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RESEARCH PAPER · Angewandte Chemie International Edition · 2008

The Versatile Chemistry and Noncentrosymmetric Crystal Structures of Salt‐Inclusion Vanadate Hybrids

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The Versatile Chemistry and Noncentrosymmetric Crystal Structures of Salt‐Inclusion Vanadate HybridsOriginalMg7V4O16(OH)2(H2O): A magnesium vanadate with a novel 3D magnesium oxide open framework12ChemInform Abstract: The Versatile Chemistry and Noncentrosymmetric Crystal Structures of Salt‐Inclusion Vanadate Hybrids.0Flux Synthesis, Crystal Structures, and Luminescence Properties of Salt-Inclusion Lanthanide Silicates: [K9F2][Ln3Si12O32] (Ln = Sm, Eu, Gd)49Synthesis and Structure of Ba5(V2O7)2Cl25Structural and spectroscopic study of Mg13.4(OH)6(HVO4)2(H0.2VO4)614A Series of New Infrared NLO Semiconductors, ZnY6Si2S14, AlxDy3(SiyAl1−y)S7, and Al0.33Sm3SiS7134Flux Synthesis of Salt-Inclusion Uranyl Silicates: [K3Cs4F][(UO2)3(Si2O7)2] and [NaRb6F][(UO2)3(Si2O7)2]47Salt-Templated Mesoporous Solids Comprised of Interlinked Polyoxovanadate Clusters27Molten Salt Synthesis and Structural Characterization of Novel Salt-Inclusion Vanadium Bronze Cs5FeV5O13Cl618Noncentrosymmetric Inorganic Oxide Materials: Synthetic Strategies and Characterisation Techniques8A3V5O14 (A = K+, Rb+, or Tl+), New Polar Oxides with a Tetragonal Tungsten Bronze Related Structural Topology: Synthesis, Structure, and Functional Properties76Extended Utility of Molten-Salt Chemistry: Unprecedented Synthesis of a Water-Soluble Salt-Inclusion Solid Comprised of High-Nuclearity Vanadium Oxide Clusters20Symmetry preservation in a new noncentrosymmetric lattice comprised of acentric POM clusters residing in bowls of Cs + -based half SOD β-cage9New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)50Small non-polar complexes exhibiting significant piezoelectric properties: Solvothermal synthesis and crystal structures of MO5V(tren)·H2O (M=Mo and W; tren=tris(2-aminoethyl)amine)7Salt-flux synthesis of complex oxides: Cs0.33MoO3, CsFe(MoO4)2, and the inverse salt-inclusion phase Cs2Mo0.65O0.21Cl5.449Noncentrosymmetric salt inclusion oxides: Role of salt lattices and counter ions in bulk polarity52Synthesis and Structure of Bismuth(III)-Containing Noncentrosymmetric Phosphates, Cs3KBi2M4(PO4)6Cl (M = Mn, Fe). Monoclinic (Cc) and Tetragonal (P43) Polymorphs Templated by Chlorine-Centered Cl(Bi2Cs) Acentric Units5The crystal structure of ilinskite, NaCu5O2(SeO3)2Cl3, and review of mixed-ligand CuOmCln coordination geometries in minerals and inorganic compounds31Chemistry of Polar Transition-Metal Oxides1High-Temperature, High-Pressure Hydrothermal Synthesis and Characterization of a Salt-Inclusion Mixed-Valence Uranium(V,VI) Silicate: [Na9F2][(UVO2)(UVIO2)2(Si2O7)2]32Synthesis and Crystal Structure of Mn3(Sb2O2)(VO4)2–x(SbO3)xCl2 (0.08 < x < 0.13), a Vanadium Oxochloride with a VV – SbIII Split Position1M3(P2O7)22–-Type Open Frameworks Featuring [M2O8] and [M3O12] Multinuclear Transition-Metal Oxide Units. Serendipitous Synthesis of Six Polymorphic Salt-Inclusion Magnetic Solids: Na2M3(P2O7)2·ACl (M = Mn, Fe; A = Rb, Cs) and K2M3(P2O7)2·CsCl (M = Fe, Mn)15Cs7Sm11[TeO3]12Cl16 and Rb7Nd11[TeO3]12Br16, the new tellurite halides of the tetragonal Rb6LiNd11[SeO3]12Cl16 