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RESEARCH PAPER · Chemical Communications · 2020

[Al(H 2 O) 6 ](IO 3 ) 2 (NO 3 ): a material with enhanced birefringence induced by synergism of two superior functional motifs

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[Al(H 2 O) 6 ](IO 3 ) 2 (NO 3 ): a material with enhanced birefringence induced by synergism of two superior functional motifsOriginalSynergism of multiple functional chromophores significantly enhancing the birefringence in layered non-centrosymmetric chalcohalides20From BaCl 2 to Ba(NO 3 )Cl: significantly enhanced birefringence derived from π-conjugated [NO 3 ]14Na3Bi(IO3)6: An Alkali-Metal Bismuth Iodate with Intriguing One-Dimensional [BiI6O18] Chains and Pressure-Induced Structural Transition11A Polar Material with Facility of Crystal Growth and a Large Second-Harmonic Generation Response3A Photochromic Zinc–Viologen Framework with a High-Contrast Nonlinear Optical Switchable Behavior24NaSb3O2(SO4)3·H2O: A New Alkali-Metal Antimony(III) Sulfate with a Unique Sb6O20H4 Unit and Moderate Birefringence19KRE(CO 3 ) 2 (RE = Eu, Gd, Tb): new mixed metal carbonates with strong photoluminescence and large birefringence15Potential optical functional crystals with large birefringence: Recent advances and future prospects322Two Indium Iodate–Nitrates with Large Birefringence Induced by Hybrid Anionic Functional Groups and Their Favorable Arrangements22ZrF2(IO3)2 and RbGaF3(IO3): Two Promising Birefringent Crystals Featuring 1D Metal-Fluoride Cationic Chains and Wide Bandgaps22Dramatically improved optical anisotropy by realizing stereochemically active lone pairs in a sulfate system, K 2 SO 4 ·HIO 323KRb 2 (NO 3 ) 2 Cl: a new birefringent crystal exhibiting a perovskite-related framework and a short cutoff edge6Nonlinear optical inorganic sulfates: The improvement of the phase matching ability driven by the structural modulation41Exceptional Optical Anisotropy Enhancement Achieved Through Dual‐Ions Cosubstitution Strategy in Novel Hybrid Bismuth Halides23Designing Optical Anisotropy: Silver-Aminoalkylpyridine Nitrate Complexes with Tunable Structures3Broadband Green Luminescence and Phase Transition in Low-Dimensional Organic–Inorganic Hybrid Iodate1Sb2O2SeO3 and Sb2O(SeO3)2: Two-Layered Antimony(III) Selenites with Enhanced Birefringence10Bi(SO4)F·H2O and Bi(SO4)(NO3)·3H2O: Chemical Substitution-Induced Birefringence Enhancement in Bismuth Sulfates6Halogen Bond Unlocks Ultra‐High Birefringence73Halogen Bond Unlocks Ultra‐High Birefringence14CdInO(BO3): An oxyborate birefringent material explored from d10 metal compounds1Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering61Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering4Recent progress in structural design strategies of high-birefringence optical crystals54From (C12H9N2)2TeBr6·2H2O to (C12H9N2)2TeBr6: Dehydration-Driven Crystal Reorganization for Birefringence Optimization6K2HGa(IO3)6: A new member of iodate families with [M(IO3)6] building blocks0Dual-tuning birefringence in hybrid crystals via Cd/Zn metal center and organic ligand isomerism0Peroxide‐Assisted Solvate Engineering Enables Record‐High Birefringence in a Solar‐Blind Transparent Crystal0Peroxide‐Assisted Solvate Engineering Enables Record‐High Birefringence in a Solar‐Blind Transparent Crystal0

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  1. Synergism of multiple functional chromophores significantly enhancing the birefringence in layered non-centrosymmetric chalcohalides

    Inorganic Chemistry Frontiers · 2020-12-23

    Junben Huang, Jianian Cheng, Bing‐Hua Lei, Zhonglei Wei, Shilie Pan, Zhihua Yang

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  2. From BaCl 2 to Ba(NO 3 )Cl: significantly enhanced birefringence derived from π-conjugated [NO 3 ]

