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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2019

From centrosymmetric to noncentrosymmetric: cation-directed structural evolution in X 3 ZnB 5 O 10 (X = Na, K, Rb) and Cs 12 Zn 4 (B 5 O 10 ) 4 crystals

Tuohetijiang Baiheti, Shujuan Han, Abudukadi Tudi, Zhihua Yang, Hualiang Yu, Shilie Pan

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From centrosymmetric to noncentrosymmetric: cation-directed structural evolution in X 3 ZnB 5 O 10 (X = Na, K, Rb) and Cs 12 Zn 4 (B 5 O 10 ) 4 crystalsOriginalResearch and Development of Zincoborates: Crystal Growth, Structural Chemistry and Physicochemical Properties20Partial Congener Substitution Induced Centrosymmetric to Noncentrosymmetric Transformation Witnessed by K3Ga3(Ge7–xMx)Se20 (M = Si, Sn) and Their Nonlinear Optical Properties51Pb 3 Ba 3 Zn 6 (BO 3 ) 8 and α-BaZn 2 (BO 3 ) 2 : new members of the zincoborates containing two different dimensional Zn–O units8From centrosymmetric to noncentrosymmetric: intriguing structure evolution in d 10 -transition metal iodate fluorides36Large optical polarizability causing positive effects on the birefringence of planar-triangular BO 3 groups in ternary borates18A Promising Fluorooxoborate Framework with Flexibile Capability for Diverse Cations to Enhance the Second Harmonic Generation14Cs 2 AlB 5 O 10 : a short-wavelength nonlinear optical crystal with moderate second harmonic generation response12In situ hydrothermal synthesis of polar second-order nonlinear optical selenate Na 5 (SeO 4 )(HSeO 4 ) 3 (H 2 O) 219A2(TeO)P2O7 (A = K, Rb, Cs): Three new tellurite-pyrophosphates with large birefringence17A non–centrosymmetric compound K7Li2Y2B15O30 by introducing more alkali metals into A7MRe2B15O30 family10NaK5Zn2(B5O10)2 and β-K3ZnB5O10: Two Zincoborates with Deep-UV Cutoff Edge9Rb 3 B 5 O 8 F 2 and K 0.6 Rb 2.4 B 5 O 8 F 2 : two new deep-ultraviolet transparent nonlinear optical fluorooxoborates designed by cation regulation13Rare-Earth Scandium Borate Fluoride with a Deep-Ultraviolet Cutoff Edge12From ZnF2 to ZnF2(H2O)4: Partial Substitution Achieves Structural Transformation and Nonlinear Optical Activity while Keeping Short Ultraviolet Cutoff Edge19Two Acentric Zn-Based l -Tartrates with Moderate Second Harmonic Generation Responses and Large Birefringence6Influence of Cation-Size Effects of Alkaline Earth (Ae) Metals on Dimensionality and Optical Anisotropy Regulation in K4AeP2S8 Thiophosphates5Polar-Layer-Driven Reconstruction of a Noncentrosymmetric Vandate Mid-Infrared Nonlinear-Optical Crystal10Chiral Bimetallic Cuprous-Lead Hybrid Iodide Single Crystals toward Occurrence of Second Harmonic Generation3K6NaCaRe2(B5O10)3 (Re = Y, Lu): Two NLO Compounds Exhibiting a Short Absorption Edge in the A7–xA’xAeRe2(B5O10)3 (x = 0, 1) Family4A-Site Cation Substitution toward Structural Transformation in Phosphates Exhibiting Short UV Transparency and Second Harmonic Response3Promising UV/DUV nonlinear optical materials with X-membered (X = multiples of 6) rings in anhydrous inorganic borates20Four zinc borates: From acentric chain to centric porous layer0LiV 3 Se 2 O 12 : A Promising Giant‐Birefringent Crystal Enabled by Significant Structural Distortion3Two scandium borate UV NLO crystals designed through chemical element substitution1Rational Design of a Strong Nonlinear Optical Crystal With Ultrawide Bandgap via Fine‐Tuning of Channel Structures0Three Rare‐Earth Metal Borates Synthesized via a Cation Substitution Strategy as Potential Zero‐Order Waveplate Materials0

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26 direct citing papers saved.

