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RESEARCH PAPER · Inorganic Chemistry · 2008

Structures and Properties of Functional Metal Selenites and Tellurites

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Structures and Properties of Functional Metal Selenites and TelluritesOriginalBiosynthesis and biological activity of enniatins49Noncentrosymmetry in Mixed Metal Oxide-Fluorides, Can We Control It?0ChemInform Abstract: Structures and Properties of Functional Metal Selenites and Tellurites0Explorations of new phases in the GaIII/InIII–MoVI–SeIV/TeIV–O systems46Explorations of new second-order NLO materials in the AgI-MoVI/WVI-TeIV-O systems62Semiorganic Nonlinear Optical Material: Preparation and Properties of (NH4)·Sr[ l -(+)-C4H2O6·B(OH)2]·4H2O47Explorations of New Phases in the GaIII/InIII-CuII-SeIV-O System15Strontium–copper selenite–chlorides: Synthesis and structural investigation24Synthesis, Structure, and Properties of the Noncentrosymmetric Hydrated Borate Na2B5O8(OH)·2H2O81A new organically templated vanadium tellurite: (H2dien)[(VO2)(TeO3)]2·2H2O (dien is diethylenetriamine)5New organically templated vanadium tellurites: (H2pn)[V2TeO8] (pn is propane-1,3-diamine)3Noncentrosymmetric Polar Oxide Material, Pb3SeO5: Synthesis, Characterization, Electronic Structure Calculations, and Structure−Property Relationships147Syntheses, Crystal Structures, and Properties of Five New Transition Metal Molybdenum(VI) Selenites and Tellurites54Explorations of new quaternary phases in the LnIII–VV(d0)–SeIV–O (Ln = Nd, Eu, Gd, Tb) systems23Hydrothermal syntheses, crystal structures and physicochemical properties of 2-D and 3-D inorganic coordination cobalt(ii)-sulfite polymers9Two new layered oxohalides in the system Cu–Yb–Te–O–Cl9Synthesis and Characterization of New Open-Framework Vanadium Tellurite Featuring an Unprecedented (3,7)-Connected Network: K3[(VVO4)(VIVO)4(TeO3)4]·4H2O3The Role of Stereoactive Lone Pairs in Templated Vanadium Tellurite Charge Density Matching21A Series of New Phases Containing Three Different Asymmetric Building Units55Synthesis, Crystal Structure, and Magnetic Properties of the Copper Selenite Chloride Cu5(SeO3)4Cl241Synthesis, structure, and properties of a novel hydrated borate Rb4[B4O5(OH)4]2·3H2O13A Series of New Ternary and Quaternary Compounds in the LiI−GaIII−TeIV−O System37A congruently melting and deep UV nonlinear optical material: Li3Cs2B5O10104Syntheses, structure and rare earth metal photoluminescence of new and known isostructural A2Mo4Sb2O18 (A=Ce, Pr, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) compounds18Li4Cs3B7O14: Synthesis, Crystal Structure, and Optical Properties84Explorations of New Second-Order Nonlinear Optical Materials in the Potassium Vanadyl Iodate System268K3B6O10Cl: A New Structure Analogous to Perovskite with a Large Second Harmonic Generation Response and Deep UV Absorption Edge670Syntheses, Crystal Structures, and Optical Properties of Indium Arsenic(III) Oxide Halides: In2(As2O5)Cl2 and In4(As2O5)(As3O7)Br314Growth, structure and properties of the non-centrosymmetric hydrated borate CaN2B8O26H3210Syntheses and Characterization of New Mid-Infrared Transparency Compounds: Centric Ba2BiGaS5 and Acentric Ba2BiInS595Synthesis and Structural Characterization of New Phases