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RESEARCH PAPER · Inorganic Chemistry · 2020

ZnIO3F: Zinc Iodate Fluoride with Large Birefringence and Wide Band Gap

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ZnIO3F: Zinc Iodate Fluoride with Large Birefringence and Wide Band GapOriginal[Al(H 2 O) 6 ](IO 3 ) 2 (NO 3 ): a material with enhanced birefringence induced by synergism of two superior functional motifs29From BiF 3 to BiF 3 ·H 2 O: diverse Bi( iii ) coordination for structural transformation and birefringence regulation14Ba(IO3)F: An Alkaline-Earth-Metal Iodate Fluoride Crystal with Large Band Gap and Birefringence24High Coordinate Metal Iodate Chlorides with Diverse Structural Motifs and Tunable Birefringence10LiGaF2(IO3)2: A mixed-metal gallium iodate-fluoride with large birefringence and wide band gap39Y 2 (Te 4 O 10 )(SO 4 ): a new sulfate tellurite with a unique Te 4 O 10 polyanion and large birefringence36Giant Optical Anisotropy in the UV‐Transparent 2D Nonlinear Optical Material Sc(IO 3 ) 2 (NO 3 )212Giant Optical Anisotropy in the UV‐Transparent 2D Nonlinear Optical Material Sc(IO 3 ) 2 (NO 3 )57Barium fluoroiodate crystals with a large band gap and birefringence22NaGaI 3 O 9 F: a new alkali metal gallium iodate combined with IO 3 − and IO 3 F 2− units16Pressure-dependent modifications in the optical and electronic properties of Fe(IO 3 ) 3 : the role of Fe 3d and I 5p lone–pair electrons15Two bismuth iodate sulfates with enhanced optical anisotropy17Na3Bi(IO3)6: An Alkali-Metal Bismuth Iodate with Intriguing One-Dimensional [BiI6O18] Chains and Pressure-Induced Structural Transition11A Polar Material with Facility of Crystal Growth and a Large Second-Harmonic Generation Response3A2MoO2F3(IO2F2) (A = Rb, Cs): Strong Nonlinear Optical Responses and Enlarged Band Gaps through Fluorine Incorporation50From CeF2(SO4)·H2O to Ce(IO3)2(SO4): Defluorinated Homovalent Substitution for Strong Second-Harmonic-Generation Effect and Sufficient Birefringence53K 3 V 2 O 3 F 4 (IO 3 ) 3 : a high-performance SHG crystal containing both five and six-coordinated V 5+ cations33K6(IO6H4)(HI2O6)(HIO3)2(IO3)4·2H2O: A Case of Iodate with Coexisting [I5+O3] and [I7+O6] Units6BaI 3 O 9 H: a new alkaline-earth metal hydroxy iodate with two groups2Mg(H 2 O) 6 [(IO 2 (OH)) 2 (IO 3 )] 2 : a new iodate with a very large band gap and optical anisotropy13Rbcl·(H2seo3)2: A New Salt-Inclusion Selenite as a Promising Uv Birefringent Material0Potential optical functional crystals with large birefringence: Recent advances and future prospects322Two Indium Iodate–Nitrates with Large Birefringence Induced by Hybrid Anionic Functional Groups and Their Favorable Arrangements22General relationship between the band-gap energy and iodine-oxygen bond distance in metal iodates15Synthesis, crystal structure and optical properties of the first bromine-containing iodate: Pb2IO3Br30NH4IO2F2 and (NH4)3(IO2F2)3·H2O: A Series of Ammonium-Containing Fluoroiodates with Wide Band Gaps12A new birefringent material, HfF2(IO3)2, with a large birefringence and improved overall performances achieved by the integration of functional