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RESEARCH PAPER · Inorganic Chemistry · 2005

New d0 Transition Metal Iodates: Synthesis, Structure, and Characterization of BaTi(IO3)6, LaTiO(IO3)5, Ba2VO2(IO3)4·(IO3), K2MoO2(IO3)4, and BaMoO2(IO3)4·H2O

Kang Min Ok, P. Shiv Halasyamani

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New d0 Transition Metal Iodates: Synthesis, Structure, and Characterization of BaTi(IO3)6, LaTiO(IO3)5, Ba2VO2(IO3)4·(IO3), K2MoO2(IO3)4, and BaMoO2(IO3)4·H2OOriginalNew d0 Transition Metal Iodates: Synthesis, Structure, and Characterization of BaTi(IO3)6, LaTiO(IO3)5, Ba2VO2(IO3)4× (IO3), K2MoO2(IO3)4, and BaMoO2(IO3)4×H2O.0Synthesis and characterisation of Fe(IO3)3 nanosized powder25Halogens and noble gases2Structural Polarity Induced by Cooperative Hydrogen Bonding and Lone-Pair Alignment in the Molecular Uranyl Iodate Na2[UO2(IO3)4(H2O)]18Vibrational spectra of some co-ordinated ligands0Vibrational spectra of transition element compounds0Hydrothermal Synthesis, Structural Characterisations, and Photoluminescence Properties of Four Inorganic‐Organic Hybrid Compounds in the Indium/Gallium Iodate Family11BaNbO(IO3)5: A New Polar Material with a Very Large SHG Response331Four novel Zn(II)/Cd(II) metal–organic frameworks constructed from 4′-(4-pyridyl)-4,2′:6′,4″-terpyridine: hydrothermal synthesis, crystal structures, and luminescent properties71Noncentrosymmetric Polar Oxide Material, Pb3SeO5: Synthesis, Characterization, Electronic Structure Calculations, and Structure−Property Relationships147Syntheses and crystal structures of four new silver(i) iodates with d 0 -transition metal cations45Syntheses, crystal structures, and properties of three new lanthanum( iii ) vanadium iodates56NaVO2(IO3)2(H2O): A Unique Layered Material Produces A Very Strong SHG Response143Explorations of New Second-Order Nonlinear Optical Materials in the KI-MII -IV-O Systems43Polar or Non-Polar? Syntheses, Crystal Structures, and Optical Properties of Three New Palladium(II) Iodates45Explorations of New Second-Order Nonlinear Optical Materials in the Potassium Vanadyl Iodate System268Structures and properties of functional metal iodates72Second-Order Nonlinear Optical Materials Based on Metal Iodates, Selenites, and Tellurites60Synthesis, crystal structure and properties of a new lead fluoride borate, Pb3OBO3F17Titanyl Iodate – A Promising Material for Infrared Nonlinear Optics Showing Structural Similarities with KTP32K4TM4(V2O7)2(IO3)4(H2O) (TM = Zn, Ni, Co): a series of quinary mixed metal–vanadium(v)–iodates18Hydrothermal preparation, structure and characterizations of noncentrosymmetric LiZnO(IO3)6VSb(SeO3)4, First Selenite Containing V3+ Cation: Synthesis, Structure, Characterization, Magnetic Properties, and Calculations15Dimensionality variations in new zirconium iodates: hydrothermal syntheses, structural determination, and characterization of BaZr(IO 3 ) 6 and K 2 Zr(IO 3 ) 619Explorations of New Second-Order Nonlinear Optical Materials in the Ternary Rubidium Iodate System: Noncentrosymmetric β-RbIO3(HIO3)2 and Centrosymmetric Rb3(IO3)3(I2O5)(HIO3)4(H2O)59α-AgI3O8 and β-AgI3O8 with Large SHG Responses: Polymerization of IO3 Groups into the I3O8 Polyiodate Anion113A series of novel mercury( i ) selenites and tellurites containing SOJT Mo 6+ cations18Recent advances on second-order NLO materials based on metal iodates328Explorations of New SHG Materials in the Alkali-Metal–Nb5+–Selenite System33Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect238Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect71Syntheses, Crystal Structures, and Properties of Two Quaternary Selenite/Tellurite‐Nitrates with Formula of