesis, Characterization, Second-Harmonic Generating, and Pyroelectric Measurements on TlSeVO5 and TlTeVO5115(NH4)2Te2WO8: A New Polar Oxide with Second-Harmonic Generating, Ferroelectric, and Pyroelectric Properties88The Versatile Chemistry and Noncentrosymmetric Crystal Structures of Salt‐Inclusion Vanadate Hybrids52A Polar Oxide ZnSnO3 with a LiNbO3-Type Structure300A rare multi-coordinate tellurite, NH4ATe4O9·2H2O (ARb or Cs): The occurrence of TeO3, TeO4, and TeO5 Polyhedra in the same material66ZnVSe2O7 and Cd6V2Se5O21: New d10 Transition-Metal Selenites with V(IV) or V(V) Cations541/∞[ZrPSe6−]: A Soluble Photoluminescent Inorganic Polymer and Strong Second Harmonic Generation Response of Its Alkali Salts85Soluble Direct‐Band‐Gap Semiconductors LiAsS2 and NaAsS2: Large Electronic Structure Effects from Weak As⋅⋅⋅S Interactions and Strong Nonlinear Optical Response194Structures and Properties of Functional Metal Selenites and Tellurites164Synthetic Approaches for Noncentrosymmetric Molybdates59Strong Second Harmonic Generation from the Tantalum Thioarsenates A3Ta2AsS11 (A = K and Rb)265Explorations of new phases in the GaIII/InIII–MoVI–SeIV/TeIV–O systems46Explorations of new second-order NLO materials in the AgI-MoVI/WVI-TeIV-O systems62Alignment of Lone Pairs in a New Polar Material: Synthesis, Characterization, and Functional Properties of Li2Ti(IO3)6307Semiorganic Nonlinear Optical Material: Preparation and Properties of (NH4)·Sr[ l -(+)-C4H2O6·B(OH)2]·4H2O47Polar or Nonpolar? A+ Cation Polarity Control in A2Ti(IO3)6(A = Li, Na, K, Rb, Cs, Tl)306Growth, Structure, and Optical Properties of a Congruent Melting Oxyborate, Bi2ZnOB2O6112BaNbO(IO3)5: A New Polar Material with a Very Large SHG Response331A Series of New Infrared NLO Semiconductors, ZnY6Si2S14, AlxDy3(SiyAl1−y)S7, and Al0.33Sm3SiS7134Noncentrosymmetric Polar Oxide Material, Pb3SeO5: Synthesis, Characterization, Electronic Structure Calculations, and Structure−Property Relationships147Syntheses, Crystal Structures, and Properties of Five New Transition Metal Molybdenum(VI) Selenites and Tellurites54Growth and Properties of Single Crystals of Noncentrosymmetric Na3VO2B6O1187Syntheses and crystal structures of four new silver(i) iodates with d 0 -transition metal cations45First-principles study of the ferroelectric and nonlinear optical properties of the LiNbO3-type ZnSnO366Syntheses, crystal structures, and properties of three new lanthanum( iii ) vanadium iodates56NaVO2(IO3)2(H2O): A Unique Layered Material Produces A Very Strong SHG Response143Key Role of Covalent Bonding in Octahedral Tilting in Perovskites81Soluble Semiconductors AAsSe2 (A = Li, Na) with a Direct-Band-Gap and Strong Second Harmonic Generation: A Combined Experimental and Theoretical Study241Explorations of New Second-Order Nonlinear Optical Materials in the KI-MII -IV-O Systems43Polar Hexagonal Tungsten Oxide (HTO) Materials: (1) Synthesis, Characterization, Functional Properties, and Structure−Property Relationships in A2(MoO3)3(SeO3) (A = Rb+ and Tl+) and (2) Classification, Structural Distortions, and Second-Harmonic Generating Properties of Known Polar HTOs104A Series of New Phases Containing Three Different Asymmetric Building Units55Novel Noncentrosymmetric Zinc Coordination Polymer Containing an Unusual Zinc Carboxylate−Sulfonate Substructure with a (10,3)-d Topology and Its Second-Harmonic-Generation Properties51Pb 2 B 5 O 9 I: An Iodide Borate with Strong Second Harmonic Generation361Polar or Non-Polar? Syntheses, Crystal Structures, and Optical Properties of Three New Palladium(II) Iodates45Bulk crystal growth and characterization of a new polar polymorph of BaTeMo2O9: α-BaTeMo2O998Explorations of New Second-Order Nonlinear Optical Materials in the Potassium Vanadyl Iodate System268Top-Seeded Solution Growth, Morphology, and Properties of a Polar Crystal Cs2TeMo3O1277K3B6O10Cl: