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RESEARCH PAPER · Inorganic Chemistry · 2019

Parallel Alignment of π-Conjugated Anions in Hydroisocyanurates Enhancing Optical Anisotropy

Xianghe Meng, Fei Liang, Jian Tang, Kaijin Kang, Tixian Zeng, Wenlong Yin, Ruixin Guo, Zheshuai Lin, Mingjun Xia

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Parallel Alignment of π-Conjugated Anions in Hydroisocyanurates Enhancing Optical AnisotropyOriginalLiO 4 tetrahedra lock the alignment of π-conjugated layers to maximize optical anisotropy in metal hydroisocyanurates44Facile Growth of an Ultraviolet Hydroisocyanurate Crystal with Strong Nonlinearity and a Wide Phase-Matching Region from π-Conjugated (HC3N3O3)2– Groups45How To Maximize Birefringence and Nonlinearity of π-Conjugated Cyanurates327“Old dog, new tricks”: the lone pair effect inducing divergent optical responses in lead cyanurates containing π-bonds18Rb3Na(H2C3N3O3)4·3H2O with Large Birefringence28Structural Diversity and Giant Birefringence in Cyanates BaCNOX (X = Cl, Br, I, and CNO) Containing Linear π-Conjugated Units: A Combined Experimental and Theoretical Study13Enhanced optical anisotropy via dimensional control in alkali-metal chalcogenides18Hydroisocyanurates X 2 Y(H 2 C 3 N 3 O 3 ) 4 ·4H 2 O (X = K, Cs; Y = Zn, Cd) with large birefringence stemming from π-conjugated (H 2 C 3 N 3 O 3 ) − anions28Optimal arrangement of π-conjugated anionic groups in hydro-isocyanurates leads to large optical anisotropy and second-harmonic generation effect42Rb 3 BaTeB 7 O 15 : a novel [B 7 O 16 ] fundamental building block in a new telluroborate with [TeO 3 ] polyhedra11A(H3C3N3O3)(NO3) (A = K, Rb): Alkali-Metal Nitrate Isocyanurates with Strong Optical Anisotropy47High Coordinate Metal Iodate Chlorides with Diverse Structural Motifs and Tunable Birefringence10A UV birefringent crystal: RbNH4(H2C3N3O3)2·2H2O14Mechanochemical Synthesis of an Ionic Cocrystal with Large Birefringence Resulting from Neutral Planar π-Conjugated Groups26K 2 Pb(H 2 C 3 N 3 O 3 ) 4 (H 2 O) 4 : a potential UV nonlinear optical material with large birefringence50Two metal-free cyanurate crystals with a large optical birefringence resulting from the combination of π-conjugated units17Cyanurates consisting of intrinsic planar π-conjugated 6-membered rings: An emerging source of optical functional materials111Tin Chloride Sulfates A3Sn2(SO4)3–xCl1+2x (A = K, Rb, Cs; x = 0, 1) as Multifunctional Optical Materials33Structure-performance relationship in tri-coordinated nonlinear optical materials toward optimal second harmonic generation and phase matching31Noncentrosymmetric (C3H7N6)6(H2PO4)4(HPO4)·4H2O and Centrosymmetric (C3H7N6)2SO4·2H2O: Exploration of Acentric Structure by Combining Planar and Tetrahedral Motifs via Hydrogen Bonds37Two Mixed Alkali Metal Isocyanurates with Wide Band Gap and Giant Birefringence2Diversity of Structures and Bonding in Alkali Metal Ureaphosphanes3Sr2Zn(C3N3O3)2: An Alkaline Earth and d10 Transition Metal Based Ultraviolet Cyanurate with Large Birefringence6A one-pot method in water to synthesize a new cyanurate K(H 2 C 3 N 3 O 3 )·H 2 O with large birefringence2The condensation of π-conjugated units: a new paradigm for designing high-performance optical crystals4

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  1. LiO 4 tetrahedra lock the alignment of π-conjugated layers to maximize optical anisotropy in metal hydroisocyanurates

    Inorganic Chemistry Frontiers · 2019-01-01

    Xianghe Meng, Fei Liang, Jian Tang, Kaijin Kang, Wenlong Yin, Tixian Zeng, Bin Kang, Zheshuai Lin, Mingjun Xia

