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RESEARCH PAPER · Inorganic Chemistry · 2019

Tuning of Emission by Eu3+ Concentration in a Pyrophosphate: the Effect of Local Symmetry

Jing Zhang, Gemei Cai, Wenjun Wang, Li Ma, Xiaojun Wang, Zhanpeng Jin

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Tuning of Emission by Eu3+ Concentration in a Pyrophosphate: the Effect of Local SymmetryOriginalCrystal structure, luminescence properties and thermal stability of BaY 2−x Eu x Ge 3 O 10 phosphors with high colour purity for blue-excited pc-LEDs12Design of core–shell phosphors with tunable luminescence and improved thermal stability by coating with g-C 3 N 418Efficient and stable Sr 3 Eu 2 B 4 O 12 red phosphor benefiting from low symmetry and distorted local environment48Structural modulation induced intensity enhancement of full color spectra: a case of Ba 3 ZnTa 2−x Nb x O 9 :Eu 3+ phosphors19The Non-Concentration-Quenching Phosphor Ca3Eu2B4O12 for WLED Application176Insight into energy transfer, color tuning, and white emission in Tm3+ and Dy3+ codoped Ca8ZnLa(PO4)7 phosphors36Tunable luminescence and energy transfer in Eu3+ doped Ca8MTb(PO4)7 (M = Mg, Zn, Ca) phosphors22Color Tuning from Greenish-Yellow to Orange-Red in Thermal-Stable KBaY(MoO4)3:Dy3+, Eu3+ Phosphors via Energy Transfer for UV W-LEDs61In‐air self‐reduction synthesis and colour tunable luminescence from SrBPO5:Eu2+–Eu3+ excited using ultraviolet light8Tuning luminescence and excellent thermal stability of Gd4.67Si3O13: Bi3+, Eu3+ with energy transfer from Bi3+ to Eu3+25A red phosphor LaSc3(BO3)4:Eu3+ with zero-thermal-quenching and high quantum efficiency for LEDs251Deep-Tissue Temperature Sensing Realized in BaY2O4:Yb3+/Er3+ with Ultrahigh Sensitivity and Extremely Intense Red Upconversion Luminescence130Structure and tunable luminescence in Sm3+/Er3+ doped host-sensitized LaNbO4 phosphor by energy transfer23Why Do Relative Intensities of Charge Transfer and Intra-4f Transitions of Eu3+ Ion Invert in Yttrium Germanate Hosts? Unravelling the Underlying Intricacies from Experimental and Theoretical Investigations31Design of a bi-functional NaScF4: Yb3+/Er3+ nanoparticles for deep-tissue bioimaging and optical thermometry through Mn2+ doping39Hetero-valent substitution strategy toward orange-red luminescence in Bi3+ doped layered perovskite oxide phosphors for high color rendering index white light-emitting diodes105Structural origins of carbon quantum dot luminescence by synchrotron x-ray spectroscopy0Remotely control Eu2+ emissions by modulating structural ordering of PO4 anion-groups in (Sr3-xCax)Ce(PO4)3:Eu2+ phosphors6Ba 3 YB 3 O 9 based phosphor ceramic plates with excellent thermal stability for wLED applications18Photoluminescence and energy transfer of efficient and thermally stable white-emitting Ca9La(PO4)7:Ce3+, Tb3+, Mn2+ phosphors26Enhanced local symmetry achieved zero-thermal-quenching luminescence characteristic in the Ca2InSbO6:Sm3+ phosphors for w-LEDs227Multipath optical thermometry realized in CaSc 2 O 4 : Yb 3+ /Er 3+ with high sensitivity and superior resolution28Daylight-White-Emitting and Abnormal Thermal Antiquenching Phosphors Based on a Layered Host SrIn 2 (P 2 O 7 ) 253Thermally stable and highly efficient red-emitting Eu3+-doped Cs3GdGe3O9 phosphors for WLEDs: non-concentration quenching and negative thermal expansion480The composition engineering of red‐emitting Eu 3+ ‐doped Ca 10.5 (PO 4 ) 7 ‐type solid solution phosphors and application in LED11Investigation of the structural and photoluminescence properties of Eu3+ doped Na6CaP2O9 phosphors for solid state lighting53In‐air self‐reduction synthesis and luminescence properties from