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RESEARCH PAPER · Nature Communications · 2019

Divalent europium-doped near-infrared-emitting phosphor for light-emitting diodes

Jianwei Qiao, Guojun Zhou, Yayun Zhou, Qinyuan Zhang, Zhiguo Xia

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Divalent europium-doped near-infrared-emitting phosphor for light-emitting diodesOriginalInsights into the complexity of the excited states of Eu-doped luminescent materials72Broadband near-infrared emission of La 3 Ga 5 GeO 14 :Tb 3+ ,Cr 3+ phosphors: energy transfer, persistent luminescence and application in NIR light-emitting diodes66Highly efficient near-infrared phosphor LaMgGa 11 O 19 :Cr 3+241Nanocrystalline structure control and tunable luminescence mechanism of Eu-doped CsPbBr 3 quantum dot glass for WLEDs100Two-site Cr 3+ occupation in the MgTa 2 O 6 :Cr 3+ phosphor toward broad-band near-infrared emission for vessel visualization215Eu2+-doped ultra-broadband VIS-NIR emitting phosphor126Enhancing Near-Infrared Photoluminescence Intensity and Spectral Properties in Yb 3+ Codoped LiScP 2 O 7 :Cr 3+345Broad-band emission in metal halide perovskites: Mechanism, materials, and applications288Energy transfer from Mn4+ to Mn5+ and near infrared emission with wide excitation band in Ca14Zn6Ga10O35:Mn phosphors67Broadband near‐infrared emission enhancement in K 2 Ga 2 Sn 6 O 16 :Cr 3+ phosphor by electron‐lattice coupling regulation87Broadband Near‐Infrared Garnet Phosphors with Near‐Unity Internal Quantum Efficiency308Strategies to approach high performance in Cr3+-doped phosphors for high-power NIR-LED light sources743Broadband near-infrared luminescence and energy transfer of Cr3+, Ce3+ co-doped Ca2LuHf2Al3O12 phosphors91Data-Driven Photoluminescence Tuning in Eu2+-Doped Phosphors76Local Structure Distortion Induced Broad Band Emission in the All-Inorganic BaScO2F:Eu2+ Perovskite53Identification of Dy 3 + / Dy 2 + as Electron Trap in Persistent Phosphors100Broadband infrared LEDs based on europium-to-terbium charge transfer luminescence152A review on fluorescence intensity ratio thermometer based on rare-earth and transition metal ions doped inorganic luminescent materials440Abnormal Bi3+-Activated NIR Emission in Highly Symmetric XAl12O19 (X = Ba, Sr, Ca) by Selective Sites Occupation106Broadband Near-Infrared Emitting Ca2LuScGa2Ge2O12:Cr3+ Phosphors: Luminescence Properties and Application in Light-Emitting Diodes202Light-emitting diodes: brighter NIR-emitting phosphor making light sources smarter135A novel thermally stable eulytite-type NaBaBi2(PO4)3:Eu3+ red-emitting phosphor for pc-WLEDs104Solid‐State Thin‐Film Broadband Short‐Wave Infrared Light Emitters53Highly efficient and air-stable Eu(II)-containing azacryptates ready for organic light-emitting diodes101Structural Engineering of Eu2+-Doped Silicates Phosphors for LED Applications242A highly efficient and thermally stable broadband Cr 3+ -activated double borate phosphor for near-infrared light-emitting diodes236Hidden Structural Evolution and Bond Valence Control in Near-Infrared Phosphors for Light-Emitting Diodes191Doping Lanthanide Ions in Colloidal Semiconductor Nanocrystals for Brighter Photoluminescence241Cr 3+ ‐Doped Sc‐Based Fluoride Enabling Highly Efficient Near Infrared Luminescence: A Case Study of K 2 NaScF 6 :Cr 3+259Persistent phosphors for the future: Fit for the right application183Recent Advances in 2D Rare Earth Materials93A novel Cr 3+ -doped Lu 2 CaMg 2 Si 3 O 12 garnet phosphor with broadband emission for near-infrared applications136Achieving the potential multifunctional near-infrared materials Ca 3 In 2−x Ga x Ge 3 O 12 :Cr 3+ using a solid state method59Deep red SrLaGa 3 O 7 :Mn 4+ for near ultraviolet excitation of white light LEDs59Enhancing and tuning broadband near-infrared (NIR) photoluminescence properties in Cr 3+ -doped Ca 2 YHf 2 Al 3 O 12 garnet phosphors via Ce 3+ /Yb 3+ -codoping for LED applications101Highly thermally stable Cr 3+ and Yb 3+ codoped Gd 2 GaSbO 7 phosphors for broadband near-infrared applications54Tuning luminescence from NIR-I to NIR-II in Cr 3+ -doped olivine phosphors for nondestructive analysis175Improving the thermal stability and luminescent efficiency of (Ba,Sr)3SiO5:Eu2+ phosphors by structure, bandgap engineering and soft chemistry synthesis method98High‐Power Broadband NIR LEDs