structure type11Synthesis, crystal structures, magnetic properties, and lattice dynamics of Ba2XCu(OH)[V2O7] with X=Cl, Br8[A 3 X][Ga 3 PS 8 ] (A = K, Rb; X = Cl, Br): promising IR non-linear optical materials exhibiting concurrently strong second-harmonic generation and high laser induced damage thresholds189Flux Growth of [NaK6F][(UO2)3(Si2O7)2] and [KK6Cl][(UO2)3(Si2O7)2]: The Effect of Surface Area to Volume Ratios on Reaction Products38Understanding the Formation of Salt-Inclusion Phases: An Enhanced Flux Growth Method for the Targeted Synthesis of Salt-Inclusion Cesium Halide Uranyl Silicates61Manganese Vanadate Chemistry in Hydrothermal BaF2 Brines: Ba3Mn2(V2O7)2F2 and Ba7Mn8O2(VO4)2F2312Polar Materials with Isolated V4+ S = 1/2 Triangles: NaSr2V3O3(Ge4O13)Cl and KSr2V3O3(Ge4O13)Cl21Three Unique Barium Manganese Vanadates from High-Temperature Hydrothermal Brines11Strontium manganese vanadates from hydrothermal brines: Synthesis and structure of Sr2Mn2(V3O10)(VO4), Sr3Mn(V2O7)2, and Sr2Mn(VO4)2(OH)11Synthesis, Structures, and Luminescent Properties of Sodium Rare‐Earth Metal(III) Chloride Oxotellurates(IV), Na2Ln3Cl3[TeO3]4 (Ln = Sm, Eu, Gd, Tb, Dy, and Ho)10Divanadate-based inorganic-organic hybrid compound: {[Cu(En)2]2V2O7} · 4H2O1Two halide-containing cesium manganese vanadates: synthesis, characterization, and magnetic properties12Hierarchical Materials as Tailored Nuclear Waste Forms: A Perspective123Formation of Open Framework Uranium Germanates: The Influence of Mixed Molten Flux and Charge Density Dependence in U-Silicate and U-Germanate Families19Understanding the Stability of Salt-Inclusion Phases for Nuclear Waste-forms through Volume-based Thermodynamics11Synthesis and structural variety of first Mn and Bi selenites and selenite chlorides7Observation of Spin Relaxation in a Vanadate Chloride with Quasi-One-Dimensional Linear Chain3Crystal Structure and Preferential Site Occupancy in Cs6Mn(H2O)2(VO3)8 and Cs5KMn(H2O)2(VO3)82Synthesis, crystal structure and properties of a new noncentrosymmetric tetraoxidomolybdate(VI)3Single crystal neutron and magnetic measurements of Rb 2 Mn 3 (VO 4 ) 2 CO 3 and K 2 Co 3 (VO 4 ) 2 CO 3 with mixed honeycomb and triangular magnetic lattices10Cu9O2(VO4)4Cl2, the First Copper Oxychloride Vanadate: Mineralogically Inspired Synthesis and Magnetic Behavior23Sodium Transition Metal Vanadates from Hydrothermal Brines: Synthesis and Characterization of NaMn4(VO4)3, Na2Mn3(VO4)3, and Na2Co3(VO4)2(OH)210Towards new cesium containing manganese vanadates via a precursor method0Expanding the Averievite Family, (MX)Cu5O2(T5+O4)2 (T5+ = P, V; M = K, Rb, Cs, Cu; X = Cl, Br): Synthesis and Single-Crystal X-ray Diffraction Study22A new salt-inclusion compound CsCl·(VOSe 2 O 5 ) 4 showing nearly isolated spin-1/2 chain structure with a typical square lattice1Synthesis, Crystal Structure and Spectral Characterization of a New Caesium–Sodium-Isopolyvanadate: Photodegradation of Methylene Blue Dye2High-Entropy Synthesis of (Cr0.7Co0.2Rh0.1)VO4 Nanospheres with Improved Visible-Light Photoresponse3Subtle symmetry breaking in averievite-related compounds, (MX)Cu 5 O 2 (VO 4 ) 2 (MX = CsBr , CsI , RbBr , RbI and KI )0Synthesis, structure and effect on cotton seed germination and seedling vigor of bis(2-hydroxybenzoate) bis(pyridine-3-carboxamide) copper(II)2

