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RESEARCH PAPER · Chemical Engineering Journal · 2020

Eu2+-doped ultra-broadband VIS-NIR emitting phosphor

Zuobin Tang, Qiang Zhang, Yaxin Cao, Yixin Li, Yuhua Wang

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Eu2+-doped ultra-broadband VIS-NIR emitting phosphorOriginalBismuth activated full spectral double perovskite luminescence materials by excitation and valence control for future intelligent LED lighting28Broadband Near‐Infrared Garnet Phosphors with Near‐Unity Internal Quantum Efficiency308Data-Driven Photoluminescence Tuning in Eu2+-Doped Phosphors76Abnormal Bi3+-Activated NIR Emission in Highly Symmetric XAl12O19 (X = Ba, Sr, Ca) by Selective Sites Occupation106Enticing applications of near‐infrared phosphors: Review and future perspectives44The photoluminescence, thermal properties and tunable color of bright green-emitting Ba3Sc(BO3)3:Ce3+/Tb3+ phosphors via efficient energy transfer41A highly efficient and thermally stable broadband Cr 3+ -activated double borate phosphor for near-infrared light-emitting diodes236A near infrared-II broad emission material with multi-spectral excitation and long persistent luminescence properties21Ab initio two-sites occupancy and broadband near-infrared emission of Cr 3+ in Li 2 MgZrO 482Advances in engineering near-infrared luminescent materials105Li/Na substitution and Yb3+ co-doping enabling tunable near-infrared emission in LiIn2SbO6:Cr3+ phosphors for light-emitting diodes143Efficient red and broadband near‐infrared luminescence in Mn 2+ /Yb 3+ ‐doped phosphate phosphor21Rapid Synthesis of Red‐Emitting Sr2Sc0.5Ga1.5O5:Eu2+ Phosphors and the Tunable Photoluminescence Via Sr/Ba Substitution90Photoluminescence tuning in Ba3ScB3O9:Eu2+ phosphor by crystal-site engineering17Advances in Near-Infrared Luminescent Materials without Cr3+: Crystal Structure Design, Luminescence Properties, and Applications171An efficient garnet-structured Na3Al2Li3F12:Cr3+ phosphor with excellent photoluminescence thermal stability for near-infrared LEDs157A highly efficient and suitable spectral profile Cr3+-doped garnet near-infrared emitting phosphor for regulating photomorphogenesis of plants278Tunable photoluminescence and temperature sensing properties of Ce3+, Eu2+ co-doped Ca2-Sr MgSi2O7 phosphors11Multi spectral responsive near infrared-II broad emission material and its LED device and imaging research12Giant Red‐Shifted Emission in (Sr,Ba)Y 2 O 4 :Eu 2+ Phosphor Toward Broadband Near‐Infrared Luminescence230Structural modulation designed a thermally robust blue-cyan emitting phosphor Y2Mg0.8Sr0.2 Al4SiO12:Eu2+ for the high color rendering index white LEDs4An Extra‐Broadband VIS‐NIR Emitting Phosphor toward Multifunctional LED Applications153Sm3+ doped novel Sr2Ga2GeO7 based high thermal stability red-emitting phosphors for efficient WLED51Ultra-broadband NIR luminescence in chromium doped magnesium aluminosilicate glass as future light sources for spectroscopy applications25Temperature-dependent long persistent luminescence properties and trap distributions in Sr2MgAl22O36: Eu2+10Accessing High-Power Near-Infrared Spectroscopy Using Cr3+-Substituted Metal Phosphate Phosphors114A non-rare earth ion doped broadband emission phosphor located in NIR-II for ethanol concentration detection14Deep-red to near-infrared luminescence from Eu 2+ -trapped exciton states in YSiO 2 N9Investigation on the Luminescent Property and Application of In2BP3O12:Cr3+ Broadband Near-Infrared Phosphor※8Synthesis and luminescent properties: Mn4+-doped Sr3NaNbO6 phosphor with far-red emission14Eu2+‐Doped Layered Double Borate Phosphor with Ultrawide Near‐Infrared Spectral Distribution in Response to Ultraviolet–Blue Light Excitation110Novel broadband near-infrared emitting phosphor LiGe2(PO4)3:Cr3+ with tuning and enhancement of NIR emission by codoping Sb5+49Broadband near-infrared emission in Cr3+-doped MgO-Al2O3-SiO2 dual-phase glass-ceramics for near-infrared spectroscopy applications23Lanthanide doped lead-free double perovskites as the promising next generation ultra-broadband light sources37Efficient near-infrared phosphors discovered by parametrizing the Eu(II) 5d-to-4f energy gap92Multi-site occupancies and dependent photoluminescence of Ca9Mg1.5(PO4)7:Eu2+ phosphors: A bifunctional platform for optical thermometer and plant growth lighting36Blue light‐excitable Eu‐doped yellow emitting borate KSr 4 B 3 O 9 phosphor for white light‐emitting diodes14Photoluminescence of Bi3+ in LiCaY5(BO3)6 and color-tunable emission through energy transfer to Eu3+/Tb3+11Environment-Dependent Eu2+-Activated Ba3CaK(PO4)3 toward White-Light Emission by Chemical Cosubstitution of the (BO3)3– Anion Group19Dopant and compositional modulation triggered long-wavelength ultra-broadband and tunable NIR emission in MgO: Cr3+ phosphor for NIR spectroscopy applications53K2SiF6:Mn4+ significantly