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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2020

Ba 2 B 7 O 12 F with novel FBB [B 7 O 16 F] and deep-ultraviolet cut-off edge

Zhaohong Miao, Yun Mo Yang, Zhonglei Wei, Zhihua Yang, Shilie Pan

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Ba 2 B 7 O 12 F with novel FBB [B 7 O 16 F] and deep-ultraviolet cut-off edgeOriginalBaB 4 O 5 F 4 with reversible phase transition featuring unprecedented fundamental building blocks of [B 16 O 21 F 16 ] in the α -phase and [B 4 O 6 F 4 ] in the β -phase19Barium fluoroiodate crystals with a large band gap and birefringence22Li 5 Cs(SO 4 ) 3 : a potential zero-order wave plate material with short deep-ultraviolet cutoff edge20BaI 3 O 9 H: a new alkaline-earth metal hydroxy iodate with two groups2Hexameric poly-fluoroberyllophosphate Na 4 Be 2 PO 4 F 5 with moderate birefringence and deep-ultraviolet transmission as a potential zero-order-waveplate crystal17Na 2 SrB 16 O 26 : a new borate with independent interpenetrating B–O networks and deep-ultraviolet cutoff edge4MM′B3O4F3 (M = K; M′ = Na, K, Cs): Alkali-Metal Fluorooxoborates with ∞1[B3O4F3] Chains and Deep-Ultraviolet Cutoff Edges12NaBa3[M2B7O16(OH)2]F2 (M = Ge, Si): Two Synthetic F Analogues of Garrelsite with [B7O16(OH)2]13– Polyanions and Deep-Ultraviolet Cutoff Edges8Cs2B4O5(OH)4: A new hydrated borate with a short UV cutoff edge2LiNaB6O9F2: A Promising UV NLO Crystal Having Fluorine‐Directed Optimal Performances and Double Interpenetrating 3[B6O9F2]∞ Networks33Rb 3 B 5 O 8 F 2 and K 0.6 Rb 2.4 B 5 O 8 F 2 : two new deep-ultraviolet transparent nonlinear optical fluorooxoborates designed by cation regulation13BaB2P2O8F2: A Fluoroborophosphate with [B2P2O8F2]∞ Layers and Deep-Ultraviolet Cutoff Edge4Fluorooxoborates: A precious treasure of deep-ultraviolet nonlinear optical materials24Ba2B9O13F4·BF4: first fluorooxoborate with unprecedented infinite [B18O26F8] tubes and deep-ultraviolet cutoff edge14Na2BaB12O18F4: A Mixed Alkali/Alkaline-Earth Metal Fluorooxoborate with Two Unprecedented Interpenetrating Three-Dimensional B–O/F Anionic Networks and a Short Ultraviolet Cutoff Edge9Rare-Earth Scandium Borate Fluoride with a Deep-Ultraviolet Cutoff Edge12Exploration of antimony( iii ) oxyhalides via single-site substitution in quest of large birefringence10Extending Unique 1D Double-Chains to 2D Layers with Birefringent Gain by Introducing a Hydroxyl Group5Na3K6(CO3)3(NO3)2X·6H2O (X = NO3, Cl, Br): Exploring High-Performance UV Birefringent Crystals Induced by Coplanar π-Conjugated CO3 and NO3 Groups15NaRbB10O14(OH)4 and Na3CsB10O16(OH)2: Two Cases of Hydroxyborates with [B5Om(OH)n] Units and Deep Ultraviolet Cutoff Edges6The electronic structures and optical properties induced by spin-orbit-coupling in LiPbPO4 compound6Review on birefringence in borates based on birefringence-active functional groups and arrangements57Cs2Pb(CO3)2: a novel mixed-metal carbonate with rare Pb-C-O one-dimensional chain0Pb2TeV2O10: A Lead Vanadate Tellurate with Wide Mid-IR Transparency and Large Birefringence Induced by Multiple Birefringence-Active Groups11Structure and optical properties of alkali rare-earth double phosphates of M3RE(PO4)2 (M = K, Rb; RE = Y, La, and Lu)4Structural Evolution and Optical Properties of Hydroxyfluorooxoborates MM′2n-1[B3O3F4(OH)]n (M = K, Cs, and Rb; M′ = K, NH4, and Cs; n = 1, 2, and 3)12Structural modification of hydroxyborates by adjusting the number of shared oxygen atoms and hydroxyl groups for further performance enhancement1Cation tuning in anionic framework hydroborates: tailored deep-ultraviolet optical crystals with large birefringence1Size effect of cations in the A2B3O4F3 family: Based on the new member Cs2B3O4F34The Layered Structure–Induced Enhanced Birefringence of LiMgPO 4 : A First‐Principles Investigation1CsB(OH) 4 (H 2 O) 2 and Na(NH 4 ) 2 B 10 O 16 OH(H 2 O): a hydroxylation modification strategy regulates the borate structures and optical properties0