in the Cubic M3Te2O6X2 (M = Sr, Ba; X = Cl, Br) Structure Family10New bidentate non-centrosymmetric borate–malate: Synthesis, structure and characterization of RbB(dl-C4H4O5)2·H2O20Synthesis, structure, and properties of the non-centrosymmetric borate Rb2CaB8O26H2412Synthesis, Structural Characterization, and Magnetic Properties of the Heteroleptic Dinuclear Nickel Selenite Complex [{Ni(TMEDA)SeO3}2]6A New Lithium Rubidium Borate Li6Rb5B11O22 with Isolated B11O22 Building Blocks72BiO(IO3): A New Polar Iodate that Exhibits an Aurivillius-Type (Bi2O2)2+ Layer and a Large SHG Response503Synthesis, crystal structure and magnetic properties of the open framework compound Co3Te2O2(PO4)2(OH)49New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)50Synthesis, structure characterization and optical properties of a new lead cadmium borate27A new congruent-melting oxyborate, Pb 4 O(BO 3 ) 2 with optimally aligned BO 3 triangles adopting layered-type arrangement112New mixed metal selenites and tellurites containing Pd 2+ ions in a square planar geometry14A novel deep UV nonlinear optical crystal Ba3B6O11F2, with a new fundamental building block, B6O14 group180Crystal growth and optical properties of a noncentrosymmetric molybdenum tellurite, Na2Te3Mo3O1641Li5Rb2B7O14: a new congruently melting compound with two kinds of B–O one-dimensional chains and short UV absorption edge25PbPt(IO3)6(H2O): a new polar material with two types of stereoactive lone-pairs and a very large SHG response80Second-Order Nonlinear Optical Materials Based on Metal Iodates, Selenites, and Tellurites60SPECIFIC AND EQUIVALENT CONDUCTIVITY OF DILUTE SODIUM SELENITE SOLUTIONS IN ORDINARY AND HEAVY WATER0Syntheses, crystal structures and properties of new lead(ii) or bismuth(iii) selenites and tellurite41Syntheses, crystal structures and SHG properties of a series of polar alkali-metal molybdenum(vi) selenites based on strandberg-type [Mo5O15(SeO3)2]4− polyanion28Synthesis and crystal structure of two synthetic oxofluoride framework compounds – Co2TeO3F2 and Co2SeO3F221Crystal structures and second-order NLO properties of borogermanates59UV Nonlinear Optical Crystal Ba2[B6O9(OH)4] Featuring Unique Chiral Layers with a New B18O42 Circle Based on BO3 and BO4 Units97Top‐seeded growth, optical properties and theoretical studies of noncentrosymmetric Te2V2O914Explorations of new selenites of the group IIIA and IVA metals13New Borate‐citrate: Synthesis, Structure, and Properties of Sr[B(C6H5O7)2](H2O)4·3H2O3Crystalline Iron Oxohalide Nanotube Pea Pods5Synthesis and Structure of Bismuth(III)-Containing Noncentrosymmetric Phosphates, Cs3KBi2M4(PO4)6Cl (M = Mn, Fe). Monoclinic (Cc) and Tetragonal (P43) Polymorphs Templated by Chlorine-Centered Cl(Bi2Cs) Acentric Units5Cerium(IV) Tellurite Halides [Ce2Te7O17]X2 (X = Cl– or Br–): The First Cerium-Containing Cationic Frameworks30Na3Cd3B(PO4)4: A New Noncentrosymmetric Borophosphate with Zero-Dimensional Anion Units81Electronic structure and optical properties of the nonlinear optical crystal Pb4O(BO3)2 by first-principles calculations10Unusual Coordination for Plutonium(IV), Cerium(IV), and Zirconium(IV) in the Cationic Layered Materials [M2Te4O11]X2 (M = Pu, Ce, Zr; X = Cl, Br)29The new nickel tellurite chloride compound Ni 15 Te 12 O 34 Cl 10 – synthesis, crystal structure and magnetic properties11Chalcogenidotellurates(IV) (TeS3)2– and (TeSe3)2– by Low‐Temperature Solvothermal Synthesis from Liquid Ammonia and Methylamine14Chemistry of Polar Transition-Metal Oxides1New tartratoborates: synthesis, structure, and characterization of non-centrosymmetric ASr[C4H2O6B(OH)2]·4H2O (A = K+, Rb+)29Pb2TiOF(SeO3)2Cl and Pb2NbO2(SeO3)2Cl: small changes in structure induced a very large SHG enhancement117Synthesis and crystal structure of Fe6Ca2(SeO3)9Cl4 – a porous oxohalide11Comparisons of Plutonium, Thorium, and Cerium Tellurite Sulfates41Zn2(VO4)(IO3): A Novel Polar Zinc(II) Vanadium(V) Iodate with a Large SHG Response94Na1.4InTe3.6O9.4: New Variant of a Hexagonal Tungsten Oxide (HTO)-Like Layered Framework Containing Both a Main-Group Cation, In3+, and a Lone-Pair Cation, Te4+14Solid-state synthesis, structure and properties of a novel open-framework cadmium selenite bromide: [Cd10(SeO3)8Br4]·HBr·H2O6Large Mid-IR Second-Order Nonlinear-Optical Effects Designed by the Supramolecular Assembly of Different Bond Types without IR Absorption33Preparation, Structure, and Second‐order Nonlinear Optical Properties of a Borate‐Carboxylic Acid Compound: NH4B[ d‐ (+)‐C4H4O5]2·H2O3Thermochromism, the Alexandrite Effect, and Dynamic Jahn–Teller Distortions in Ho2Cu(TeO3)2(SO4)221Li 0.8 Mg 2.1 B 2 O 5 F: the first borate fluoride with magnesium–oxygen–fluorine octahedral chains20Crystal growth and calculation of the electronic band structure and density of states of Li3Cs2B5O1013New type of complex alkali and alkaline earth metal borates with isolated (B12O24)12− anionic group35Cobalt selenium oxohalides: catalysts for water oxidation15Th(VO 3 ) 2 (SeO 3 ) and Ln(VO 3 ) 2 (IO 3 ) (Ln = Ce, Pr, Nd, Sm, and Eu): unusual cases of aliovalent substitution45Challenges in the Search for Magnetic Coupling in 3d/4f Materials: Syntheses, Structures, and Magnetic Properties of the Lanthanide Copper Heterobimetallic Compounds, RE2Cu(TeO3)2(SO4)229Crystal Structure and Magnetic Properties of FeSeO3F—Alternating Antiferromagnetic S = 5/2 chains42α-AgI3O8 and β-AgI3O8 with Large SHG Responses: Polymerization of IO3 Groups into the I3O8 Polyiodate Anion113Crystal Structure, Physical Properties, and Electronic and Magnetic Structure of the Spin S = 5/2 Zigzag Chain Compound Bi2Fe(SeO3)2OCl332Synthesis, Crystal Structure and Thermal Decomposition of the New Cadmium Selenite Chloride, Cd4(SeO3)2OCl210Expansion of the Rich Structures and Magnetic Properties of Neptunium Selenites: Soft Ferromagnetism in Np(SeO3)213Synthesis, crystal structure, and optical properties of a new lead barium borate, PbBa 2 (B 3 O 6 ) 217Specific heat capacity and thermodynamic properties of CuTeO3 and HgTeO35Dimensional and Coordination Number Reductions in a Large Family of Lanthanide Tellurite Sulfates21Pb 4 V 6 O 16 (SeO 3 ) 3 (H 2 O), Pb 2 VO 2 (SeO 3 ) 2 Cl, and PbVO 2 (SeO 3 )F: New Lead(II)–Vanadium(V) Mixed-Metal Selenites Featuring Novel Anionic Skeletons67LnV3Te3O15(OH)3·nH2O (Ln = Ce, Pr, Nd, Sm, Eu, Gd; n = 1–2): A New Series of Semiconductors with Mixed-Valent Tellurium (IV,VI) Oxoanions14A Synthetic Route toward Layered Materials: Introducing Stereochemically Active Lone-Pairs into Transition Metal Oxohalides25Effect of Halogen (Cl, Br) on