improves water resistance and luminescence performance by coating green emission graphene quantum dots4Producing Tunable Broadband Near-Infrared Emission through Co-Substitution in (Ga1–xMgx)(Ga1–xGex)O3:Cr3+77Achievement of broadband NIR emission in double perovskite NaLaMgWO6 via non-equivalent substitution of Cr3+17Powder synthesis and luminescence of a novel yellow-emitting Ba5Si11Al7N25: Eu2+ phosphor discovered by a single-particle-diagnosis approach for warm w-LEDs50Review—Photoluminescence Spectroscopy of Eu2+-Activated Phosphors: From Near-UV to Deep Red Luminescence25A novel narrow-band blue-emitting phosphor with high efficiency and thermal stability for WLEDs and FEDs31An efficient and thermally stable Cr 3+ -activated Y 2 GdSc 2 Al 2 GaO 12 garnet phosphor for NIR spectroscopy applications14Near-infrared emission of Cr3+ in five-coordinated field13Broadband and Multimode Near‐Infrared Emitter Based on Cr3+‐Activated Stannate for Multifunctional Applications75Single‐Site Occupancy of Eu 2+ in Multiple Cations Enables Efficient Ultra‐Broadband Visible to Near‐Infrared Luminescence83La3Ga5SiO14:Cr3+: A broadband near-infrared phosphor induced by the two-site occupation of Cr3+43Infrared to Short-Wave Infrared-Emitting Phosphors for Light-Emitting Diode Applications23Deep-red to NIR emission of Mn4+ and Cr3+ doped La2MgTiO6 phosphor with multifunctional applications20Mn-Activated Fluoride Phosphors Modified by Surfactant with Outstanding Water Resistance and Luminescent Thermal Properties18Two-site occupation in Cr3+-activated BaIn2(P2O7)2 phosphor for broadband near-infrared thermometry and LED applications30Luminescence characteristics of Ce3+/Eu2+ activated (Ba, Sr)3YB3O9 phosphors3Divalent ansa-Octaphenyllanthanocenes: Synthesis, Structures, and EuII Luminescence9Near-Infrared LuCa 2 ScZrGa 2 GeO 12 :Cr 3+ Garnet Phosphor with Ultra-broadband Emission for NIR LED Applications60Cr3+-free broadband near-infrared phosphors NaAl5O8:Fe3+42Ultra-broadband near-infrared Cr3+-doped multi-phase glass-ceramics realized by the selective enrichment strategy for near-infrared spectroscopy applications14Selective enrichment strategy induces ultra-broadband NIR emission in Cr3+-doped multi-phase glass-ceramics for NIR spectroscopy applications10Broadband emission characteristics and WLED application of self-activated YMZn3AlO7 (M=Ca, Sr, Ba) phosphors5Preparation, optical properties and energy transfer of SrLaAlO4: Dy3+, Eu3+20A promising yellow-emitting langbeinite-type phosphor NaBaY 2 (PO 4 ) 3 :Eu 2+ for WLEDs10Robust efficiency stability and excellent aging resistance broadband NIR all-inorganic LEDs based on Tellurium-doped germanate glasses for multifunctional applications2Unusual red luminescence and super thermal stability of a new narrow-band emission phosphor for backlight display application21Bright Cyan Emission in Eu-Doped Borosilicate Glasses by Optimizing Reduction of Eu3+ to Eu2+ in Ambient Atmosphere3Enhanced NIR emission and thermal stability of La 2 MgSnO 6 :Mn 4+ ,Ni 2+ via energy transfer15Tailoring Emission Characteristics of Na-Sc Co-Substituted Camgge2o6:Cr3+ Phosphors for Iris Acquisition0An efficient and thermally stable red emitting Eu2+ doped oxide for rechargeable portable flashlight62BaLiZn 3 (PO 4 ) 3 :Eu 2+ : Ultranarrow-Band Violet Emission in a Highly Symmetric Crystal Structure24Realization and optimization of bismuth-activated Ba3Ga2O5Cl2 yellow phosphor for high-quality white LEDs82Bright cyan emission from Eu-Doped borosilicate glasses by optimizing reduction of Eu3+ to Eu2+ in ambient atmosphere44Manipulating cationic ordering toward highly efficient and zero-thermal-quenching cyan photoluminescence34Highly thermally stable SrLaMgTaO6: Cr3+ double-perovskite phosphors for night-vision applications23A far-red-emitting LiGaTiO4:Cr3+ phosphor for potential application in plant growth LEDs18Achieving broadband NIR-I to NIR-II emission in layer-structured Mg4Nb2O9:Cr3+,Yb3+ phosphor for multifunctional applications12Fast response Sc3+-sensitized K2NbF7:Mn4+ phosphors with high luminescence intensity and moisture resistance selected by DFT calculations10Tailoring emission characteristics of Na+-Sc3+ co-substituted CaMgGe2O6:Cr3+ phosphors for iris acquisition7Remarkable broadband NIR emission of BaCa2MgSi2O8:Cr3+ phosphors and Eu2+ co-doping modulation7Strategy to optimize the broadband near-infrared emission based on Eu2+-doped sulfureted garnet phosphors toward emerging spectroscopy applications28Demonstration of Eu3+ → Eu2+ Energy Transfer in NIR Emitting CaO:Eu2+,Eu3+ LED Phosphor and its Implication for the Role of Eu3+ as a Killer Center for Long Wavelength Eu2+ Emission20Optical characteristics, Judd-Ofelt analysis of enhanced luminescence by flux in thermally stable, novel Eu3+- doped BaZr(PO4)2 phosphor for indoor lighting applications13Sunlight‐Activated Eu2+‐Doped Red Persistent Luminescence