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RESEARCH PAPER · Chemistry of Materials · 2020

Abnormal Bi3+-Activated NIR Emission in Highly Symmetric XAl12O19 (X = Ba, Sr, Ca) by Selective Sites Occupation

Yi Wei, Zhiyu Gao, Xiaohan Yun, Hang Yang, Yixin Liu, Guogang Li

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Abnormal Bi3+-Activated NIR Emission in Highly Symmetric XAl12O19 (X = Ba, Sr, Ca) by Selective Sites OccupationOriginalRecent Advances in Super Broad Infrared Luminescence Bismuth-Doped Crystals75A highly sensitive ratiometric optical cryothermometer using a new broadband emitting trivalent bismuth singly activated Ba 2 ZnSc(BO 3 ) 3 microcrystal10Complex crystal structure and photoluminescence of Bi 3+ -doped and Bi 3+ /Eu 3+ co-doped Ca 7 Mg 2 Ga 6 O 1819Deep red SrLaGa 3 O 7 :Mn 4+ for near ultraviolet excitation of white light LEDs59Mechanisms of bismuth-activated near-infrared photoluminescence – a first-principles study on the MXCl 3 series11Multi-site Cr 3+ occupation-related broadband NIR luminescence in Cr 3+ -doped Li 3 Mg 2 NbO 634Sr 3 Y(BO 3 ) 3 :Bi 3+ phosphor with excellent thermal stability and color tunability for near-ultraviolet white-light LEDs84Trap Depth Engineering in Mgga2o4: Bi3+ for Muticolor Dynamic Anti-Counterfeiting, Encryption And Optical Temperature Sensing Applications142Site-selective excitation and photoluminescence properties of a cyan-emitting NaGd9(SiO4)6O2: Bi3+ phosphor for potential application in white light-emitting diodes32Learning from Mineral Structures toward New Luminescence Materials for Light-Emitting Diode Applications146Li/Na substitution and Yb3+ co-doping enabling tunable near-infrared emission in LiIn2SbO6:Cr3+ phosphors for light-emitting diodes143Simultaneous Broadening and Enhancement of Cr 3+ Photoluminescence in LiIn 2 SbO 6 by Chemical Unit Cosubstitution: Night‐Vision and Near‐Infrared Spectroscopy Detection Applications325Simultaneous Broadening and Enhancement of Cr3+Photoluminescence in LiIn2SbO6by Chemical Unit Cosubstitution: Night‐Vision and Near‐Infrared Spectroscopy Detection Applications5Design principles for achieving red emission in Eu2+/Eu3+ doped inorganic solids83Bi3+ occupancy rearrangement in K2-xAxMgGeO4 phosphor to achieve ultra-broad-band white emission based on alkali metal substitution engineering38Bismuth activated blue phosphor with high absorption efficiency for white LEDs55Advances in Near-Infrared Luminescent Materials without Cr3+: Crystal Structure Design, Luminescence Properties, and Applications171An efficient garnet-structured Na3Al2Li3F12:Cr3+ phosphor with excellent photoluminescence thermal stability for near-infrared LEDs157Tailored Luminescence Output of Bi3+-Doped BaGa2O4 Phosphors with the Assistance of the Introduction of Sr2+ Ions as Secondary Cations23Giant Red‐Shifted Emission in (Sr,Ba)Y 2 O 4 :Eu 2+ Phosphor Toward Broadband Near‐Infrared Luminescence230A novel differential display material: K3LuSi2O7: Tb3+/Bi3+ phosphor with thermal response, time resolution and luminescence color for optical anti-counterfeiting56Anti-thermal-quenching, color-tunable and ultra-narrow-band cyan green-emitting phosphor for w-LEDs with enhanced color rendering85Ultra-broadband NIR luminescence in chromium doped magnesium aluminosilicate glass as future light sources for spectroscopy applications25First-principles study on luminescent properties of Bi3+-doped ALuGeO4 (A = Li, Na): Insights into effects of host cation on emission wavelength22Enabling narrowband cyan photoluminescence and long-lasting ultraviolet-A persistent luminescence in Bi 3+ single-doped Sr 3 Sc 2 Ge 3 O 12 phosphors by selective site occupation48Improving the luminescence property of the novel yellow-emitting phosphor SrLa 2 Sc 2 O 7 :Bi 3+ with charge compensators (Li + , Na + , K + ) and its application in NUV-based white LEDs12Synthesis and luminescent properties: Mn4+-doped Sr3NaNbO6 phosphor with far-red emission14Synthesis of broadband NIR garnet phosphor Ca 4 ZrGe 3 O 12 : Cr 3+ , Yb 3+ for NIR pc-LED applications148Sn4+ induced Bi3+ multi-lattice selective occupation and its color-tunable emission of La2MgZrO6: Bi3+, Sn4+ double perovskite phosphors24Obtain full visible spectrum light-emitting diode illumination