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RESEARCH PAPER · Angewandte Chemie International Edition · 2019

Site‐Selective Occupancy of Eu 2+ Toward Blue‐Light‐Excited Red Emission in a Rb 3 YSi 2 O 7 :Eu Phosphor

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Site‐Selective Occupancy of Eu 2+ Toward Blue‐Light‐Excited Red Emission in a Rb 3 YSi 2 O 7 :Eu PhosphorOriginalNon-concentration quenching, good thermal stability and high quantum efficiency of K 5 Y(P 2 O 7 ) 2 :Eu 3+ /Tb 3+ phosphors with a novel two-dimensional layer structure79Synthesis and photoluminescence properties of Eu2+/Eu3+ or Ce3+/Eu3+ co-doped Sr5(BO3)3F compounds18Synthesis and investigation of orange-emitting Eu2+ doped Ba4Li2B10O20 phosphor5A solid-state chemist’s eye for the development of materials science in China5Photoluminescence Control of UCr 4 C 4 -Type Phosphors with Superior Luminous Efficiency and High Color Purity via Controlling Site Selection of Eu 2+ Activators112New strategy of designing a novel yellow-emitting phosphor Na4Hf2Si3O12:Eu2+ for multifunctional applications21Mn4+activated Al2O3red-emitting ceramic phosphor with excellent thermal conductivity38The photoluminescence properties and latent photocatalytic hydrogen evolution application of AlN:Eu3+27Concentration quenching and thermal stability of Eu2+ emission in green emitting phosphor Li2BaSiO4: Eu2+31A Double‐Band Emitter with Ultranarrow‐Band Blue and Narrow‐Band Green Luminescence15Divalent europium-doped near-infrared-emitting phosphor for light-emitting diodes665Crystal structure refinement, photoluminescence properties and energy transfer of multicolor tunable Ca2Al2SiO7:Tm3+, Dy3+ for NUV white-light-emitting diodes20Enhanced luminescence of a new red phosphor Na13Sr2Ta2(PO4)9:Eu3+ by co-doping charge compensators Li+/Na+/K+21A new eulytite-type Pb3Bi(PO4)3:Eu3+ red-emitting phosphor: Synthesis, structure and photoluminescence characteristics38Novel Te doping in Y2O3–Al2O3 system phosphor5Luminescence and energy transfer of color-tunable Lu2MgAl4SiO12:Eu2+,Ce3+,Mn2+ phosphors43Orange-red-emitting Sm3+-doped double perovskite CaY0·5Ta0·5O3 phosphor with highly thermal stability for white LED applications32Tuning of Emission by Eu3+ Concentration in a Pyrophosphate: the Effect of Local Symmetry122A rapid in situ synthesis of wide-spectrum CD@BaCl 2 phosphors via anti-solvent recrystallization for white LEDs10Full-visible-spectrum lighting realized by a novel Eu 2+ -doped cyan-emitting borosilicate phosphor26Massive red shift of Ce 3+ in Y 3 Al 5 O 12 incorporating super-high content of Ce48Phase stabilization of red-emitting olivine-type NaMgPO 4 :Eu 2+ phosphors via molten-phase quenching29Photon upconversion afterglow materials toward visualized information coding/decoding23A novel Eu3+-doped phosphate glass for reddish orange emission: Preparation, structure and fluorescence properties79Eu2+-doped ultra-broadband VIS-NIR emitting phosphor129Multi-site occupancies and photoluminescence characteristics in developed Eu2+-activated Ba5SiO4Cl6 bifunctional platform: Towards manufacturable optical thermometer and indoor illumination32Yellow/Orange-Emitting ABZn 2 Ga 2 O 7 :Bi 3+ (A = Ca, Sr; B = Ba, Sr) Phosphors: Optical Temperature Sensing and White Light-Emitting Diode Applications261Broad-band emission in metal halide perovskites: Mechanism, materials, and applications288A novel wide-excitation and narrow-band blue-emitting phosphor