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RESEARCH PAPER · Journal of the American Chemical Society · 2019

Rational Design via Synergistic Combination Leads to an Outstanding Deep-Ultraviolet Birefringent Li2Na2B2O5 Material with an Unvalued B2O5 Functional Gene

Min Zhang, Donghai An, Cong Hu, Xinglong Chen, Zhihua Yang, Shilie Pan

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Rational Design via Synergistic Combination Leads to an Outstanding Deep-Ultraviolet Birefringent Li2Na2B2O5 Material with an Unvalued B2O5 Functional GeneOriginalBa 3 Ca 4 (BO 3 ) 3 (SiO 4 )Cl: a new non-centrosymmetric complex alkaline-earth metal borosilicate chloride with a deep-ultraviolet cut-off edge19CO(NH 2 ) 2 ·NH 4 Cl: an ultraviolet birefringent material with conjugated CO groups16From centrosymmetric to noncentrosymmetric: cation-directed structural evolution in X 3 ZnB 5 O 10 (X = Na, K, Rb) and Cs 12 Zn 4 (B 5 O 10 ) 4 crystals26K 2 [B 4 O 5 (OH) 4 ]·H 2 O and K 2 [B 4 O 5 (OH) 4 ]: two new hydrated potassium borates with isolated [B 4 O 5 (OH) 4 ] 2− units and different structural frameworks8Li 3 Ba 4 Sc 3 (BO 3 ) 4 (B 2 O 5 ) 2 : featuring the coexistence of isolated BO 3 and B 2 O 5 units18LiO 4 tetrahedra lock the alignment of π-conjugated layers to maximize optical anisotropy in metal hydroisocyanurates44Sr[B(OH) 4 ](IO 3 ) and Li 4 Sr 5 [B 12 O 22 (OH) 4 ](IO 3 ) 2 : two unprecedented metal borate-iodates showing a subtle balance of enlarged band gap and birefringence34β‐CsB9O14: A Triple‐Layered Borate with Edge‐Sharing BO4 Tetrahedra Exhibiting a Short Cutoff Edge and a Large Birefringence30Parallel Alignment of π-Conjugated Anions in Hydroisocyanurates Enhancing Optical Anisotropy25Research and Development of Zincoborates: Crystal Growth, Structural Chemistry and Physicochemical Properties20Growth and optical properties of a promising Deep-ultraviolet birefringent crystal Ba2Mg(BO3)236How To Maximize Birefringence and Nonlinearity of π-Conjugated Cyanurates327K5B19O31: A Deep‐Ultraviolet Congruent Melting Compound6Sn2B5O9Cl: A Material with Large Birefringence Enhancement Activated Prepared via Alkaline‐Earth‐Metal Substitution by Tin255Sn2B5O9Cl: A Material with Large Birefringence Enhancement Activated Prepared via Alkaline‐Earth‐Metal Substitution by Tin33Pb 3 Ba 3 Zn 6 (BO 3 ) 8 and α-BaZn 2 (BO 3 ) 2 : new members of the zincoborates containing two different dimensional Zn–O units8A new iodate-phosphate Pb 2 (IO 3 )(PO 4 ) achieving great improvement in birefringence activated by (IO 3 ) − groups53“Old dog, new tricks”: the lone pair effect inducing divergent optical responses in lead cyanurates containing π-bonds18Rb3Na(H2C3N3O3)4·3H2O with Large Birefringence28(NH 4 ) 3 [B(OH) 3 ] 2 (COOH) 3 : a graphite-like UV nonlinear optical material with a large birefringence via structural optimization31[Al(H 2 O) 6 ](IO 3 ) 2 (NO 3 ): a material with enhanced birefringence induced by synergism of two superior functional motifs29[O 2 Pb 3 ] 2 (BO 3 )I: a new lead borate iodide with 1∞[O 2 Pb 3 ] double chains6Enhanced optical anisotropy via dimensional control in alkali-metal chalcogenides18Facile synthesis of cesium trithiocyanurate with high ionic conductivity and large birefringence properties17From BaAl 2 (BO 3 ) 2 O to SnAl 2 (BO 3 ) 2 F 2 : structure transformation based on ion regulation3From BiF 3 to BiF 3 ·H 2 O: diverse Bi( iii ) coordination for