Bi(SeO 3 )(NO 3 ) and Bi 3 (μ 3 ‐OH)(TeO 3 ) 3 (NO 3 ) 216The enhancement of birefringence resulted from anionic dimensionality changes through adjusting cationic density14Acentric La3(IO3)8(OH) and La(IO3)2(NO3): Partial Substitution of Iodate Anions in La(IO3)3 by Hydroxide or Nitrate Anion55Lanthanide Inorganic Solids Based on Main Group Borates and Oxyanions of Lone Pair Cations12Influence of A-site cations on germanium iodates as mid-IR nonlinear optical materials: A 2 Ge(IO 3 ) 6 (A = Li, K, Rb and Cs) and BaGe(IO 3 ) 6 ·H 2 O43A Series of Mixed-Metal Germanium Iodates as Second-Order Nonlinear Optical Materials71Mo6+ Cation Enrichment of the Structure Chemistry of Iodates: Syntheses, Structures, and Calculations of Ba(MoO2)2(IO3)4O, Ba3[(MoO2)2(IO3)4O(OH)4]·2H2O, and Sr[(MoO2)6(IO4)2O4]·H2O24Synthesis and Crystal Structure of New Indium Iodate (K0.6Na0.4Ba)In[IO3]64Excellent Infrared Nonlinear Optical Crystals BaMO(IO3)5 (M = V, Ta) Predicted by First Principle Calculations9A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions137A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions23An energy band engineering design to enlarge the band gap of KTiOPO 4 (KTP)-type sulfates via aliovalent substitution66Synthesis, structure and characterization of M(IO 3 ) 2 (HIO 3 ) (M = Ca, Sr) as new anhydrous alkaline earth metal bis-iodate hydrogeniodate compounds16HBa2.5(IO3)6(I2O5) and HBa(IO3)(I4O11): Explorations of Second-Order Nonlinear Optical Materials in the Alkali-Earth Polyiodate System49New polymorphism for BaTi(IO 3 ) 6 with two polymorphs crystallizing in the same space group11CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework132CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework22Structural Diversity of Molybdate Iodate and Fluoromolybdate: Syntheses, Structures, and Calculations on Na3(MoO4)(IO3) and Na3Cs(MoO2F4)218Synthesis and Crystal Structure of New Iodate Na3Fe[IO3]6 of the A3M[IO3]6 Structural Family (A = Na, K, Rb, Cs, Tl; M = Ti, Fe, Ge, In, Pt)5Bond-length distributions for ions bonded to oxygen: results for the transition metals and quantification of the factors underlying bond-length variation in inorganic solids128Synthesis, Structure, and Characterization of d0 Transition-Metal Iodate: BaTi(IO3)6·0.5H2O12SrTi(IO 3 ) 6 ·2H 2 O and SrSn(IO 3 ) 6 : distinct arrangements of lone pair electrons leading to large birefringences11Titanium Iodates with a Second-Harmonic-Generation Response8Synthesis and Characterization of Ammonium Potassium Tellurium Polyoxomolybdate: (NH4)2K2TeMo6O22·2H2O with One-Dimensional Anionic Polymeric Chain [TeMo6O22]4−5An Effective Strategy for Designing Nonlinear Optical Crystals by Combining the Structure‐Directing Property of Oxyfluorides with Chemical Substitution73An Effective Strategy for Designing Nonlinear Optical Crystals by Combining the Structure‐Directing Property of Oxyfluorides with Chemical Substitution10New layered nonlinear optical iodate Cs 3 Ta(IO 3 ) 8 : topology-symmetry analysis and structure prediction6Synthesis and Structure of a New Iodate Cs5[Sc2(IO3)9](IO3)2 with a Complex Framework Based on the Condensation of [Sc(IO3)6] Building Blocks4Novel cesium cerium( iv ) iodate Cs 2 Ce(IO 3 ) 6 : hydrothermal synthesis, crystal structures and thermal stability2Diversity of [M(IO3)6] Building Blocks in Iodate Families and the New Trigonal Polymorph of Cs2HIn(IO3)64Diversity of fundamental building blocks [M(IO3)6] in iodate families and new trigonal polymorph of Cs2HIn(IO3)60From Ba2Bi2Zn(PO4)4 to Ba2Bi2Cu(PO4)4: Rational design of an ultraviolet phosphate with enhanced birefringence2K2HGa(IO3)6: A new member of iodate families with [M(IO3)6] building blocks0