A New Structure Analogous to Perovskite with a Large Second Harmonic Generation Response and Deep UV Absorption Edge670Syntheses and Characterization of New Mid-Infrared Transparency Compounds: Centric Ba2BiGaS5 and Acentric Ba2BiInS595Structures and properties of functional metal iodates72Polymorphism of BaTeMo 2 O 9 : A New Polar Polymorph and the Phase Transformation186Rational Synthesis of Noncentrosymmetric Metal–Organic Frameworks for Second-Order Nonlinear Optics1005New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)50First-principles study of misfit strain-stabilized ferroelectric SnTiO 359MgTeMoO6: A neutral layered material showing strong second-harmonic generation110PbPt(IO3)6(H2O): a new polar material with two types of stereoactive lone-pairs and a very large SHG response80Second-Order Nonlinear Optical Materials Based on Metal Iodates, Selenites, and Tellurites60Crystal structures and second-order NLO properties of borogermanates59UV Nonlinear Optical Crystal Ba2[B6O9(OH)4] Featuring Unique Chiral Layers with a New B18O42 Circle Based on BO3 and BO4 Units97Lone‐Pair‐Induced Covalency as the Cause of Temperature‐ and Field‐Induced Instabilities in Bismuth Sodium Titanate555Influence of the Cation Size on the Framework Structures and Space Group Centricities in AMo2O5(SeO3)2 (A = Sr, Pb, and Ba)93Dielectric properties of a polar ZnSnO3 with LiNbO3-type structure47Cs 4 Mo 5 P 2 O 22 : a first Strandberg-type POM with 1D straight chains of polymerized [Mo 5 P 2 O 23 ] 6− units and moderate second harmonic generation response83Coexistence of magnetic and electrical order in the new perovskite-like (C3N2H5)[Mn(HCOO)3] formate61New Fluoride Carbonates: Centrosymmetric KPb2(CO3)2F and Noncentrosymmetric K2.70Pb5.15(CO3)5F367Zn2(VO4)(IO3): A Novel Polar Zinc(II) Vanadium(V) Iodate with a Large SHG Response94Metal Chalcogenides: A Rich Source of Nonlinear Optical Materials680Pb3B6O11F2: the first non-centrosymmetric lead borate fluoride with a large second harmonic generation response61High-Pressure Synthesis, Crystal Structure, and Phase Stability Relations of a LiNbO 3 -Type Polar Titanate ZnTiO 3 and Its Reinforced Polarity by the Second-Order Jahn–Teller Effect152Noncentrosymmetric YVSe2O8 and Centrosymmetric YVTe2O8: Macroscopic Centricities Influenced by the Size of Lone Pair Cation Linkers63A Nitrate Nonlinear Optical Crystal Pb16(OH)16(NO3)16 with a Large Second-Harmonic Generation Response57α-AgI3O8 and β-AgI3O8 with Large SHG Responses: Polymerization of IO3 Groups into the I3O8 Polyiodate Anion113Li2CdGeS4, A Diamond-Like Semiconductor with Strong Second-Order Optical Nonlinearity in the Infrared and Exceptional Laser Damage Threshold193Strong Second Harmonic Generation (SHG) Originating from Combined Second-Order Jahn–Teller (SOJT) Distortive Cations in a New Noncentrosymmetric Tellurite, InNb(TeO4)252First-principles materials applications and design of nonlinear optical crystals259Role of Acentric Displacements on the Crystal Structure and Second-Harmonic Generating Properties of RbPbCO3F and CsPbCO3F90Pb 4 V 6 O 16 (SeO 3 ) 3 (H 2 O), Pb 2 VO 2 (SeO 3 ) 2 Cl, and PbVO 2 (SeO 3 )F: New Lead(II)–Vanadium(V) Mixed-Metal Selenites Featuring Novel Anionic Skeletons67Excellent Sun-Light-Driven Photocatalytic Activity by Aurivillius Layered Perovskites, Bi5–xLaxTi3FeO15 (x = 1, 2)110High-performance, high-temperature piezoelectric BiB 3 O 6 crystals65PbGa 4 S 7 : a wide-gap nonlinear optical material91Recent advances on second-order NLO materials based on metal iodates328Pb7O(OH)3(CO3)3(BO3): First Mixed Borate and Carbonate Nonlinear Optical Material Exhibiting Large Second-Harmonic Generation Response74Cs(TaO 2 ) 3 (SeO 3 ) 2 and Cs(TiOF) 3 (SeO 3 ) 2 : Structural and Second Harmonic Generation Changes Induced by the Different d 0 -TM Coordination Octahedra67The lone-pairs enhanced birefringence and SHG