groups19MIO 3 F (M = Co and Ni): Magnetic Iodate Fluorides with Zigzag Chains16ZrF2(IO3)2 and RbGaF3(IO3): Two Promising Birefringent Crystals Featuring 1D Metal-Fluoride Cationic Chains and Wide Bandgaps22RbCl·(H2SeO3)2: A Salt-Inclusion Selenite Featuring Short UV Cut-Off Edge and Large Birefringence15Dramatically improved optical anisotropy by realizing stereochemically active lone pairs in a sulfate system, K 2 SO 4 ·HIO 323Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropy21Recent advances in F-containing iodate nonlinear optical materials6Wide‐Bandgap Rare‐Earth Iodate Single Crystals for Superior X‐Ray Detection and Imaging21Quartz‐Like Structure, Optical Activity, and High Stability in the First Chiral Cation‐Coordinated Perovskite Semiconductor11A survey of stereoactive oxysalts for linear and nonlinear optical applications40YSO4F·H2O: A Deep-Ultraviolet Birefringent Rare-Earth Sulfate Fluoride with Enhanced Birefringence Induced by Fluorinated Y-Centered Polyhedra19Optically Anisotropic Mixed-Metal Fluoroiodate Ba2[GaF5(IO3F)] with a Wide Optical Transparent Window and a Moderate Birefringence6Vanadate Crystals with an Enhanced Birefringence and a Broadened Transparency Spectrum through Controlled [VO3]∞ Chain Arrangements and Alkali Metal Cation Introduction4C(NH2)3MoO3(IO3): A Molybdenyl Iodate with Giant Birefringence Designed via a Cation–Anion Synergetic Interaction Strategy36Enhancement of Birefringence in π-Conjugated Oxyfluorides Achieved via van der Waals Layered Structural Optimization10Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals66Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals8Bi(SO4)F·H2O and Bi(SO4)(NO3)·3H2O: Chemical Substitution-Induced Birefringence Enhancement in Bismuth Sulfates6Functional Modules Map of Unexplored Chemical Space: Guiding the Discovery of Giant Birefringent Materials76Synthesis and characterization of a two-dimensional antiferromagnet KNiB4O6F3 with triangular spin lattice5The impact of anionic group arrangement on the optical properties of the arsenate series0(NH 4 ) 2 Cd 2 Cl 3 F 3 and (NH 4 ) 2 Cd 2 Br 3 F 3 : The First Fluoride‐Containing d 10 Metal Mixed Halides Exhibiting Superior Ultraviolet Nonlinear Optical Properties28The birefringence in orthorhombic and triclinic lead-iodates and the functional basic units' contribution: A first-principles investigation3Series of New Alkali Metal Hafnium-Based Iodates A2Hf(IO3)6 (A = K, Rb, Cs) and Isomorphic Ba2Zn(IO3)6 with Large Birefringence1Recent progress in structural design strategies of high-birefringence optical crystals54[ICl 4 ] − : A large anisotropic planar anion group produces giant birefringence2Optical anisotropy in Mo–Te–O frameworks constructed from distorted MoO 6 and TeO 3 units0中红外氧化物非线性光学晶体研究进展(特邀)0Density-Compensated Polarizability Anisotropy for Record Birefringence in Short-Wavelength Ultraviolet Inorganic Crystals11IO3–-Mediated Short-Range Magnetic Order in 2D Honeycomb LiFe(IO3)2F20Non-π-conjugated tetrahedra-based optical crystals: The improvement of the linear and nonlinear optical properties by the combination of trigonal pyramidal [XO3] (X = I, Se, Te) units1