via bismuth-activated cyan phosphors23Novel one-dimensional Ga2O3:Cr3+ nanofibers with broadband emission for near infrared LED sources13Cr3+/Yb3+/Nd3+-doped Ba2LaGa11O20 broadband NIR phosphors for NIR pc-LED and c-Si solar cells10Luminescence characteristics of Bi3+, Cr3+ and Bi3+/Cr3+ activated Sr3Y2Ge3O12 phosphors27Multiple Strategies to Approach High-Efficiency Luminescence Controllable in Blue/Cyan/Green-Emitting Bi 3+ -Activated Phosphors30Thermal Quenching Mechanism of Metal–Metal Charge Transfer State Transition Luminescence Based on Double-Band-Gap Modulation24A super stable Near-Infrared garnet phosphor resistant to thermal Quenching, thermal degradation and hydrolysis57A novel blue emitting phosphor LaScO3:Bi3+ for white LEDs: high quantum efficiency, high color purity and excellent thermal stability34High-Efficiency Continuous-Luminescence-Controllable Performance and Antithermal Quenching in Bi 3+ -Activated Phosphors35Synthesis and luminescent properties of strontium aluminates activated with bismuth ions1Light-Induced Charge Transfer to Achieve Deep-Red Emission in SrSc2O4:Bi toward Multiple Optical Applications17Achieving the ultra-broadband near-infrared La3SnGa5O14:Cr3+ phosphor via multiple lattice sites occupation for biological nondestructive detection and night-vision technology45Bismuth‐Activated Persistent Phosphors65Achievement of broadband NIR emission in double perovskite NaLaMgWO6 via non-equivalent substitution of Cr3+17Recent Advances in Chromium‐Doped Near‐Infrared Luminescent Materials: Fundamentals, Optimization Strategies, and Applications252Double‐Site Occupation Triggered Broadband and Tunable NIR‐I and NIR‐II Luminescence in AlNbO4:Cr3+ Phosphors15A metal-to-metal charge transfer induced green-yellow phosphor CsAlGe 2 O 6 :Bi 3+ for full-spectrum LED devices13An Efficient Narrow-band Blue-emitting Phosphor Ba3Y2B6O15:Bi3+ and Its Application7Exclusive confinement of Bi 3+ -activators in the triangular prism enabling efficient and thermally stable green emission in the tridymite-type phosphor CaBaGa 4 O 8 :Bi 3+13Novel highly efficient Bi 3+ -activated phosphors for warm WLEDs39A broad emission band of phosphor Cs2Zn3(P2O7)2:Mn2+ induced by multi-sites of Mn2+12La3Ga5SiO14:Cr3+: A broadband near-infrared phosphor induced by the two-site occupation of Cr3+43Recent Advances in Multi-Site Luminescent Materials: Design, Identification and Regulation20Anionic Regulation toward Bi3+ Selective Occupation for Full-Spectrum White Light Emission33First-Principles and Experimental Study of Trace Impurities and Near-Infrared Emission in Alkaline Earth Hexaaluminates21Synthesis and luminescence characteristics of an efficient broadband NIR phosphor: Cr3+ activated GaTa0.5Nb0.5O420Bi3+-activated dual-wavelength emitting phosphors toward effective optical thermometry45Developing Broadband Cr3+-Substituted Phosphor-Converted Near-Infrared Light Sources38Near-Infrared LuCa 2 ScZrGa 2 GeO 12 :Cr 3+ Garnet Phosphor with Ultra-broadband Emission for NIR LED Applications60Novel “Anti-Zeolite” Ba3Sr3B4O12: Eu3+ Phosphors: Crystal Structure, Optical Properties, and Photoluminescence2Two Noncentrosymmetric Bismuth Phosphates: Rational Design Synthesis and Optical Properties4Cr3+-activated NaInSi2O6: An efficient broadband near-infrared phosphor with its applications in LED22Selective enrichment strategy induces ultra-broadband NIR emission in Cr3+-doped multi-phase glass-ceramics for NIR spectroscopy applications10Multifunctional near-infrared Zn2TiO4:Cr3+ phosphors for luminescence, thermometry, and plant cultivation24Abnormal Bi3+ activated NIR phosphor toward multifunctional LED applications19Energy transfer in Bi3+-Sm3+ co-doped phosphors for temperature sensing and imaging39Near‐Infrared Emission of Sm2+ in Oxynitrides14Prolonged Red Persistent Luminescence in Bi3+ Single-Doped LiGa5O8: Regulating Traps by Site Selective Occupation18Regulation of the luminescence of Bi3+-activated Ca5Ga6O14 phosphors by varying doping concentration and composition design5Direct laser printing of 3D optical imaging based on full-spectrum solar-absorption-enhanced perovskite-type oxides1Structure, luminescence properties, and valence-induced spectral behavior of a bismuth-activated garnet