response: A DFT investigation on M2B5O9Cl (M=Sr, Ba, and Pb)47Pb17O8Cl18: A Promising IR Nonlinear Optical Material with Large Laser Damage Threshold Synthesized in an Open System223Pb2Ba3(BO3)3Cl: A Material with Large SHG Enhancement Activated by Pb-Chelated BO3 Groups279First-principles study on phase transition and ferroelectricity in lithium niobate and tantalate55Large Birefringent Materials, Na6Te4W6O29 and Na2TeW2O9: Synthesis, Structure, Crystal Growth, and Characterization73KPb 2 (PO 3 ) 5 : a novel nonlinear optical lead polyphosphate with a short deep-UV cutoff edge109Organic–Inorganic Perovskites: Structural Versatility for Functional Materials Design2906LiNa 5 Mo 9 O 30 : Crystal Growth, Linear, and Nonlinear Optical Properties79“All-Three-in-One”: A New Bismuth–Tellurium–Borate Bi3TeBO9 Exhibiting Strong Second Harmonic Generation Response223Bi3OF3(IO3)4: Metal Oxyiodate Fluoride Featuring a Carbon-Nanotube-like Topological Structure with Large Second Harmonic Generation Response121Learning from data to design functional materials without inversion symmetry95Bandgap Narrowing of Lead-Free Perovskite-Type Hybrids for Visible-Light-Absorbing Ferroelectric Semiconductors98ABi2(IO3)2F5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second‐Harmonic Generation Response with a Wide Bandgap140Tailored Engineering of an Unusual (C 4 H 9 NH 3 ) 2 (CH 3 NH 3 ) 2 Pb 3 Br 10 Two‐Dimensional Multilayered Perovskite Ferroelectric for a High‐Performance Photodetector288Tailored Engineering of an Unusual (C 4 H 9 NH 3 ) 2 (CH 3 NH 3 ) 2 Pb 3 Br 10 Two‐Dimensional Multilayered Perovskite Ferroelectric for a High‐Performance Photodetector85Remarkable impact of low BiYbO 3 doping levels on the local structure and phase transitions of BaTiO 343The first lead fluorooxoborate PbB 5 O 8 F: achieving the coexistence of large birefringence and deep-ultraviolet cut-off edge75Functional Materials Design via Structural Regulation Originated from Ions Introduction: A Study Case in Cesium Iodate System90A Series of Rare-Earth Borates K 7 MRE 2 B 15 O 30 (M = Zn, Cd, Pb; RE = Sc, Y, Gd, Lu) with Large Second Harmonic Generation Responses103Assisting the Effective Design of Polar Iodates with Early Transition-Metal Oxide Fluoride Anions206Ce(IO3)2F2⋅H2O: The First Rare‐Earth‐Metal Iodate Fluoride with Large Second Harmonic Generation Response66Pb 2 GaF 2 (SeO 3 ) 2 Cl: Band Engineering Strategy by Aliovalent Substitution for Enlarging Bandgap while Keeping Strong Second Harmonic Generation Response178A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions137Centrosymmetric K 2 SO 4 ·(SbF 3 ) 2 and noncentrosymmetric Rb 2 SO 4 ·(SbF 3 ) 2 resulting from cooperative effects of lone pair and cation size63New lead-free perovskite Rb 7 Bi 3 Cl 16 nanocrystals with blue luminescence and excellent moisture-stability90A Niobium Oxyiodate Sulfate with a Strong Second‐Harmonic‐Generation Response Built by Rational Multi‐Component Design114HBa2.5(IO3)6(I2O5) and HBa(IO3)(I4O11): Explorations of Second-Order Nonlinear Optical Materials in the Alkali-Earth Polyiodate System49Two Polar Molybdenum(VI) Iodates(V) with Large Second-Harmonic Generation Responses67Stabilization of O–O Bonds by d0 Cations in Li4+ x Ni1– x WO6 (0 ≤ x ≤ 0.25) Rock Salt Oxides as the Origin of Large Voltage Hysteresis85Designing excellent mid-infrared nonlinear optical materials with fluorooxo-functional group of d0 transition metal oxyfluorides63Two-dimensional organic–inorganic hybrid Ruddlesden–Popper perovskite materials: preparation, enhanced stability, and applications in photodetection60Two-stage evolution from phosphate to sulfate of new KTP-type family members as UV nonlinear optical materials through chemical cosubstitution-oriented design51Alignment of Polar Moieties Leading to Strong Second Harmonic Response in KCsMoP2O951Enhancement of Second-Order Optical