Mg21Ca4Na4(PO4)18:Eu2+–Eu3+ excited using ultraviolet light2Synthesise, energy transfer and tunable emission properties of Ba2La2ZnW2O12:Sm3+ phosphors86Performance improvement of Si solar cell via down - Conversion and plasmonic processes using Eu3+ doped TeO2-GeO2-PbO glasses with silver nanoparticles as cover layer30In‐doped LiCa 2.98 MgV 3 O 12 rare‐earth‐free phosphor with a high photoluminescence quantum yield of 67.4%9Ultrasensitive optical thermometer based on abnormal thermal quenching Stark transitions operating beyond 1500 nm24Amorphous Alumina: A Bright Red Matrix for Flexible and Transparent Anti-counterfeiting25Enhanced up-conversion luminescence and temperature sensing property of Ba3-xSrxLu4O9:Tm3+/Yb3+ phosphors42Phase transition and enhanced photoluminescence behaviour of rare earth activated ZnMoO4@(GO/r/GO) nanocomposites8Increasing Doping Solubility of RE3+ Ions in Fergusonite BiVO4 via Pressure-Induced Phase Transition11Dependence of Luminous Performance on Eu3+ Site Occupation in SrIn2(P2O7)2: The Effect of the Local Environment35Highly efficient and thermally stable Eu3+ activated phosphate based phosphors for wLEDs: An experimental and DFT study53Enhancement of Eu2+ photoluminescence behavior in NaBaB9O15 based on the K+ doping13The Charge Transfer Band as a Key to Study the Site Selection Preference of Eu3+ in Inorganic Crystals56Emerging near-unity internal quantum efficiency and color purity from red-emitting phosphors for warm white LED with enhanced color rendition33Co-crystallization of red emitting (NH 4 ) 3 Sc(SO 4 ) 3 :Eu 3+ microfibers: structure–luminescence relationship for promising application in optical thermometry9Phase Transition from La2ti2o7 to Latio3 Induced by Li+ Doping: Enhanced Local Symmetry and Particle Uniformity Achieved an Efficient Mn4+ Activated Far Red Phosphor for Agricultural Cultivation0Revealing Eu 3+ -doped yttrium pyrogermanate as a soft UV excitable phosphor: retaining the pros of the commercial phosphor and compensating for the cons13The Local Symmetry of Eu3+-Activated Li4ca2b8o16 Red-Emitting Phosphors with High Color Purity and Excellent Thermal Stability0Regulation of Local Site Structures to Stabilize Mixed-Valence Eu2+/3+ under a Reducing Atmosphere for Multicolor Photoluminescence23Enhancing the photoluminescence performance of Ca5(PO4)2SiO4:Re3+ (Re = Eu, Sm) phosphors with A3+ (A = La, Bi) codoping and white light-emitting diode application28Tuning of emission by effect of local symmetry in BaLaLiWO6:Dy3+/Eu3+ for WLEDs41Luminescence and structural properties of Ca1-xZrO3:Eux: An experimental and theoretical approach3Change from La2Ti2O7 to LaTiO3 induced by Li2CO3 addition: Higher local symmetry and particle uniformity achieved an efficient Mn4+ activated far red phosphor for agricultural cultivation8Photoluminescence properties of Ba3In2WO9: Eu3+: a novel red-emitting phosphor for WLEDs24Photoluminescence behavior of Eu 3+ doped XAl 2 O 4 (X = Mg, Ca, Sr and Ba) phosphors: a comparative study2Triple luminescent center energy transfer enables color tuning in Na3Y(PO4)2:RE3+ (RE = Tb/Eu/Tm) for w-LEDs7Preparation and characterization of an efficient and ultra-narrow fluorescence of Eu(III) complex with ultrasensitive sensing to gallic acid3Eu3+-activated Sr3LaNb3O12 red-emitting phosphors with excellent color stability for high color rendering w-LEDs8(INVITED)Rare-earth ions doped glasses based on TeO2 and GeO2 with and without nanoparticles used as cover to increase Si solar cell performance: A review of recent results4The local symmetry of trivalent europium ion activated Li4Ca2B8O16 red-emitting phosphors with high color purity and excellent thermal stability27Perovskite A-site symmetry