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  1. Mg7V4O16(OH)2(H2O): A magnesium vanadate with a novel 3D magnesium oxide open framework

    Inorganic Chemistry Communications · 2008-05-24

    Ting Hu, Ji-Bei Lin, Fang Kong, Jiang‐Gao Mao

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  2. ChemInform Abstract: The Versatile Chemistry and Noncentrosymmetric Crystal Structures of Salt‐Inclusion Vanadate Hybrids.

    ChemInform · 2008-07-04

    Wendy Lee Queen, J. Palmer West, Shiou‐Jyh Hwu, Donald G. VanDerveer, Matthew C. Zarzyczny, Ryan A. Pavlick

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  3. Flux Synthesis, Crystal Structures, and Luminescence Properties of Salt-Inclusion Lanthanide Silicates: [K9F2][Ln3Si12O32] (Ln = Sm, Eu, Gd)

    Inorganic Chemistry · 2008-09-03

    Ming-Feng Tang, Pei-Yun Chiang, Yu-Han Su, Yu‐Chi Jung, Guang‐Yi Hou, Bor‐Chen Chang, Kwang‐Hwa Lii

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  4. Synthesis and Structure of Ba5(V2O7)2Cl2

    Journal of Chemical Crystallography · 2008-10-15

    Kulugammana G. S. Ranmohotti, Wendy Lee Queen, J. Palmer West, Don G. VanDerveer, Shiou‐Jyh Hwu

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  5. Structural and spectroscopic study of Mg13.4(OH)6(HVO4)2(H0.2VO4)6

    Crystal Research and Technology · 2008-10-20

    Tamara Đorđević, Ljiljana Karanović, Ekkehart Tillmanns

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  6. A Series of New Infrared NLO Semiconductors, ZnY6Si2S14, AlxDy3(SiyAl1−y)S7, and Al0.33Sm3SiS7

    Inorganic Chemistry · 2009-07-09

    Sheng‐Ping Guo, Guo‐Cong Guo, Ming‐Sheng Wang, Jian‐Ping Zou, Gang Xu, Guojian Wang, Xifa Long, Jin‐Shun Huang

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  7. Flux Synthesis of Salt-Inclusion Uranyl Silicates: [K3Cs4F][(UO2)3(Si2O7)2] and [NaRb6F][(UO2)3(Si2O7)2]

    Inorganic Chemistry · 2009-07-28

    Cheng‐Shiuan Lee, Sue‐Lein Wang, Yen-Hung Chen, Kwang‐Hwa Lii

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  8. Salt-Templated Mesoporous Solids Comprised of Interlinked Polyoxovanadate Clusters

    Inorganic Chemistry · 2010-01-12

    Wendy Lee Queen, Shiou‐Jyh Hwu, Shane Reighard

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  9. Molten Salt Synthesis and Structural Characterization of Novel Salt-Inclusion Vanadium Bronze Cs5FeV5O13Cl6

    Inorganic Chemistry · 2010-04-20

    Parisa Mahjoor, Susan E. Latturner

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  10. Noncentrosymmetric Inorganic Oxide Materials: Synthetic Strategies and Characterisation Techniques

    Unknown journal · 2010-06-11

    P. Shiv Halasyamani

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  11. A3V5O14 (A = K+, Rb+, or Tl+), New Polar Oxides with a Tetragonal Tungsten Bronze Related Structural Topology: Synthesis, Structure, and Functional Properties

    Inorganic Chemistry · 2010-07-07

    Jeongho Yeon, Sang-Hwan Kim, P. Shiv Halasyamani

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  12. Extended Utility of Molten-Salt Chemistry: Unprecedented Synthesis of a Water-Soluble Salt-Inclusion Solid Comprised of High-Nuclearity Vanadium Oxide Clusters