  1. Research and Development of Zincoborates: Crystal Growth, Structural Chemistry and Physicochemical Properties

    Molecules · 2019-07-30

    Yanna Chen, Min Zhang, Miriding Mutailipu, Kenneth Reinhard Poeppelmeier, Shilie Pan

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  2. Partial Congener Substitution Induced Centrosymmetric to Noncentrosymmetric Transformation Witnessed by K3Ga3(Ge7–xMx)Se20 (M = Si, Sn) and Their Nonlinear Optical Properties

    Inorganic Chemistry · 2019-09-25

    Xiaohui Li, Nian‐Tzu Suen, Yang Chi, Yueling Sun, Anhua Gong, Huaiguo Xue, Sheng‐Ping Guo

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  3. Pb 3 Ba 3 Zn 6 (BO 3 ) 8 and α-BaZn 2 (BO 3 ) 2 : new members of the zincoborates containing two different dimensional Zn–O units

    Inorganic Chemistry Frontiers · 2019-10-09

    Xiaobo Pan, Hongping Wu, Shichao Cheng, Zhengping Wang

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  4. From centrosymmetric to noncentrosymmetric: intriguing structure evolution in d 10 -transition metal iodate fluorides

    Chemical Communications · 2020-01-01

    Liling Cao, Min Luo, Chensheng Lin, Yuqiao Zhou, Dan Zhao, Tao Yan, Ning Ye

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  5. Large optical polarizability causing positive effects on the birefringence of planar-triangular BO 3 groups in ternary borates

    Dalton Transactions · 2020-01-01

    Xinyuan Zhou, Junben Huang, Gemei Cai, Heng-Wei Zhou, Yineng Huang, Xin Su

    Read original paper ↗ ·

  6. A Promising Fluorooxoborate Framework with Flexibile Capability for Diverse Cations to Enhance the Second Harmonic Generation

    Chemistry - A European Journal · 2020-01-16

    Shichao Cheng, Miriding Mutailipu, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  7. Cs 2 AlB 5 O 10 : a short-wavelength nonlinear optical crystal with moderate second harmonic generation response

    Dalton Transactions · 2020-12-10

    Tuohetijiang Baiheti, Shujuan Han, Wenqi Jin, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  8. In situ hydrothermal synthesis of polar second-order nonlinear optical selenate Na 5 (SeO 4 )(HSeO 4 ) 3 (H 2 O) 2

    Inorganic Chemistry Frontiers · 2021-01-01

    Chao Wu, Xingxing Jiang, Lin Lin, Tianhui Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  9. A2(TeO)P2O7 (A = K, Rb, Cs): Three new tellurite-pyrophosphates with large birefringence

    Journal of Alloys and Compounds · 2021-02-02

    Min Zhao, Weimin Dong, Yuandong Wu, Dajiang Mei, Shaoguo Wen, Thomas Doert

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  10. A non–centrosymmetric compound K7Li2Y2B15O30 by introducing more alkali metals into A7MRe2B15O30 family

    Journal of Solid State Chemistry · 2021-10-04

    Jingfang Zhou, Rukang K. Li

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  11. NaK5Zn2(B5O10)2 and β-K3ZnB5O10: Two Zincoborates with Deep-UV Cutoff Edge

    Inorganic Chemistry · 2022-10-10

    Wenjuan Ma, Jie Zhang, Feng Yu, Bin Dai

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  12. Rb 3 B 5 O 8 F 2 and K 0.6 Rb 2.4 B 5 O 8 F 2 : two new deep-ultraviolet transparent nonlinear optical fluorooxoborates designed by cation regulation

    Inorganic Chemistry Frontiers · 2022-12-06

    Ruonan Zhang, Bingliang Cheng, Xuping Wang, Rong Yang, Zhihua Yang, Shujuan Han, Shilie Pan

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  13. Rare-Earth Scandium Borate Fluoride with a Deep-Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2023-09-04