Material for Night‐Vision Signage, Anti‐Counterfeiting and Location Detection30Synthesis of a novel broadband near-infrared fluoride phosphor with nearly 100% internal quantum efficiency using a cationic substitution strategy13Luminescent properties of Ce3 +, Li+, Eu2+ and Ce3+-Eu2+ energy transfer in Sr2-xBaxSiO4 phosphor6Bi 3+ -sensitized Dy 3+ emission for tunable luminescence and efficiency enhancement in LiY 6 O 5 (BO 3 ) 3 phosphors4Efficient zero-dimensional near-infrared perovskite synthesis using an ultrasound-assisted strategy and its application in information encryption8Insights into quantum cutting and downshifting contributions to near-infrared Yb III luminescence in 1D coordination polymers1Research progress on the design and regulation of Eu 2+ /Ce 3+ -activated anti-/zero thermal quenching phosphors9Tunable broadband visible emission achieved by phase transformation-driven self-reduction of Eu 3+ to Eu 2+ in a calcium phosphate matrix6Near-infrared emission of Eu2+ in M4Li(BN2)3 (M = Ca, Sr, Ba)1Preparation of Ba9Lu2Si6O24:Sm3+ red phosphor and its application in white LEDs16Enhanced broadband near-infrared luminescence via phase engineering of Cr3+-doped crystals6Visible Light Excited Yb3+‐Doped Phosphor Via Eu2+ Bridged Energy Transfer Toward NIR‐II Spectroscopy Application13Non‐Stoichiometric Calcium Addition in Red‐Emitting CaSc 2 O 4 :Eu 2+ Phosphor Toward Enhanced Photoluminescence Quantum Efficiency for LED Applications27Efficient dual broadband VIS-NIR emission in Mo-doped double perovskites enabling detection and imaging applications11Optical properties and applications of Na-β"-Al2O3: Cr3+, Eu2+ phosphors0β-Ca3(PO4)2-type Eu2+-doped Phosphor: Applications in optical thermometry and full-spectrum lighting5Wavelength-Tunable of Broad Red to Near-Infrared Emission in (Sr,Ba)3Sc4O9 :Eu2+ Phosphors: Crystal Field Effects and Thermal Stability6Multi-functional blue phosphor design based on K+ ions structural regulation7Recent progress in Eu2+ activated red phosphors for white LEDs and laser displays: focusing on efficient host screening and innovative structural design20Develop Superior Green‐Emitting K‐Rich Eu 2+ ‐Activated Nepheline Phosphors for n‐UV‐Driven Pc‐WLEDs1Structure and luminescence of Gd3Ga3MgSiO12:Cr3+ garnet phosphor with highly efficient broadband near-infrared emitting toward pc-LED application7Multi-site occupied Cs2Ba3(P2O7)2:Eu2+ phosphor with blue-green dual emission for full-spectrum lighting2A Novel Cyan‐Emitting Phosphor K 3 Ca 0.3 Y 0.7 Si 2 O 7 :Ce 3+ Enables Full‐Spectrum Lighting and Fingerprint Detection via Phase‐Structure Alteration9Tailoring cationic configurations in β‐Ca 3 (PO 4 ) 2 ‐type matrices for gentle orange emission toward eye‐comfort lighting2Revolutionary near-infrared phosphors with emerging structures and mechanisms driving next-generation applications32Topological Understanding of Luminescence in Eu 2+ -Doped Borate Phosphors3Sm3+ doped novel Sr3In2Ge3O12 orange-red emitting phosphor for WLEDs with high color purity and color rendering index9Mo 4+ ‐Doped Cs 4 ZnBi 2 Cl 12 Lead‐Free Double Perovskite for Near‐Infrared Luminescence2Eu2+-doping induced phase transformation and blue–cyan luminescence in KAlSi3O8 phosphors5Tunable energy transfer in Bi3 + and Eu3+ co-doped Sr2Al2SiO7 phosphors: Toward warm WLEDs and hierarchical anti-counterfeiting3Activating Deep‐Red Emission in Borate Phosphors via Low‐Coordination Engineering for Efficient Plant Lighting7Beyond single-ion doping: K + –Bi 3+ synergy enables crop-tailored blue luminescence through crystal field engineering1Broadband yellow-green emitting Bi3+-doped La2MgHfO6 double perovskite phosphor for WLED1Boosting broadband NIR luminescence in Mo4+-doped Cs2TeCl6 perovskite for toluene detection via cerium doping3Engineering Fe3+ Multi-site Occupation and Lattice Regulation in a Double Perovskite Ba2LuSbO6 phosphor for broadband near-infrared luminescence0Re 4+ -mediated multi-exciton energy transfer enables super-broadband multiphoton excited luminescence for diversified photonic applications0Enhanced broadband near-infrared emission based on cation substitution in Cr3+ ion doped YGdScSbO7 phosphor0Recent developments in near-infrared phosphors for broad-band light-emitting diodes light sources9Tunable Broadband Red-To-Near-Infrared Emission in Eu 2+ -Activated Sr 1– x Ba x La 2 Sc 2 O 7 Phosphors via Site-Selective Occupation and Cation Substitution3A flexible rare-earth-activated CaYAl3O7 scintillation screen for high-resolution and irradiation-stable X-ray imaging0Engineering Fe3+ dual-site occupation and lattice regulation in a double perovskite Ba2LuSbO6 phosphor for broadband near-infrared luminescence0Thermally robust garnet yellow-green phosphors with near-unity quantum yield for white light-emitting diodes0Luminescence properties and multifunctional applications of Sr2+-regulated Ca19Mg2(PO4)14: Eu2+ phosphor0

