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RESEARCH PAPER · Laser & Photonics Review · 2020

Anti‐Thermal‐Quenching Bi 3+ Luminescence in a Cyan‐Emitting Ba 2 ZnGe 2 O 7 :Bi Phosphor Based on Zinc Vacancy

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Anti‐Thermal‐Quenching Bi 3+ Luminescence in a Cyan‐Emitting Ba 2 ZnGe 2 O 7 :Bi Phosphor Based on Zinc VacancyOriginalA study of negative-thermal-quenching (Ba/Ca)AlSi 5 O 2 N 7 :Eu 2+ phosphors6A zero-thermal-quenching perovskite-like phosphor with an ultra-narrow-band blue-emission for wide color gamut backlight display applications67Luminescence property improvement and controllable color regulation of a novel Bi 3+ doped Ca 2 Ta 2 O 7 green phosphor through charge compensation engineering and energy transfer19MGa 2 B 2 O 7 :Bi 3+ ,Al 3+ (M = Sr, Ba) blue phosphors with a quantum yield of 99% and negative thermal quenching14Preparation of zero-thermal-quenching tunable emission bismuth-containing phosphors through the topochemical design of ligand configuration31A single-phase full-color phosphor Sr2Ca2La(PO4)3O:Eu2+,Tb3+,Mn2+: Photoluminescence and energy transfer16Site occupancy and photoluminescence properties of cyan-emitting K2Ca2Si2O7:Bi3+ phosphor for white light emitting diodes44The synthesis and photoluminescence characteristics Bi3+/Dy3+ doped Ca2LaTaO6 phosphors upon the NUV light excitation11Artificial mimics of light-harvesting organic pigment via a double-perovskite structure (LiLa2SbO6:Bi3+, Mg2+, Mn4+) with single-composition and structure-activity relationship5Anti-thermal quenching of Eu3+ luminescence in negative thermal expansion Zr(WO4)238Tailored Luminescence Output of Bi3+-Doped BaGa2O4 Phosphors with the Assistance of the Introduction of Sr2+ Ions as Secondary Cations23Constructing a Model for Tuning the Thermal Quenching Properties of Bismuth-Doped Phosphors by Energy-Gap Modulation34Highly Efficient Green‐Emitting Phosphor BaZnAl 10 O 17 :Mn 2+ with Ultra‐Narrow Band and Extremely Low Thermal Quenching for Wide Color Gamut LCD Backlights59Anti-thermal-quenching red-emitting phosphors based on lanthanide doped negative-thermal-expansion (NTE) hosts46Variation from Zero to Negative Thermal Quenching of Phosphor with Assistance of Defect States45Anti-thermal-quenching, color-tunable and ultra-narrow-band cyan green-emitting phosphor for w-LEDs with enhanced color rendering85Highly sensitive optical thermometer of Sm 3+ , Mn 4+ activated LaGaO 3 phosphor for the regulated thermal behavior34Achieving highly thermostable red emission in singly Mn 2+ -doped BaXP 2 O 7 (X = Mg/Zn) via self-reduction36Enabling narrowband cyan photoluminescence and long-lasting ultraviolet-A persistent luminescence in Bi 3+ single-doped Sr 3 Sc 2 Ge 3 O 12 phosphors by selective site occupation48Oxygen vacancy content drives self-reduction and anti-thermal quenching40Tuning of the thermal quenching performance of Bi 3+ -doped scheelite Ca(Mo/W)O 4 solid solution phosphors13How to Obtain Anti‐Thermal‐Quenching Inorganic Luminescent Materials for Light‐Emitting Diode Applications252Efficient and Thermally Stable Broad-Band Near-Infrared Emission in a KAlP 2 O 7 :Cr 3+ Phosphor for Nondestructive Examination191Luminescence temperature anti-quenching in CdSe/CdS core/shell and CdSe/CdS/ZnS core/double shell nanostructures0Luminescence characteristics of SrZnSO:M (M = Bi3+, Mn2+ and Tb3+) phosphors16Metal To Metal Charge Transfer Induced Efficient Yellow/Far‐Red Luminescence in Na2Ca3(Nb, Ta)2O9:Bi3+ toward the Applications of White‐LEDs and Plant Growth Light48Superb thermal stability purple-blue phosphor through synergistic effect of emission compensation and