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RESEARCH PAPER · The Journal of Physical Chemistry Letters · 2020

Data-Driven Photoluminescence Tuning in Eu2+-Doped Phosphors

Shunqi Lai, Ming Zhao, Jianwei Qiao, Мaxim S. Моlokeev, Zhiguo Xia

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Data-Driven Photoluminescence Tuning in Eu2+-Doped PhosphorsOriginalAbnormal Bi3+-Activated NIR Emission in Highly Symmetric XAl12O19 (X = Ba, Sr, Ca) by Selective Sites Occupation106Enhancing and tuning broadband near-infrared (NIR) photoluminescence properties in Cr 3+ -doped Ca 2 YHf 2 Al 3 O 12 garnet phosphors via Ce 3+ /Yb 3+ -codoping for LED applications101Opportunities for Next-Generation Luminescent Materials through Artificial Intelligence85Advances in engineering near-infrared luminescent materials105Learning from Mineral Structures toward New Luminescence Materials for Light-Emitting Diode Applications146The composition engineering of red‐emitting Eu 3+ ‐doped Ca 10.5 (PO 4 ) 7 ‐type solid solution phosphors and application in LED11Machine Learning-Enabled Design and Prediction of Protein Resistance on Self-Assembled Monolayers and Beyond41The Phase Transition and Photoluminescence Properties of (Ca9−x Sr x )Mg1.5(PO4)7:Eu2+ Solid-Solution Phosphors3Rapid Synthesis of Red‐Emitting Sr2Sc0.5Ga1.5O5:Eu2+ Phosphors and the Tunable Photoluminescence Via Sr/Ba Substitution90Novel double-perovskite SrLaLiTeO6:Mn4+ far-red phosphor with superior thermal stability for indoor plant growth LED58A terbium-sensitized Eu3+-activated deep-red-emitting phosphor for plant growth LED application72Single-phase far-red-emitting ZnAl2O4:Cr3+ phosphor for application in plant growth LEDs118Advances in Near-Infrared Luminescent Materials without Cr3+: Crystal Structure Design, Luminescence Properties, and Applications171Giant Red‐Shifted Emission in (Sr,Ba)Y 2 O 4 :Eu 2+ Phosphor Toward Broadband Near‐Infrared Luminescence230A novel differential display material: K3LuSi2O7: Tb3+/Bi3+ phosphor with thermal response, time resolution and luminescence color for optical anti-counterfeiting56Tailoring Luminescent Properties of SrS:Ce by Modulating Defects: Sr-Deficiency and Na+ Doping1Garnet-type far-red emitting Li6CaLa2Nb2O12: Mn4+, Bi3+ phosphor for full-spectrum white LED22Broadband yellow light emissions of hybrid lead silver bimetallic halides7Investigation of the Solid-Solution Limit, Crystal Structure, and Thermal Quenching Mitigation of Sr-Substituted Rb2CaP2O7:Eu2+ Phosphors for White LED Applications26Tailoring the Luminescent Properties of SrS:Ce3+ by Sr-Deficiency and Na+ Doping15Effect of ionic couple substitution on the enhanced photoluminescence properties of (BaMg)1-x(KxAl10+x)O17:Eu2+ phosphor for white LEDs application7K replaces Rb towards cyan to red ultra-wideband perovskite-type phosphors for full-spectrum lighting8A Mn4+ activated (Gd,La)2(Zn,Mg)TiO6 deep-red emission phosphor: The luminescence properties and potential application for full-spectrum pc-LEDs14Expanded visible-near-infrared temperature sensing properties in view of ultra-broadband tunable luminescence in Mg3Y2Ge3O12:Ce3+, Cr3+ phosphors with advanced applications18Exploring the structural stability and optical properties of rare-earth doped K3LuSi2O7 phosphor from first-principles calculations4Photoluminescence properties of Yb2+-doped Ba0.75Al11O17.25 green phosphor ceramic2Rapid discovery of new Eu 2+ -activated phosphors with a designed luminescence color using a data-driven approach15A far-red-emitting ZnAl 1.95 Cr 0.05 O 4 phosphor for plant growth LED applications24Ceramics phosphor powders4Introduction to properties of aluminates and its scope0Novel broadband NIR phosphors Y 2 Mg 2 Ga 2 Si 2 O 12 : x Cr 3+ for NIR LED applications30Recent progress in phosphor technology1Ion Substitution Strategy toward High-Efficiency Near-Infrared Photoluminescence of Cs2KIn1–yAlyF6:Cr3+ Solid Solutions54A nitriding garnet structure cyan emitting phosphor Ca2(Y, Ce)Hf2(Al, Si)3(O, N)12 with high efficiency and excellent thermal stability10The Luminescence Properties of the Interstitial Eu2+ in SrB2O4 for UV Light‐Emitting Diode6Tunable broadband near-infrared emission in LiScO2:Cr3+ phosphor induced by the variation of chromium ion concentration26Machine learning investigation to predict the relationship between photoluminescence and crystalline properties of blue phosphor Ba0.9-xSrxMgAl10O17:Eu2+6Simultaneous realization of tunable luminescence and enhanced thermal stability in Eu2+-based blue-green phosphors for multifunctional applications16Recent Advances in Light-Conversion Phosphors for Plant