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  1. BaB 4 O 5 F 4 with reversible phase transition featuring unprecedented fundamental building blocks of [B 16 O 21 F 16 ] in the α -phase and [B 4 O 6 F 4 ] in the β -phase

    Chemical Communications · 2021-01-01

    Wenbin Zhang, Siru Guo, Shujuan Han, Liying Wang, Xin Hua Zhou, Zhihua Yang, Shilie Pan

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  2. Barium fluoroiodate crystals with a large band gap and birefringence

    Inorganic Chemistry Frontiers · 2021-01-01

    Liang Zhu, Minqiang Gai, Wenqi Jin, Yun Mo Yang, Zhihua Yang, Shilie Pan

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  3. Li 5 Cs(SO 4 ) 3 : a potential zero-order wave plate material with short deep-ultraviolet cutoff edge

    New Journal of Chemistry · 2021-01-01

    Yuchen Yan, Yanna Chen, Bao Jiang, Qun Jing, Jun Zhang

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  4. BaI 3 O 9 H: a new alkaline-earth metal hydroxy iodate with two groups

    New Journal of Chemistry · 2022-01-01

    Wenjuan Ma, Jianlong Huang, Bin Dai, Feng Yu

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  5. Hexameric poly-fluoroberyllophosphate Na 4 Be 2 PO 4 F 5 with moderate birefringence and deep-ultraviolet transmission as a potential zero-order-waveplate crystal

    Inorganic Chemistry Frontiers · 2022-01-01

    Yuanyu Yang, Yao Guo, Yi-Gang Chen, Xiwei Hu, Xia Zhang, Xian‐Ming Zhang, Xian-Ming Zhang, Xian-Ming Zhang

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  6. Na 2 SrB 16 O 26 : a new borate with independent interpenetrating B–O networks and deep-ultraviolet cutoff edge

    Dalton Transactions · 2022-01-01

    Zhikang Chen, Kewang Zhang, Bei Zhang, Jun Zhang

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  7. MM′B3O4F3 (M = K; M′ = Na, K, Cs): Alkali-Metal Fluorooxoborates with ∞1[B3O4F3] Chains and Deep-Ultraviolet Cutoff Edges

    Inorganic Chemistry · 2022-02-02

    Zhikang Chen, Kewang Zhang, Zi‐Jian Li, Fangfang Zhang, Zhihua Yang, Shilie Pan

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  8. NaBa3[M2B7O16(OH)2]F2 (M = Ge, Si): Two Synthetic F Analogues of Garrelsite with [B7O16(OH)2]13– Polyanions and Deep-Ultraviolet Cutoff Edges

    Inorganic Chemistry · 2022-07-05

    Weijie Xie, Chun‐Li Hu, Zhi Gang Fang, Ming‐Yang Cao, Yuan Hua Lin, Jiang‐Gao Mao

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  9. Cs2B4O5(OH)4: A new hydrated borate with a short UV cutoff edge

    Inorganica Chimica Acta · 2022-10-19

    Aixin Zhu, Jianbang Chen, Yanhui Zhang, Zhi Guo Su

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  10. LiNaB6O9F2: A Promising UV NLO Crystal Having Fluorine‐Directed Optimal Performances and Double Interpenetrating 3[B6O9F2]∞ Networks

    Advanced Optical Materials · 2022-12-03

    Xiaojing Li, Zilong Chen, Fuming Li, Fangfang Zhang, Zhihua Yang, Shilie Pan

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  11. Rb 3 B 5 O 8 F 2 and K 0.6 Rb 2.4 B 5 O 8 F 2 : two new deep-ultraviolet transparent nonlinear optical fluorooxoborates designed by cation regulation

    Inorganic Chemistry Frontiers · 2022-12-06

    Ruonan Zhang, Bingliang Cheng, Xuping Wang, Rong Yang, Zhihua Yang, Shujuan Han, Shilie Pan

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  12. BaB2P2O8F2: A Fluoroborophosphate with [B2P2O8F2]∞ Layers and Deep-Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2023-01-04

    Jinbin Fan, Mengfan Wu, Bingliang Cheng, Jian Wei Han

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  13. Fluorooxoborates: A precious treasure of deep-ultraviolet nonlinear optical materials

    Chinese Journal of Structural Chemistry · 2023-02-03

    Hongkang Su, Ziting Yan, Xueling Hou, Min Zhang

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  14. Ba2B9O13F4·BF4: first fluorooxoborate with unprecedented infinite [B18O26F8] tubes and deep-ultraviolet cutoff edge

    Science China Chemistry · 2023-02-23

    Huan Pei, Xuefei Wang, Jie Zhang, Fangfang Zhang, Zhihua Yang, Shilie Pan

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  15. Na2BaB12O18F4: A Mixed Alkali/Alkaline-Earth Metal Fluorooxoborate with Two Unprecedented Interpenetrating Three-Dimensional B–O/F Anionic Networks and a Short Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2023-03-16

    Tuohetijiang Baiheti, Abudukadi Tudi, Minqiang Gai, Xuping Wang, Shujuan Han

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  16. Rare-Earth Scandium Borate Fluoride with a Deep-Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2023-09-04