structural transformation and birefringence regulation14Large optical polarizability causing positive effects on the birefringence of planar-triangular BO 3 groups in ternary borates18M 4 LiBe 4 P 7 O 24 and M 4 Li(Li 3 P)P 7 O 24 (M = Cs, Rb): deep-ultraviolet nonlinear-optical phosphates with a tetrahedra-substituted paracelsian-like framework9Optimal arrangement of π-conjugated anionic groups in hydro-isocyanurates leads to large optical anisotropy and second-harmonic generation effect42Te 3 O 3 (PO 4 ) 2 : a phosphate crystal with large birefringence activated by the highly distorted [TeO 5 ] group and antiparallel [PO 4 ] pseudo-layer33An Unprecedented Antimony(III) Borate with Strong Linear and Nonlinear Optical Responses224An Unprecedented Antimony(III) Borate with Strong Linear and Nonlinear Optical Responses42An Exceptional Peroxide Birefringent Material Resulting from d–π Interactions99An Exceptional Peroxide Birefringent Material Resulting from d–π Interactions15ZnIO3F: Zinc Iodate Fluoride with Large Birefringence and Wide Band Gap57Enhanced nonlinear optical functionality in birefringence and refractive index dispersion of the deep-ultraviolet fluorooxoborates123Strong Second Harmonic Generation in a Tungsten Bronze Oxide by Enhancing Local Structural Distortion48Li4Ca2B8O16: A Borate with a Unique Fundamental Building Block and a Short Cutoff Edge14New Alkaline-Earth Metal Fluoroiodates Exhibiting Large Birefringence and Short Ultraviolet Cutoff Edge with Highly Polarizable (IO 3 F) 2– Units63High Coordinate Metal Iodate Chlorides with Diverse Structural Motifs and Tunable Birefringence10Gadolinium-Rich Borate Gd 17.33 (BO 3 ) 4 (B 2 O 5 ) 2 O 16 Exhibiting a Magnetocaloric Effect24CsHgNO3Cl2: A New Nitrate UV Birefringent Material Exhibiting an Optimized Layered Structure49Series of Crystals with Giant Optical Anisotropy: A Targeted Strategic Research19Series of Crystals with Giant Optical Anisotropy: A Targeted Strategic Research140Ba 2 B 7 O 12 F with novel FBB [B 7 O 16 F] and deep-ultraviolet cut-off edge31Giant Optical Anisotropy in the UV‐Transparent 2D Nonlinear Optical Material Sc(IO 3 ) 2 (NO 3 )212Giant Optical Anisotropy in the UV‐Transparent 2D Nonlinear Optical Material Sc(IO 3 ) 2 (NO 3 )57α‐SnF 2 : A UV Birefringent Material with Large Birefringence and Easy Crystal Growth24α‐SnF 2 : A UV Birefringent Material with Large Birefringence and Easy Crystal Growth210Origin of ultra-wide IR transmission and ultra-large birefringence of mercurous halide series with one dimensional chain-like structure: An ab initio study15AB 11 O 16 (OH) 2 (A = K and Cs): interpenetrating 2D layers with large birefringence7Borates: A Rich Source for Optical Materials1089Synergism of multiple functional chromophores significantly enhancing the birefringence in layered non-centrosymmetric chalcohalides20The synthesis, characterization, and theoretical analysis of (NH 4 ) 3 PbCl 52Sn3B8O15: A Ternary Tin(II) Borate with Flexible [B8O18]12– Fundamental Building Block Formed by [B7O16]11– and [BO3]3– Groups10A new rare-earth borate birefringent crystal with quasi-two-dimensional [BO 3 ] layers23Ba 4 Ca(B 2 O 5 ) 2 F 2 : π-conjugation of B 2 O 5 in the planar pentagonal layer achieving large second harmonic generation of pyro -borate34Barium fluoroiodate crystals with a large band gap and birefringence22Distinctive modulation of optical anisotropy by halogens in α/β-Cd–P–X (X = Cl, Br, and I)2From BaCl 2 to Ba(NO 3 )Cl: significantly enhanced birefringence derived from π-conjugated [NO 3 ]14K 2 Pb(H 2 C 3 N 3 O 3 ) 4 (H 2 O) 4 : a potential UV nonlinear optical material with large birefringence50LaTeBO 5 : a new borotellurite with a large birefringence activated by the highly distorted [Te (iv) O 4 ] group16Li 5 Cs(SO 4 ) 3 : a potential zero-order wave plate material with short deep-ultraviolet cutoff edge20Na 2 La 2 B 10 O 19 : a new lanthanum sodium borate with infinite 2D layer 2∞[B 10 O 19 ] 8− and moderate birefringence4Pb 2.28 Ba 1.72 B 10 O 19 featuring a three-dimensional B–O anionic network with edge-sharing [BO 4 ] obtained under ambient pressure6Two bismuth iodate sulfates with enhanced optical anisotropy17New Polymorphism for Ba3Zn2(BO3)3F with Two Polymorphs Exhibiting Anomalous Phase Transition2Na3Bi(IO3)6: An Alkali-Metal Bismuth Iodate with Intriguing One-Dimensional [BiI6O18] Chains and Pressure-Induced Structural Transition11The First Positive Uniaxial Cyanurate Crystals Containing a Crown-like Anionic Group Arrangement and Strengthened Optical Anisotropy17Fluorine‐Driven Enhancement of Birefringence in the Fluorooxosulfate: A Deep Evaluation from a Joint Experimental and Computational Study139Na2Rb2SrB18O30 with [B9O19]11− fundamental building block consisting of three [B3O7]5− groups5Li3La2(BO3)3 and Li1.75Na1.25La2(BO3)3: A Great Enhancement in Birefringence Induced by Optimal Arrangement of π-Conjugated [BO3] Units28Tunable Circularly Polarized Luminescence from Single Crystal and Powder of the Simplest Tetraphenylethylene Helicate87Achieving Short‐Wavelength Phase‐Matching Second Harmonic Generation in Boron‐Rich Borosulfate with Planar [BO3] Units102Achieving Short‐Wavelength Phase‐Matching Second Harmonic Generation in Boron‐Rich Borosulfate with Planar [BO3] Units9LiB9O15·H2dap·H2O: A Cotemplated Acentric Layer-Pillared Borate Built by Mixed Oxoboron Clusters12Polymorphic Pb14O8I12 and Pb7O4I6 oxyhalides featuring unprecedented [O8Pb14] clusters with broad IR transparency20Enhancement of band gap and birefringence induced via π -conjugated chromophore with “tail effect”28From β‐Na2B6O10 to Na3AlB8O15 and Na3Al2B7O15: Structural Tuning of Anionic‐Group Architectures by Substitution of [BO4] by [AlO4] Covalent Tetrahedra10CsCu 3 SbS 4 : rational design of a two-dimensional layered material with giant birefringence derived from Cu 3 SbS 442K 3 V 2 O 3 F 4 (IO 3 ) 3 : a high-performance SHG crystal containing both five and six-coordinated V 5+ cations33Ba 2 B 5 O 8 (OH) 2 (NO 3 )·3H 2 O: the design of an alkaline earth metal borate-nitrate optimized from a hydroxylic borate4( R )- and ( S )-[C 8 H 10 NO 3 ] 2 [NbOF 5 ]: noncentrosymmetric niobium oxyfluorides with large optical anisotropy3(C 3 N 6 H 7 ) 2 SiF 6 ·H 2 O: an ultraviolet birefringent crystal exceeding the intrinsic energy gap of an organic reagent38A flexible functional module to regulate ultraviolet optical nonlinearity for achieving a balance between a second-harmonic generation response and birefringence43Ba 2 Zn 2 B 6 O 13 : coplanar [B 2 O 5 ] in unnoted U-shaped [B 6 O 13 ] groups achieving large birefringence6CsB 3 O 4 (OH) 2 : a new deep-ultraviolet birefringent crystal with [B 3 O 4 (OH) 2 ] anionic group8Hexameric poly-fluoroberyllophosphate Na 4 Be 2 PO 4 F 5 with moderate birefringence and deep-ultraviolet transmission as a potential zero-order-waveplate