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RESEARCH PAPER · Chemistry - A European Journal · 2019

β‐CsB9O14: A Triple‐Layered Borate with Edge‐Sharing BO4 Tetrahedra Exhibiting a Short Cutoff Edge and a Large Birefringence

Shujuan Han, Chunmei Huang, Abudukadi Tudi, Shuaishuai Hu, Zhihua Yang, Shilie Pan

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β‐CsB9O14: A Triple‐Layered Borate with Edge‐Sharing BO4 Tetrahedra Exhibiting a Short Cutoff Edge and a Large BirefringenceOriginalResearch and Development of Zincoborates: Crystal Growth, Structural Chemistry and Physicochemical Properties20Sr 5 TeO 2 (BO 3 ) 4 and NaSr 5 (BO 3 )(SiO 4 ) 2 : two inorganic metal borate derivatives with diverse zero dimensional anions21Rb3Na(H2C3N3O3)4·3H2O with Large Birefringence28Effect of anion dimensionality on optical properties: the ∞ [B 7 O 10 (OH) 2 ] layer in CsB 7 O 10 (OH) 2 vs. the ∞ [B 7 O 12 ] framework in CsBaB 7 O 1219High-temperature, high-pressure hydrothermal synthesis, crystal structure, and infrared and NMR spectroscopy of a barium lead borate with a 2D layer structure: [Ba 3 Pb(H 2 O)][B 11 O 19 (OH) 3 ]6Synthesis, characterization and crystal structure of a new mixed alkali and alkaline-earth metal borate Rb 9 Ba 24 (BO 3 ) 196La3B6O13(OH): The First Acentric High‐Pressure Borate Displaying Edge‐Sharing BO4 Tetrahedra25Two New Ferroborates with Three‐Dimensional Framework and Wide Transmittance Window2Flux synthesis and characterization of two barium hydroxyborosilicates with triple and single tetrahedral layers: Ba2[Si3B3O12(OH)] and Ba[Si2BO6(OH)]3Li4Ca2B8O16: A Borate with a Unique Fundamental Building Block and a Short Cutoff Edge14Ba3(BO3)(CO3)F: The First Borate Carbonate Fluoride Synthesized by the High‐Temperature Solution Method19Y 2 (Te 4 O 10 )(SO 4 ): a new sulfate tellurite with a unique Te 4 O 10 polyanion and large birefringence36Synthesis, crystal structure and luminescence properties of a new samarium borate phosphate, CsNa2Sm2(BO3)(PO4)24High-pressure synthesis of REB5O8(OH)2 (RE = Ho, Er, Tm)3Borates: A Rich Source for Optical Materials1089A new rare-earth borate birefringent crystal with quasi-two-dimensional [BO 3 ] layers23Li 5 Cs(SO 4 ) 3 : a potential zero-order wave plate material with short deep-ultraviolet cutoff edge20Pb 2.28 Ba 1.72 B 10 O 19 featuring a three-dimensional B–O anionic network with edge-sharing [BO 4 ] obtained under ambient pressure6Three mixed-alkaline-metal borates with {Li@B 12 O x (OH) 24− x } ( x = 18, 22) clusters: from isolated oxoboron cluster to unusual layer11Toward the Coordination Fingerprint of the Edge-Sharing BO4 Tetrahedra9Bi2[B2(SeO3)6]: A Metal Boroselenite with a Unique Zero-Dimensional [B2(SeO3)6]6– Anionic Group and Large Birefringence31NaRbB3O4F3: A New Fluorooxoborate with a Short UV Cutoff Edge Enriching the Structural Chemistry of Borate7Edge-sharing BO 4 tetrahedra and penta-coordinated silicon in the high-pressure modification of NaBSi 3 O 814Sc 2 F 2 (B 2 O 5 ): a deep ultraviolet scandium borate fluoride exhibiting large birefringence induced by the synergistic effect of B 2 O 5 and ScO n F 2 groups38Design of New Borates with Deep Ultraviolet Transparency Inspired by the Flexibility of Unusual Triple-Layered Frameworks3Hydroxylherderite (Ca 2 Be 2 P 2 O 8 (OH) 2 ) stability under extreme conditions (up to 750°C/100 GPa)6Topologically prone or cation compression restricted phase transition: An example of feldspar-related SrGe2B2O82The transformation of a zero-dimensional cluster into a one-dimensional chain structure achieving a dramatically enhanced birefringence in tin( ii )-based oxalates33Recent Progress in Crystalline Borates with Edge-Sharing BO4 Tetrahedra21REV 3 (BO 3 ) 4 (RE = La–Nd): a series of rare earth vanadoborates exhibit large birefringence induced by distorted V III O 6 groups2