Nonlinearity in a Lutetium Selenite by Monodentate Anion Partial Substitution58Enhanced nonlinear optical functionality in birefringence and refractive index dispersion of the deep-ultraviolet fluorooxoborates123Bond-length distributions for ions bonded to oxygen: results for the transition metals and quantification of the factors underlying bond-length variation in inorganic solids128AGa 3 F 6 (SeO 3 ) 2 (A = Rb, Cs): A New Type of Phase-Matchable Hexagonal Tungsten Oxide Material with Strong Second-Harmonic Generation Responses63Ba2[MoO3(OH)(IO3)2]IO3: A Promising SHG Material Featuring a Λ-Shaped Functional Motif Achieved by Universal Mono-Site Substitution50A review: A new insight for electronic polarizability and chemical bond strength in Bi2O3-based glasses54Cs 3 Pb 2 (CH 3 COO) 2 X 5 (X=I, Br): Halides with Strong Second‐Harmonic Generation Response Induced by Acetate Groups75Ba(MoO 2 F) 2 (QO 3 ) 2 (Q = Se, Te): Partial Fluorination of MoO 6 Octahedra Enabling Two Polar Solids with Strong and Phase Matchable SHG Response69A new perspective on the composition-structure-property relationships on Nb/Mo/Cr-doped O3-type layered oxide as cathode materials for sodium-ion batteries64Impact of Mg and Ti doping in O3 type NaNi 1/2 Mn 1/2 O 2 on reversibility and phase transition during electrochemical Na intercalation111High-Performance Second-Harmonic-Generation (SHG) Materials: New Developments and New Strategies323A2MoO2F3(IO2F2) (A = Rb, Cs): Strong Nonlinear Optical Responses and Enlarged Band Gaps through Fluorine Incorporation50Giant Second-Harmonic Generation Response and Large Band Gap in the Partially Fluorinated Mid-Infrared Oxide RbTeMo 2 O 8 F149Li2MTeO6 (M=Ti, Sn): Mid‐Infrared Nonlinear Optical Crystal with Strong Second Harmonic Generation Response and Wide Transparency Range72An Effective Strategy for Designing Nonlinear Optical Crystals by Combining the Structure‐Directing Property of Oxyfluorides with Chemical Substitution73Ca3(TeO3)2(MO4) (M = Mo, W): Mid-Infrared Nonlinear Optical Tellurates with Ultrawide Transparency Ranges and Superhigh Laser-Induced Damage Thresholds46Lead-free B-site bimetallic perovskite photocatalyst for efficient benzylic C–H bond activation63Pressure‐Driven Two‐Step Second‐Harmonic‐Generation Switching in BiOIO344Structural role of Nb2O5 in glass-forming ability, electronic polarizability and nanocrystallization in glasses: A review77Potential optical functional crystals with large birefringence: Recent advances and future prospects322Ultrawide Bandgap and Outstanding Second‐Harmonic Generation Response by a Fluorine‐Enrichment Strategy at a Transition‐Metal Oxyfluoride Nonlinear Optical Material51Chemistry, Structure, and Function of Lone Pairs in Extended Solids117Hybrid Germanium Bromide Perovskites with Tunable Second Harmonic Generation122Local Polarity-Induced Assembly of Second-Order Nonlinear Optical Materials128The Antiperovskite‐Type Oxychalcogenides Ae3Q[GeOQ3] (Ae = Ba, Sr; Q = S, Se) with Large Second Harmonic Generation Responses and Wide Band Gaps68Anisotropic structure building unit involving diverse chemical bonds: a new opportunity for high-performance second-order NLO materials181Intense d‐p Hybridization in Nb3O15 Tripolymer Induced the Largest Second Harmonic Generation Response and Birefringence in Germanates51Advances in aliovalent substitution strategy for the design and synthesis of nonlinear optical materials: d0 transition metal/gallium iodates and selenites71Recent advances in IR nonlinear optical chalcogenides with well-balanced comprehensive performance57Lattice pinning in MoO3 via coherent interface with stabilized Li+ intercalation72Highly Birefringent d 0 Transition Metal Fluoroantimonite in the Mid Infrared Band: Order–Disorder Regulation by Cationic Size83Giant Optical Anisotropy in a Covalent Molybdenum Tellurite via Oxyanion Polymerization43