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  1. New d0 Transition Metal Iodates: Synthesis, Structure, and Characterization of BaTi(IO3)6, LaTiO(IO3)5, Ba2VO2(IO3)4× (IO3), K2MoO2(IO3)4, and BaMoO2(IO3)4×H2O.

    ChemInform · 2005-05-17

    Kang Min Ok, P. Shiv Halasyamani

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  2. Synthesis and characterisation of Fe(IO3)3 nanosized powder

    Journal of Alloys and Compounds · 2005-10-03

    Christine Galez, Yannick Mugnier, J. Bouillot, Yannick Lambert, Ronan Le Dantec

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  3. Halogens and noble gases

    Annual Reports Section A (Inorganic Chemistry) · 2006-01-01

    Alan K. Brisdon

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  4. Structural Polarity Induced by Cooperative Hydrogen Bonding and Lone-Pair Alignment in the Molecular Uranyl Iodate Na2[UO2(IO3)4(H2O)]

    Inorganic Chemistry · 2006-08-19

    Travis H. Bray, James V. Beitz, Amanda C. Bean, Yaqin Yu, Thomas E. Albrecht‐Schmitt

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  5. Vibrational spectra of some co-ordinated ligands

    Royal Society of Chemistry eBooks · 2007-08-17

    G. Davidson

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  6. Vibrational spectra of transition element compounds

    Royal Society of Chemistry eBooks · 2007-08-17

    G. Davidson

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  7. Hydrothermal Synthesis, Structural Characterisations, and Photoluminescence Properties of Four Inorganic‐Organic Hybrid Compounds in the Indium/Gallium Iodate Family

    European Journal of Inorganic Chemistry · 2008-04-21

    Xiaomin Liu, Guanghua Li, Bin Hu, Yang Yu, Yawei Hu, Minghui Bi, Zhan Shi, Shouhua Feng

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  8. BaNbO(IO3)5: A New Polar Material with a Very Large SHG Response

    Journal of the American Chemical Society · 2009-06-22

    Chuan‐Fu Sun, Chun‐Li Hu, Xiang Xu, Ji‐Bei Ling, Ting Hu, Fang Kong, Xifa Long, Jiang‐Gao Mao

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  9. Four novel Zn(II)/Cd(II) metal–organic frameworks constructed from 4′-(4-pyridyl)-4,2′:6′,4″-terpyridine: hydrothermal synthesis, crystal structures, and luminescent properties

    CrystEngComm · 2009-09-22

    Bao-Cheng Wang, Qing‐Ran Wu, Huai‐Ming Hu, Xiaoli Chen, Zhenhua Yang, Yi-Qing Shangguan, Meng‐Lin Yang, Ganglin Xue

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  10. Noncentrosymmetric Polar Oxide Material, Pb3SeO5: Synthesis, Characterization, Electronic Structure Calculations, and Structure−Property Relationships

    Chemistry of Materials · 2009-10-12

    Sang‐Hwan Kim, Jeongho Yeon, P. Shiv Halasyamani

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  11. Syntheses and crystal structures of four new silver(i) iodates with d 0 -transition metal cations

    Dalton Transactions · 2009-12-03

    Chuan‐Fu Sun, Chun‐Li Hu, Fang Kong, Bing‐Ping Yang, Jiang‐Gao Mao

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  12. Syntheses, crystal structures, and properties of three new lanthanum( iii ) vanadium iodates