nonradiative transition restriction of Eu2+31Single Bi3+ Ultrabroadband White Luminescence in Double Perovskite via Crystal Lattice Engineering toward Light‐Emitting Diode Applications86Multiple Strategies to Approach High-Efficiency Luminescence Controllable in Blue/Cyan/Green-Emitting Bi 3+ -Activated Phosphors30A multicolor‐emitted phosphor for temperature sensing and multimode dynamic anti‐counterfeiting18Controlling defects to improve the emission intensity of NaMgBO3:1%Ce3+ blue-cyan phosphor3High-Efficiency Continuous-Luminescence-Controllable Performance and Antithermal Quenching in Bi 3+ -Activated Phosphors35Luminescence Property, Color Tunability, and Optical Thermometry Behavior of Bismuth-Europium Codoped Strontium-Anorthite-Type Phosphors9Exploration of up-conversion thermal enhancement mechanism and application on temperature sensing of Sc2W3O12: Yb3+, Er3+ materials50Rare earth free BaZnBO3F:Bi2+ phosphor with a narrow-band red emission13Luminescence properties, tunable emission and energy transfer of Ca9MgLi(PO4)7:Bi3+/Eu3+ phosphor19Fabrication of ZnO dual electron transport layer via atomic layer deposition for highly stable and efficient CsPbBr3 perovskite nanocrystals light-emitting diodes9Synthesis, adjustable-color emission and energy transfer of Ba2MgSi2O7:Sm3+, Bi3+ phosphors76Ba5GeO4Br6:Bi3+, a promising cyan phosphor for high-quality full-spectrum white light illumination34On The Validity of the Defect- Induced Negative Thermal Quenching of Eu2+-Doped Phosphors7Study on luminescence properties of Bi3+ doped Ba2YAlO5:A wide-band yellow emitting phosphor with excellent thermal stability20Achieving excellent thermostable red emission in singly Mn 2+ -doped near-zero thermal expansion (NZTE) material Li 2 Zn 3 (P 2 O 7 ) 26Ba 3 LuGa 2 O 7.5 :Bi 3+ phosphors with potential application in full-spectrum WLEDs and temperature sensing73Energy transfer and tunable emission in BaSrGd 4 O 8 :Bi 3+ ,Eu 3+ phosphors for warm WLED9Investigation of the luminescence properties and energy transfer mechanisms in Gd 3 TaO 7 :Bi 3+ ,Eu 3+ phosphors for their potential application in full-spectrum WLEDs10Modulation of Bi 3+ luminescence from broadband green to broadband deep red in Lu 2 WO 6 by Gd 3+ doping and its applications in high color rendering index white LED and near-infrared LED18Superlattice-stabilized structure and charge transfer assisted photoluminescence enhancement in a samarium-doped high entropy perovskite oxide17Thin highly transparent visible/near-infrared Ta-doped TiO2 electrode5Achievement of full-visible-spectrum lighting in Bi3+-activated strontium gallates via lattice site occupancy engineering toward WLEDs applications32Effect of doping on the structural, optical and electrical properties of La-doped ZnO thin films35Tunable emission color and anti-thermal-quenching behaviors in niobates for high-sensitive optical thermometry53Polymer‐Encapsulated Halide Perovskite Color Converters to Overcome Blue Overshoot and Cyan Gap of White Light‐Emitting Diodes59Eu 3+ ‐Activated Single‐Band Ratiometric Nanothermometry by Lattice Negative Thermal Expansion79Energy transfer and luminescent properties of Lu2WO6:Bi3+,Eu3+ red emission phosphor26Recent Advances in Light-Conversion Phosphors for Plant Growth and Strategies for the Modulation of Photoluminescence Properties47Adjustment of Bi 3+ Luminescence and Thermal Quenching Properties by B′-Site Ion Substitution Strategy in Double Perovskite CaLaMgSb/TaO 6 :Bi 3+ Phosphor33Cation defects succeed in triggering super stability of narrow-band blue-emitting phosphors Ca3Sc2Si3O12: Bi3+ for backlighting display application29Developing Thermally Stable