    Read original paper ↗ ·

  2. Facile Growth of an Ultraviolet Hydroisocyanurate Crystal with Strong Nonlinearity and a Wide Phase-Matching Region from π-Conjugated (HC3N3O3)2– Groups

    Inorganic Chemistry · 2019-08-15

    Xianghe Meng, Fei Liang, Kaijin Kang, Jian Tang, Tixian Zeng, Zheshuai Lin, Mingjun Xia

    Read original paper ↗ ·

  3. How To Maximize Birefringence and Nonlinearity of π-Conjugated Cyanurates

    Journal of the American Chemical Society · 2019-09-12

    Jing Lu, Yu‐Kun Lian, Lin Xiong, Qianru Wu, Min Zhao, Ke-Xin Shi, Ling Chen, Li‐Ming Wu

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  4. “Old dog, new tricks”: the lone pair effect inducing divergent optical responses in lead cyanurates containing π-bonds

    Dalton Transactions · 2019-12-11

    Xianghe Meng, Kaijin Kang, Fei Liang, Jian Tang, Zheshuai Lin, Wenlong Yin, Mingjun Xia

    Read original paper ↗ ·

  5. Rb3Na(H2C3N3O3)4·3H2O with Large Birefringence

    ACS Omega · 2019-12-13

    Mukeremu Aibibula, Li Wang, Shuzhao Huang

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  6. Structural Diversity and Giant Birefringence in Cyanates BaCNOX (X = Cl, Br, I, and CNO) Containing Linear π-Conjugated Units: A Combined Experimental and Theoretical Study

    Crystal Growth & Design · 2019-12-27

    Jian Tang, Xianghe Meng, Fei Liang, Kaijin Kang, Tixian Zeng, Mingjun Xia, Wenlong Yin, Zheshuai Lin, Bin Kang

    Read original paper ↗ ·

  7. Enhanced optical anisotropy via dimensional control in alkali-metal chalcogenides

    Physical Chemistry Chemical Physics · 2020-01-01

    Jingmei Min, Ailijiang Abudurusuli, Junjie Li, Shilie Pan, Zhihua Yang

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  8. Hydroisocyanurates X 2 Y(H 2 C 3 N 3 O 3 ) 4 ·4H 2 O (X = K, Cs; Y = Zn, Cd) with large birefringence stemming from π-conjugated (H 2 C 3 N 3 O 3 ) − anions

    CrystEngComm · 2020-01-01

    Kaijin Kang, Xianghe Meng, Fei Liang, Jian Tang, Tixian Zeng, Wenlong Yin, Zheshuai Lin, Mingjun Xia

    Read original paper ↗ ·

  9. Optimal arrangement of π-conjugated anionic groups in hydro-isocyanurates leads to large optical anisotropy and second-harmonic generation effect

    Inorganic Chemistry Frontiers · 2020-01-01

    Xianghe Meng, Kaijin Kang, Fei Liang, Jian Tang, Wenlong Yin, Zheshuai Lin, Mingjun Xia

    Read original paper ↗ ·

  10. Rb 3 BaTeB 7 O 15 : a novel [B 7 O 16 ] fundamental building block in a new telluroborate with [TeO 3 ] polyhedra

    Dalton Transactions · 2020-01-01

    Jun Sun, Miriding Mutailipu, Shichao Cheng, Zhihua Yang, Shilie Pan

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  11. A(H3C3N3O3)(NO3) (A = K, Rb): Alkali-Metal Nitrate Isocyanurates with Strong Optical Anisotropy

    Inorganic Chemistry · 2020-06-28

    Xia Hao, Min Luo, Chensheng Lin, Guang Peng, Tao Yan, Donghong Lin, Liling Cao, Xifa Long, Guangsai Yang, Ning Ye

    Read original paper ↗ ·

  12. High Coordinate Metal Iodate Chlorides with Diverse Structural Motifs and Tunable Birefringence

    Crystal Growth & Design · 2020-07-07

    Ying‐Jie Jia, Yi-Gang Chen, Ting Wang, Yao Guo, Xiao‐Fang Guan, Xian‐Ming Zhang

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  13. A UV birefringent crystal: RbNH4(H2C3N3O3)2·2H2O