    Inorganic Chemistry · 2011-09-27

    Wendy Lee Queen, J. Palmer West, JoAn S. Hudson, Shiou‐Jyh Hwu

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  13. Symmetry preservation in a new noncentrosymmetric lattice comprised of acentric POM clusters residing in bowls of Cs + -based half SOD β-cage

    Chemical Communications · 2011-11-16

    Wendy Lee Queen, J. Palmer West, Shiou‐Jyh Hwu, T. Thao Tran, P. Shiv Halasyamani, Don G. VanDerveer

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  14. New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)

    Inorganic Chemistry · 2011-12-06

    Jeongho Yeon, Sang-Hwan Kim, Sau Doan Nguyen, Hana Lee, P. Shiv Halasyamani

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  15. Small non-polar complexes exhibiting significant piezoelectric properties: Solvothermal synthesis and crystal structures of MO5V(tren)·H2O (M=Mo and W; tren=tris(2-aminoethyl)amine)

    Journal of Solid State Chemistry · 2012-02-24

    Maren Rasmussen, Christian Näther, Ulrich Bismayer, Wolfgang Bensch

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  16. Salt-flux synthesis of complex oxides: Cs0.33MoO3, CsFe(MoO4)2, and the inverse salt-inclusion phase Cs2Mo0.65O0.21Cl5.44

    The Philosophical Magazine A Journal of Theoretical Experimental and Applied Physics · 2012-04-02

    Parisa Mahjoor, Susan E. Latturner

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  17. Noncentrosymmetric salt inclusion oxides: Role of salt lattices and counter ions in bulk polarity

    Journal of Solid State Chemistry · 2012-06-20

    J. Palmer West, Shiou‐Jyh Hwu

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  18. Synthesis and Structure of Bismuth(III)-Containing Noncentrosymmetric Phosphates, Cs3KBi2M4(PO4)6Cl (M = Mn, Fe). Monoclinic (Cc) and Tetragonal (P43) Polymorphs Templated by Chlorine-Centered Cl(Bi2Cs) Acentric Units

    Inorganic Chemistry · 2012-08-27

    J. Palmer West, Dino Sulejmanovic, Shiou‐Jyh Hwu, Jian Ping He, Don G. VanDerveer, Boyd Johnson

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  19. The crystal structure of ilinskite, NaCu5O2(SeO3)2Cl3, and review of mixed-ligand CuOmCln coordination geometries in minerals and inorganic compounds

    Mineralogy and Petrology · 2012-11-15

    Sergey V. Krivovichev, С. К. Филатов, L. P. Vergasova

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  20. Chemistry of Polar Transition-Metal Oxides

    Elsevier eBooks · 2013-01-01

    P. Shiv Halasyamani

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  21. High-Temperature, High-Pressure Hydrothermal Synthesis and Characterization of a Salt-Inclusion Mixed-Valence Uranium(V,VI) Silicate: [Na9F2][(UVO2)(UVIO2)2(Si2O7)2]

    Inorganic Chemistry · 2013-05-31

    Yu‐Chih Chang, Wen‐Jung Chang, S. Boudin, Kwang‐Hwa Lii

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  22. Synthesis and Crystal Structure of Mn3(Sb2O2)(VO4)2–x(SbO3)xCl2 (0.08 < x < 0.13), a Vanadium Oxochloride with a VV – SbIII Split Position

    Zeitschrift für anorganische und allgemeine Chemie · 2014-10-27

    Iwan Zimmermann, Mats Johnsson

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  23. M3(P2O7)22–-Type Open Frameworks Featuring [M2O8] and [M3O12] Multinuclear Transition-Metal Oxide Units. Serendipitous Synthesis of Six Polymorphic Salt-Inclusion Magnetic Solids: Na2M3(P2O7)2·ACl (M = Mn, Fe; A = Rb, Cs) and K2M3(P2O7)2·CsCl (M = Fe, Mn)

    Inorganic Chemistry · 2014-11-21

    Jianhua Gao, Jian Li, Dino Sulejmanovic, Shiou‐Jyh Hwu

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  24. Cs7Sm11[TeO3]12Cl16 and Rb7Nd11[TeO3]12Br16, the new tellurite halides of the tetragonal Rb6LiNd11[SeO3]12Cl16 structure type