Defect-Assisted Phosphors of BaSc2Ge3O10:Bi3+ for Pc-UV-LEDs Applications20Large negative thermal quenching of upconversion luminescence through selective excitation in a YAG:Yb/Er transparent ceramics8Breaking the balance of chemical ratio in ZnAl2O4 to regulate activators and traps for multimode luminescence – A new strategy13Tailor Traps in Bi3+-Doped NaGdGeO4 Phosphors by Introducing Eu3+ Ions to Switch Multimodal Phosphorescence Emission17A novel broad-band red K2MgSiO4:Eu2+ phosphor and defect-induced tunable emission from red to yellow20A Novel Cyan Phosphor (K,Rb) 3 GdSi 2 O 7 :Ce 3+ for Full‐Spectrum Lighting through Local Structure Tailoring48Phonon‐Assisted Negative Thermal Quenching in a One‐Photon Up‐Conversion Phosphor for Thermometry39Regulation of Anti‐Thermal Quenching and Emission Color in Eu 2+ ‐Activated Na‐Beta‐Alumina Phosphors for Full‐Spectrum Illumination11High-Quantum-Efficiency Blue Phosphors with Superior Thermal Stability Derived from Eu3+-Doped Faujasite Y Zeolite11Modulating the antithermal-quenching of praseodymium-activated phosphor by the position of intervalence charge transfer state6Cationic substitution engineering induced Multi-Color light emitting of bismuth in Tantalate used for WLED12K2CaPO4F:Eu2+,RE3+ for pc-WLEDs: Cationic substitution inducing tunable emission and anti-thermal quenching8Regulation of the luminescence of Bi3+-activated Ca5Ga6O14 phosphors by varying doping concentration and composition design5A negative-thermal-quenching LaMgAl11O19: Er3+, Sm3+ phosphor achieved by energy transfer from Er3+ to Sm3+10Full-visible-spectrum LED lighting by using a near-UV-excitable broadband blue-emitting Ca2LuHf2GaAl2O12:Ce3+ garnet phosphor43Unusual red luminescence and super thermal stability of a new narrow-band emission phosphor for backlight display application21Trap engineering through chemical doping for ultralong X-ray persistent luminescence and anti-thermal quenching in Zn 2 GeO 451Zero-thermal-quenching and charge compensation for efficient luminescence in Ca9ZnK(PO4)7:Sm3+: Optimizing defect engineering47A novel blue emitting phosphor Ca 1− y Sr y ScBO 4 :Bi 3+ with zero-thermal quenching for multi-scenario application13Enhanced optical properties of CsPbX 3 (X = Cl, Br, and I) perovskite nanocrystal glasses through bismuth doping for light-emitting applications4Regulating luminescence thermal quenching based on the synergistic effect of energy transfer and energy gap modulation3Unraveling the origin of broadband yellow emission in Bi 3+ -doped LuXnGaO 4 (Xn = Mg, Zn) phosphors9SrGa 2 B 2 O 7 : Bi 3+ , M + (M = Li, Na, K), Novel Deep‐Blue Phosphors with High Quantum Yields and Negative Thermal Quenching for High‐Quality White LED22Negative Thermal Quenching of Photoluminescence: An Evaluation from the Macroscopic Viewpoint28Filling the Cyan Gap in wLEDs with Ba2MgWO6:Bi3+ Solid Solution for Full-Spectrum LED Illumination4Realizing Red Mechanoluminescence of ZnS: Mn2+ Through Ferromagnetic Coupling50Highly Stable Oxynitride Persistent Phosphors with Widely Distributed Traps for Information Storage and Anticounterfeiting13Defect regulation of a distinctive synthetic Eu2+-doped SiAlON S-phase towards controllable spectra and thermal quenching for white-light-emitting diode17Superior Quantum Efficiency Blue‐Emitting Phosphors with High Thermal Stability toward Multipurpose LED Applications57Novel GdAlGe2O7:Bi3+,Eu3+ phosphors with anti-thermal quenching properties for high sensitivity optical temperature measurement35Tunable Anti‐Thermal Quenching Luminescence of Eu 3+ ‐Doped Metal‐Organic Framework and Temperature‐Dependent Photonic Coding48Manipulating cationic ordering toward