Enabled by Highly Efficient Blue‐to‐NIR Conversion113Surface-Protected High-Efficiency Nanophosphors via Space-Limited Ship-in-a-Bottle Synthesis for Broadband Near-Infrared Mini-Light-Emitting Diodes71Learning from Mineral Structures toward New Luminescence Materials for Light-Emitting Diode Applications146A High Efficiency Trivalent Chromium-Doped Near-Infrared-Emitting Phosphor and Its NIR Spectroscopy Application166Eu 2+ Stabilized at Octahedrally Coordinated Ln 3+ Site Enabling Red Emission in Sr 3 LnAl 2 O 7.5 (Ln = Y or Lu) Phosphors61Superior thermally-stable narrow-band green emitter from Mn2+-doped zero thermal expansion (ZTE) material78Li/Na substitution and Yb3+ co-doping enabling tunable near-infrared emission in LiIn2SbO6:Cr3+ phosphors for light-emitting diodes143Simultaneous Broadening and Enhancement of Cr 3+ Photoluminescence in LiIn 2 SbO 6 by Chemical Unit Cosubstitution: Night‐Vision and Near‐Infrared Spectroscopy Detection Applications325Rapid Synthesis of Red‐Emitting Sr2Sc0.5Ga1.5O5:Eu2+ Phosphors and the Tunable Photoluminescence Via Sr/Ba Substitution90Design principles for achieving red emission in Eu2+/Eu3+ doped inorganic solids83A General Ammonium Salt Assisted Synthesis Strategy for Cr3+‐Doped Hexafluorides with Highly Efficient Near Infrared Emissions212A terbium-sensitized Eu3+-activated deep-red-emitting phosphor for plant growth LED application72Single-phase far-red-emitting ZnAl2O4:Cr3+ phosphor for application in plant growth LEDs118Sb 3+ ‐Doping in Cesium Zinc Halides Single Crystals Enabling High‐Efficiency Near‐Infrared Emission370Advances in Near-Infrared Luminescent Materials without Cr3+: Crystal Structure Design, Luminescence Properties, and Applications171An efficient garnet-structured Na3Al2Li3F12:Cr3+ phosphor with excellent photoluminescence thermal stability for near-infrared LEDs157Ytterbium-Doped CsPbCl 3 Quantum Cutters for Near-Infrared Light-Emitting Diodes94Cr 3+ Activated Garnet Phosphor with Efficient Blue to Far‐Red Conversion for pc‐LED175Efficient broadband near-infrared luminescence of Cr3+ doped fluoride K2NaInF6 and its NIR-LED application toward veins imaging175A highly efficient and suitable spectral profile Cr3+-doped garnet near-infrared emitting phosphor for regulating photomorphogenesis of plants278A Highly Efficient Eu2+ Excited Phosphor with Luminescence Tunable in Visible Range and Its Applications for Plant Growth66Giant Red‐Shifted Emission in (Sr,Ba)Y 2 O 4 :Eu 2+ Phosphor Toward Broadband Near‐Infrared Luminescence230Efficient and Broadband LiGaP2O7:Cr3+ Phosphors for Smart Near‐Infrared Light‐Emitting Diodes231Narrow Bandwidth Luminescence in Sr2Li(Al,Ga)O4:Eu2+ by Selective Site Occupancy Engineering for High Definition Displays52A novel differential display material: K3LuSi2O7: Tb3+/Bi3+ phosphor with thermal response, time resolution and luminescence color for optical anti-counterfeiting56Achieving an ultra-broadband infrared emission through efficient energy transfer in LiInP2O7: Cr3+, Yb3+ phosphor80An Extra‐Broadband VIS‐NIR Emitting Phosphor toward Multifunctional LED Applications153Chromium Ion Pair Luminescence: A Strategy in Broadband Near-Infrared Light-Emitting Diode Design283Trade‐off Lattice Site Occupancy Engineering Strategy for Near‐Infrared Phosphors with Ultrabroad and Tunable Emission98Spectrally tunable and thermally stable near-infrared luminescence in Na 3 Sc 2 (PO 4 ) 3 :Cr 3+ phosphors by Ga 3+ co-doping for light-emitting diodes62Two Selective Sites Control of Cr3+‐Doped ABO4 Phosphors for Tuning Ultra‐Broadband Near‐Infrared Photoluminescence and Multi‐Applications124Octahedron-dependent near-infrared luminescence in Cr3+-activated phosphors99Efficient Ultra‐Broadband Ga 4 GeO 8 :Cr 3+ Phosphors with Tunable Peak Wavelengths from 835 to 980 nm for NIR pc‐LED Application134Accessing High-Power Near-Infrared Spectroscopy Using Cr3+-Substituted Metal Phosphate Phosphors114Synthesis of broadband NIR garnet phosphor Ca 4 ZrGe 3 O 12 : Cr 3+ , Yb 3+ for NIR pc-LED applications148Eu2+‐Doped Layered Double Borate Phosphor with Ultrawide Near‐Infrared Spectral Distribution in Response to Ultraviolet–Blue Light Excitation110Structural Rigidity Control toward Cr3+-Based Broadband Near-Infrared Luminescence with Enhanced Thermal Stability243Glass‐Crystallized Luminescence Translucent Ceramics toward High‐Performance