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  1. Research and Development of Zincoborates: Crystal Growth, Structural Chemistry and Physicochemical Properties

    Molecules · 2019-07-30

    Yanna Chen, Min Zhang, Miriding Mutailipu, Kenneth Reinhard Poeppelmeier, Shilie Pan

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  2. Sr 5 TeO 2 (BO 3 ) 4 and NaSr 5 (BO 3 )(SiO 4 ) 2 : two inorganic metal borate derivatives with diverse zero dimensional anions

    Dalton Transactions · 2019-10-27

    Ru‐Ling Tang, Chun‐Li Hu, Jianghe Feng, Zhi Gang Fang, Yan Chen, Fang Kong, Jiang‐Gao Mao

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  3. Rb3Na(H2C3N3O3)4·3H2O with Large Birefringence

    ACS Omega · 2019-12-13

    Mukeremu Aibibula, Li Wang, Shuzhao Huang

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  4. Effect of anion dimensionality on optical properties: the ∞ [B 7 O 10 (OH) 2 ] layer in CsB 7 O 10 (OH) 2 vs. the ∞ [B 7 O 12 ] framework in CsBaB 7 O 12

    Dalton Transactions · 2019-12-30

    Zhaohong Miao, Yun Mo Yang, Zhonglei Wei, Zhihua Yang, Shilie Pan

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  5. High-temperature, high-pressure hydrothermal synthesis, crystal structure, and infrared and NMR spectroscopy of a barium lead borate with a 2D layer structure: [Ba 3 Pb(H 2 O)][B 11 O 19 (OH) 3 ]

    Dalton Transactions · 2020-01-01

    Yu-Chen Kuo, Hsin‐Kuan Liu, Sue‐Lein Wang, Kwang‐Hwa Lii

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  6. Synthesis, characterization and crystal structure of a new mixed alkali and alkaline-earth metal borate Rb 9 Ba 24 (BO 3 ) 19

    New Journal of Chemistry · 2020-01-01

    Xiaowen Niu, Li Wang

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  7. La3B6O13(OH): The First Acentric High‐Pressure Borate Displaying Edge‐Sharing BO4 Tetrahedra

    Chemistry - A European Journal · 2020-01-14

    Birgit Fuchs, Günter Heymann, Xuefei Wang, Abudukadi Tudi, Lkhamsuren Bayarjargal, Renée Siegel, Adrian Schmutzler, Jürgen Senker, Bastian Joachim, Andreas Saxer, Zhihua Yang, Shilie Pan, Hubert Huppertz

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  8. Two New Ferroborates with Three‐Dimensional Framework and Wide Transmittance Window

    European Journal of Inorganic Chemistry · 2020-03-19

    Huimin Song, Naizheng Wang, Yunfei Li, Wang Liu, Zheshuai Lin, Jiyong Yao, Guochun Zhang

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  9. Flux synthesis and characterization of two barium hydroxyborosilicates with triple and single tetrahedral layers: Ba2[Si3B3O12(OH)] and Ba[Si2BO6(OH)]

    Journal of Solid State Chemistry · 2020-03-24

    Ling-Wei Chang, Hsin‐Kuan Liu, Kwang‐Hwa Lii

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  10. Li4Ca2B8O16: A Borate with a Unique Fundamental Building Block and a Short Cutoff Edge

    Inorganic Chemistry · 2020-06-01

    Peng Rong Ren, Yun Mo Yang, Ming Wen, Hao Li, Zhihua Yang, Shilie Pan

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  11. Ba3(BO3)(CO3)F: The First Borate Carbonate Fluoride Synthesized by the High‐Temperature Solution Method

    Chemistry - A European Journal · 2020-09-25

    Chunmei Huang, Fangfang Zhang, Shichao Cheng, Zhihua Yang, Hao Li, Shilie Pan

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  12. Y 2 (Te 4 O 10 )(SO 4 ): a new sulfate tellurite with a unique Te 4 O 10 polyanion and large birefringence

    Inorganic Chemistry Frontiers · 2020-10-26

    Pengfei Li, Chun‐Li Hu, Fang Kong, Shao‐Ming Ying, Jiang‐Gao Mao

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  13. Synthesis, crystal structure and luminescence properties of a new samarium borate phosphate, CsNa2Sm2(BO3)(PO4)2