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  1. [Al(H 2 O) 6 ](IO 3 ) 2 (NO 3 ): a material with enhanced birefringence induced by synergism of two superior functional motifs

    Chemical Communications · 2020-01-01

    Zhiyong Bai, Chun‐Li Hu, Dongmei Wang, Lehui Liu, Lizhen Zhang, Yisheng Huang, Feifei Yuan, Zhoubin Lin

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  2. From BiF 3 to BiF 3 ·H 2 O: diverse Bi( iii ) coordination for structural transformation and birefringence regulation

    CrystEngComm · 2020-01-01

    Xian Liu, Can Yang, Qi Wu, Juan Sun, Fei Liang

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  3. Ba(IO3)F: An Alkaline-Earth-Metal Iodate Fluoride Crystal with Large Band Gap and Birefringence

    Inorganic Chemistry · 2020-05-13

    Huixin Fan, Guang Peng, Chensheng Lin, Kaichuang Chen, Shunda Yang, Ning Ye

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  4. High Coordinate Metal Iodate Chlorides with Diverse Structural Motifs and Tunable Birefringence

    Crystal Growth & Design · 2020-07-07

    Ying‐Jie Jia, Yi-Gang Chen, Ting Wang, Yao Guo, Xiao‐Fang Guan, Xian‐Ming Zhang

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  5. LiGaF2(IO3)2: A mixed-metal gallium iodate-fluoride with large birefringence and wide band gap

    Science China Materials · 2020-07-22

    Jin Chen, Chun‐Li Hu, Jiang‐Gao Mao

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  6. Y 2 (Te 4 O 10 )(SO 4 ): a new sulfate tellurite with a unique Te 4 O 10 polyanion and large birefringence

    Inorganic Chemistry Frontiers · 2020-10-26

    Pengfei Li, Chun‐Li Hu, Fang Kong, Shao‐Ming Ying, Jiang‐Gao Mao

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  7. Giant Optical Anisotropy in the UV‐Transparent 2D Nonlinear Optical Material Sc(IO 3 ) 2 (NO 3 )

    Angewandte Chemie International Edition · 2020-11-04

    Chao Wu, Xingxing Jiang, Zujian Wang, Lin Lin, Zheshuai Lin, Zhipeng Huang, Xifa Long, Mark Graeme Humphrey, Chi Zhang

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  8. Giant Optical Anisotropy in the UV‐Transparent 2D Nonlinear Optical Material Sc(IO 3 ) 2 (NO 3 )

    Angewandte Chemie · 2020-11-04

    Chao Wu, Xingxing Jiang, Zujian Wang, Lin Lin, Zheshuai Lin, Zhipeng Huang, Xifa Long, Mark Graeme Humphrey, Chi Zhang

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  9. Barium fluoroiodate crystals with a large band gap and birefringence

    Inorganic Chemistry Frontiers · 2021-01-01

    Liang Zhu, Minqiang Gai, Wenqi Jin, Yun Mo Yang, Zhihua Yang, Shilie Pan

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  10. NaGaI 3 O 9 F: a new alkali metal gallium iodate combined with IO 3 − and IO 3 F 2− units

    Dalton Transactions · 2021-01-01

    Dandan Wang, Pifu Gong, Xinyuan Zhang, Zheshuai Lin, Zhanggui Hu, Yicheng Wu

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  11. Pressure-dependent modifications in the optical and electronic properties of Fe(IO 3 ) 3 : the role of Fe 3d and I 5p lone–pair electrons

    Inorganic Chemistry Frontiers · 2021-01-01

    Akun Liang, Plácida Rodríguez-Hernández, Alfonso Muñoz, Saqib Rahman, Alfredo Segura, Daniel Errandonea

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  12. Two bismuth iodate sulfates with enhanced optical anisotropy

    Dalton Transactions · 2021-01-01

    Yilin Li, Chun‐Li Hu, Jin Chen, Jiang‐Gao Mao

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  13. Na3Bi(IO3)6: An Alkali-Metal Bismuth Iodate with Intriguing One-Dimensional [BiI6O18] Chains and Pressure-Induced Structural Transition

    Inorganic Chemistry · 2021-02-11

    Huimin Song, Dequan Jiang, Naizheng Wang, Wenhao Xing, Ruixin Guo, Zheshuai Lin, Jiyong Yao, Yonggang Wang, Heng Tu, Guochun Zhang

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  14. A Polar Material with Facility of Crystal Growth and a Large Second-Harmonic Generation Response