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  1. Asymmetric Cation Coordination in Oxide Materials: Influence of Lone‐Pair Cations on the Intra‐octahedral Distortion in d0 Transition Metals

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  2. New d0 Transition Metal Iodates: Synthesis, Structure, and Characterization of BaTi(IO3)6, LaTiO(IO3)5, Ba2VO2(IO3)4·(IO3), K2MoO2(IO3)4, and BaMoO2(IO3)4·H2O

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  3. (C6H16N2)2[Mo8O26]: a new β-octamolybdate salt

    Acta Crystallographica Section E Structure Reports Online · 2005-03-25

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  4. Mixed-Metal Tellurites: Synthesis, Structure, and Characterization of Na1.4Nb3Te4.9O18 and NaNb3Te4O16

    Inorganic Chemistry · 2005-05-01

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  5. Directed Synthesis of Noncentrosymmetric Molybdates

    Crystal Growth & Design · 2005-07-26

    Eric A. Muller, Robert J. Cannon, Amy Narducci Sarjeant, Kang Min Ok, P. Shiv Halasyamani, Alexander J. Norquist

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  6. (C4H14N2)2[Mo8O26]·2H2O: a new molybdate salt

    Acta Crystallographica Section E Structure Reports Online · 2005-07-30

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  7. Synthesis, crystal structure and magnetic property of a new nickel selenite chloride: Ni5(SeO3)4Cl2

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  8. The first tin(II) vanadium(III) phosphate SnVPO5: Crystal structure and magnetic properties

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  9. Predicting morphotropic phase boundary locations and transition temperatures in Pb- and Bi-based perovskite solid solutions from crystal chemical data and first-principles calculations

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  10. Luminescent Lanthanide Selenites and Tellurites Decorated by MoO4 Tetrahedra or MoO6 Octahedra: Nd2MoSe2O10, Gd2MoSe3O12, La2MoTe3O12, and Nd2MoTe3O12

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  11. Unusual High‐Temperature Structural Behaviour in Ferroelectric Bi2WO6

    Chemistry - A European Journal · 2005-11-28

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  12. A new noncentrosymmetric tellurite: BaMo2Te2O11(H2O) with {Mo(1)Mo(2)O10}n spiral chains

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  13. [Cd2(Te6O13)][Cd2Cl6] and Cd7Cl8(Te7O17): Novel Tellurium(IV) Oxide Slabs and Unusual Cadmium Chloride Architectures