    Qianzhen Zhang, Ran An, Abudukadi Tudi, Zhihua Yang, Xifa Long, Yun Mo Yang

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  14. From ZnF2 to ZnF2(H2O)4: Partial Substitution Achieves Structural Transformation and Nonlinear Optical Activity while Keeping Short Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2024-01-17

    Yue‐Qi Wei, Wei Xu, Lei Huai, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  15. Two Acentric Zn-Based l -Tartrates with Moderate Second Harmonic Generation Responses and Large Birefringence

    Inorganic Chemistry · 2024-03-14

    Ting Yu, Jiahao Wan, Jingye Yang, Xiaokang Luo, Man Xie, Lehui Liu, Hongming Liu

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  16. Influence of Cation-Size Effects of Alkaline Earth (Ae) Metals on Dimensionality and Optical Anisotropy Regulation in K4AeP2S8 Thiophosphates

    Inorganic Chemistry · 2024-04-23

    Xinyu Tian, Ning Zhao, Kui Wu, Jingjing Xu, Dazhi Lu, Haohai Yu, Huaijin Zhang

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  17. Polar-Layer-Driven Reconstruction of a Noncentrosymmetric Vandate Mid-Infrared Nonlinear-Optical Crystal

    Inorganic Chemistry · 2024-10-28

    Haochen Li, Haotian Tian, Pifu Gong, Tianyu Wang, Qian Wu, Mingjun Xia

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  18. Chiral Bimetallic Cuprous-Lead Hybrid Iodide Single Crystals toward Occurrence of Second Harmonic Generation

    Inorganic Chemistry · 2024-12-02

    Danping Chen, Peihan Wang, Yanqing Liu, Guokui Liu, Jing Wei, Yongshen Zheng, Yangyang Dang

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  19. K6NaCaRe2(B5O10)3 (Re = Y, Lu): Two NLO Compounds Exhibiting a Short Absorption Edge in the A7–xA’xAeRe2(B5O10)3 (x = 0, 1) Family

    Inorganic Chemistry · 2024-12-19

    Wencong Li, Zhaowei Hu, Yanyan Ding, Yueting Zhu, Qun Jing, Lili Liu

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  20. A-Site Cation Substitution toward Structural Transformation in Phosphates Exhibiting Short UV Transparency and Second Harmonic Response

    Inorganic Chemistry · 2025-08-11

    Hanjing Huang, Xianghao Kong, Huijian Zhao, Ning Ye, Zhanggui Hu, Conggang Li

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  21. Promising UV/DUV nonlinear optical materials with X-membered (X = multiples of 6) rings in anhydrous inorganic borates

    Coordination Chemistry Reviews · 2025-08-26

    Bailin Chen, Shuai An, Xueling Hou, Shilie Pan

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  22. Four zinc borates: From acentric chain to centric porous layer

    Chinese Journal of Structural Chemistry · 2025-10-22

    Juan Chen, Jin-Ni Zhao, Guo‐Yu Yang

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  23. LiV 3 Se 2 O 12 : A Promising Giant‐Birefringent Crystal Enabled by Significant Structural Distortion

    Small · 2025-12-26

    Feng Qiuyuan, Jialong Wang, Qun Jing, Xiaoyu Dong, Shilie Pan

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  24. Two scandium borate UV NLO crystals designed through chemical element substitution

    Chemical Communications · 2026-01-01

    Zelong Liu, Huijian Zhao, Longyun Xu, Ning Jia, Ning Ye, Zhanggui Hu, Conggang Li

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  25. Rational Design of a Strong Nonlinear Optical Crystal With Ultrawide Bandgap via Fine‐Tuning of Channel Structures

    Laser & Photonics Review · 2026-08-15

    Zilong Geng, Zuju Ma, Ruibiao Fu, Xin-Tao Wu

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  26. Three Rare‐Earth Metal Borates Synthesized via a Cation Substitution Strategy as Potential Zero‐Order Waveplate Materials

    Advanced Optical Materials · 2026-09-30

    Bailin Chen, Yaqi Jin, Hucai Yang, Hangwei Jia, Zhihua Yang, Xueling Hou, Shilie Pan

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