crystal17Inducing large birefringence by enhancing asymmetric electron distribution of Y–O polyhedra21KF·B(OH) 3 : a KBBF-type material with large birefringence and remarkable deep-ultraviolet transparency33KRE(CO 3 ) 2 (RE = Eu, Gd, Tb): new mixed metal carbonates with strong photoluminescence and large birefringence15Li 7 SrScB 12 O 24 and Li 7 Ba 0.6 Ca 0.4 ScB 12 O 24 : two new quaternary rare-earth borates with short UV cutoff edges4Na 2 SrB 16 O 26 : a new borate with independent interpenetrating B–O networks and deep-ultraviolet cutoff edge4Na 3 YB 8 O 15 : a new rare-earth borate with an infinite one-dimensional [B 8 O 15 ] ∞ chain and a short ultraviolet cutoff edge8NH 4 (B 6 PO 10 (OH) 4 )·H 2 O: exhibiting the largest birefringence in borophosphates43Pb 2 Al 2 B 3 O 8 F 3 : structure and properties of a new fluoroaluminoborate with non-traditional chain-like B 3 O 8 groups4Rbcl·(H2seo3)2: A New Salt-Inclusion Selenite as a Promising Uv Birefringent Material0Crystal Structure and Theoretical Analysis of Cs2Ca3(SO4)47Review of Heteroleptic Tetrahedra as Birefringent or Nonlinear Optical Motifs17MM′B3O4F3 (M = K; M′ = Na, K, Cs): Alkali-Metal Fluorooxoborates with ∞1[B3O4F3] Chains and Deep-Ultraviolet Cutoff Edges12Potential optical functional crystals with large birefringence: Recent advances and future prospects322Two Indium Iodate–Nitrates with Large Birefringence Induced by Hybrid Anionic Functional Groups and Their Favorable Arrangements22Advances in second-order nonlinear optical sulfates38Layered Perovskite-like Nitrate Cs2Pb(NO3)2Br2 as a Multifunctional Optical Material40CsY(SO4)2·4H2O: A Deep-Ultraviolet Birefringent Crystal Induced by an Edge-Sharing Connection26LiB5O5F2(OH)4: A new deep-ultraviolet birefringent crystal with [B5O5F2(OH)4] anionic group28Synthesis, crystal structure and optical properties of the first bromine-containing iodate: Pb2IO3Br30Promising Deep‐Ultraviolet Birefringent Materials via Rational Design and Assembly of Planar π‐Conjugated [B(OH)3] and [B3O3(OH)3] Functional Species6Promising Deep‐Ultraviolet Birefringent Materials via Rational Design and Assembly of Planar π‐Conjugated [B(OH)3] and [B3O3(OH)3] Functional Species83Double‐Modification Oriented Design of a Deep‐UV Birefringent Crystal Functionalized by [B12O16F4(OH)4] Clusters9Double‐Modification Oriented Design of a Deep‐UV Birefringent Crystal Functionalized by [B12O16F4(OH)4] Clusters139Enhancement of Birefringence in Borophosphate Pushing Phase-Matching into the Short-Wavelength Region150Yin–Yang Complementarity Strategy Achieving Giant Optical Anisotropy in a Metal-free Birefringent Material C(NH2)3(HC4O4)14Rearrangement of [B2O5] Dimers within [B7O14] Clusters Enables Enhanced Optical Anisotropy in Li3Cs6Al2B14O28F4Enhanced low-field magnetocaloric effect in Dy-doped hexagonal GdBO3 compounds18An excellent deep-ultraviolet birefringent material based on [BO2]∞ infinite chains185NaB3O4F(OH): A Hydroxyfluorooxoborate with One-Dimensional Chain Featuring Large Birefringence and Short Ultraviolet Cutoff Edge5Deep Ultraviolet-Transparent Materials with Strong Second-Harmonic Response50(C3N6H7)2SbF5·H2O Exhibiting Strong Optical Anisotropy from the Optimal Arrangement of π-Conjugated (C3N6H7)+ Groups31Tailored Ordered Structures with Functional Units of Distorted [NbO6] and Antiparallel [GeO4] for Enhanced Birefringence in Germanate Crystal15KC9H5O6(H2O): A Promising UV