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  14. Na2Te3Mo3O16: A New Molybdenum Tellurite with Second-Harmonic Generating and Pyroelectric Properties

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  15. Structure prediction of ordered and disordered multiple octahedral cation perovskites using SPuDS

    Acta Crystallographica Section B Structural Science · 2006-05-15

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  16. Distortions in Octahedrally Coordinated d0 Transition Metal Oxides: A Continuous Symmetry Measures Approach

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  17. Directed Synthesis of Noncentrosymmetric Molybdates Using Composition Space Analysis

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  18. Structural Polarity Induced by Cooperative Hydrogen Bonding and Lone-Pair Alignment in the Molecular Uranyl Iodate Na2[UO2(IO3)4(H2O)]

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  19. Synthesis, Crystal Structure and Characterization of the Barium Zinc Tellurate Disilicate: Ba3Zn6[TeO6][Si2O7]2

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  20. The α-phase of SrTeO3 at 295 K

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  21. Syntheses and characterization of zero-dimensional molybdoantimonites, A2(Mo4Sb2O18) (A=Y, La, Nd, Sm, Gd and Dy)

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  22. Composition space analysis of templated molybdates

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  23. Synthesis, crystal and band structures, and optical properties of a new lanthanide–alkaline earth tellurium(IV) oxide: La2Ba(Te3O8)(TeO3)2

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  24. Effects of Reaction Gel Dehydration on the Synthesis of Cu(NC5H5)4VOF4 and [Cu(NC5H5)4VOF4][Cu(NC5H5)4(H2O)VOF4]·H2O

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  25. Structure and Bonding in SnWO4, PbWO4, and BiVO4: Lone Pairs vs Inert Pairs

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  26. New Luminescent Solids in the Ln−W(Mo)−Te−O−(Cl) Systems

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  27. Synthesis, Structure, Characterization, and Calculations of Two New Sn2+−W6+−oxides, Sn2WO5 and Sn3WO6

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  28. Biosynthesis and biological activity of enniatins

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  29. Two New Noncentrosymmetric Polar Oxides: Synthesis, Characterization, Second-Harmonic Generating, and Pyroelectric Measurements on TlSeVO5 and TlTeVO5

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  30. (NH4)2Te2WO8: A New Polar Oxide with Second-Harmonic Generating, Ferroelectric, and Pyroelectric Properties

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  31. Syntheses, crystal structures and optical properties of the first strontium selenium(IV) and tellurium(IV) oxychlorides: Sr3(SeO3)(Se2O5)Cl2 and Sr4(Te3O8)Cl4

    Journal of Solid State Chemistry · 2007-12-18

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  32. The first examples of lanthanide selenite-carboxylate compounds: syntheses, crystal structures and properties

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  33. The Versatile Chemistry and Noncentrosymmetric Crystal Structures of Salt‐Inclusion Vanadate Hybrids

    Angewandte Chemie International Edition · 2008-04-09

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  34. The Versatile Chemistry and Noncentrosymmetric Crystal Structures of Salt‐Inclusion Vanadate Hybrids

    Angewandte Chemie · 2008-04-09

    Wendy Lee Queen, J. Palmer West, Shiou‐Jyh Hwu, Donald G. VanDerveer, Matthew C. Zarzyczny, Ryan A. Pavlick

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  35. A Polar Oxide ZnSnO3 with a LiNbO3-Type Structure

    Journal of the American Chemical Society · 2008-05-01

    Yoshiyuki Inaguma, Masashi Yoshida, Tetsuhiro Katsumata

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  36. A rare multi-coordinate tellurite, NH4ATe4O9·2H2O (ARb or Cs): The occurrence of TeO3, TeO4, and TeO5 Polyhedra in the same material

    Journal of Solid State Chemistry · 2008-05-08

    JunHo Kim, P. Shiv Halasyamani

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  37. ZnVSe2O7 and Cd6V2Se5O21: New d10 Transition-Metal Selenites with V(IV) or V(V) Cations