phosphor9Preparation and photoluminescence characterization of LuBO3:Bi3+, Cr3+ fluorescent materials for non-visual lighting applications8Achieving ultra-broadband NIR Gd2Mg3Ge3O12:Cr3+,Yb3+ garnet phosphors through energy transfer15Charge carrier trapping management in Bi3+ and lanthanides doped Li(Sc,Lu)GeO4 for x-ray imaging, anti-counterfeiting, and force recording63Superior Quantum Efficiency Blue‐Emitting Phosphors with High Thermal Stability toward Multipurpose LED Applications57Crystal structure of strontium aluminates phosphors containing bismuth oxides2Rationalization of near-infrared luminescence of bismuth ions in mixed oxides9Ultraviolet-B and Near-Infrared Dual-Band Luminescence in Bi 3+ /Bi 2+ Codoped Persistent Phosphor for Optical Storage Application46Heterostructure anion-groups guided design enabling customizable Eu2+ spectrum behavior in borophosphate7Effect of ion occupancy and Li+ ion doping on luminescence characteristics of CaLaGaO4:Bi3+ blue phosphor30Unlocking Cr3+–Cr3+ Coupling in Spinel: Ultrabroadband Near-Infrared Emission beyond 900 nm with High Efficiency and Thermal Stability112Highly thermal-stable broadband near-infrared emission of Cr3+ doped spinel CdGa2O4 phosphors17Optimization of blue-cyan emitting Bi3+-doped phosphors for NUV-driven WLEDs19Deep-trap ultraviolet persistent phosphor for advanced optical storage application in bright environments103Cr3+-doped Na2CaSn2Ge3O12 garnet showing broadband near-infrared emission at 820 nm with zero thermal quenching and near-unity quantum yield48Broadband Near-Infrared Emission of Sm2+ in Highly Stable (Ba,Sr)Al3Si3O4N5 for Encryption and Nondestructive Inspection11Li+ induced site occupation engineering in Bi3+ activated spinel-type phosphor for multiple optoelectronic applications7Annealing BaAl 2 O 4 :Tb 3+ /Tb 4+ in air and a reducing atmosphere: a strategy to enhance luminescence by eliminating Tb 4+10Crystallographic site engineering of a single Bi 3+ -doped single-component Ca 5 Ga 6 O 14 :Bi 3+ phosphor for full-spectrum white light emission and highly sensitive optical thermometry10Efficient Sr 2 Ta 2 O 7 :Bi 3+ ,Ln 3+ (Ln 3+ = Eu 3+ ,Sm 3+ ) phosphors for optical thermometry and anti-counterfeiting20Near-infrared luminescent materials: a review of their practical applications and prospective advancements47Novel red-emitting SrBi2B4O10:Eu3+ phosphors: Synthesis, crystal structure and luminescence4Sr9La2W4O24: Bi3+/Nd3+ phosphors with anomalous red to near-infrared emission (550–1500 nm) and high efficient quantum cutting for multi-application6Bi3+ doped Sr3Y2(BO3)4 phosphors for full-spectrum WLEDs and temperature sensing11Trace Bi3+ doped single-phase Ca3WO6 phosphor with tunable cool-to-warm white light emission5Ionic substitution combined with flux doping triggered near-unity efficiency and thermally stable NIR luminescence in Al6Ge2O13: Cr3+, Si4+ phosphor for NIR spectroscopy applications6Efficient Tuning of Blue-to-Cyan-Green Emission in Bismuth(III)-Doped Alkaline-Earth Aluminates via Crystal Site Engineering2Ultrawideband Emission of Bi 3+ Ions Spanning Visible to Near‐Infrared Spectral Regions (400 nm–1700 nm)0Ultrawideband Emission of Bi 3+ Ions Spanning Visible to Near‐Infrared Spectral Regions (400 nm–1700 nm)12A Multi‐functional Smart Window for Converting Sunlight into Absorbable Fluctuating Light to Enhance Plant Growth and Stress Tolerance16Unlocking High External Quantum Yield for Broadband Near‐Infrared Emission From Lead‐Free Perovskite Variant Solid Solutions Cs 2 Te 1‒ x Mo x Cl 64F − substitution-induced high-efficiency broadband near-infrared MgAl 2 O 4 :Fe 3+ phosphors for night-vision and biomedical imaging4Multimodal stimulus responsive luminescence in MgGa 2 O 4 :Bi 3+ phosphors via thermal-assisted energy transfer1Red/near-infrared emitting phosphors based on Bi 3+ ions: recent advances, materials design, and applications3Color-tunable and persistent luminescence of ZGGO: Bi3+/Eu3+ phosphors for dynamic multimode anti-counterfeiting3Suppressing oxygen vacancies and boosting Fe3+ near-infrared emission via charge compensation0An ultra-broadband green-emitting phosphor K2ZnSi3O8:Eu2+ with excellent thermal recovery for high-quality WLEDs0

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