tuning to achieve high quantum efficiency phosphor for WLED applications18Complete B-site cation regulation accomplish UV-excited red phosphors in double perovskite oxides13Preparation of Eu(III) Complexes Containing Maleopimaric Acid Anhydride with Ultra-narrow and Efficient Fluorescence Emission for High Determination on Gallic Acid in Acetonitrile Solution7Mixed occupation, double valence and tunable emission of Eu in BaIn2(P2O7)212Crystal defect induced zero thermal quenching β-NaYF 4 : Eu 3+ , Sm 3+ red-emitting phosphor10An efficient blue-excitable broadband Y 3 ScAl 4 O 12 :Ce 3+ garnet phosphor for WLEDs13Color-tunable emissions realized by Tb 3+ to Eu 3+ energy transfer in ZnGdB 5 O 10 under near-UV excitation9Thermal-stability synergy improvement of Sm 3+ and Eu 3+ in Ca 3.6 In 3.6 (PO 4 ) 6 : the effect of local symmetry30Tunable luminescence in Eu 3+ /Sm 3+ single-doped LuNbO 4 for optical thermometry and anti-counterfeiting59Thermally stable novel double perovskite orange-red emitting Sr2InTaO6:Sm3+ phosphors with high CRI for WLEDs34High-sensitivity Eu3+/Mn4+ co-doped Li4AlSbO6 perovskite type thermometry with efficient dual emission4Structural and optical properties of Mg 1− x Mn x P 2 O 6 ( x = 0–1.0) magnesium metaphosphate11In Situ Generating YVO 4 :Eu 3+ ,Bi 3+ Downshifting Phosphors in SiO 2 Antireflection Coating for Efficiency Enhancement and Ultraviolet Stability of Silicon Solar Cells25A novel Ca2ScNbO6:Eu3+ phosphor with excellent thermal stability for high color rendering WLED24Luminescence properties and optical sensing behaviors of Sr2GdSbO6:Eu3+ phosphors57Orange-red-emitting BaSrGd4O8:Sm3+ phosphors with high thermal stability for applications in w-LEDs and latent fingerprints38Emission enhancement of Eu3+ doped Ba2Zn(BO3)2 by adding charge compensators9Luminescence and photocatalytic properties of bifunctional materials CaTi2O4(OH)2:Eu3+ and [CaTi2O4(OH)2–CaTiO3]:Eu3+8Sites engineering induced adjustable emission in orange-red Ca4-xLu2xHf1-xGe3O12:Eu3+ phosphor with excellent photoluminescent property4Co-Doping Effect of Mn2+ and Eu3+ on Luminescence in Strontiowhitlockite Phosphors9A brief review of characteristic luminescence properties of Eu 3+ in mixed-anion compounds53Cation vacancy-boosted BaZnB 4 O 8 : x Eu 3+ phosphors with high quantum yield and thermal stability for pc-WLEDs17Synthesis and photoluminescence properties of high color purity red emitting Li2MgTi3O8:Eu3+ phosphors for warm W-LEDs35Impact of Structural Changes on Energy Transfer in the Anion-Engineered Re3+:Y2O3 Through Low-Temperature Synthesis Approach4Colour tuning via energy transfer of K2Ba(MoO4)2: Dy3+/Eu3+ phosphors with thermal-stable property2Tuning of emission in BaLa1−x−yGa3O7:xDy3+, yEu3+ by local symmetry effects for WLEDs0Eu3+ activated gadolinium oxide quantum dots: Biocompatible red luminescent phosphor for photonic, latent fingerprint imaging, and anticancer therapy13Eu3+ Species as a Luminescent Probe for Fast Monitoring of the Chemical State of Ceria Catalysts18Eu3+ doped Ca3LiSbO6 and Eu3+, Li+ co-doped Ca3LiSbO6 phosphors for white light-emitting diodes12Thermally‐Induced Reentrant Order‐Disorder‐Order Transitions in ALa 9 (GeO 4 ) 6 O 2 Apatites3Regulating the redshift of the charge transfer band edge and antithermal quenching by ion substitution strategy in YP1-xVxO4:Eu3+ phosphor12An efficient red phosphor LuNb2VO9:Eu3+ with broadband excitation and abnormal thermal quenching properties for personal identification, security ink, and w-LEDs12Achieving Eu 2+ Luminescence at Trivalent Lattice Site in Rb 3 Y(PO 4 ) 2 :Eu toward Multicolor Emissions by Carbon and Hydrogen Coreduction23Optical characteristics, Judd-Ofelt analysis