    New Journal of Chemistry · 2021-01-01

    Zhen Chen, Hao Zeng, Shujuan Han, Zhihua Yang, Shilie Pan

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  3. Na3Bi(IO3)6: An Alkali-Metal Bismuth Iodate with Intriguing One-Dimensional [BiI6O18] Chains and Pressure-Induced Structural Transition

    Inorganic Chemistry · 2021-02-11

    Huimin Song, Dequan Jiang, Naizheng Wang, Wenhao Xing, Ruixin Guo, Zheshuai Lin, Jiyong Yao, Yonggang Wang, Heng Tu, Guochun Zhang

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  4. A Polar Material with Facility of Crystal Growth and a Large Second-Harmonic Generation Response

    Crystal Growth & Design · 2021-02-19

    Dongmei Wang, Zhiyong Bai, Lehui Liu, Lei Hu, Yisheng Huang, Feifei Yuan, Dongshan Wei, Zhoubin Lin, Lizhen Zhang

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  5. A Photochromic Zinc–Viologen Framework with a High-Contrast Nonlinear Optical Switchable Behavior

    Crystal Growth & Design · 2021-09-03

    Shi-Li Li, Hui-Min Xu, Yan Zhang, Wen Yang, Zhikai Qi, Jian Zhang, Xian‐Ming Zhang

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  6. NaSb3O2(SO4)3·H2O: A New Alkali-Metal Antimony(III) Sulfate with a Unique Sb6O20H4 Unit and Moderate Birefringence

    Crystal Growth & Design · 2021-12-09

    Kui Wang, Xiaofei Li, Chao He, Jinhua Li, Xing‐Tao An, Li Wei, Qi Wei, Guo‐Ming Wang

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  7. KRE(CO 3 ) 2 (RE = Eu, Gd, Tb): new mixed metal carbonates with strong photoluminescence and large birefringence

    Inorganic Chemistry Frontiers · 2022-01-01

    Yuan Hua Lin, Chun‐Li Hu, Zhi Gang Fang, Jin Chen, Weijie Xie, Yan Chen, Jianpu Wang, Jiang‐Gao Mao

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  8. Potential optical functional crystals with large birefringence: Recent advances and future prospects

    Coordination Chemistry Reviews · 2022-02-08

    Abudukadi Tudi, Shujuan Han, Zhihua Yang, Shilie Pan

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  9. Two Indium Iodate–Nitrates with Large Birefringence Induced by Hybrid Anionic Functional Groups and Their Favorable Arrangements

    Inorganic Chemistry · 2022-02-14

    Yu Huang, Ting-Kun Jiang, Bing‐Ping Yang, Chun‐Li Hu, Zhi Gang Fang, Jiang‐Gao Mao

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  10. ZrF2(IO3)2 and RbGaF3(IO3): Two Promising Birefringent Crystals Featuring 1D Metal-Fluoride Cationic Chains and Wide Bandgaps

    Inorganic Chemistry · 2022-10-26

    Jin Chen, Ke‐Zhao Du

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  11. Dramatically improved optical anisotropy by realizing stereochemically active lone pairs in a sulfate system, K 2 SO 4 ·HIO 3

    Inorganic Chemistry Frontiers · 2023-01-01

    Zhiyong Bai, Kang Min Ok

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  12. KRb 2 (NO 3 ) 2 Cl: a new birefringent crystal exhibiting a perovskite-related framework and a short cutoff edge

    Dalton Transactions · 2023-01-01

    Zhiyuan Zhang, Die Xu, Zhencheng Wu, Mei Hu, Xin Su, Yineng Huang

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  13. Nonlinear optical inorganic sulfates: The improvement of the phase matching ability driven by the structural modulation

    Coordination Chemistry Reviews · 2023-08-02

    Yanran Shang, Junxin Xu, Hongyuan Sha, Zujian Wang, Chao He, Rongbing Su, Xiaoming Yang, Xifa Long

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  14. Exceptional Optical Anisotropy Enhancement Achieved Through Dual‐Ions Cosubstitution Strategy in Novel Hybrid Bismuth Halides