with hafnium silicon multiple rings structure for photoluminescence and cathodoluminescence20Weak thermal quenching and tunable luminescence in Ce:Y3(Al,Sc)5O12 transparent ceramics for high power white LEDs/LDs83Synthesis, structure and optical properties of novel thermally robust Dy3+-doped Ca9Sc(PO4)7 phosphors for NUV-excited white LEDs35Preparation, luminescence properties and electronic structure of RE (RE=Eu3+,Sm3+,Dy3+)-doped multi-color silico-phosphate Ca15(PO4)2(SiO4)6 phosphors31Borate Hydrides as a New Material Class: Structure, Computational Studies, and Spectroscopic Investigations on Sr5(BO3)3H and Sr5(11BO3)3D19Role of energy band structure on the luminescence performance of double perovskite La2LiMO6:Eu3+ (M=Sb, Ta, Nb) red emitting phosphors16Engineering mixed polyanion red-emitting Rb2Bi(PO4)(WO4):Eu3+ phosphors with negligible thermal quenching and high quantum yield27Data-Driven Photoluminescence Tuning in Eu2+-Doped Phosphors77Energy transfer and photo/cathodoluminescence performances investigation of a luminescent material Ce3+/Tb3+ co-doped Na2Ca2Si2O7 for multifunctional applications15Two targets with one strategy: Insights into the role of aluminum atoms on the luminescence properties and thermal stability in Mn4+-doped calcium aluminozincate phosphor16Abnormal Bi3+-Activated NIR Emission in Highly Symmetric XAl12O19 (X = Ba, Sr, Ca) by Selective Sites Occupation108Luminescence of Mn4+ activated Li4Ti5O1216Great emission enhancement of high-efficient broadband K3YSi2O7: Eu red phosphor via enhancing crystallinity44Localized Charge Accumulation Driven by Li+ Incorporation for Efficient LED Phosphors with Tunable Photoluminescence77Exploiting the diverse photoluminescence behaviors of NaLuF4:xEu3+ nanoparticles and g-C3N4 to realize versatile applications in white light-emitting diode and optical thermometer163Structural Engineering of Eu2+-Doped Silicates Phosphors for LED Applications241Synthesis and luminescence properties of apatite-type red-emitting Ba2La8(GeO4)6O2:Eu3+ phosphors32Anti‐Thermal‐Quenching Bi 3+ Luminescence in a Cyan‐Emitting Ba 2 ZnGe 2 O 7 :Bi Phosphor Based on Zinc Vacancy162A novel Eu2+-activated calcium zirconium silicate phosphor: Ca3ZrSi2O9:Eu2+24Two-Site Occupancy Induced a Broad-Band Emission in Phosphor K2YZr(PO4)3:Eu2+ for White-Light-Emitting Diode Applications47Structural and optical characteristics of novel rare‐earth‐free red-emitting BaSn(PO4)2:Mn4+ phosphor35Complex crystal structure and photoluminescence of Bi 3+ -doped and Bi 3+ /Eu 3+ co-doped Ca 7 Mg 2 Ga 6 O 1819Design of highly efficient deep-red emission in the Mn 4+ doped new-type structure CaMgAl 10 O 17 for plant growth LED light23Scope and future prospects of pyrophosphate-based phosphors0Structure, luminescence of Eu 2+ and Eu 3+ in CaMgSi 2 O 6 and their co-existence for the excitation-wavelength/temperature driven colour evolution33Very stable and high-quantum-yield phosphor Na 2 BaSr(PO 4 ) 2 :Eu 2+ for plant growth LEDs42Improving the thermal stability and luminescent efficiency of (Ba,Sr)3SiO5:Eu2+ phosphors by structure, bandgap engineering and soft chemistry synthesis method101Single phase white LED phosphor Ca3YAl3B4O15:Ce3+,Tb3+,Sm3+ with superior performance: Color-tunable and energy transfer study184Multi-site occupancies and luminescence properties of cyan-emitting Ca9–NaGd2/3(PO4)7:Eu2+ phosphors for white light-emitting diodes25Thermally stable and highly efficient