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    Dmitri O. Charkin, Cameron Black, Lewis J. Downie, Dmitry E. Sklovsky, Peter S. Berdonosov, Andrei V. Olenev, Wuzong Zhou, Philip Lightfoot, В. А. Долгих

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  25. Synthesis, crystal structures, magnetic properties, and lattice dynamics of Ba2XCu(OH)[V2O7] with X=Cl, Br

    Journal of Solid State Chemistry · 2015-09-12

    Kewen Sun, Alexander P. Litvinchuk, Joshua H. Tapp, Angela Möller

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  26. [A 3 X][Ga 3 PS 8 ] (A = K, Rb; X = Cl, Br): promising IR non-linear optical materials exhibiting concurrently strong second-harmonic generation and high laser induced damage thresholds

    Chemical Science · 2016-01-01

    Bin‐Wen Liu, Hui‐Yi Zeng, Xiao‐Ming Jiang, Guan‐E Wang, Shu‐Fang Li, Li Xu, Guo‐Cong Guo

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  27. Flux Growth of [NaK6F][(UO2)3(Si2O7)2] and [KK6Cl][(UO2)3(Si2O7)2]: The Effect of Surface Area to Volume Ratios on Reaction Products

    Crystal Growth & Design · 2016-02-02

    Gregory W. Morrison, Hans‐Conrad zur Loye

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  28. Understanding the Formation of Salt-Inclusion Phases: An Enhanced Flux Growth Method for the Targeted Synthesis of Salt-Inclusion Cesium Halide Uranyl Silicates

    Journal of the American Chemical Society · 2016-05-24

    Gregory W. Morrison, Mark D. Smith, Hans‐Conrad zur Loye

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  29. Manganese Vanadate Chemistry in Hydrothermal BaF2 Brines: Ba3Mn2(V2O7)2F2 and Ba7Mn8O2(VO4)2F23

    Inorganic Chemistry · 2016-12-05

    Liurukara Duminda Sanjeewa, Colin D. McMillen, Michael A. McGuire, Joseph W. Kolis

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  30. Polar Materials with Isolated V4+ S = 1/2 Triangles: NaSr2V3O3(Ge4O13)Cl and KSr2V3O3(Ge4O13)Cl

    Chemistry of Materials · 2017-01-03

    Liurukara Duminda Sanjeewa, Michael A. McGuire, Colin D. McMillen, Vasile Ovidiu Garlea, Joseph W. Kolis

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  31. Three Unique Barium Manganese Vanadates from High-Temperature Hydrothermal Brines

    Inorganic Chemistry · 2017-03-20

    Tiffany M. Smith Pellizzeri, Colin D. McMillen, Yimei Wen, George D. Chumanov, Joseph W. Kolis

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  32. Strontium manganese vanadates from hydrothermal brines: Synthesis and structure of Sr2Mn2(V3O10)(VO4), Sr3Mn(V2O7)2, and Sr2Mn(VO4)2(OH)

    Journal of Solid State Chemistry · 2017-07-05

    Tiffany M. Smith Pellizzeri, Colin D. McMillen, Steven Pellizzeri, Yimei Wen, Rachel B. Getman, George D. Chumanov, Joseph W. Kolis

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  33. Synthesis, Structures, and Luminescent Properties of Sodium Rare‐Earth Metal(III) Chloride Oxotellurates(IV), Na2Ln3Cl3[TeO3]4 (Ln = Sm, Eu, Gd, Tb, Dy, and Ho)

    Zeitschrift für anorganische und allgemeine Chemie · 2017-10-02

    Dmitri O. Charkin, Sabine Zitzer, Stefan Greiner, Sergey Gennadievich Dorofeev, Andrei V. Olenev, Peter S. Berdonosov, Thomas Schleid, В. А. Долгих

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  34. Divanadate-based inorganic-organic hybrid compound: {[Cu(En)2]2V2O7} · 4H2O

    Russian Journal of Coordination Chemistry · 2017-11-01

    K. Wang, Jing Li, Zhijie Liang, P. T. Ma, Diaodiao Zhang, Jingyang Niu, J. P. Wang

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  35. Two halide-containing cesium manganese vanadates: synthesis, characterization, and magnetic properties

