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RESEARCH PAPER · Angewandte Chemie · 2019

Sn2B5O9Cl: A Material with Large Birefringence Enhancement Activated Prepared via Alkaline‐Earth‐Metal Substitution by Tin

Jingyu Guo, Abudukadi Tudi, Shujuan Han, Zhihua Yang, Shilie Pan

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Sn2B5O9Cl: A Material with Large Birefringence Enhancement Activated Prepared via Alkaline‐Earth‐Metal Substitution by TinOriginalAn Unprecedented Antimony(III) Borate with Strong Linear and Nonlinear Optical Responses224An Unprecedented Antimony(III) Borate with Strong Linear and Nonlinear Optical Responses42K 2 Sb(P 2 O 7 )F: Cairo Pentagonal Layer with Bifunctional Genes Reveal Optical Performance297K2Sb(P2O7)F: Cairo Pentagonal Layer with Bifunctional Genes Reveal Optical Performance38Series of Crystals with Giant Optical Anisotropy: A Targeted Strategic Research19Series of Crystals with Giant Optical Anisotropy: A Targeted Strategic Research140Giant Optical Anisotropy in the UV‐Transparent 2D Nonlinear Optical Material Sc(IO 3 ) 2 (NO 3 )212Giant Optical Anisotropy in the UV‐Transparent 2D Nonlinear Optical Material Sc(IO 3 ) 2 (NO 3 )57An Antimony(III) Fluoride Oxalate with Large Birefringence45Nonlinear Optical Oxythiophosphate Approaching the Good Balance with Wide Ultraviolet Transparency, Strong Second Harmonic Effect, and Large Birefringence92Nonlinear Optical Oxythiophosphate Approaching the Good Balance with Wide Ultraviolet Transparency, Strong Second Harmonic Effect, and Large Birefringence13Sb6O7(SO4)2: A Promising Ultraviolet Nonlinear Optical Material with an Enhanced Second‐Harmonic‐Generation Response Activated by SbIII Lone‐Pair Stereoactivity62M(NH 2 SO 3 ) 2 (M=Sr, Ba): Two Deep‐Ultraviolet Transparent Sulfamates Exhibiting Strong Second Harmonic Generation Responses and Moderate Birefringence142M(NH 2 SO 3 ) 2 (M=Sr, Ba): Two Deep‐Ultraviolet Transparent Sulfamates Exhibiting Strong Second Harmonic Generation Responses and Moderate Birefringence27Na2Rb2SrB18O30 with [B9O19]11− fundamental building block consisting of three [B3O7]5− groups5Hydroxyfluorooxoborate Na[B3O3F2(OH)2]⋅[B(OH)3]: Optimizing the Optical Anisotropy with Heteroanionic Units for Deep Ultraviolet Birefringent Crystals146Hydroxyfluorooxoborate Na[B3O3F2(OH)2]⋅[B(OH)3]: Optimizing the Optical Anisotropy with Heteroanionic Units for Deep Ultraviolet Birefringent Crystals16Sn2PO4I: An Excellent Birefringent Material with Giant Optical Anisotropy in Non π‐Conjugated Phosphate212Sn2PO4I: An Excellent Birefringent Material with Giant Optical Anisotropy in Non π‐Conjugated Phosphate22Hierarchical Modulation of Optical Anisotropy Driven by Metal Cation Polyhedra in Fluorooxoborates MIIB4O6F2 (MII=Be, Mg, Pb, Zn, Cd)6Introducing a New d0 Sc3+ Asymmetric Ion for Functional Materials: Large Birefringence Enhancement by ScO6 in Ba3Sc2(BO3)411Promising Deep‐Ultraviolet Birefringent Materials via Rational Design and Assembly of Planar π‐Conjugated [B(OH)3] and [B3O3(OH)3] Functional Species6Promising Deep‐Ultraviolet Birefringent Materials via Rational Design and Assembly of Planar π‐Conjugated [B(OH)3] and [B3O3(OH)3] Functional Species83An Optically Anisotropic Crystal with Large Birefringence Arising from Cooperative π Orbitals81An Optically Anisotropic Crystal with Large Birefringence Arising from Cooperative π Orbitals22Intense d‐p Hybridization in Nb3O15 Tripolymer Induced the Largest Second Harmonic Generation Response and Birefringence in Germanates51Intense d‐p Hybridization in Nb3O15 Tripolymer Induced the Largest Second Harmonic Generation Response and Birefringence in Germanates7Deep Eutectic Solvents Synthesis of A2Sb(C2O4)Cl3 (A = NH4, K, Rb) with Superior Optical Performance26Metal Methanesulfonates with Mixed Anionic Groups with Large Band Gaps and Enhanced Birefringence50Highly Polarizable Phosphorus‐Centered Tetrahedra and π‐Conjugated Carbon‐Centered Triangular Moieties Inducing Large Anisotropy and Short‐Wavelength Phase‐Matching23Confinement π‐Conjugated Moiety Tailoring to Achieve Record Deep‐UV Nonlinearity in Sulfates0Electronegativity Adaption Approach for Solar‐Blind UV Birefringent Crystals With Ultrawide Bandgaps1Three Rare‐Earth Metal Borates Synthesized via a Cation Substitution Strategy as Potential Zero‐Order Waveplate Materials0