    Acta Crystallographica Section C Structural Chemistry · 2020-11-13

    Dan Zhao, Lin-Ying Shi, Rui-Juan Zhang, Ya-Li Xue

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  14. High-pressure synthesis of REB5O8(OH)2 (RE = Ho, Er, Tm)

    Zeitschrift für Naturforschung B · 2020-12-04

    Michael Zoller, Hubert Huppertz

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  15. Borates: A Rich Source for Optical Materials

    Chemical Reviews · 2020-12-14

    Miriding Mutailipu, Kenneth Reinhard Poeppelmeier, Shilie Pan

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  16. A new rare-earth borate birefringent crystal with quasi-two-dimensional [BO 3 ] layers

    Journal of Materials Chemistry C · 2021-01-01

    Hongyuan Sha, Bingxuan Li, Zheyao Xiong, Zujian Wang, Caiping Liu, Rongbing Su, Chao He, Xiaoming Yang, Xifa Long

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  17. Li 5 Cs(SO 4 ) 3 : a potential zero-order wave plate material with short deep-ultraviolet cutoff edge

    New Journal of Chemistry · 2021-01-01

    Yuchen Yan, Yanna Chen, Bao Jiang, Qun Jing, Jun Zhang

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  18. Pb 2.28 Ba 1.72 B 10 O 19 featuring a three-dimensional B–O anionic network with edge-sharing [BO 4 ] obtained under ambient pressure

    Inorganic Chemistry Frontiers · 2021-01-01

    Siru Guo, Wenbin Zhang, Rong Yang, Min Zhang, Zhihua Yang, Shilie Pan

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  19. Three mixed-alkaline-metal borates with {Li@B 12 O x (OH) 24− x } ( x = 18, 22) clusters: from isolated oxoboron cluster to unusual layer

    CrystEngComm · 2021-01-01

    Qi–Ming Qiu, Guo‐Yu Yang

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  20. Toward the Coordination Fingerprint of the Edge-Sharing BO4 Tetrahedra

    Inorganic Chemistry · 2021-01-21

    Éric Quarez, Éric Gautron, Michaël Paris, David Gajan, Jean‐Yves Mevellec

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  21. Bi2[B2(SeO3)6]: A Metal Boroselenite with a Unique Zero-Dimensional [B2(SeO3)6]6– Anionic Group and Large Birefringence

    Inorganic Chemistry · 2021-03-02

    Ru‐Ling Tang, Chun‐Li Hu, Weijie Xie, Q. Huang, Jiang‐Gao Mao

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  22. NaRbB3O4F3: A New Fluorooxoborate with a Short UV Cutoff Edge Enriching the Structural Chemistry of Borate

    Chemistry - An Asian Journal · 2021-08-20

    Rui Zhang, Jie Zhang, Zhihua Yang, Shujuan Han, Shilie Pan

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  23. Edge-sharing BO 4 tetrahedra and penta-coordinated silicon in the high-pressure modification of NaBSi 3 O 8

    Inorganic Chemistry Frontiers · 2022-01-01

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  24. Sc 2 F 2 (B 2 O 5 ): a deep ultraviolet scandium borate fluoride exhibiting large birefringence induced by the synergistic effect of B 2 O 5 and ScO n F 2 groups

    Inorganic Chemistry Frontiers · 2022-01-01

    Ru‐Ling Tang, Wei Xu, Weijie Xie, Chun‐Li Hu

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  25. Design of New Borates with Deep Ultraviolet Transparency Inspired by the Flexibility of Unusual Triple-Layered Frameworks

    Crystal Growth & Design · 2022-06-13

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  26. Hydroxylherderite (Ca 2 Be 2 P 2 O 8 (OH) 2 ) stability under extreme conditions (up to 750°C/100 GPa)

    Journal of the American Ceramic Society · 2022-12-04

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  27. Topologically prone or cation compression restricted phase transition: An example of feldspar-related SrGe2B2O8

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  28. The transformation of a zero-dimensional cluster into a one-dimensional chain structure achieving a dramatically enhanced birefringence in tin( ii )-based oxalates

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  29. Recent Progress in Crystalline Borates with Edge-Sharing BO4 Tetrahedra

    Molecules · 2023-06-28

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  30. REV 3 (BO 3 ) 4 (RE = La–Nd): a series of rare earth vanadoborates exhibit large birefringence induced by distorted V III O 6 groups

    Chemical Communications · 2026-01-01

    Yu-Long Wei, Wen-Dong Yao, Yi‐Lei Lv, Liang Ma, Ru‐Ling Tang

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