    Qianzhen Zhang, Ran An, Abudukadi Tudi, Zhihua Yang, Xifa Long, Yun Mo Yang

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  17. Exploration of antimony( iii ) oxyhalides via single-site substitution in quest of large birefringence

    Inorganic Chemistry Frontiers · 2024-01-01

    Chenhui Hu, Dongdong Chu, Xueling Hou, Feng Zhang, Jian Wei Han

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  18. Extending Unique 1D Double-Chains to 2D Layers with Birefringent Gain by Introducing a Hydroxyl Group

    Inorganic Chemistry · 2024-03-18

    Yanhui Zhang, Wenjuan Ma, Yun Mo Yang, Xifa Long, Zhi Guo Su

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  19. Na3K6(CO3)3(NO3)2X·6H2O (X = NO3, Cl, Br): Exploring High-Performance UV Birefringent Crystals Induced by Coplanar π-Conjugated CO3 and NO3 Groups

    Inorganic Chemistry · 2024-04-23

    Wencong Li, Junbo Wang, Lili Liu, Chunmei Huang, Yanyan Ding, Mengmeng Zhu, Jindan Tian, Hai-Xin Qi, Yaoqing Chu, Jiayue Xu

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  20. NaRbB10O14(OH)4 and Na3CsB10O16(OH)2: Two Cases of Hydroxyborates with [B5Om(OH)n] Units and Deep Ultraviolet Cutoff Edges

    Inorganic Chemistry · 2024-04-24

    Huanhuan Zhao, Die Xu, Zhaohui Chen

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  21. The electronic structures and optical properties induced by spin-orbit-coupling in LiPbPO4 compound

    Journal of Physics D Applied Physics · 2024-05-07

    Xudong Leng, Mei Hu, Qun Jing, Haiming Duan, Henglei Chen, Zhaohui Chen

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  22. Review on birefringence in borates based on birefringence-active functional groups and arrangements

    Science China Chemistry · 2024-06-14

    Qianzhen Zhang, Ran An, Zhihua Yang, Xifa Long, Shilie Pan, Yun Mo Yang

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  23. Cs2Pb(CO3)2: a novel mixed-metal carbonate with rare Pb-C-O one-dimensional chain

    Journal of Materials Science · 2024-08-01

    Qun Jing, Mei Hu, Jialong Wang, Yi Jiang, Haiming Duan, Zhaohui Chen

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  24. Pb2TeV2O10: A Lead Vanadate Tellurate with Wide Mid-IR Transparency and Large Birefringence Induced by Multiple Birefringence-Active Groups

    Inorganic Chemistry · 2024-10-11

    Yanyan Ding, Mengmeng Zhu, Junbo Wang, Bo Li, Hai-Xin Qi, Lili Liu, Yaoqing Chu

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  25. Structure and optical properties of alkali rare-earth double phosphates of M3RE(PO4)2 (M = K, Rb; RE = Y, La, and Lu)

    Optical Materials · 2024-10-13

    Qun Jing, Mei Hu, Menglin Zhu, Jialong Wang, Haiming Duan, Zhaohui Chen

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  26. Structural Evolution and Optical Properties of Hydroxyfluorooxoborates MM′2n-1[B3O3F4(OH)]n (M = K, Cs, and Rb; M′ = K, NH4, and Cs; n = 1, 2, and 3)

    Chemistry of Materials · 2024-11-25

    Huan Pei, Luyong Zhang, Huanhuan Cheng, Shi‐Bin Wang, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  27. Structural modification of hydroxyborates by adjusting the number of shared oxygen atoms and hydroxyl groups for further performance enhancement

    Dalton Transactions · 2024-12-13

    Xiaoqin Ma, Xin-Jun Zhao, QinglianT. Zhang, Xifa Long, Yun Mo Yang

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  28. Cation tuning in anionic framework hydroborates: tailored deep-ultraviolet optical crystals with large birefringence

    New Journal of Chemistry · 2025-01-01

    Yansheng Jiang, Hangwei Jia, Wenhu Wang, Muhammad Arif, Xiuling Yan, Xueling Hou

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  29. Size effect of cations in the A2B3O4F3 family: Based on the new member Cs2B3O4F3

    Materials Today Chemistry · 2025-03-06

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  30. The Layered Structure–Induced Enhanced Birefringence of LiMgPO 4 : A First‐Principles Investigation

    physica status solidi (b) · 2025-06-26

    Dianyi Hu, Xu Ji, Mei Hu, Hongheng Chen, Xiuhua Cui, Ming‐Hsien Lee

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  31. CsB(OH) 4 (H 2 O) 2 and Na(NH 4 ) 2 B 10 O 16 OH(H 2 O): a hydroxylation modification strategy regulates the borate structures and optical properties

    Dalton Transactions · 2026-01-01

    Kelibinuer Wulamu, Ziting Yan, Dongdong Chu, Juanjuan Lu, Yanhui Zhang, Hong Du

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