of enhanced luminescence by flux in thermally stable, novel Eu3+- doped BaZr(PO4)2 phosphor for indoor lighting applications13Suppressed concentration quenching and tunable photoluminescence in Eu2+-activated Rb3Y(PO4)2 phosphors for full-spectrum lighting87Luminescent color modulation of Zn/BaAl2O4:0.2%Eu phosphors for LED application4Structure–Photoluminescence Relationship in Ce3+-Doped K5Y(P2O7)2 and Its Sensitization to Dy3+ with Enhanced White Light Emission7Self‐reduction triggered color tuning of Eu 3+ ‐doped aluminosilicate glass for solid‐state white illumination4A novel highly thermally stable phosphor powder Ba2LuSbO6: Eu3+ for latent fingerprint visualization16High-brightness and high-color-purity red-emitting Ca8MEu(PO4)7 (M = Mg and Zn) phosphate phosphors for near-UV-pumped pc-WLEDs40Tunable orange-deep red photoluminescence in amorphous KZn 1− x Mn x (PO 3 ) 3 phosphors and anti-counterfeiting applications1Structural, optical and electrical properties of Eu doped sodium borosilicate and lead silicate glasses4Synthesis, Structure and Luminescence Properties of Novel Red-Emitting Na2SrSi2O6:Eu3+ Phosphors5Well-Organized Single White-Emitting GdMoBO6:Eu3+, Tb3+, Dy3+/Bi3+ Phosphors Enabled by the Energy Transfer Process for White LED-Based Indoor Lighting6The multichannel fluorescence emission of europium(III) complex based on dehydroabietic acid derivative for detection of haloacetic acids0A novel red-emitting Cd2CaTeO6: Eu3+ phosphor with abnormal thermal quenching properties for personal identification and w-LEDs16Formation of mineral-like phases in the system Sr9In(PO4)7–Ca9Ln(PO4)70The extremely efficient and luminous-thermal-stable red phosphor based on new layered and rigid phosphate12Rational synthesis of Eu3+ and Yb3+ single −doped and co-doped Ba0.5Sr0.5TiO3 phosphors for dynamic anti-counterfeiting and fingerprint recognition applications7The efficient fluorescence probe for haloacetic acids detection based on the Eu(III) complex constructed by dehydroabietic amine and phenanthroline0Structure and luminescence properties of Eu 3+ -activated GaGd 2 SbO 7 for light-emitting diodes3Highly thermally stable La3SnGa5O14: Sm3+ orange-red phosphors for optical thermometers and fingerprint detection8Eu3+ doped LiCaGd(MoO4)3 red phosphors for WLED applications5Near-white emission in Ba2Sc2B4O11: Bi3+, Eu3+ phosphors exhibiting magnetic and electric dipole transition variations4Ba3EuGa2O7.5 red-emitting phosphor combining anti-thermal quenching with high efficiency for white light-emitting diodes and latent fingerprint1Enhanced Thermal Stability in Eu 3+ -Doped Phosphors by Red-Shifting the Charge Transfer Band8Highly transparent and color-neutral Eu 3+ -doped glass luminescent solar concentrators for scalable BIPV integration3Eu 2+ Luminescence Stabilization at Ln 3+ Sites Promoted by Interstitial Alkali‐Metal Defects5Color-tunable and persistent luminescence of ZGGO: Bi3+/Eu3+ phosphors for dynamic multimode anti-counterfeiting3Water-dispersed smart Eu(III)-induced nanocarriers of polystyrene-b-poly(acrylic acid) for co-delivery and pH-responsive controlled release of drug0A novel red-emitting NaSrTiTaO6:Eu3+ phosphor for application in high CRI w-LEDs and latent fingerprints4Synthesis and luminescent properties of novel double perovskite Ca2SrWO6: Eu3+ red phosphor1Monocapped square antiprism geometry enhanced far-red emission in CaLuAlO4:Eu3+ with high thermal stability for versatile applications0Synthesis, photoluminescence, and application potential of reddish-orange emitting Eu3+-Doped BaSN phosphors0The Eu 3+ ‐Based Luminescent Marker—A Powerful Tool for Fast Monitoring of Ce 4+ /Ce 3+ Transitions in Ru/Ceria‐Based Catalysts0