Broadband NIR LEDs120Photoluminescence Properties of AScSi 2 O 6 :Cr 3+ (A = Na and Li) Phosphors with High Efficiency and Thermal Stability for Near-Infrared Phosphor-Converted Light-Emitting Diode Light Sources175Competitive Site Occupation toward Improved Quantum Efficiency of SrLaScO 4 :Eu Red Phosphors for Warm White LEDs103Crystal‐Field Engineering Control of an Ultraviolet–Visible‐Responsive Near‐Infrared‐Emitting Phosphor and Its Applications in Plant Growth, Night Vision, and NIR Spectroscopy Detection123Efficient and Thermally Stable Broad-Band Near-Infrared Emission in a KAlP 2 O 7 :Cr 3+ Phosphor for Nondestructive Examination191Eu2+ Doping Concentration-Induced Site-Selective Occupation and Photoluminescence Tuning in KSrScSi2O7:Eu2+ Phosphor77A novel Cr3+-activated far-red titanate phosphor: synthesis, luminescence enhancement and application prospect59Design of a Novel Near-Infrared Luminescence Material Li2Mg3TiO6:Cr3+ with an Ultrawide Tuning Range Applied to Near-Infrared Light-Emitting Diodes111A near-infrared phosphor doped with Cr3+ towards zero-thermal-quenching for high-power LEDs56Near‐Infrared Light‐Emitting Diodes utilizing a Europium‐Activated Calcium Oxide Phosphor with External Quantum Efficiency of up to 54.7%320Highly Efficient Broad-Band Green-Emitting Cerium(III)-Activated Garnet Phosphor Allows the Fabrication of Blue-Chip-Based Warm-White LED Device with a Superior Color Rendering Index69Highly efficient Fe3+-doped A2BB′O6 (A = Sr2+, Ca2+; B, B′ = In3+, Sb5+, Sn4+) broadband near-infrared-emitting phosphors for spectroscopic analysis251Efficient near-infrared phosphors discovered by parametrizing the Eu(II) 5d-to-4f energy gap92Efficient, Stable, and Ultra‐Broadband Near‐Infrared Garnet Phosphors for Miniaturized Optical Applications89Modulation of Thermally Stable Photoluminescence in Cr 3+ -Based Near-Infrared Phosphors201Efficient Broadband Near‐Infrared Emission from Lead‐Free Halide Double Perovskite Single Crystal166Highly Distorted Antimony(III) Chloride [Sb 2 Cl 8 ] 2− Dimers for Near‐Infrared Luminescence up to 1070 nm160Blue LED‐Pumped Broadband Short‐Wave Infrared Emitter Based on LiMgPO4:Cr3+,Ni2+ Phosphor97Enhancement of Near‐Infrared Phosphor Luminescence Properties via Construction of Stable and Compact Energy Transfer Paths54A super stable Near-Infrared garnet phosphor resistant to thermal Quenching, thermal degradation and hydrolysis57Interstitial Li + Occupancy Enabling Radiative/Nonradiative Transition Control toward Highly Efficient Cr 3+ -Based Near-Infrared Luminescence83Near-Infrared Broadband ZnTa2O6:Cr3+ Phosphor for pc-LEDs and Its Application to Nondestructive Testing64Advances in Chromium‐Activated Phosphors for Near‐Infrared Light Sources489A Zero-Thermal-Quenching Blue Phosphor for Sustainable and Human-Centric WLED Lighting130Ultra‐Broadband Green‐Emitting Phosphors without Cyan Gap Based on Double‐Heterovalent Substitution Strategy for Full‐Spectrum WLED Lighting89Environmentally-friendly and low-cost Fe3+-doped broadband NIR light-emitting phosphors54High-Efficiency and Wavelength-Tunable Near-Infrared Emission of Lanthanide Ions Doped Lead-Free Halide Double Perovskite Nanocrystals toward Fluorescence Imaging70Highly Efficient Broadband Near-Infrared Luminescence with Zero-Thermal-Quenching in Garnet Y3In2Ga3O12:Cr3+ Phosphors185A Super‐Broadband NIR Dual‐Emitting Mg2SnO4:Cr3+,Ni2+ Phosphor for Ratiometric Phosphor‐Converted NIR Light Source Applications61Broadband NIR Phosphor Ca2LuScAl2Si2O12:Cr3+ for NIR LED Applications151Producing Tunable Broadband Near-Infrared Emission through Co-Substitution in (Ga1–xMgx)(Ga1–xGex)O3:Cr3+77Site-Selective Occupancy Control of Cr Ions toward Ultrabroad-Band Infrared Luminescence with a Spectral Width up to 419 nm79Recent Advances in Chromium‐Doped Near‐Infrared Luminescent Materials: Fundamentals, Optimization Strategies, and Applications252Highly efficient and thermally stable broadband NIR phosphors by rationally bridging Cr 3+ –Yb 3+ in LiScGe 2 O 6 for optical bioimaging69Boosting Energy Transfer from Self‐Trapped Exciton to Er3+ Through Sb3+ Doping in Cs2Na(Lu/Er)Cl6 Double Perovskites57Structural confinement toward suppressing concentration and thermal quenching for improving near-infrared luminescence of Fe 3+69LaMgGa11O19:Cr3+,Ni2+ as Blue‐Light Excitable Near‐Infrared Luminescent Materials