    Dalton Transactions · 2010-01-01

    Chuan‐Fu Sun, Ting Hu, Xiang Xu, Jiang‐Gao Mao

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  13. NaVO2(IO3)2(H2O): A Unique Layered Material Produces A Very Strong SHG Response

    Chemistry of Materials · 2010-01-12

    Bing‐Ping Yang, Chun‐Li Hu, Xiang Xu, Chuan‐Fu Sun, Jian‐Han Zhang, Jiang‐Gao Mao

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  14. Explorations of New Second-Order Nonlinear Optical Materials in the KI-MII -IV-O Systems

    Inorganic Chemistry · 2010-04-16

    Pei-Xin Li, Chun‐Li Hu, Xiang Xu, Rui‐Yao Wang, Chuan‐Fu Sun, Jiang‐Gao Mao

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  15. Polar or Non-Polar? Syntheses, Crystal Structures, and Optical Properties of Three New Palladium(II) Iodates

    Inorganic Chemistry · 2010-09-20

    Chuan‐Fu Sun, Chun‐Li Hu, Xiang Xu, Jiang‐Gao Mao

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  16. Explorations of New Second-Order Nonlinear Optical Materials in the Potassium Vanadyl Iodate System

    Journal of the American Chemical Society · 2011-03-23

    Chuan‐Fu Sun, Chun‐Li Hu, Xiang Xu, Bing‐Ping Yang, Jiang‐Gao Mao

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  17. Structures and properties of functional metal iodates

    Science China Chemistry · 2011-05-30

    Chuan‐Fu Sun, Bing‐Ping Yang, Jiang‐Gao Mao

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  18. Second-Order Nonlinear Optical Materials Based on Metal Iodates, Selenites, and Tellurites

    Structure and bonding · 2012-01-01

    Fang Kong, Chuan‐Fu Sun, Bing‐Ping Yang, Jiang‐Gao Mao

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  19. Synthesis, crystal structure and properties of a new lead fluoride borate, Pb3OBO3F

    Materials Research Bulletin · 2012-02-01

    Wenwu Zhao, Shilie Pan, Xiaoyu Dong, Junjie Li, Xuelin Tian, Xiaoyun Fan, Zhaohui Chen, Fangfang Zhang

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  20. Titanyl Iodate – A Promising Material for Infrared Nonlinear Optics Showing Structural Similarities with KTP

    European Journal of Inorganic Chemistry · 2012-08-23

    Yan Suffren, Isabelle Gautier‐Luneau

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  21. K4TM4(V2O7)2(IO3)4(H2O) (TM = Zn, Ni, Co): a series of quinary mixed metal–vanadium(v)–iodates

    CrystEngComm · 2013-01-01

    Bing‐Ping Yang, Xiang Xu, Chao Huang, Jiang‐Gao Mao

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  22. Hydrothermal preparation, structure and characterizations of noncentrosymmetric LiZnO(IO3)

    Solid State Sciences · 2013-09-10

    Jianhua Gao, Shuai Li, Jian Li, Liurukara Duminda Sanjeewa

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  23. VSb(SeO3)4, First Selenite Containing V3+ Cation: Synthesis, Structure, Characterization, Magnetic Properties, and Calculations

    Inorganic Chemistry · 2013-11-21

    Yiseul Shin, Dong Woo Lee, Kwang‐Yong Choi, Hyun‐Joo Koo, Kang Min Ok

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  24. Dimensionality variations in new zirconium iodates: hydrothermal syntheses, structural determination, and characterization of BaZr(IO 3 ) 6 and K 2 Zr(IO 3 ) 6

    Dalton Transactions · 2014-01-01

    Hyun Sun Ahn, Dong Woo Lee, Kang Min Ok

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  25. Explorations of New Second-Order Nonlinear Optical Materials in the Ternary Rubidium Iodate System: Noncentrosymmetric β-RbIO3(HIO3)2 and Centrosymmetric Rb3(IO3)3(I2O5)(HIO3)4(H2O)