Growth and Strategies for the Modulation of Photoluminescence Properties47Structure and photoluminescence studies of Rb3GdSi2O7: Eu2+ phosphor used for NUV converted white LEDs10Cation substitution induced highly symmetric crystal structure in cyan-green-emitting Ca2La1-xLuxHf2Al3O12:Ce3+ solid-solution phosphors with enhanced photoluminescence emission and thermal stability: Toward full-visible-spectrum white LEDs41A novel K3(Y0.88Yb0.10Er0.02)Si2O7 silicate phosphor for multi-mode thermometry of high sensitivity through up-conversion luminescence20Structural and luminescence characterization of red-emitting Li6SrLa2Nb2O12:Eu3+ phosphors with excellent thermal stability17A Novel Cyan Phosphor (K,Rb) 3 GdSi 2 O 7 :Ce 3+ for Full‐Spectrum Lighting through Local Structure Tailoring48Unleashing the Power of Artificial Intelligence in Materials Design179Efficient deep-red luminescence with high colour purity from Mn4+-doped ZnAl2O4 nanophosphor19A guide to comprehensive phosphor discovery for solid-state lighting245Isolated Coordination Polyhedron Confinement in ABP2O7:Mn2+ (A = Ba/Sr; B = Mg/Zn)5Multi-site occupancy high-efficient Mg2LaTaO6:Cr3+ phosphor for application in broadband NIR pc-LEDs62GPT-Assisted Learning of Structure–Property Relationships by Graph Neural Networks: Application to Rare-Earth-Doped Phosphors16Broadband Sensitized Near-Infrared Emission in Eu2+-Nd3+ Co-Doped Baal2o4 as a Spectral Modulator for Silicon Solar Cells0Preparation of a novel violet-excitable Na 3 YSi 2 O 7 :Eu 2+ green phosphor via salt-flux assistance and its luminescence properties15Progress of Ce 3+ /Eu 2+ doped phosphors for violet chip based full-spectra lighting42Tunable emission of Ce 3+ in (K, Rb) 3 GdSi 2 O 7 phosphors toward broadband cyan luminescence5Eu2+ doping and Mg2+-coupled Zn2+, Ca2+ and Sr2+ cations induce tunable orange-blue luminescence in cordierite3Broadband sensitized near‐infrared emission in Eu2+‐Nd3+ co‐doped BaAl2O4 as a potential spectral modulator for silicon solar cells4High‐Performance Tunable Near‐Infrared Emitters of Cr 3+ ‐Activated Garnet Phosphor Enabled by Chemical Unit Co‐Substitution29A yellow-green-emitting phosphor K3LaSi2O7:Eu2+ with superior thermal stability for solid-state lighting9Accelerating Materials Discovery of Novel Europium(II)-Activated Phosphors through Machine Learning Classification of Europium Valences11Recent progress of inorganic phosphors in artificial plant cultivation LEDs46Insights into quantum cutting and downshifting contributions to near-infrared Yb III luminescence in 1D coordination polymers1Photoluminescent materials for solar spectral conversion greenhouse films13A cationic substitution strategy was employed to synthesize phosphor K2NaIn1-xAlxF6: Cr3+, Mn4+ with enhanced optical properties and thermal stability18Recent progress in Cr3+ doped phosphors for indoor plant cultivation LEDs: A review17Broadening and Enhancing the Emission of Phosphor Li2MgTi3O8:Cr3+ by Cation Substitution10Enhanced ultraviolet–visible to near-infrared down-conversion of Pr3+-Yb3+ co-doped Ca2MgSi2O7 by doping with Eu2+ ions3Near-unity quantum efficiency and remarkable anti-thermal quenching of Cr3+-activated Gd3AlGa4O12 garnet emitter for advanced broadband NIR light source5Machine learning-driven discovery of efficient narrow-band green phosphor for wide-color-gamut backlight displays9A Novel Cyan‐Emitting Phosphor K 3 Ca 0.3 Y 0.7 Si 2 O 7 :Ce 3+ Enables Full‐Spectrum Lighting and Fingerprint Detection via Phase‐Structure Alteration9Dual-mode thermometry design of Eu3+-doped phosphors regulate Antithermal quenching performance through charge transfer band edge red-shift1Controlling trap energy re-releasing under near-infrared photo-stimulated luminescence in CaxSr1-xS: Eu2+ , Sm3+ phosphors for optical anti-counterfeiting0Data-Driven Advances in Rare-Earth Substituted Inorganic Phosphors for Solid-State Lighting and Display Applications: A 6G Perspective0Progress and Prospects of Persistent Luminescent Nanocrystals in Biomedical Applications6A review of artificial intelligence approaches for the development of upconversion and downconversion phosphors1Machine learning prediction of luminescence concentration quenching of Tb3+-doped inorganic phosphors0Machine Learning‐Triggered Auto‐Discovery and Promotion of Luminescent Materials: From Predictive Modeling to Autonomous Laboratories0

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  6. The composition engineering of red‐emitting Eu 3+ ‐doped Ca 10.5 (PO 4 ) 7 ‐type solid solution phosphors and application in LED

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