with Ultra‐Wide Emission and High External Quantum Efficiency111Broadband and Multimode Near‐Infrared Emitter Based on Cr3+‐Activated Stannate for Multifunctional Applications75Regulating Eu 2+ Multisite Occupation through Structural Disorder toward Broadband Near-Infrared Emission91Single‐Site Occupancy of Eu 2+ in Multiple Cations Enables Efficient Ultra‐Broadband Visible to Near‐Infrared Luminescence83Strong Self‐Trapped Exciton Emission and Highly Efficient Near‐Infrared luminescence in Sb3+‐Yb3+ Co‐doped Cs2AgInCl6 Double Perovskite144Facile Synthesis of Highly Efficient and Thermally Stable BaAl 4 Sb 2 O 12 :Eu 2+ Phosphor in Air72Achieving High Quantum Efficiency Broadband NIR Mg4Ta2O9:Cr3+ Phosphor Through Lithium‐Ion Compensation189Multimode‐Responsive Luminescence Smart Platform by Single‐Sm3+‐Doped Phosphors55Broadband Emission Origin in Metal Halide Perovskites: Are Self‐Trapped Excitons or Ions?198Deep‐Red Ca3Al2Ge3O12:Eu3+ Garnet Phosphor with Near‐Unity Internal Quantum Efficiency and High Thermal Stability for Plant Growth Application67Thermally Stable Red‐Emitting Oxide Ceramics for Laser Lighting153Unraveling Luminescent Energy Transfer Pathways: Futuristic Approach of Miniature Shortwave Infrared Light-Emitting Diode Design66Broad-Band Sensitization in Cr3+–Er3+ Co-Doped Cs2AgInCl6 Double Perovskites with 1.5 μm Near-Infrared Emission88A broadband near-infrared nanoemitter powered by mechanical action110Intervalence charge transfer of Cr3+-Cr3+ aggregation for NIR-II luminescence165Tetracoordinate Fe 3+ Activated Li 2 ZnAO 4 (A = Si, Ge) Near-Infrared Luminescent Phosphors65Multimodal luminescence in Pr3+ single-doped Li2CaSiO4 phosphor for optical information storage and anti-counterfeiting applications128Six‐ and five‐coordinated Cr 3+ in Ga 2 GeO 5 invokes tunable broadband near‐infrared emission toward night‐vision applications61How to Achieve Excellent Luminescence Properties of Cr Ion‐Doped Near‐Infrared Phosphors103High‐Performance NIR Emission in Chromium‐Doped Garnet Phosphors Enabled by Structure and Excitation Regulation67Achieving Broadband NIR Emission in Fe 3+ ‐Activated ALaBB′O 6 (A = Ba, Sr, Ca; B–B′ = Li–Te, Mg–Sb) Phosphors via Multi‐Site Ionic Co‐Substitutions60Chromium Cluster Luminescence: Advancing Near‐Infrared Light‐Emitting Diode Design for Next‐Generation Broadband Compact Light Sources64Rapid synthesis of phosphor-glass composites in seconds based on particle self-stabilization117Stimuli‐Responsive Lanthanide Activated Piezoelectric LiNbO 3 Microcrystals for Multimode Luminescence and Optical Sensing Applications57Efficient Near-Infrared Luminescence with Near-Unity Photoluminescence Quantum Yield in Erbium-Doped Double Perovskites Cs 2 NaYCl 6 under Green Light Excitation55Laser-driven broadband near-infrared light source with watt-level output280Near‐infrared emitting metal halide materials: Luminescence design and applications78Advances in Fe3+-activated luminescent materials for near-infrared light sources64LaMg6Ga6S16: a chemical stable divalent lanthanide chalcogenide70Boosting Near‐Infrared Emission in Spinel‐Type Phosphor via Oxygen Vacancy Engineering for Versatile Application121Highly Efficient and Thermally Stable Broadband NIR Phosphors with Superlong Afterglow Performance and their Multifunctional Applications53Unlocking Cr3+–Cr3+ Coupling in Spinel: Ultrabroadband Near-Infrared Emission beyond 900 nm with High Efficiency and Thermal Stability112Amorphous to Crystalline Phase Transformation Enables Tunable Persistent Luminescence for Multi‐Mode Optical Information Storage53Regulating the broadband near-infrared emission of Eu2+-doped Ca3Sc2Si3O12 phosphors through constructing defect for diversified applications56Suppressed concentration quenching and tunable photoluminescence in Eu2+-activated Rb3Y(PO4)2 phosphors for full-spectrum lighting87Phosphor‐in‐Ceramic‐Converted Laser‐Driven Near‐Infrared Light Sources for Multiple Intelligent Spectroscopy Applications103Compositional engineering of phase-stable and highly efficient deep-red emitting phosphor for advanced plant lighting systems94Constructing Broadband Near‐Infrared Garnet Emitters CaGd 2 Ga 4 SiO 12 :Cr 3+ with Unity Quantum Efficiency and High Thermal Stability for Versatile Applications72A review of recent advances in Ce3+-activated garnet phosphors for blue-chip-pumped pc-WLEDs81