Nonlinear-Optical Material with Large Birefringence Based on a π-Conjugated (C9H5O6)−Group11A new birefringent material, HfF2(IO3)2, with a large birefringence and improved overall performances achieved by the integration of functional groups19ZrF2(IO3)2 and RbGaF3(IO3): Two Promising Birefringent Crystals Featuring 1D Metal-Fluoride Cationic Chains and Wide Bandgaps22Ba6Zn6(B3O6)6(B6O12): Barium Zinc Borate Contains π-Conjugated [B3O6]3– Anions and [B6O12]6– Anion with Edge-Sharing BO4 Tetrahedra36Achieving effective balance between bandgap and birefringence by confining π-conjugation in an optically anisotropic crystal39RE(OH) 2 NO 3 (RE = Tb, Dy, Ho, and Er): Synthesis and Nonlinear Optical Properties of Water-Resistant Lanthanide Hydroxide Nitrates15Li2PbB2O5: A Pyroborate with Large Birefringence Induced by the Synergistic Effect of Stereochemical Active Lone Pair Cations and π-Conjugated [B2O5] Groups14Li0.5Na0.5AlB2O4F2: Fluoroaluminoborate with Aligned 1∞[BO2] Chain Induced by Unprecedented [AlO3F3]6− Species Features Enhanced Birefringence30Giant low-field magnetocaloric effect in hexagonal Eu3B2O6 compound13Aluminoborates as Nonlinear Optical Materials79Aluminoborates as Nonlinear Optical Materials14RbCl·(H2SeO3)2: A Salt-Inclusion Selenite Featuring Short UV Cut-Off Edge and Large Birefringence15Dramatically improved optical anisotropy by realizing stereochemically active lone pairs in a sulfate system, K 2 SO 4 ·HIO 323Enhancing birefringence of non-π-conjugated sulfate systems through rare-earth metal-centered polyhedra10Evaluating refractive index and birefringence of nonlinear optical crystals: Classical methods and new developments45K 5 [B 3 O 3 F 4 (OH)] 2 (NO 3 ): the first hydroxyfluorooxoborate-nitrate with a short ultraviolet cutoff edge and large birefringence18KMB 4 O 6 F 3 (M = Co, Fe): two-dimensional magnetic fluorooxoborates with triangular lattices directed by triangular BO 3 units16KRb 2 (NO 3 ) 2 Cl: a new birefringent crystal exhibiting a perovskite-related framework and a short cutoff edge6Li2AB5O8F2 (A = Na and K): two new deep-ultraviolet transparent fluorooxoborates with moderate birefringence designed by targeted dimensional modulation7Linear π-conjugated units of the D ∞h point group as superior ultraviolet birefringent units1Mg assists in modulating the dimensionalities of the anionic frameworks of borates1Recent advances on the synthesis of Sb(III)-based inorganic ultraviolet nonlinear optical materials47Recent progress in borate-based short-wavelength nonlinear optical crystals with boron–oxygen skeleton modification28Synthesis and characterization of Cs 2 Zn 4 V 4 O 15 —a new vanadate in the Cs–Zn–V–O quaternary system5Synthesis, structures and properties of two new selenite optical materials: K 2 Zn 3 Se 4 O 12 and K 4 Zn 3 V 4 Se 2 O 192β-(C 3 H 7 N 6 ) 2 Cl 2 ·H 2 O and (C 3 H 7 N 6 )F·H 2 O: two UV birefringent crystals induced by uniformly aligned structural groups35BaB2P2O8F2: A Fluoroborophosphate with [B2P2O8F2]∞ Layers and Deep-Ultraviolet Cutoff Edge4Pb2Cl2(HPO3)(H2O) and Pb3Br2(HPO3)2: Two Phosphite Halides with 3D Structural Networks and Enlarged Birefringence18Rational Design of the First Ammonium Magnesium Borate with Deep-Ultraviolet Cutoff Edge and Moderate Birefringence and Further Investigation into the Nature of Ammonium in the Borate System15Two Carboxylate-Cyanurates with Strong Optical Anisotropy and Large Band Gaps6