    Dalton Transactions · 2018-01-01

    Tiffany M. Smith Pellizzeri, Michael A. McGuire, Colin D. McMillen, Yimei Wen, George D. Chumanov, Joseph W. Kolis

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  36. Hierarchical Materials as Tailored Nuclear Waste Forms: A Perspective

    Chemistry of Materials · 2018-06-22

    Hans‐Conrad zur Loye, Theodore M. Besmann, Jake Amoroso, Kyle S. Brinkman, Agnès Grandjean, Charles H. Henager, Shenyang Hu, Scott T. Misture, Simon Robert Phillpot, Natalia B. Shustova, Hui Wang, Robert J. Koch, Gregory W. Morrison, Ekaterina A. Dolgopolova

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  37. Formation of Open Framework Uranium Germanates: The Influence of Mixed Molten Flux and Charge Density Dependence in U-Silicate and U-Germanate Families

    Inorganic Chemistry · 2018-08-20

    Haijian Li, Eike M. Langer, Philip Kegler, Giuseppe Modolo, Evgeny V. Alekseev

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  38. Understanding the Stability of Salt-Inclusion Phases for Nuclear Waste-forms through Volume-based Thermodynamics

    Scientific Reports · 2018-10-11

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  39. Synthesis and structural variety of first Mn and Bi selenites and selenite chlorides

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  40. Observation of Spin Relaxation in a Vanadate Chloride with Quasi-One-Dimensional Linear Chain

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  41. Crystal Structure and Preferential Site Occupancy in Cs6Mn(H2O)2(VO3)8 and Cs5KMn(H2O)2(VO3)8

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  42. Synthesis, crystal structure and properties of a new noncentrosymmetric tetraoxidomolybdate(VI)

    Journal of Molecular Structure · 2019-12-04

    Bikshandarkoil R. Srinivasan, Sudesh M. Morajkar, Savita S. Khandolkar, Vivekanand V. Gobre, R.A. Apreyan

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  43. Single crystal neutron and magnetic measurements of Rb 2 Mn 3 (VO 4 ) 2 CO 3 and K 2 Co 3 (VO 4 ) 2 CO 3 with mixed honeycomb and triangular magnetic lattices

    Dalton Transactions · 2020-01-01

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  44. Cu9O2(VO4)4Cl2, the First Copper Oxychloride Vanadate: Mineralogically Inspired Synthesis and Magnetic Behavior

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  45. Sodium Transition Metal Vanadates from Hydrothermal Brines: Synthesis and Characterization of NaMn4(VO4)3, Na2Mn3(VO4)3, and Na2Co3(VO4)2(OH)2

    European Journal of Inorganic Chemistry · 2020-08-10

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  46. Towards new cesium containing manganese vanadates via a precursor method

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  47. Expanding the Averievite Family, (MX)Cu5O2(T5+O4)2 (T5+ = P, V; M = K, Rb, Cs, Cu; X = Cl, Br): Synthesis and Single-Crystal X-ray Diffraction Study

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    Ilya V. Kornyakov, Victoria A. Ginga, Oleg I. Siidra, Sergey V. Krivovichev

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  48. A new salt-inclusion compound CsCl·(VOSe 2 O 5 ) 4 showing nearly isolated spin-1/2 chain structure with a typical square lattice

    CrystEngComm · 2024-01-01

    Wenya Xiang, Guozhao Wang, Zhiying Zhao, Meiyan Cui, Zhangzhen He

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  49. Synthesis, Crystal Structure and Spectral Characterization of a New Caesium–Sodium-Isopolyvanadate: Photodegradation of Methylene Blue Dye

    Journal of Chemical Crystallography · 2024-03-04

    Tahmineh Kohanfekr, Mohammad Hakimi, Hasan Ali Hosseini, Michal Dušek, Monika Kučeráková

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  50. High-Entropy Synthesis of (Cr0.7Co0.2Rh0.1)VO4 Nanospheres with Improved Visible-Light Photoresponse

    Crystal Growth & Design · 2025-08-05

    Hyeonho Cho, Yejin Kim, Jong Kyu Kim, Myung Hwa Kim, Hak Ki Yu

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