red-emitting Eu3+-doped Cs3GdGe3O9 phosphors for WLEDs: non-concentration quenching and negative thermal expansion484Learning from Mineral Structures toward New Luminescence Materials for Light-Emitting Diode Applications146The composition engineering of red‐emitting Eu 3+ ‐doped Ca 10.5 (PO 4 ) 7 ‐type solid solution phosphors and application in LED11A High Efficiency Trivalent Chromium-Doped Near-Infrared-Emitting Phosphor and Its NIR Spectroscopy Application168Superior thermally-stable narrow-band green emitter from Mn2+-doped zero thermal expansion (ZTE) material78Spontaneous-reduction and photoluminescence tuning in singly-doped Ba5-Ca (PO4)3Cl:Eu2+/Eu3+ phosphors23Synthesis red-emitting Ca2LaNbO6:xSm3+ phosphors for good color-rendering-index white-LED devices19Glass crystallization making red phosphor for high-power warm white lighting237Research on Molecular Structure and Electronic Properties of Ln3+ (Ce3+, Tb3+, Pr3+)/Li+ and Eu2+ Co-Doped Sr2Si5N8 via DFT Calculation5Efficient red and broadband near‐infrared luminescence in Mn 2+ /Yb 3+ ‐doped phosphate phosphor21Synthesis and photoluminescence of high color purity red-emitting BaLaLiTeO6:Eu3+ phosphors24Preparation and photoluminescent property of blue-emitting phosphors Sr5Al2F16:Eu2+6Rapid Synthesis of Red‐Emitting Sr2Sc0.5Ga1.5O5:Eu2+ Phosphors and the Tunable Photoluminescence Via Sr/Ba Substitution92Design principles for achieving red emission in Eu2+/Eu3+ doped inorganic solids85Photoluminescence tuning in Ba3ScB3O9:Eu2+ phosphor by crystal-site engineering17A novel Eu-dependent G-La2Si2O7 single matrix phosphor for white light-emitting diodes2Structural, magneto-optical and dielectric properties of phosphate tellurite glasses8Warm white light emission, thermochromic property and long persistent luminescence derived from multi-sites of Eu2+/Eu3+ in host lattice71Single-phase far-red-emitting ZnAl2O4:Cr3+ phosphor for application in plant growth LEDs119Advances in Near-Infrared Luminescent Materials without Cr3+: Crystal Structure Design, Luminescence Properties, and Applications173Surface modification of Mg2InSbO6:Eu3+ phosphors and applications for white light-emitting diodes and visualization of latent fingerprint45Giant Red‐Shifted Emission in (Sr,Ba)Y 2 O 4 :Eu 2+ Phosphor Toward Broadband Near‐Infrared Luminescence231Narrow Bandwidth Luminescence in Sr2Li(Al,Ga)O4:Eu2+ by Selective Site Occupancy Engineering for High Definition Displays53Extension of Spectral Shift Controls from Equivalent Substitution to an Energy Migration Model Based on Eu2+/Tb3+-Activated Ba4–xSrxGd3–xLuxNa3(PO4)6F2 Phosphors11A new oxyapatite red phosphor Eu3+-doped Ca3Y7(BO4)(SiO4)5O: Synthesis, structure and luminescence properties36Achievement of high-efficiency sunlight-like emission in Rb2CaP2O7: Ce3+, Eu2+ phosphors16Anti-thermal-quenching red-emitting phosphors based on lanthanide doped negative-thermal-expansion (NTE) hosts46Achieving zero-thermal quenching luminescence in ZnGa2O4: 0.02Eu3+ red phosphor48Enhanced luminescence performances of BaLaMgTaO6:Mn4+ red phosphor by Bi3+, Ca2+ doping for indoor plant lighting supplementary LED23Structure tailoring and defect engineering of LED phosphors with enhanced thermal stability and superior quantum efficiency44Synthesis, crystal structure and luminescence property in Y2ZnGe4O12:Eu3+1Phosphors of Rb3La1−xTbxSi2O7 with K3NdSi2O7-type structure1(INVITED)KRbAl2B2O7: Eu2+: A new blue-emitting luminescent material with