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  1. Ba 3 Ca 4 (BO 3 ) 3 (SiO 4 )Cl: a new non-centrosymmetric complex alkaline-earth metal borosilicate chloride with a deep-ultraviolet cut-off edge

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  2. CO(NH 2 ) 2 ·NH 4 Cl: an ultraviolet birefringent material with conjugated CO groups

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  3. From centrosymmetric to noncentrosymmetric: cation-directed structural evolution in X 3 ZnB 5 O 10 (X = Na, K, Rb) and Cs 12 Zn 4 (B 5 O 10 ) 4 crystals

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  4. K 2 [B 4 O 5 (OH) 4 ]·H 2 O and K 2 [B 4 O 5 (OH) 4 ]: two new hydrated potassium borates with isolated [B 4 O 5 (OH) 4 ] 2− units and different structural frameworks

    New Journal of Chemistry · 2019-01-01

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  5. Li 3 Ba 4 Sc 3 (BO 3 ) 4 (B 2 O 5 ) 2 : featuring the coexistence of isolated BO 3 and B 2 O 5 units

    New Journal of Chemistry · 2019-01-01

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  6. LiO 4 tetrahedra lock the alignment of π-conjugated layers to maximize optical anisotropy in metal hydroisocyanurates

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  7. Sr[B(OH) 4 ](IO 3 ) and Li 4 Sr 5 [B 12 O 22 (OH) 4 ](IO 3 ) 2 : two unprecedented metal borate-iodates showing a subtle balance of enlarged band gap and birefringence

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  8. β‐CsB9O14: A Triple‐Layered Borate with Edge‐Sharing BO4 Tetrahedra Exhibiting a Short Cutoff Edge and a Large Birefringence

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  9. Parallel Alignment of π-Conjugated Anions in Hydroisocyanurates Enhancing Optical Anisotropy

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  11. Growth and optical properties of a promising Deep-ultraviolet birefringent crystal Ba2Mg(BO3)2

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  13. K5B19O31: A Deep‐Ultraviolet Congruent Melting Compound

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  14. Sn2B5O9Cl: A Material with Large Birefringence Enhancement Activated Prepared via Alkaline‐Earth‐Metal Substitution by Tin

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  15. Sn2B5O9Cl: A Material with Large Birefringence Enhancement Activated Prepared via Alkaline‐Earth‐Metal Substitution by Tin

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  16. Pb 3 Ba 3 Zn 6 (BO 3 ) 8 and α-BaZn 2 (BO 3 ) 2 : new members of the zincoborates containing two different dimensional Zn–O units

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  17. A new iodate-phosphate Pb 2 (IO 3 )(PO 4 ) achieving great improvement in birefringence activated by (IO 3 ) − groups

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  18. “Old dog, new tricks”: the lone pair effect inducing divergent optical responses in lead cyanurates containing π-bonds

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  19. Rb3Na(H2C3N3O3)4·3H2O with Large Birefringence

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  20. (NH 4 ) 3 [B(OH) 3 ] 2 (COOH) 3 : a graphite-like UV nonlinear optical material with a large birefringence via structural optimization

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  21. [Al(H 2 O) 6 ](IO 3 ) 2 (NO 3 ): a material with enhanced birefringence induced by synergism of two superior functional motifs

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  22. [O 2 Pb 3 ] 2 (BO 3 )I: a new lead borate iodide with 1∞[O 2 Pb 3 ] double chains

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  23. Enhanced optical anisotropy via dimensional control in alkali-metal chalcogenides

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  24. Facile synthesis of cesium trithiocyanurate with high ionic conductivity and large birefringence properties