    Inorganic Chemistry Communications · 2020-07-27

    Mukeremu Aibibula, Li Wang

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  14. Mechanochemical Synthesis of an Ionic Cocrystal with Large Birefringence Resulting from Neutral Planar π-Conjugated Groups

    Crystal Growth & Design · 2020-11-10

    Xianghe Meng, Kaijin Kang, Youquan Liu, Jian Tang, Xingxing Jiang, Wenlong Yin, Zheshuai Lin, Mingjun Xia

    Read original paper ↗ ·

  15. K 2 Pb(H 2 C 3 N 3 O 3 ) 4 (H 2 O) 4 : a potential UV nonlinear optical material with large birefringence

    Inorganic Chemistry Frontiers · 2021-01-01

    Yan Chen, Chun‐Li Hu, Zhi Gang Fang, Jiang‐Gao Mao

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  16. Two metal-free cyanurate crystals with a large optical birefringence resulting from the combination of π-conjugated units

    Dalton Transactions · 2021-01-01

    Xiaomeng Liu, Lei Kang, Ruixin Guo, Zheshuai Lin

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  17. Cyanurates consisting of intrinsic planar π-conjugated 6-membered rings: An emerging source of optical functional materials

    Coordination Chemistry Reviews · 2021-04-14

    Xianghe Meng, Wenlong Yin, Mingjun Xia

    Read original paper ↗ ·

  18. Tin Chloride Sulfates A3Sn2(SO4)3–xCl1+2x (A = K, Rb, Cs; x = 0, 1) as Multifunctional Optical Materials

    Inorganic Chemistry · 2021-05-14

    Yuwei Ge, Qiang Wang, Fei Yang, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

    Read original paper ↗ ·

  19. Structure-performance relationship in tri-coordinated nonlinear optical materials toward optimal second harmonic generation and phase matching

    Coordination Chemistry Reviews · 2021-06-08

    Fengjuan Hou, Dajiang Mei, Mingjun Xia, Yuandong Wu

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  20. Noncentrosymmetric (C3H7N6)6(H2PO4)4(HPO4)·4H2O and Centrosymmetric (C3H7N6)2SO4·2H2O: Exploration of Acentric Structure by Combining Planar and Tetrahedral Motifs via Hydrogen Bonds

    Inorganic Chemistry · 2022-06-16

    Shu‐Fang Li, Liang Hu, Yao Ma, Fei‐Fei Mao, Jie Zheng, Xiu‐Du Zhang, Dong Yan

    Read original paper ↗ ·

  21. Two Mixed Alkali Metal Isocyanurates with Wide Band Gap and Giant Birefringence

    Crystal Growth & Design · 2024-05-15

    Xinyue Wang, Jinhui Wang, Xinyuan Zhang, Fei Liang, Zhanggui Hu, Yicheng Wu

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  22. Diversity of Structures and Bonding in Alkali Metal Ureaphosphanes

    Helvetica Chimica Acta · 2024-05-28

    Michelle H. Crabbe, Alan Robert Kennedy, Catherine Weetman, Robert E. Mulvey

    Read original paper ↗ ·

  23. Sr2Zn(C3N3O3)2: An Alkaline Earth and d10 Transition Metal Based Ultraviolet Cyanurate with Large Birefringence

    Inorganic Chemistry · 2025-02-03

    N.F. Wang, Xinyuan Zhang, Fei Liang, Zhanggui Hu, Yicheng Wu

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  24. A one-pot method in water to synthesize a new cyanurate K(H 2 C 3 N 3 O 3 )·H 2 O with large birefringence

    Dalton Transactions · 2025-11-17

    Bingheng Ji, Chu Chu, Bingbing Zhang, Jian Wang

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  25. The condensation of π-conjugated units: a new paradigm for designing high-performance optical crystals

    Chemical Society Reviews · 2026-01-01

    Hangwei Jia, Bailin Chen, Fangfang Zhang, Xueling Hou, Shilie Pan

    Read original paper ↗ ·
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