    Inorganic Chemistry · 2008-06-24

    Hai-Long Jiang, Fang Kong, Yang Fan, Jiang‐Gao Mao

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  38. 1/∞[ZrPSe6−]: A Soluble Photoluminescent Inorganic Polymer and Strong Second Harmonic Generation Response of Its Alkali Salts

    Journal of the American Chemical Society · 2008-08-21

    Santanu Banerjee, Christos D. Malliakas, Joon Ik Jang, John B. Ketterson, Mercouri G. Kanatzidis

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  39. Soluble Direct‐Band‐Gap Semiconductors LiAsS2 and NaAsS2: Large Electronic Structure Effects from Weak As⋅⋅⋅S Interactions and Strong Nonlinear Optical Response

    Angewandte Chemie · 2008-08-28

    Tarun Kumar Bera, Jung‐Hwan Song, Arthur J Freeman, Joon Ik Jang, John B. Ketterson, Mercouri G. Kanatzidis

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  40. Soluble Direct‐Band‐Gap Semiconductors LiAsS2 and NaAsS2: Large Electronic Structure Effects from Weak As⋅⋅⋅S Interactions and Strong Nonlinear Optical Response

    Angewandte Chemie International Edition · 2008-08-29

    Tarun Kumar Bera, Jung‐Hwan Song, Arthur J Freeman, Joon Ik Jang, John B. Ketterson, Mercouri G. Kanatzidis

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  41. Structures and Properties of Functional Metal Selenites and Tellurites

    Inorganic Chemistry · 2008-09-29

    Jiang‐Gao Mao, Hai‐Long Jiang, Fang Kong

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  42. Synthetic Approaches for Noncentrosymmetric Molybdates

    Inorganic Chemistry · 2008-09-29

    Desmond J. Hubbard, Alexander R. Johnston, Hernan Sanchez Casalongue, Amy Narducci Sarjeant, Alexander J. Norquist

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  43. Strong Second Harmonic Generation from the Tantalum Thioarsenates A3Ta2AsS11 (A = K and Rb)

    Journal of the American Chemical Society · 2008-12-17

    Tarun Kumar Bera, Joon Ik Jang, John B. Ketterson, Mercouri G. Kanatzidis

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  44. Explorations of new phases in the GaIII/InIII–MoVI–SeIV/TeIV–O systems

    Dalton Transactions · 2009-01-01

    Fang Kong, Chun‐Li Hu, Ting Hu, Yong Lian Zhou, Jiang‐Gao Mao

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  45. Explorations of new second-order NLO materials in the AgI-MoVI/WVI-TeIV-O systems

    Dalton Transactions · 2009-01-01

    Yong Lian Zhou, Chun‐Li Hu, Ting Hu, Fang Kong, Jiang‐Gao Mao

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  46. Alignment of Lone Pairs in a New Polar Material: Synthesis, Characterization, and Functional Properties of Li2Ti(IO3)6

    Journal of the American Chemical Society · 2009-02-04

    Hong‐Young Chang, Sang‐Hwan Kim, P. Shiv Halasyamani, Kang Min Ok

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  47. Charge density matching in templated molybdates

    Journal of Solid State Chemistry · 2009-03-07

    Hernan Sanchez Casalongue, Sarah J. Choyke, Amy Narducci Sarjeant, Joshua Schrier, Alexander J. Norquist

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  48. Semiorganic Nonlinear Optical Material: Preparation and Properties of (NH4)·Sr[ l -(+)-C4H2O6·B(OH)2]·4H2O

    Inorganic Chemistry · 2009-04-09

    Xiaoyun Fan, Shilie Pan, Xueling Hou, Gang Yu Liu, Jide Wang

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  49. Polar or Nonpolar? A+ Cation Polarity Control in A2Ti(IO3)6(A = Li, Na, K, Rb, Cs, Tl)

    Journal of the American Chemical Society · 2009-04-22

    Hong‐Young Chang, Sang‐Hwan Kim, Kang Min Ok, P. Shiv Halasyamani

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  50. Growth, Structure, and Optical Properties of a Congruent Melting Oxyborate, Bi2ZnOB2O6

    Chemistry of Materials · 2009-05-21

    Feng Li, Xueling Hou, Shilie Pan, Xian Wang

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