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  25. From BaAl 2 (BO 3 ) 2 O to SnAl 2 (BO 3 ) 2 F 2 : structure transformation based on ion regulation

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  26. From BiF 3 to BiF 3 ·H 2 O: diverse Bi( iii ) coordination for structural transformation and birefringence regulation

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  27. Large optical polarizability causing positive effects on the birefringence of planar-triangular BO 3 groups in ternary borates

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  28. M 4 LiBe 4 P 7 O 24 and M 4 Li(Li 3 P)P 7 O 24 (M = Cs, Rb): deep-ultraviolet nonlinear-optical phosphates with a tetrahedra-substituted paracelsian-like framework

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  29. Optimal arrangement of π-conjugated anionic groups in hydro-isocyanurates leads to large optical anisotropy and second-harmonic generation effect

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  30. Te 3 O 3 (PO 4 ) 2 : a phosphate crystal with large birefringence activated by the highly distorted [TeO 5 ] group and antiparallel [PO 4 ] pseudo-layer

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  31. An Unprecedented Antimony(III) Borate with Strong Linear and Nonlinear Optical Responses

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  32. An Unprecedented Antimony(III) Borate with Strong Linear and Nonlinear Optical Responses

    Angewandte Chemie · 2020-02-14

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  33. An Exceptional Peroxide Birefringent Material Resulting from d–π Interactions

    Angewandte Chemie International Edition · 2020-03-18

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  34. An Exceptional Peroxide Birefringent Material Resulting from d–π Interactions

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  35. ZnIO3F: Zinc Iodate Fluoride with Large Birefringence and Wide Band Gap

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  36. Enhanced nonlinear optical functionality in birefringence and refractive index dispersion of the deep-ultraviolet fluorooxoborates

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  37. Strong Second Harmonic Generation in a Tungsten Bronze Oxide by Enhancing Local Structural Distortion

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  38. Li4Ca2B8O16: A Borate with a Unique Fundamental Building Block and a Short Cutoff Edge

    Inorganic Chemistry · 2020-06-01

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  39. New Alkaline-Earth Metal Fluoroiodates Exhibiting Large Birefringence and Short Ultraviolet Cutoff Edge with Highly Polarizable (IO 3 F) 2– Units

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  40. High Coordinate Metal Iodate Chlorides with Diverse Structural Motifs and Tunable Birefringence

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  41. Gadolinium-Rich Borate Gd 17.33 (BO 3 ) 4 (B 2 O 5 ) 2 O 16 Exhibiting a Magnetocaloric Effect

    Inorganic Chemistry · 2020-07-10

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  42. CsHgNO3Cl2: A New Nitrate UV Birefringent Material Exhibiting an Optimized Layered Structure

    Inorganic Chemistry · 2020-08-26

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  43. Series of Crystals with Giant Optical Anisotropy: A Targeted Strategic Research

    Angewandte Chemie · 2020-10-07

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  44. Series of Crystals with Giant Optical Anisotropy: A Targeted Strategic Research

    Angewandte Chemie International Edition · 2020-10-07

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  45. Ba 2 B 7 O 12 F with novel FBB [B 7 O 16 F] and deep-ultraviolet cut-off edge

    Inorganic Chemistry Frontiers · 2020-10-30

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  46. Giant Optical Anisotropy in the UV‐Transparent 2D Nonlinear Optical Material Sc(IO 3 ) 2 (NO 3 )

    Angewandte Chemie International Edition · 2020-11-04

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  47. Giant Optical Anisotropy in the UV‐Transparent 2D Nonlinear Optical Material Sc(IO 3 ) 2 (NO 3 )

    Angewandte Chemie · 2020-11-04

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  48. α‐SnF 2 : A UV Birefringent Material with Large Birefringence and Easy Crystal Growth

    Angewandte Chemie · 2020-11-10

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  49. α‐SnF 2 : A UV Birefringent Material with Large Birefringence and Easy Crystal Growth

    Angewandte Chemie International Edition · 2020-11-10

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  50. Origin of ultra-wide IR transmission and ultra-large birefringence of mercurous halide series with one dimensional chain-like structure: An ab initio study

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