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  35. A novel thermally stable eulytite-type NaBaBi2(PO4)3:Eu3+ red-emitting phosphor for pc-WLEDs

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  41. Structural Engineering of Eu2+-Doped Silicates Phosphors for LED Applications

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  42. Effect of annealing temperature on persistent luminescence of Y3Al2Ga3O12:Cr3+ co-doped with Ce3+ and Pr3+

    Optical Materials · 2020-10-27

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  43. Sensitizing Full‐Spectrum Lanthanide Luminescence within a Semiconductor CaZnOS Host

    Advanced Photonics Research · 2020-10-31

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  44. Synthesis and luminescence properties of apatite-type red-emitting Ba2La8(GeO4)6O2:Eu3+ phosphors

    Journal of Rare Earths · 2020-11-02

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  45. Valence State Control of Manganese in MgAl2O4:Mn4+ Phosphor by Varying the Al2O3 Crystal Form

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  46. A highly efficient and thermally stable broadband Cr 3+ -activated double borate phosphor for near-infrared light-emitting diodes

    Journal of Materials Chemistry C · 2020-11-10

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  47. Site Occupancies, VUV-UV–vis Photoluminescence, and X‑ray Radioluminescence of Eu2+-Doped RbBaPO4

    Inorganic Chemistry · 2020-11-13

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  48. A novel Eu2+-activated calcium zirconium silicate phosphor: Ca3ZrSi2O9:Eu2+

    Journal of Luminescence · 2020-11-21

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  49. Influence of temperature on near-infrared luminescence, energy transfer mechanism and the temperature sensing ability of La2MgTiO6: Nd3+ double perovskites

    Sensors and Actuators A Physical · 2020-11-23

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  50. Emerging high-power NIR-emitting phosphor-converted LEDs

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