    Crystal Growth & Design · 2021-02-19

    Dongmei Wang, Zhiyong Bai, Lehui Liu, Lei Hu, Yisheng Huang, Feifei Yuan, Dongshan Wei, Zhoubin Lin, Lizhen Zhang

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  15. A2MoO2F3(IO2F2) (A = Rb, Cs): Strong Nonlinear Optical Responses and Enlarged Band Gaps through Fluorine Incorporation

    Chemistry of Materials · 2021-06-23

    Yilei Hu, Xingxing Jiang, Chao Wu, Zhipeng Huang, Zheshuai Lin, Mark Graeme Humphrey, Chi Zhang

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  16. From CeF2(SO4)·H2O to Ce(IO3)2(SO4): Defluorinated Homovalent Substitution for Strong Second-Harmonic-Generation Effect and Sufficient Birefringence

    Chemistry of Materials · 2021-11-22

    Tianhui Wu, Xingxing Jiang, Yiran Zhang, Zujian Wang, Hongyuan Sha, Chao Wu, Zheshuai Lin, Zhipeng Huang, Xifa Long, Mark Graeme Humphrey, Chi Zhang

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  17. K 3 V 2 O 3 F 4 (IO 3 ) 3 : a high-performance SHG crystal containing both five and six-coordinated V 5+ cations

    Chemical Science · 2021-12-06

    Jin Chen, Chun‐Li Hu, Yilin Li, Yan Chen, Qianqian Chen, Jiang‐Gao Mao

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  18. K6(IO6H4)(HI2O6)(HIO3)2(IO3)4·2H2O: A Case of Iodate with Coexisting [I5+O3] and [I7+O6] Units

    Inorganic Chemistry · 2021-12-17

    Jun Sun, Tushagu Abudouwufu, Congcong Jin, Zhiyong Guo, Min Zhang

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  19. BaI 3 O 9 H: a new alkaline-earth metal hydroxy iodate with two groups

    New Journal of Chemistry · 2022-01-01

    Wenjuan Ma, Jianlong Huang, Bin Dai, Feng Yu

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  20. Mg(H 2 O) 6 [(IO 2 (OH)) 2 (IO 3 )] 2 : a new iodate with a very large band gap and optical anisotropy

    Journal of Materials Chemistry C · 2022-01-01

    Yang Li, Kang Min Ok

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  21. Rbcl·(H2seo3)2: A New Salt-Inclusion Selenite as a Promising Uv Birefringent Material

    SSRN Electronic Journal · 2022-01-01

    Huan Wang, Lili Liu, Zhaowei Hu, Junbo Wang, Mengmeng Zhu, Jiayue Xu

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  22. Potential optical functional crystals with large birefringence: Recent advances and future prospects

    Coordination Chemistry Reviews · 2022-02-08

    Abudukadi Tudi, Shujuan Han, Zhihua Yang, Shilie Pan

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  23. Two Indium Iodate–Nitrates with Large Birefringence Induced by Hybrid Anionic Functional Groups and Their Favorable Arrangements

    Inorganic Chemistry · 2022-02-14

    Yu Huang, Ting-Kun Jiang, Bing‐Ping Yang, Chun‐Li Hu, Zhi Gang Fang, Jiang‐Gao Mao

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  24. General relationship between the band-gap energy and iodine-oxygen bond distance in metal iodates

    Physical Review Materials · 2022-04-28

    Akun Liang, Robin Turnbull, Plácida Rodríguez-Hernández, Alfonso Muñoz, M. Jasmin, Lan-Ting Shi, Daniel Errandonea

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  25. Synthesis, crystal structure and optical properties of the first bromine-containing iodate: Pb2IO3Br3

    Solid State Sciences · 2022-04-28

    Bao Jiang, Kewang Zhang, Yuchen Yan, Yanhui Zhang, Zhi Su

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  26. NH4IO2F2 and (NH4)3(IO2F2)3·H2O: A Series of Ammonium-Containing Fluoroiodates with Wide Band Gaps