    Inorganic Chemistry · 2014-01-15

    Xiang Xu, Bing‐Ping Yang, Chao Huang, Jiang‐Gao Mao

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  26. α-AgI3O8 and β-AgI3O8 with Large SHG Responses: Polymerization of IO3 Groups into the I3O8 Polyiodate Anion

    Chemistry of Materials · 2014-04-25

    Xiang Xu, Chun‐Li Hu, Bingxuan Li, Bing‐Ping Yang, Jiang‐Gao Mao

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  27. A series of novel mercury( i ) selenites and tellurites containing SOJT Mo 6+ cations

    Inorganic Chemistry Frontiers · 2014-10-15

    Xue‐Li Cao, Fang Kong, Chun‐Li Hu, Jiang‐Gao Mao

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  28. Recent advances on second-order NLO materials based on metal iodates

    Coordination Chemistry Reviews · 2015-01-25

    Chun‐Li Hu, Jiang‐Gao Mao

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  29. Explorations of New SHG Materials in the Alkali-Metal–Nb5+–Selenite System

    Inorganic Chemistry · 2015-10-29

    Xue‐Li Cao, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  30. Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect

    Angewandte Chemie International Edition · 2017-01-16

    Fei‐Fei Mao, Chun‐Li Hu, Xiang Xu, Dong Yan, Bing‐Ping Yang, Jiang‐Gao Mao

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  31. Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect

    Angewandte Chemie · 2017-01-16

    Fei‐Fei Mao, Chun‐Li Hu, Xiang Xu, Dong Yan, Bing‐Ping Yang, Jiang‐Gao Mao

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  32. Syntheses, Crystal Structures, and Properties of Two Quaternary Selenite/Tellurite‐Nitrates with Formula of Bi(SeO 3 )(NO 3 ) and Bi 3 (μ 3 ‐OH)(TeO 3 ) 3 (NO 3 ) 2

    ChemistrySelect · 2017-02-01

    Jun‐Ling Song, Cheng Qian

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  33. The enhancement of birefringence resulted from anionic dimensionality changes through adjusting cationic density

    Journal of Alloys and Compounds · 2017-05-11

    Lili Liu, Yun Mo Yang, Zhihua Yang, Shilie Pan

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  34. Acentric La3(IO3)8(OH) and La(IO3)2(NO3): Partial Substitution of Iodate Anions in La(IO3)3 by Hydroxide or Nitrate Anion

    Inorganic Chemistry · 2017-11-09

    Fei‐Fei Mao, Chun‐Li Hu, Bingxuan Li, Jiang‐Gao Mao

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  35. Lanthanide Inorganic Solids Based on Main Group Borates and Oxyanions of Lone Pair Cations

    Chinese Journal of Chemistry · 2017-11-17

    Fang Kong, Yun‐Xiang Ma, Jiang‐Gao Mao

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  36. Influence of A-site cations on germanium iodates as mid-IR nonlinear optical materials: A 2 Ge(IO 3 ) 6 (A = Li, K, Rb and Cs) and BaGe(IO 3 ) 6 ·H 2 O

    Journal of Materials Chemistry C · 2018-01-01

    Hongming Liu, Xingxing Jiang, Xiaoxiao Wang, Lei Yang, Zheshuai Lin, Zhanggui Hu, Xiang‐Gao Meng, Xingguo Chen, Jingui Qin

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  37. A Series of Mixed-Metal Germanium Iodates as Second-Order Nonlinear Optical Materials

    Chemistry of Materials · 2018-03-13

    Fei‐Fei Mao, Chun‐Li Hu, Jin Chen, Jiang‐Gao Mao

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  38. Mo6+ Cation Enrichment of the Structure Chemistry of Iodates: Syntheses, Structures, and Calculations of Ba(MoO2)2(IO3)4O, Ba3[(MoO2)2(IO3)4O(OH)4]·2H2O, and Sr[(MoO2)6(IO4)2O4]·H2O