the Symmetry of Flexible Perovskite-Related Framework36A series of novel mercury( i ) selenites and tellurites containing SOJT Mo 6+ cations18Synthesis, Structure, and Optical Properties of BiCu2(TeO3)(SO4)(OH)313(3 + 1)-Dimensional commensurately modulated structure and photoluminescence properties of diborate KSbOB 2 O 513Effect of the cation size on the framework structures of magnesium tungstate, A 4 Mg(WO 4 ) 3 (A = Na, K), R 2 Mg 2 (WO 4 ) 3 (R = Rb, Cs)31Organically templated linear metal sulfites2Structural and magnetic studies on three new mixed metal copper( ii ) selenites and tellurites16Cs(TaO 2 ) 3 (SeO 3 ) 2 and Cs(TiOF) 3 (SeO 3 ) 2 : Structural and Second Harmonic Generation Changes Induced by the Different d 0 -TM Coordination Octahedra67Syntheses, structures, and characterizations of a new second-order nonlinear optical material: Pb2(SeO3)(NO3)232Two New Crystals in LimCsnBm+nO2(m+n) (m + n = 5, 7; m > n) Series: Noncentrosymmetric Li5Cs2B7O14 and Centrosymmetric Li4CsB5O1016Structure–Property Correlations in the Heterobimetallic 4f/3d Materials Ln2M(TeO3)2(SO4) (Ln = Y, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, or Lu; M = Co or Zn)25Pb4(OH)4(BrO3)3(NO3): An Example of SHG Crystal in Metal Bromates Containing π-Conjugated Planar Triangle59Versatile Coordination Mode of LiNaB8O13 and α- and β-LiKB8O13 via the Flexible Assembly of Four-Connected B5O10 and B3O7 Groups19Rb 2 SeOCl 4 ·H 2 O: a polar material among the alkali metal selenite halides with a strong SHG response18Sb-Based antiferromagnetic oxychlorides: MSb 2 O 3 (OH)Cl (M = Mn, Fe, Co) with 2D spin-dimer structures9Diverse Lanthanide Coordination and Selective Ion Exchange in the Microporous Selenites Na4Ln4(SeO3)7O·nH2O (Ln = Gd, Tb, Dy, Ho, Er, Tm, and Yb)5Synthesis and Characterization of Three New Layered Vanadium Tellurites, MVTe2O8 (M = Al, Ga, and Mn): Three-Dimensional (3-D) Antiferromagnetic Behavior of MnVTe2O8 with a Zigzag S = 2 Spin Chain19Dimers of oxocentred [OCu4]6+ tetrahedra in two novel copper selenite chlorides, K[Cu3O](SeO3)2Cl and Na2[Cu7O2] (SeO3)4Cl4, and related minerals and inorganic compounds20Top-Seeded Solution Crystal Growth, Morphology, Optical and Thermal Properties of Ba3(ZnB5O10)PO442Cd3(MoO4)(TeO3)2: A Polar 3D Compound Containing d10–d0 SCALP-Effect Cations85Organic–inorganic hybrid three-dimensional metal sulfite-oxalates with honeycomb-like structures12Organically templated inorganic–organic hybrid metal (Zn and Cd) Sulfite–oxalates with layered and three-dimensional structures7Two tartratoborates with hybrid anionic groups from unusual condensation reactions9New vanadium tellurites: Syntheses, structures, optical properties of noncentrosymmetric VTeO 4 (OH), centrosymmetric Ba 2 V 4 O 8 (Te 3 O 10 )12Syntheses, Structures, and Characterization of Quaternary Tellurites, Li3MTe4O11 (M = Al, Ga, and Fe)13Structural motifs in heteroleptic copper and cadmium selenites7Probing the Influence of Acidity and Temperature to Th(IV) on Hydrolysis, Nucleation, and Structural Topology16Li7(TeO3)3F: A Lithium Fluoride Tellurite with Large Second Harmonic Generation Responses and a Short Ultraviolet Cutoff Edge39Lanthanide Inorganic Solids Based on Main Group Borates and Oxyanions of Lone Pair Cations12A(VO 2 F)(SeO 3 ) (A = Sr, Ba) and