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  1. An Unprecedented Antimony(III) Borate with Strong Linear and Nonlinear Optical Responses

    Angewandte Chemie International Edition · 2020-02-14

    Youchao Liu, Xiaomeng Liu, Shuai Liu, Qingran Ding, Yanqiang Li, Lina Li, Sangen Zhao, Zheshuai Lin, Junhua Luo, Maochun Hong

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  2. An Unprecedented Antimony(III) Borate with Strong Linear and Nonlinear Optical Responses

    Angewandte Chemie · 2020-02-14

    Youchao Liu, Xiaomeng Liu, Shuai Liu, Qingran Ding, Yanqiang Li, Lina Li, Sangen Zhao, Zheshuai Lin, Junhua Luo, Maochun Hong

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  3. K 2 Sb(P 2 O 7 )F: Cairo Pentagonal Layer with Bifunctional Genes Reveal Optical Performance

    Angewandte Chemie International Edition · 2020-08-03

    Yalan Deng, Ling Huang, Xuehua Dong, Lei Wang, Kang Min Ok, Hongmei Zeng, Zhien Lin, Guohong Zou

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  4. K2Sb(P2O7)F: Cairo Pentagonal Layer with Bifunctional Genes Reveal Optical Performance

    Angewandte Chemie · 2020-08-03

    Yalan Deng, Ling Huang, Xuehua Dong, Lei Wang, Kang Min Ok, Hongmei Zeng, Zhien Lin, Guohong Zou

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  5. Series of Crystals with Giant Optical Anisotropy: A Targeted Strategic Research

    Angewandte Chemie · 2020-10-07

    Tinghao Tong, Wenyao Zhang, Zhihua Yang, Shilie Pan

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  6. Series of Crystals with Giant Optical Anisotropy: A Targeted Strategic Research

    Angewandte Chemie International Edition · 2020-10-07

    Tinghao Tong, Wenyao Zhang, Zhihua Yang, Shilie Pan

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  7. Giant Optical Anisotropy in the UV‐Transparent 2D Nonlinear Optical Material Sc(IO 3 ) 2 (NO 3 )

    Angewandte Chemie International Edition · 2020-11-04

    Chao Wu, Xingxing Jiang, Zujian Wang, Lin Lin, Zheshuai Lin, Zhipeng Huang, Xifa Long, Mark Graeme Humphrey, Chi Zhang

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  8. Giant Optical Anisotropy in the UV‐Transparent 2D Nonlinear Optical Material Sc(IO 3 ) 2 (NO 3 )

    Angewandte Chemie · 2020-11-04

    Chao Wu, Xingxing Jiang, Zujian Wang, Lin Lin, Zheshuai Lin, Zhipeng Huang, Xifa Long, Mark Graeme Humphrey, Chi Zhang

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  9. An Antimony(III) Fluoride Oxalate with Large Birefringence

    Chemistry - A European Journal · 2020-12-10

    Yangxin Chen, Zhangxian Chen, Zhou Yang, Yanqiang Li, Youchao Liu, Qingran Ding, Xin Chen, Sangen Zhao, Junhua Luo

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  10. Nonlinear Optical Oxythiophosphate Approaching the Good Balance with Wide Ultraviolet Transparency, Strong Second Harmonic Effect, and Large Birefringence

