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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2019

Ba 3 Ca 4 (BO 3 ) 3 (SiO 4 )Cl: a new non-centrosymmetric complex alkaline-earth metal borosilicate chloride with a deep-ultraviolet cut-off edge

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Ba 3 Ca 4 (BO 3 ) 3 (SiO 4 )Cl: a new non-centrosymmetric complex alkaline-earth metal borosilicate chloride with a deep-ultraviolet cut-off edgeOriginalFull-visible-spectrum lighting realized by a novel Eu 2+ -doped cyan-emitting borosilicate phosphor25K 4 (PO 2 F 2 ) 2 (S 2 O 7 ): first fluorooxophosphorsulfate with mixed-anion [S 2 O 7 ] 2− and [PO 2 F 2 ] − groups14Synthesis, characterization and crystal structure of a new mixed alkali and alkaline-earth metal borate Rb 9 Ba 24 (BO 3 ) 196Flux synthesis and characterization of two barium hydroxyborosilicates with triple and single tetrahedral layers: Ba2[Si3B3O12(OH)] and Ba[Si2BO6(OH)]3A new acentric borate–nitrate Cs 3 B 8 O 13 (NO 3 ) with interpenetrating porous 3D covalent and ionic lattices8High-temperature, high-pressure hydrothermal synthesis, crystal structure, and solid state NMR spectroscopy of a lead borosilicate with boron–silicon mixing: Pb 6 B 2 Si 8 O 255In situ hydrothermal synthesis of polar second-order nonlinear optical selenate Na 5 (SeO 4 )(HSeO 4 ) 3 (H 2 O) 219Hexameric poly-fluoroberyllophosphate Na 4 Be 2 PO 4 F 5 with moderate birefringence and deep-ultraviolet transmission as a potential zero-order-waveplate crystal17NaBa3[M2B7O16(OH)2]F2 (M = Ge, Si): Two Synthetic F Analogues of Garrelsite with [B7O16(OH)2]13– Polyanions and Deep-Ultraviolet Cutoff Edges8Oxychalcogenides as Promising Ultraviolet Nonlinear Optical Candidates: Experimental and Theoretical Studies of AEGeOS2(AE = Sr and Ba)24A novel broadband Ba 3 Ca 4 (BO 3 ) 3 (SiO 4 )Cl:Mn 4+ near-infrared phosphor with a special pseudo-octahedral Mn 4+ coordination structure12Mg 2 Pb 2 Si 2 O 7 F 2 : a new lead-containing alkali earth metal silicate fluoride with a short cutoff edge2Two UV optical crystals with strong optical anisotropy, large band gaps and an α-BBO type structure7Synthesis, crystal structure, and photoluminescence of new strontium barium nitrido-alumino-silicate phosphor, Sr27.9Ba22.8Al61.4Si174.6N328.4:Eu2+1Na 10 Zn(NO 3 ) 4 (SO 3 S) 4 : a nonlinear optical crystal combining inorganic π-conjugated and non-π-conjugated heteroanion groups8Cd8(BO3)4SiO4: Metal Cation Inducing the Formation of Isolated [BO3] and [SiO4] Units in Borate Silicate15Ba3Zn4Si4O15: A Novel Centrosymmetric Silicate with Isolated SiO4 and Si2O7 Units0Learning From Nature: The Rational Non‐Centrosymmetric Structural Design in the Honeycomb‐Like Gaudefroyite Family23Borosilicates as deep-ultraviolet transparent nonlinear optical crystals: Structural motifs, performance limits and future directions9

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  1. Full-visible-spectrum lighting realized by a novel Eu 2+ -doped cyan-emitting borosilicate phosphor

    CrystEngComm · 2020-01-01

    Qiang Zhang, Xicheng Wang, Yuhua Wang

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  2. K 4 (PO 2 F 2 ) 2 (S 2 O 7 ): first fluorooxophosphorsulfate with mixed-anion [S 2 O 7 ] 2− and [PO 2 F 2 ] − groups

    Dalton Transactions · 2020-01-01

    Wenyao Zhang, Wenqi Jin, Zhihua Yang, Shilie Pan

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  3. Synthesis, characterization and crystal structure of a new mixed alkali and alkaline-earth metal borate Rb 9 Ba 24 (BO 3 ) 19

    New Journal of Chemistry · 2020-01-01

    Xiaowen Niu, Li Wang

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  4. Flux synthesis and characterization of two barium hydroxyborosilicates with triple and single tetrahedral layers: Ba2[Si3B3O12(OH)] and Ba[Si2BO6(OH)]

    Journal of Solid State Chemistry · 2020-03-24

    Ling-Wei Chang, Hsin‐Kuan Liu, Kwang‐Hwa Lii

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  5. A new acentric borate–nitrate Cs 3 B 8 O 13 (NO 3 ) with interpenetrating porous 3D covalent and ionic lattices