Ba(MOF 2 )(TeO 4 ) (M = Mo, W): first examples of alkali-earth selenites/tellurites with a fluorinated d 0 -TM octahedron33A Well‐Established POM‐based Single‐Crystal Proton‐Conducting Model Incorporating Multiple Weak Interactions42Li6M(SeO3)4 (M = Co, Ni, and Cd) and Li2Zn(SeO3)2: Selenites with Late Transition-Metal Cations32Role of Bis(triphenylphosphine)iminium Cation [PNP]+ on the Crystal Packing of [PNP]+[HSeO3]− Solvate Salt2Synthesis and Physical Properties of the Oxofluoride Cu2(SeO3)F213Transition Metal Selenite Halides: A Fascinating Family of Magnetic Compounds38[Ag 2 M(Te 2 O 5 ) 2 ]SO 4 (M = Ce IV or Th IV ): A New Purely Inorganic d/f-Heterometallic Cationic Material12Controlled Growth of Layered Acentric CdTeMoO6 Single Crystals with Linear and Nonlinear Optical Properties50Crystal structures and characterizations of two new selenite chlorides: 1D Ba2Zn(SeO3)2Cl2 and 2D BaZn2(SeO3)2Cl26Immobilization of Alkali Metal Fluorides via Recrystallization in a Cationic Lamellar Material, [Th(MoO4)(H2O)4Cl]Cl·H2O3PbCdF(SeO 3 )(NO 3 ): A Nonlinear Optical Material Produced by Synergistic Effect of Four Functional Units52Interrelationship «Composition - Structure - Property» for Acentric Selenite Crystals0Changes of optical transition models caused by crystal structural changes in CaSe2O50M 2 (SeO 3 )F 2 (M = Zn, Cd): understanding the structure directing effect of [SeO 3 ] 2− groups on constructing ordered oxyfluorides15Rational Design and Synthesis of a Deep-Ultraviolet Nonlinear Optical Fluorinated Orthophosphate: BaZn(PO4)F16Synthesis, Structure, and Magnetic Properties of Two Mercury Selenite Antiferromagnets HgM(SeO 3 ) 2 (H 2 O) 2 (M = Co, Ni)10[Ln6O8] Cluster‐Encapsulating Polyplumbites as New Polyoxometalate Members and Record Inorganic Anion‐Exchange Materials for ReO4− Sequestration21NaYTe2O7: A new compound with mixed valence of tellurium and large birefringence6Lone-pair self-containment in pyritohedron-shaped closed cavities: optimized hydrothermal synthesis, structure, magnetism and lattice thermal conductivity of Co 15 F 2 (TeO 3 ) 1413Dicobalt (II) hydroxo-selenite: Hydrothermal synthesis, crystal structure and magnetic properties of Co2SeO3(OH)26MII2M3IIIF3(Te6F2O16) (MII = Pb, Ba; MIII = Al, Ga): New mixed anionic tellurites with isolated Te6 coplanar rings23Hydrothermal syntheses and crystal structures of molybdenum tellurites8Y 2 (Te 4 O 10 )(SO 4 ): a new sulfate tellurite with a unique Te 4 O 10 polyanion and large birefringence36Hydrogen-Bond-Assisted Alignment of [MCu(SeO 3 ) 4 Cl(H 2 O)] 4– (M = Fe, Ga) Anionic Layers to Form Two Polar Oxychlorides: Pb 2 MCu(SeO 3 ) 4 Cl(H 2 O)10Pb 2 TiFO(SeO 3 ) 2 Br: a new polar compound with the strongest second harmonic generation in the selenite bromide family29Synthesis and Characterization of Ammonium Potassium Tellurium Polyoxomolybdate: (NH4)2K2TeMo6O22·2H2O with One-Dimensional Anionic Polymeric Chain [TeMo6O22]4−5Structure-performance relationship in tri-coordinated nonlinear optical materials toward optimal second harmonic generation and phase matching31KIn0.33IIITe0.67VITe2IVO7: Zirconolite-like Mixed-Valent Metal Oxide with a 3D Framework2Flux synthesis, crystal structure, and characterization of a gamma-vanadate selenite polymorph1Functional crystalline porous materials1