    Angewandte Chemie International Edition · 2020-12-20

    Xinyuan Zhang, Lei Kang, Pifu Gong, Zheshuai Lin, Yicheng Wu

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  11. Nonlinear Optical Oxythiophosphate Approaching the Good Balance with Wide Ultraviolet Transparency, Strong Second Harmonic Effect, and Large Birefringence

    Angewandte Chemie · 2020-12-21

    Xinyuan Zhang, Lei Kang, Pifu Gong, Zheshuai Lin, Yicheng Wu

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  12. Sb6O7(SO4)2: A Promising Ultraviolet Nonlinear Optical Material with an Enhanced Second‐Harmonic‐Generation Response Activated by SbIII Lone‐Pair Stereoactivity

    Chemistry - A European Journal · 2020-12-23

    Qi Wei, Chao He, Kui Wang, Xiao‐Fang Duan, Xing‐Tao An, Jinhua Li, Guo‐Ming Wang

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  13. M(NH 2 SO 3 ) 2 (M=Sr, Ba): Two Deep‐Ultraviolet Transparent Sulfamates Exhibiting Strong Second Harmonic Generation Responses and Moderate Birefringence

    Angewandte Chemie International Edition · 2021-01-19

    Xia Hao, Min Luo, Chensheng Lin, Guang Peng, Feng Xu, Ning Ye

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  14. M(NH 2 SO 3 ) 2 (M=Sr, Ba): Two Deep‐Ultraviolet Transparent Sulfamates Exhibiting Strong Second Harmonic Generation Responses and Moderate Birefringence

    Angewandte Chemie · 2021-01-19

    Xia Hao, Min Luo, Chensheng Lin, Guang Peng, Feng Xu, Ning Ye

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  15. Na2Rb2SrB18O30 with [B9O19]11− fundamental building block consisting of three [B3O7]5− groups

    Zeitschrift für anorganische und allgemeine Chemie · 2021-06-16

    Jingjing Zheng, Ting Zhang, Junwei Feng, Donghai An, Chunyan Bai, Yi Sun

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  16. Hydroxyfluorooxoborate Na[B3O3F2(OH)2]⋅[B(OH)3]: Optimizing the Optical Anisotropy with Heteroanionic Units for Deep Ultraviolet Birefringent Crystals

    Angewandte Chemie International Edition · 2021-06-21

    Congcong Jin, Xuping Shi, Hao Zeng, Shujuan Han, Zhen Chen, Zhihua Yang, Miriding Mutailipu, Shilie Pan

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  17. Hydroxyfluorooxoborate Na[B3O3F2(OH)2]⋅[B(OH)3]: Optimizing the Optical Anisotropy with Heteroanionic Units for Deep Ultraviolet Birefringent Crystals

    Angewandte Chemie · 2021-06-21

    Congcong Jin, Xuping Shi, Hao Zeng, Shujuan Han, Zhen Chen, Zhihua Yang, Miriding Mutailipu, Shilie Pan

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  18. Sn2PO4I: An Excellent Birefringent Material with Giant Optical Anisotropy in Non π‐Conjugated Phosphate

    Angewandte Chemie International Edition · 2021-09-15

    Jingyu Guo, Abudukadi Tudi, Shujuan Han, Zhihua Yang, Shilie Pan

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  19. Sn2PO4I: An Excellent Birefringent Material with Giant Optical Anisotropy in Non π‐Conjugated Phosphate

    Angewandte Chemie · 2021-09-15

    Jingyu Guo, Abudukadi Tudi, Shujuan Han, Zhihua Yang, Shilie Pan

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  20. Hierarchical Modulation of Optical Anisotropy Driven by Metal Cation Polyhedra in Fluorooxoborates MIIB4O6F2 (MII=Be, Mg, Pb, Zn, Cd)

    Chemistry - A European Journal · 2021-12-27

    Shan Shu, Junben Huang, Chenhui Hu, Shilie Pan, Zhihua Yang

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  21. Introducing a New d0 Sc3+ Asymmetric Ion for Functional Materials: Large Birefringence Enhancement by ScO6 in Ba3Sc2(BO3)4