good thermal stability0A novel red-emitting phosphor K 2 MgGeO 4 :Eu 3+ for WLEDs: zero-thermal quenching induced by heterovalent substitution27Achieving highly thermostable red emission in singly Mn 2+ -doped BaXP 2 O 7 (X = Mg/Zn) via self-reduction36Self-reduction-induced BaMgP 2 O 7 :Eu 2+/3+ : a multi-stimuli-responsive phosphor for X-ray detection, anti-counterfeiting and optical thermometry36Structural studies on varied concentrations of europium doped strontium phosphate glasses24Tunable concentration/excitation-dependent deep-red and white light emission in single-phase Eu 2+ -activated Sc-based oxide phosphors for blue/UV-LEDs32Sites occupancy of Eu2+/Mn2+ codoped Ca2(Mg0.5Al0.5)(Si1.5Al0.5)O7 blue-green phosphors5An energy transfer strategy for highly luminescent green-emitting Ce3+/Tb3+ codoped Ca2LaHf2Al3O12 garnet phosphors in white light-emitting diodes21Eu2+ Doping Concentration-Induced Site-Selective Occupation and Photoluminescence Tuning in KSrScSi2O7:Eu2+ Phosphor79Controllable synthesis of bifunctional material Ca2Ti2O6:Eu3+ and its comparative study on luminescence and photocatalytic properties with CaTiO3:Eu3+11K replaces Rb towards cyan to red ultra-wideband perovskite-type phosphors for full-spectrum lighting8A high quantum yield red phosphor NaGdSiO4: Eu3+ with intense emissions from the 5D0→7F1,2 transition44A novel sulfide phosphor, BaNaAlS3:Eu2+, discovered via particle swarm optimization24Exploring the structural stability and optical properties of rare-earth doped K3LuSi2O7 phosphor from first-principles calculations4Manganese activated narrowband red-emitting Cs2KInF6:Mn4+ phosphor with high colour purity for backlight display16Directly imaging of the atomic structure of luminescent centers in CaYAlO4:Ce3+6Multichannel Control of PersL/Upconversion/Down-Shifting Luminescence in a Single Core–Shell Nanoparticle for Information Encryption32Light-Induced Charge Transfer to Achieve Deep-Red Emission in SrSc2O4:Bi toward Multiple Optical Applications17Unraveling the Evolution of Luminescence Center in an Eu‐Doped Orthophosphate: Beyond the Probe Limitation to Trace Activator5Blue-light-excited red emission in a CaO:Eu phosphor16Recent Developments of Microscopic Study for Lanthanide and Manganese Doped Luminescent Materials9A novel red-emitting Na5W3O9F5:Eu3+ phosphor with high color purity for blue-based WLEDs61Stabilization of Eu 2+ in Li 2 B 4 O 7 with the BO 3 network through U 6+ co-doping and defect engineering8Sr/Ba substitution induced higher thermal stability far red-emitting Ba 1− y Sr y LaLiWO 6 :Mn 4+ phosphors for plant growth applications13Exploiting Desired Phosphor‐In‐Glass for All‐Inorganic Solid‐State White Illumination47A far-red-emitting ZnAl 1.95 Cr 0.05 O 4 phosphor for plant growth LED applications25A multi-centre activated single-phase white light phosphor with high efficiency for near-UV based WLEDs71Ceramics phosphor powders4Cyan-rich sunlight-like spectra from Mn 2+ -doped CsCd(Cl 1− y Br y ) 3 perovskites with dual tunable emissions and high stability2Equivalent chemical substitution in double–double perovskite-type ALaLiTeO 6 :Mn 4+ (A = Ba 2+ , Sr 2+ , Ca 2+ ) phosphors enabling wide range crystal field strength regulation and efficient far-red emission17Limited energy migration and circumscribed multiphonon relaxation produced non-concentration quenching in a novel dazzling red-emitting phosphor6Non-rare-earth-doped submicron-grade narrow-band red