    Dalton Transactions · 2021-01-01

    Zilong Chen, Chengfa Wu, Hao Zeng, Feng Yu

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  6. High-temperature, high-pressure hydrothermal synthesis, crystal structure, and solid state NMR spectroscopy of a lead borosilicate with boron–silicon mixing: Pb 6 B 2 Si 8 O 25

    Dalton Transactions · 2021-01-01

    Ling-Wei Chang, Kwang‐Hwa Lii

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  7. In situ hydrothermal synthesis of polar second-order nonlinear optical selenate Na 5 (SeO 4 )(HSeO 4 ) 3 (H 2 O) 2

    Inorganic Chemistry Frontiers · 2021-01-01

    Chao Wu, Xingxing Jiang, Lin Lin, Tianhui Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

    Read original paper ↗ ·
  8. Hexameric poly-fluoroberyllophosphate Na 4 Be 2 PO 4 F 5 with moderate birefringence and deep-ultraviolet transmission as a potential zero-order-waveplate crystal

    Inorganic Chemistry Frontiers · 2022-01-01

    Yuanyu Yang, Yao Guo, Yi-Gang Chen, Xiwei Hu, Xia Zhang, Xian‐Ming Zhang, Xian-Ming Zhang, Xian-Ming Zhang

    Read original paper ↗ ·
  9. NaBa3[M2B7O16(OH)2]F2 (M = Ge, Si): Two Synthetic F Analogues of Garrelsite with [B7O16(OH)2]13– Polyanions and Deep-Ultraviolet Cutoff Edges

    Inorganic Chemistry · 2022-07-05

    Weijie Xie, Chun‐Li Hu, Zhi Gang Fang, Ming‐Yang Cao, Yuan Hua Lin, Jiang‐Gao Mao

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  10. Oxychalcogenides as Promising Ultraviolet Nonlinear Optical Candidates: Experimental and Theoretical Studies of AEGeOS2(AE = Sr and Ba)

    Inorganic Chemistry · 2022-09-21

    Hedi Yang, Shenghua Zhou, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  11. A novel broadband Ba 3 Ca 4 (BO 3 ) 3 (SiO 4 )Cl:Mn 4+ near-infrared phosphor with a special pseudo-octahedral Mn 4+ coordination structure

    Dalton Transactions · 2023-01-01

    Jiutian Wang, Tao Tan, Ran Pang, Da Li, Chengyu Li, Su Zhang, Lihong Jiang, Hongjie Zhang

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  12. Mg 2 Pb 2 Si 2 O 7 F 2 : a new lead-containing alkali earth metal silicate fluoride with a short cutoff edge

    New Journal of Chemistry · 2023-01-01

    Zhiyuan Zhang, Lihan Deng, Die Xu, Mei Ying Hu, Zhencheng Wu, Xin Su, Yineng Huang

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  13. Two UV optical crystals with strong optical anisotropy, large band gaps and an α-BBO type structure

    Dalton Transactions · 2023-01-01

    Lehui Liu, Feifei Yuan, Yisheng Huang, Zhoubin Lin, Lizhen Zhang

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  14. Synthesis, crystal structure, and photoluminescence of new strontium barium nitrido-alumino-silicate phosphor, Sr27.9Ba22.8Al61.4Si174.6N328.4:Eu2+

    Journal of Alloys and Compounds · 2023-09-01

    Fumitaka Yoshimura, Hisanori Yamane

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  15. Na 10 Zn(NO 3 ) 4 (SO 3 S) 4 : a nonlinear optical crystal combining inorganic π-conjugated and non-π-conjugated heteroanion groups

    Inorganic Chemistry Frontiers · 2023-11-07

    Zihao Yu, Qingran Ding, Yuhang Jiang, Weiqi Huang, Changsheng Yang, Sangen Zhao, Junhua Luo

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  16. Cd8(BO3)4SiO4: Metal Cation Inducing the Formation of Isolated [BO3] and [SiO4] Units in Borate Silicate

    Inorganic Chemistry · 2023-12-19

    Guangsheng Xu, Huimin Li, Jian Wei Han, Xueling Hou, Zhihua Yang, Shilie Pan

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  17. Ba3Zn4Si4O15: A Novel Centrosymmetric Silicate with Isolated SiO4 and Si2O7 Units

    Zeitschrift für anorganische und allgemeine Chemie · 2024-06-19

    Aihaimaitijiang Ababaikeri, Gulimeikereyi Tuniyazi, Yanhui Zhang, Dilnur Malik

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  18. Learning From Nature: The Rational Non‐Centrosymmetric Structural Design in the Honeycomb‐Like Gaudefroyite Family

    Advanced Functional Materials · 2024-10-10

    Fanlu Bu, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  19. Borosilicates as deep-ultraviolet transparent nonlinear optical crystals: Structural motifs, performance limits and future directions

    Chinese Journal of Structural Chemistry · 2025-09-01

    Yangfeifei Ou, Xiaoliang Zhou, You‐Zhao Lan, Jian‐Wen Cheng

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