highly efficient and zero-thermal-quenching cyan photoluminescence34Colour change and long-persistent properties of a new phosphor YBaZn3GaO7:Bi3+/Eu3+6Achieving the Anomalous Far‐Red Emission of Eu3+ by Tailoring Distorted Square Antiprism Symmetry in Potassium‐Bismuth‐Phosphates47Single-Band Ratiometric Thermometry Strategy Based on the Completely Reversed Thermal Excitation of O 2– → Eu 3+ CTB Edge and Eu 3+ 4f → 4f Transition25A Novel Broadband Green Phosphor La2W2O9: Bi3+, and Its Application in High Color-Rendering Index pc-WLED1Preparation and Luminescence Properties of Broadband Orange-Emitting Persistent ScBaZn3GaO7:Bi3+ Phosphor22Preparation and optical properties of Bi3+-doped K4SrGe3O9 as a UVA phosphor6Cation substitution strategy realizing controllable spectral shape and multiple applications in a novel blue-cyan emitting KBaScSi2O7:Bi3+ phosphor4Full-Visible-Spectrum White LEDs Enabled by a Blue-Light-Excitable Cyan Phosphor136Eu2+-activated hexagonal aluminate solid solution phosphors with high quantum efficiency and anti-thermal quenching for pc-LEDs20Luminescence Properties of Bi3+-Doped Gd2O3 Phosphor under UV and X-ray Excitation14Disorder–Order transition and Metal-to-Metal charge transfer induced rare Orangish-Red emission in Bi3+-Activated double perovskite phosphors27Photoluminescence properties of Dy3+/Pr3+ co-doped NaLaMgWO6 double perovskite phosphors for solid-state lighting7Dual-mode optical thermometry via efficient Bi3+→Eu3+ energy transfer in CaScAlSiO6 phosphors18Bi3+ ion enhanced self-activated blue phosphor Ba3Ga2O6 for temperature sensing7An anti-thermal-quenching organic–inorganic hybrid manganese-based single-crystal scintillator for high-temperature X-ray imaging31Efficiency optimization of BaY 2 Al 2− y Sc y Ga 2 SiO 12 : x Cr 3+ garnet phosphors with sustained anti-thermal quenching behavior7Energy transfer and charge compensation of Ba 2 ZnGe 2 O 7 :Tb 3+ ,Eu 3+ phosphors for white LEDs14Enhanced optical properties and optical temperature sensing performance of SrGa 4 O 7 :Bi 3+ co-doped with K + and Cr 3+ via charge compensation and energy transfer4Modulating excitation light to alter temperature-dependence of two-photon upconversion luminescence in Yb 3+ /Tm 3+ co-doped LuAG transparent ceramics3Multi-mode tunable luminescence in Bi 3+ -activated oxyfluoride phosphors for multi-level anti-counterfeiting applications10Research progress on the design and regulation of Eu 2+ /Ce 3+ -activated anti-/zero thermal quenching phosphors9Investigation on tunable red and white emissions in Bi3+/Eu3+ co-doped Y2Zr2O7 microcrystals2Double Perovskite Scintillators Enabled by Co‐Doped Trap Regulation for Thermally Enhanced X‐Ray Imaging31Stimuli-responsive luminescence in doped inorganic crystals5Zero-thermal-quenching broadband NIR-II emitting Mg4Nb2O9: Ni2+ phosphor via defective engineering and multi-site occupation14Adjustable emission and energy transfer of BaGdGaO4: Bi3+, Eu3+ phosphors with high quantum efficiency for multifunctional applications9Luminescence improvement of Ce3+-doped Lu2CaMg2Si3O12 orange phosphor for WLED based on Ca vacancy3La 3+ –Al 3+ cosubstitution and enhanced luminescence in the green SrAl 2 Si 2 O 8 :Mn 2+ for liquid crystal display backlights3Eco-friendly synthesis and multifunctional applications of Ba2ZnGe2O7:Bi3+ phosphors for advanced radiation dosimetry and high-performance w-LEDs21Symmetry and singular site-occupancy-controlled strong near-narrow-band cyan emission from Ca3Xn2Ge3O12:Bi3 + (Xn = Sc, Y, Lu) phosphors for healthy WLED lighting8Green emitting Sr2ZnGe2O7:Mn2+ phosphor: A dual function material for w- LEDs and YOLOv8x based latent fingerprint