phosphors for W-LED as well as FED and enhanced Bi 3+ -doped blue light absorption32Novel highly efficient Bi 3+ -activated phosphors for warm WLEDs39Regulating anti-thermal quenching to zero thermal quenching for highly efficient blue-emitting Eu 2+ -doped K-beta-alumina phosphors21Apatite oxynitride phosphor (Mg,Y)5Si3(O,N)13:Ce 3+ ,Mn 2+ : A single‐phased host with solar‐like and efficient emission5Eu3+‐activated red phosphor Ca3YAl3B4O15 with low thermal quenching behaviour9Synthesis, structure, luminescence and photocatalytic properties of CaTiO(SiO4):Eu3+4Photoluminescence properties of novel blue-light excited orange-red phosphors Sr3Al2Si3O12:Eu2+23Local Structure and Self‐Defect Evolution under Nonstoichiometric Effect Unlock Zero‐Thermal‐Quenching15Regulating Eu 2+ Multisite Occupation through Structural Disorder toward Broadband Near-Infrared Emission93Novel orange-red phosphor Sr3Al2Si3O12:Eu3+ excited by ultraviolet or blue light with excellent thermal stability and color purity27Facile Synthesis of Highly Efficient and Thermally Stable BaAl 4 Sb 2 O 12 :Eu 2+ Phosphor in Air72Site‐Engineering for Controlling Multiple‐Excitation and Emission in Eu2+‐Activated CaSrSiO4 Phosphors in Marine Fisheries19Novel red-emitting Sr3LaTa3O12:Eu3+ phosphor with high color purity and stability for w-LEDs and visualization of latent fingerprint37A Mechanochemically Synthesized Hybrid Bismuth Halide as Highly Efficient Red Phosphor for Blue Chip‐Based WLED33Synthesis, Photoluminescent Characteristics and Eu3+-Induced Phase Transitions in Sr3Zr2O7:Eu3+ Red Phosphors13Blue light induced red phosphors Sr2CeO4:Eu3+ through co-doping with M2+ (Mg, Ba, Ca) and spectroscopic properties applied in WLEDs6Structure and photoluminescence studies of Rb3GdSi2O7: Eu2+ phosphor used for NUV converted white LEDs10Cyan-to-yellow color tunable NaAlSiO4:Eu2+ with high quantum efficiency and thermal stability for white light-emitting diodes14Orange and yellow emissions through Sm3+ and Tb3+/Sm3+ doped potassium-zinc phosphate glasses for WLED applications21Site Occupation Engineering toward Giant Red-Shifted Photoluminescence in (Ba,Sr)2LaGaO5:Eu2+ Phosphors63Energy transfer of Eu2+→Eu3+ improves the photoluminescence properties of orange-red phosphor La2O2S:Eu27Improved thermal stability and quantum efficiency of novel cyan phosphors toward full-visible-spectrum lighting15Charge compensating effect of cation doping on the enhanced luminescent and stability of La2LiTaO6:Mn4+ red phosphor22Upconversion luminescence and optical thermometry behaviors of Yb3+ and Ho3+ co-doped GYTO crystal16Mg2+–Ca2+/Sr2+–Ca2+ bicationic sites inducing Eu2+ occupying triggering C2S emitting structure unit evolution and luminescence characteristics0Ce3+-Doped Li2Ca5Gd(BO3)5 Phosphors with Multiple Luminescent Centers and High Pressure Sensitivity under Near UV Excitation10Spectroscopic investigation of K5La(MoO4)4:Sm3+ red phosphor with excellent thermal stability and color purity for white LEDs45Highly Efficient Narrow-Band Green-Emitting Na 3 K 5 (Li 3 SiO 4 ) 8 :Eu 2+ Phosphor with Low Thermal Quenching50Millimeter-Sized K2MnF6:Si4+, NH4+ Red-Luminescent Crystals with High Absorption Efficiency (AEmax of 93.5%) and External Quantum Efficiency (EQEmax of 68.9%) Grown by Cooling-Induced Crystallization11Achieving a Eu 2+ -doped NIR phosphor via ionic modulation and its multifunctional applications4

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