    Small · 2024-01-17

    Zhiyong Bai, Kang Min Ok

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  15. Designing Optical Anisotropy: Silver-Aminoalkylpyridine Nitrate Complexes with Tunable Structures

    Inorganic Chemistry · 2024-01-23

    Myung‐Ho Choi, Yang Li, Kang Min Ok

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  16. Broadband Green Luminescence and Phase Transition in Low-Dimensional Organic–Inorganic Hybrid Iodate

    Inorganic Chemistry · 2024-04-17

    Yangwu Guo, Ziwei Yu, Kui Wang, Meiqiu Dong, Xinyi Li, Xinglong Yang, Yù Zhang

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  17. Sb2O2SeO3 and Sb2O(SeO3)2: Two-Layered Antimony(III) Selenites with Enhanced Birefringence

    Inorganic Chemistry · 2024-06-04

    Han Luo, Yu Zhang, Tingyu Wang, Ling Huang, Liling Cao, Xuehua Dong, Guohong Zou

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  18. Bi(SO4)F·H2O and Bi(SO4)(NO3)·3H2O: Chemical Substitution-Induced Birefringence Enhancement in Bismuth Sulfates

    Inorganic Chemistry · 2024-07-04

    Jiachen Lu, Yang Li, Yunseung Kuk, Seung-Hun Choi, Kyungmo Kim, Chanhee Ko, Zhiyong Bai, Kang Min Ok

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  19. Halogen Bond Unlocks Ultra‐High Birefringence

    Angewandte Chemie International Edition · 2024-07-10

    Jin Chen, Mingsheng Xu, Huai‐Yu Wu, Jun‐Yan Wu, Ke‐Zhao Du

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  20. Halogen Bond Unlocks Ultra‐High Birefringence

    Angewandte Chemie · 2024-07-10

    Jin Chen, Miao‐Bin Xu, Huai‐Yu Wu, Jun‐Yan Wu, Ke‐Zhao Du

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  21. CdInO(BO3): An oxyborate birefringent material explored from d10 metal compounds

    Journal of Molecular Structure · 2024-08-03

    Runqing Liu, Rongwei Shi, Jiming Huang, Fen Ye, Senlin Leng

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  22. Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering

    Angewandte Chemie International Edition · 2024-08-15

    Huan Zhou, Meng Cheng, Dongdong Chu, Xu Liu, Ran An, Shilie Pan, Shilie Pan, Zhihua Yang

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  23. Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering

    Angewandte Chemie · 2024-08-15

    Huan Zhou, Meng Cheng, Dongdong Chu, Xu Liu, Ran An, Shilie Pan, Zhihua Yang

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  24. Recent progress in structural design strategies of high-birefringence optical crystals

    Coordination Chemistry Reviews · 2025-05-08

    A-Lan Xu, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  25. From (C12H9N2)2TeBr6·2H2O to (C12H9N2)2TeBr6: Dehydration-Driven Crystal Reorganization for Birefringence Optimization

    Inorganic Chemistry · 2025-09-25

    Shiyi Wang, Yingzi Zhang, Yu Yan, Xuehua Dong, Liling Cao, Ling Huang, Guohong Zou

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  26. K2HGa(IO3)6: A new member of iodate families with [M(IO3)6] building blocks

    Journal of Molecular Structure · 2025-11-30

    Runqing Liu, Yuntian Zhao, Huaifeng Wang, Jiming Huang, Shibo Guan, Senlin Leng

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  27. Dual-tuning birefringence in hybrid crystals via Cd/Zn metal center and organic ligand isomerism

    Dalton Transactions · 2026-01-01

    Yaoguo Shen, Xinyi Wang, Mengqing Wu, Yiman Yang, Lingxin Yan

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  28. Peroxide‐Assisted Solvate Engineering Enables Record‐High Birefringence in a Solar‐Blind Transparent Crystal

    Angewandte Chemie International Edition · 2026-06-22

    Yang Li, Congcong Jin, Kang Min Ok

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  29. Peroxide‐Assisted Solvate Engineering Enables Record‐High Birefringence in a Solar‐Blind Transparent Crystal

    Angewandte Chemie · 2026-06-22

    Yang Li, Congcong Jin, Kang Min Ok

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