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  1. Biosynthesis and biological activity of enniatins

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    S Firáková, Bohumil Proksa, M. Šturdíková

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  2. Noncentrosymmetry in Mixed Metal Oxide-Fluorides, Can We Control It?

    MRS Proceedings · 2008-01-01

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  3. ChemInform Abstract: Structures and Properties of Functional Metal Selenites and Tellurites

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  4. Explorations of new phases in the GaIII/InIII–MoVI–SeIV/TeIV–O systems

    Dalton Transactions · 2009-01-01

    Fang Kong, Chun‐Li Hu, Ting Hu, Yong Lian Zhou, Jiang‐Gao Mao

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  5. Explorations of new second-order NLO materials in the AgI-MoVI/WVI-TeIV-O systems

    Dalton Transactions · 2009-01-01

    Yong Lian Zhou, Chun‐Li Hu, Ting Hu, Fang Kong, Jiang‐Gao Mao

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  6. Semiorganic Nonlinear Optical Material: Preparation and Properties of (NH4)·Sr[ l -(+)-C4H2O6·B(OH)2]·4H2O

    Inorganic Chemistry · 2009-04-09

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  7. Explorations of New Phases in the GaIII/InIII-CuII-SeIV-O System

    Inorganic Chemistry · 2009-06-18

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  8. Strontium–copper selenite–chlorides: Synthesis and structural investigation

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  9. Synthesis, Structure, and Properties of the Noncentrosymmetric Hydrated Borate Na2B5O8(OH)·2H2O

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  10. A new organically templated vanadium tellurite: (H2dien)[(VO2)(TeO3)]2·2H2O (dien is diethylenetriamine)

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  11. New organically templated vanadium tellurites: (H2pn)[V2TeO8] (pn is propane-1,3-diamine)

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  12. Noncentrosymmetric Polar Oxide Material, Pb3SeO5: Synthesis, Characterization, Electronic Structure Calculations, and Structure−Property Relationships

    Chemistry of Materials · 2009-10-12

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  13. Syntheses, Crystal Structures, and Properties of Five New Transition Metal Molybdenum(VI) Selenites and Tellurites

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  14. Explorations of new quaternary phases in the LnIII–VV(d0)–SeIV–O (Ln = Nd, Eu, Gd, Tb) systems

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  15. Hydrothermal syntheses, crystal structures and physicochemical properties of 2-D and 3-D inorganic coordination cobalt(ii)-sulfite polymers

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  16. Two new layered oxohalides in the system Cu–Yb–Te–O–Cl

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  17. Synthesis and Characterization of New Open-Framework Vanadium Tellurite Featuring an Unprecedented (3,7)-Connected Network: K3[(VVO4)(VIVO)4(TeO3)4]·4H2O

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  18. The Role of Stereoactive Lone Pairs in Templated Vanadium Tellurite Charge Density Matching

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  19. A Series of New Phases Containing Three Different Asymmetric Building Units

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  20. Synthesis, Crystal Structure, and Magnetic Properties of the Copper Selenite Chloride Cu5(SeO3)4Cl2

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  21. Synthesis, structure, and properties of a novel hydrated borate Rb4[B4O5(OH)4]2·3H2O

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  22. A Series of New Ternary and Quaternary Compounds in the LiI−GaIII−TeIV−O System

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  23. A congruently melting and deep UV nonlinear optical material: Li3Cs2B5O10

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  24. Syntheses, structure and rare earth metal photoluminescence of new and known isostructural A2Mo4Sb2O18 (A=Ce, Pr, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) compounds

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  25. Li4Cs3B7O14: Synthesis, Crystal Structure, and Optical Properties

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  26. Explorations of New Second-Order Nonlinear Optical Materials in the Potassium Vanadyl Iodate System

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  27. K3B6O10Cl: A New Structure Analogous to Perovskite with a Large Second Harmonic Generation Response and Deep UV Absorption Edge

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  28. Syntheses, Crystal Structures, and Optical Properties of Indium Arsenic(III) Oxide Halides: In2(As2O5)Cl2 and In4(As2O5)(As3O7)Br3

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  29. Growth, structure and properties of the non-centrosymmetric hydrated borate CaN2B8O26H32

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  30. Syntheses and Characterization of New Mid-Infrared Transparency Compounds: Centric Ba2BiGaS5 and Acentric Ba2BiInS5

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  31. Synthesis and Structural Characterization of New Phases in the Cubic M3Te2O6X2 (M = Sr, Ba; X = Cl, Br) Structure Family

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  32. New bidentate non-centrosymmetric borate–malate: Synthesis, structure and characterization of RbB(dl-C4H4O5)2·H2O

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  40. A new congruent-melting oxyborate, Pb 4 O(BO 3 ) 2 with optimally aligned BO 3 triangles adopting layered-type arrangement

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  41. New mixed metal selenites and tellurites containing Pd 2+ ions in a square planar geometry

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  44. Li5Rb2B7O14: a new congruently melting compound with two kinds of B–O one-dimensional chains and short UV absorption edge

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