    Inorganic Chemistry · 2018-07-19

    Yahui Li, Hongping Wu, Bingbing Zhang, Zhihua Yang, Guopeng Han, Shilie Pan

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  39. Synthesis and Crystal Structure of New Indium Iodate (K0.6Na0.4Ba)In[IO3]6

    Crystallography Reports · 2018-09-01

    Elena L. Belokoneva, Alina S. Karamysheva, Olga V. Dimitrova, Anatoly S. Volkov

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  40. Excellent Infrared Nonlinear Optical Crystals BaMO(IO3)5 (M = V, Ta) Predicted by First Principle Calculations

    Materials · 2018-09-24

    Yingfeng Li, Mengqi Cui, Hejin Yan, Yang‐Xin Yu, Meicheng Li, Xiang Li, Lihua Chu, Bing Jiang, Mingde Qin

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  41. A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions

    Angewandte Chemie International Edition · 2018-12-27

    Jin Chen, Chun‐Li Hu, Fei‐Fei Mao, Jiang‐He Feng, Jiang‐Gao Mao

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  42. A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions

    Angewandte Chemie · 2018-12-27

    Jin Chen, Chun‐Li Hu, Fei‐Fei Mao, Jiang‐He Feng, Jiang‐Gao Mao

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  43. An energy band engineering design to enlarge the band gap of KTiOPO 4 (KTP)-type sulfates via aliovalent substitution

    Journal of Materials Chemistry C · 2019-01-01

    Fei Yang, Lijuan Huang, Lijuan Huang, Xiaoyu Zhao, Ling Huang, Ling Huang, Daojiang Gao, Jian Bi, Xin Wang, Guohong Zou

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  44. Synthesis, structure and characterization of M(IO 3 ) 2 (HIO 3 ) (M = Ca, Sr) as new anhydrous alkaline earth metal bis-iodate hydrogeniodate compounds

    Dalton Transactions · 2019-01-01

    Yawen An, Yang Zhong, Tongqing Sun, Haijun Wang, Zhenpeng Hu, Hongde Liu, Shiguo Liu, Yongfa Kong, Jingjun Xu

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  45. HBa2.5(IO3)6(I2O5) and HBa(IO3)(I4O11): Explorations of Second-Order Nonlinear Optical Materials in the Alkali-Earth Polyiodate System

    Inorganic Chemistry · 2019-03-06

    Fei‐Fei Mao, Chun‐Li Hu, Jin Chen, Baolin Wu, Jiang‐Gao Mao

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  46. New polymorphism for BaTi(IO 3 ) 6 with two polymorphs crystallizing in the same space group

    Dalton Transactions · 2020-01-01

    Zhen Qian, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  47. CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework

    Angewandte Chemie International Edition · 2020-02-06

    Jin Chen, Chun‐Li Hu, Xiaohan Zhang, Bingxuan Li, Bing‐Ping Yang, Jiang‐Gao Mao

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  48. CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework

    Angewandte Chemie · 2020-02-06

    Jin Chen, Chun‐Li Hu, Xiaohan Zhang, Bingxuan Li, Bing‐Ping Yang, Jiang‐Gao Mao

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  49. Structural Diversity of Molybdate Iodate and Fluoromolybdate: Syntheses, Structures, and Calculations on Na3(MoO4)(IO3) and Na3Cs(MoO2F4)2

    Inorganic Chemistry · 2020-02-13

    Tingting Shi, Fangfang Zhang, Yahui Li, Le Gao, Zhihua Yang, Shilie Pan

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  50. Synthesis and Crystal Structure of New Iodate Na3Fe[IO3]6 of the A3M[IO3]6 Structural Family (A = Na, K, Rb, Cs, Tl; M = Ti, Fe, Ge, In, Pt)

    Crystallography Reports · 2020-05-01

    Olga Reutova, Elena L. Belokoneva, Olga V. Dimitrova, Anatoly S. Volkov

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