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  1. Crystal structure, luminescence properties and thermal stability of BaY 2−x Eu x Ge 3 O 10 phosphors with high colour purity for blue-excited pc-LEDs

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  2. Design of core–shell phosphors with tunable luminescence and improved thermal stability by coating with g-C 3 N 4

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  3. Efficient and stable Sr 3 Eu 2 B 4 O 12 red phosphor benefiting from low symmetry and distorted local environment

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  4. Structural modulation induced intensity enhancement of full color spectra: a case of Ba 3 ZnTa 2−x Nb x O 9 :Eu 3+ phosphors

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  8. Color Tuning from Greenish-Yellow to Orange-Red in Thermal-Stable KBaY(MoO4)3:Dy3+, Eu3+ Phosphors via Energy Transfer for UV W-LEDs

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  9. In‐air self‐reduction synthesis and colour tunable luminescence from SrBPO5:Eu2+–Eu3+ excited using ultraviolet light

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  10. Tuning luminescence and excellent thermal stability of Gd4.67Si3O13: Bi3+, Eu3+ with energy transfer from Bi3+ to Eu3+

    Ceramics International · 2020-06-08

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  11. A red phosphor LaSc3(BO3)4:Eu3+ with zero-thermal-quenching and high quantum efficiency for LEDs

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  12. Deep-Tissue Temperature Sensing Realized in BaY2O4:Yb3+/Er3+ with Ultrahigh Sensitivity and Extremely Intense Red Upconversion Luminescence

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  13. Structure and tunable luminescence in Sm3+/Er3+ doped host-sensitized LaNbO4 phosphor by energy transfer

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  14. Why Do Relative Intensities of Charge Transfer and Intra-4f Transitions of Eu3+ Ion Invert in Yttrium Germanate Hosts? Unravelling the Underlying Intricacies from Experimental and Theoretical Investigations

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  15. Design of a bi-functional NaScF4: Yb3+/Er3+ nanoparticles for deep-tissue bioimaging and optical thermometry through Mn2+ doping

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  16. Hetero-valent substitution strategy toward orange-red luminescence in Bi3+ doped layered perovskite oxide phosphors for high color rendering index white light-emitting diodes

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  17. Structural origins of carbon quantum dot luminescence by synchrotron x-ray spectroscopy

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  18. Remotely control Eu2+ emissions by modulating structural ordering of PO4 anion-groups in (Sr3-xCax)Ce(PO4)3:Eu2+ phosphors

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  19. Ba 3 YB 3 O 9 based phosphor ceramic plates with excellent thermal stability for wLED applications

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  21. Enhanced local symmetry achieved zero-thermal-quenching luminescence characteristic in the Ca2InSbO6:Sm3+ phosphors for w-LEDs

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  23. Daylight-White-Emitting and Abnormal Thermal Antiquenching Phosphors Based on a Layered Host SrIn 2 (P 2 O 7 ) 2

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  24. Thermally stable and highly efficient red-emitting Eu3+-doped Cs3GdGe3O9 phosphors for WLEDs: non-concentration quenching and negative thermal expansion

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  25. The composition engineering of red‐emitting Eu 3+ ‐doped Ca 10.5 (PO 4 ) 7 ‐type solid solution phosphors and application in LED

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  26. Investigation of the structural and photoluminescence properties of Eu3+ doped Na6CaP2O9 phosphors for solid state lighting

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  27. In‐air self‐reduction synthesis and luminescence properties from Mg21Ca4Na4(PO4)18:Eu2+–Eu3+ excited using ultraviolet light

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  29. Performance improvement of Si solar cell via down - Conversion and plasmonic processes using Eu3+ doped TeO2-GeO2-PbO glasses with silver nanoparticles as cover layer

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  30. In‐doped LiCa 2.98 MgV 3 O 12 rare‐earth‐free phosphor with a high photoluminescence quantum yield of 67.4%

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  31. Ultrasensitive optical thermometer based on abnormal thermal quenching Stark transitions operating beyond 1500 nm