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  1. Bismuth activated full spectral double perovskite luminescence materials by excitation and valence control for future intelligent LED lighting

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  4. Abnormal Bi3+-Activated NIR Emission in Highly Symmetric XAl12O19 (X = Ba, Sr, Ca) by Selective Sites Occupation

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  34. Lanthanide doped lead-free double perovskites as the promising next generation ultra-broadband light sources

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  35. Efficient near-infrared phosphors discovered by parametrizing the Eu(II) 5d-to-4f energy gap

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  36. Multi-site occupancies and dependent photoluminescence of Ca9Mg1.5(PO4)7:Eu2+ phosphors: A bifunctional platform for optical thermometer and plant growth lighting

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  37. Blue light‐excitable Eu‐doped yellow emitting borate KSr 4 B 3 O 9 phosphor for white light‐emitting diodes

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  38. Photoluminescence of Bi3+ in LiCaY5(BO3)6 and color-tunable emission through energy transfer to Eu3+/Tb3+

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  39. Environment-Dependent Eu2+-Activated Ba3CaK(PO4)3 toward White-Light Emission by Chemical Cosubstitution of the (BO3)3– Anion Group

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  40. Dopant and compositional modulation triggered long-wavelength ultra-broadband and tunable NIR emission in MgO: Cr3+ phosphor for NIR spectroscopy applications

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  41. K2SiF6:Mn4+ significantly improves water resistance and luminescence performance by coating green emission graphene quantum dots

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  42. Producing Tunable Broadband Near-Infrared Emission through Co-Substitution in (Ga1–xMgx)(Ga1–xGex)O3:Cr3+

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  43. Achievement of broadband NIR emission in double perovskite NaLaMgWO6 via non-equivalent substitution of Cr3+

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  44. Powder synthesis and luminescence of a novel yellow-emitting Ba5Si11Al7N25: Eu2+ phosphor discovered by a single-particle-diagnosis approach for warm w-LEDs

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  45. Review—Photoluminescence Spectroscopy of Eu2+-Activated Phosphors: From Near-UV to Deep Red Luminescence

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  46. A novel narrow-band blue-emitting phosphor with high efficiency and thermal stability for WLEDs and FEDs

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