    ChemPhysChem · 2022-02-11

    Jingfang Zhou, Rukang K. Li

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  22. Promising Deep‐Ultraviolet Birefringent Materials via Rational Design and Assembly of Planar π‐Conjugated [B(OH)3] and [B3O3(OH)3] Functional Species

    Angewandte Chemie · 2022-04-29

    Jiahao Jiao, Meng Cheng, Rong Yang, Yuchen Yan, Min Zhang, Fangfang Zhang, Zhihua Yang, Shilie Pan

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  23. Promising Deep‐Ultraviolet Birefringent Materials via Rational Design and Assembly of Planar π‐Conjugated [B(OH)3] and [B3O3(OH)3] Functional Species

    Angewandte Chemie International Edition · 2022-04-29

    Jiahao Jiao, Meng Cheng, Rong Yang, Yuchen Yan, Min Zhang, Fangfang Zhang, Zhihua Yang, Shilie Pan

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  24. An Optically Anisotropic Crystal with Large Birefringence Arising from Cooperative π Orbitals

    Angewandte Chemie International Edition · 2022-07-29

    Yanqiang Li, Xu Zhang, Zhou Yang, Weiqi Huang, Yipeng Song, Han Wang, Minjuan Li, Maochun Hong, Junhua Luo, Sangen Zhao

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  25. An Optically Anisotropic Crystal with Large Birefringence Arising from Cooperative π Orbitals

    Angewandte Chemie · 2022-07-29

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  26. Intense d‐p Hybridization in Nb3O15 Tripolymer Induced the Largest Second Harmonic Generation Response and Birefringence in Germanates

    Angewandte Chemie International Edition · 2023-01-05

    Kaichuang Chen, Chensheng Lin, Jindong Chen, Guangsai Yang, Haotian Tian, Min Luo, Tao Yan, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Ning Ye, Guang Peng

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  27. Intense d‐p Hybridization in Nb3O15 Tripolymer Induced the Largest Second Harmonic Generation Response and Birefringence in Germanates

    Angewandte Chemie · 2023-01-05

    Kaichuang Chen, Chensheng Lin, Jindong Chen, Guangsai Yang, Haotian Tian, Min Luo, Tao Yan, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Ning Ye, Guang Peng

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  28. Deep Eutectic Solvents Synthesis of A2Sb(C2O4)Cl3 (A = NH4, K, Rb) with Superior Optical Performance

    Advanced Optical Materials · 2023-01-17

    Die Zhang, Qiang Wang, Han Luo, Liling Cao, Xuehua Dong, Ling Huang, Daojiang Gao, Guohong Zou

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  29. Metal Methanesulfonates with Mixed Anionic Groups with Large Band Gaps and Enhanced Birefringence

    Chemistry of Materials · 2024-02-16

    Mingli Liang, Yujie Zhang, Eugene Izvarin, Michael J. Waters, James M. Rondinelli, P. Shiv Halasyamani

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  30. Highly Polarizable Phosphorus‐Centered Tetrahedra and π‐Conjugated Carbon‐Centered Triangular Moieties Inducing Large Anisotropy and Short‐Wavelength Phase‐Matching

    Advanced Optical Materials · 2025-01-28

    Wen-Bin Zhang, Muhammad Arif, Huan Zhou, Ran An, Zhihua Yang, Xueling Hou, Shilie Pan, Shujuan Han

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  31. Confinement π‐Conjugated Moiety Tailoring to Achieve Record Deep‐UV Nonlinearity in Sulfates

    Angewandte Chemie · 2026-03-05

    Yujie Fan, Cheng Hu, Li Wu, Chensheng Lin, Chao Wang, Huixin Fan, Tao Yan, Min Luo

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  32. Electronegativity Adaption Approach for Solar‐Blind UV Birefringent Crystals With Ultrawide Bandgaps

    Angewandte Chemie · 2026-04-23

    Xinwei Zhou, Zhiyong Bai, Ji Qi, Yuexin Zhang, Weiqi Huang, Yipeng Song, Yong Wang, Chang Liu, Sangen Zhao, Junhua Luo

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  33. Three Rare‐Earth Metal Borates Synthesized via a Cation Substitution Strategy as Potential Zero‐Order Waveplate Materials

    Advanced Optical Materials · 2026-09-30

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