detection13Time- and temperature-dependent dynamic fluorescence of non-stoichiometric induced defective phosphors and multiple applications33Oxygen-mediated structural optimization in SrGa2S4:Eu2+: A dual enhancement of thermal stability and luminescent intensity2Effect of oxygen vacancy in enhancing the red afterglow in Eu3+ doped and M3+ (M = Ho, Er, Dy) co-doped Sr2MgSi2O7 phosphors8A narrow-band Bi³ ⁺-activated blue phosphor with high thermal stability for multiple applications1Europium(II) Activated Blue–Cyan Aluminosilicate Phosphors with Zero Thermal Quenching3Multi-site engineering of Bi3+ in Ca3Y2Si3O12 enables excitation-switchable blue-to-green luminescence for full-spectrum white LEDs0Calcium Vacancy Generated Luminescence Improvement of the Ca 3 Sc 2 Si 3 O 12 :Ce 3+ Phosphor for WLED1Design of LiTaO3:Eu3+ phosphors for high-sensitivity single-band optical thermometry through charge transfer band edge red-shift4A Novel Cyan‐Emitting Phosphor K 3 Ca 0.3 Y 0.7 Si 2 O 7 :Ce 3+ Enables Full‐Spectrum Lighting and Fingerprint Detection via Phase‐Structure Alteration9Interstitial‐Li Induced Oxygen Defect in Self‐Activated BaAl 2 B 2 O 7 for Enhancing Near‐Infrared Luminescence and Thermal Stability11A novel broadband cyan-emitting phosphor Ba3TaGa3Ge2O14:Bi3+ for temperature measurement5Enthalpy Relaxation Mediated Control of NIR Emission in Bi‐Doped Glass0Photochromic and long persistent luminescence properties of Bi3+ doped SrGa4O729Mechanism of Bi3+ role selection in multi-ion-doped persistent phosphors3Sn4+ mediated Bi3+ occupation engineering in titanogermanate phosphors: Broad-spectrum emission design for application in healthy lighting0Enhancing Abnormal Thermal Quenching Characteristics of Y 1– x La x NbO 4 :Pr 3+ Phosphors through Energy Transfer Enhancement and Intervalence Charge Transfer Modulation Synergistic Strategy0Synergistic effect of Bi3+ and extrinsic self-trapped excitons towards effective polychromatic luminescence in layered Sr3Sc2O5Cl20A Multi‐functional Smart Window for Converting Sunlight into Absorbable Fluctuating Light to Enhance Plant Growth and Stress Tolerance16Beyond single-ion doping: K + –Bi 3+ synergy enables crop-tailored blue luminescence through crystal field engineering1Dual-mode thermometry design of Eu3+-doped phosphors regulate Antithermal quenching performance through charge transfer band edge red-shift1Anti-Thermal-Quenching Phosphors Based on Metal Halides16Bi 3+ -doped BaMScO 4 (M = Y, Gd) phosphors as multiple-mode optical thermometers for potential applications in optical thermometry and temperature imaging3A dicationic ionic liquid strategy to enhance the thermal stability of manganese bromide scintillators5A novel green-emitting phosphor NaLa 9 Ge 6 O 26 : x Tb 3+ with anti-thermal quenching for WLEDs0Broad visible emission from a blue-light-excitable single-phase NaLaS 2 :Bi 3+ phosphor for high-CRI white LEDs0Bi3+-doped Ca3La2Si3O12 phosphors with dual emission centers and anti-thermal quenching effect0High thermal stability and red emitting phosphor Sr2LiAlO4: Sm3+ for white LED3Trap-Engineered Deep Ultraviolet and NIR Persistent Bi-Activated Phosphor: Luminescence Tailoring via Secondary Cation Substitution in the Garnet Framework2Nd 3+ Doping Induced Anti‐Thermal Quenching in Rare‐Earth Lead‐Free Halide Double Perovskite Toward High‐Resolution X‐Ray Imaging6Thermoluminescence properties and trap parameters of undoped K₃Gd(BO₂)₆ phosphor1

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  4. MGa 2 B 2 O 7 :Bi 3+ ,Al 3+ (M = Sr, Ba) blue phosphors with a quantum yield of 99% and negative thermal quenching

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