    Journal of the American Ceramic Society · 2021-06-23

    Guotao Xiang, Meng‐Lin Yang, Qing Hua Xia, Sha Jiang, Yongjie Wang, Xianju Zhou, Li Li, Li Ma, Xiaojun Wang, Jiahua Zhang

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  32. Amorphous Alumina: A Bright Red Matrix for Flexible and Transparent Anti-counterfeiting

    ACS Sustainable Chemistry & Engineering · 2021-07-16

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  33. Enhanced up-conversion luminescence and temperature sensing property of Ba3-xSrxLu4O9:Tm3+/Yb3+ phosphors

    Ceramics International · 2021-08-12

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  34. Phase transition and enhanced photoluminescence behaviour of rare earth activated ZnMoO4@(GO/r/GO) nanocomposites

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  35. Increasing Doping Solubility of RE3+ Ions in Fergusonite BiVO4 via Pressure-Induced Phase Transition

    The Journal of Physical Chemistry C · 2021-09-29

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  36. Dependence of Luminous Performance on Eu3+ Site Occupation in SrIn2(P2O7)2: The Effect of the Local Environment

    Inorganic Chemistry · 2021-10-25

    Yijia Liu, Guihua Li, Rongrong Wang, Gemei Cai

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  37. Highly efficient and thermally stable Eu3+ activated phosphate based phosphors for wLEDs: An experimental and DFT study

    Journal of Alloys and Compounds · 2021-11-10

    Mohan Lal Meena, Chung‐Hsin Lu, Sudipta Som, Rajneesh Chaurasiya, Shawn D. Lin

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  38. Enhancement of Eu2+ photoluminescence behavior in NaBaB9O15 based on the K+ doping

    Journal of Luminescence · 2021-12-01

    Guihua Li, Pingfan Wu, Bo Ye, Gemei Cai

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  39. The Charge Transfer Band as a Key to Study the Site Selection Preference of Eu3+ in Inorganic Crystals

    Inorganic Chemistry · 2021-12-07

    Jingyu Feng, Zhiying Wang, Hanyu Xu, Mochen Jia, Yanling Wei, Zuoling Fu

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  40. Emerging near-unity internal quantum efficiency and color purity from red-emitting phosphors for warm white LED with enhanced color rendition

    Journal of Alloys and Compounds · 2021-12-10

    Liangling Sun, Yuanyuan Liu, Bin Wang, Shengchun Yang

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  41. Co-crystallization of red emitting (NH 4 ) 3 Sc(SO 4 ) 3 :Eu 3+ microfibers: structure–luminescence relationship for promising application in optical thermometry

    CrystEngComm · 2022-01-01

    Л.А. Пасечник, Alena O. Peshehonova, Olga A. Lipina, Ирина Сергеевна Медянкина, Andrey N. Enyashin, Alexander Yu. Chufarov, Alexander P. Tyutyunnik

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  42. Phase Transition from La2ti2o7 to Latio3 Induced by Li+ Doping: Enhanced Local Symmetry and Particle Uniformity Achieved an Efficient Mn4+ Activated Far Red Phosphor for Agricultural Cultivation

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  43. Revealing Eu 3+ -doped yttrium pyrogermanate as a soft UV excitable phosphor: retaining the pros of the commercial phosphor and compensating for the cons

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  45. Regulation of Local Site Structures to Stabilize Mixed-Valence Eu2+/3+ under a Reducing Atmosphere for Multicolor Photoluminescence

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  46. Enhancing the photoluminescence performance of Ca5(PO4)2SiO4:Re3+ (Re = Eu, Sm) phosphors with A3+ (A = La, Bi) codoping and white light-emitting diode application

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  47. Tuning of emission by effect of local symmetry in BaLaLiWO6:Dy3+/Eu3+ for WLEDs

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  48. Luminescence and structural properties of Ca1-xZrO3:Eux: An experimental and theoretical approach

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  49. Change from La2Ti2O7 to LaTiO3 induced by Li2CO3 addition: Higher local symmetry and particle uniformity achieved an efficient Mn4+ activated far red phosphor for agricultural cultivation

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  50. Photoluminescence properties of Ba3In2WO9: Eu3+: a novel red-emitting phosphor for WLEDs

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