    Inorganic Chemistry · 2022-07-21

    Jianlong Huang, Fengjiao Guo, Zhiyong Guo, Jianbang Chen, Bin Dai, Feng Yu

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  27. A new birefringent material, HfF2(IO3)2, with a large birefringence and improved overall performances achieved by the integration of functional groups

    Scripta Materialia · 2022-10-10

    Yu Huang, Zhi Gang Fang, Bing‐Ping Yang, Xueying Zhang, Jiang‐Gao Mao

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  28. MIO 3 F (M = Co and Ni): Magnetic Iodate Fluorides with Zigzag Chains

    Inorganic Chemistry · 2022-10-26

    Hang Liu, Yanhong Wang, Ya-Dong Zhou, Shuang Li, Yaling Dou, Tao Wang, Hongcheng Lu

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  29. ZrF2(IO3)2 and RbGaF3(IO3): Two Promising Birefringent Crystals Featuring 1D Metal-Fluoride Cationic Chains and Wide Bandgaps

    Inorganic Chemistry · 2022-10-26

    Jin Chen, Ke‐Zhao Du

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  30. RbCl·(H2SeO3)2: A Salt-Inclusion Selenite Featuring Short UV Cut-Off Edge and Large Birefringence

    Inorganic Chemistry · 2022-12-23

    Huan Wang, Lili Liu, Zhaowei Hu, Junbo Wang, Mengmeng Zhu, Yu Meng, Jiayue Xu

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  31. Dramatically improved optical anisotropy by realizing stereochemically active lone pairs in a sulfate system, K 2 SO 4 ·HIO 3

    Inorganic Chemistry Frontiers · 2023-01-01

    Zhiyong Bai, Kang Min Ok

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  32. Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropy

    Inorganic Chemistry Frontiers · 2023-01-01

    Yi‐Lei Lv, Lei Huai, Yu-Long Wei, Liang Ma, Yue‐Qi Wei, Wenlong Liu, Ru‐Ling Tang

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  33. Recent advances in F-containing iodate nonlinear optical materials

    Chinese Journal of Structural Chemistry · 2023-01-01

    Dong Gao, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  34. Wide‐Bandgap Rare‐Earth Iodate Single Crystals for Superior X‐Ray Detection and Imaging

    Advanced Science · 2023-03-22

    Xieming Xu, Fang Wang, Weiwei Xu, Hao Lü, Lingfei Lv, Hongyuan Sha, Xiao‐Ming Jiang, Shaofan Wu, Shuai‐Hua Wang

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  35. Quartz‐Like Structure, Optical Activity, and High Stability in the First Chiral Cation‐Coordinated Perovskite Semiconductor

    Advanced Optical Materials · 2023-06-27

    Xiang‐Bin Han, Chao‐Yang Chai, Ming‐Liang Jin, Chang‐Chun Fan, Wen Zhang

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  36. A survey of stereoactive oxysalts for linear and nonlinear optical applications

    Materials Today Physics · 2023-08-12

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  37. YSO4F·H2O: A Deep-Ultraviolet Birefringent Rare-Earth Sulfate Fluoride with Enhanced Birefringence Induced by Fluorinated Y-Centered Polyhedra

    Inorganic Chemistry · 2023-10-12

    Dong‐Xue Jiao, Huili Zhang, Xiao-Fei Li, Chao He, Jinhua Li, Qi Wei, Guo‐Yu Yang

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  38. Optically Anisotropic Mixed-Metal Fluoroiodate Ba2[GaF5(IO3F)] with a Wide Optical Transparent Window and a Moderate Birefringence

    Inorganic Chemistry · 2023-10-17

    Yuhang Wang, Fu-Ying Li, Dong‐Xue Jiao, Qi Wei, Li Wei, Guo‐Yu Yang

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  39. Vanadate Crystals with an Enhanced Birefringence and a Broadened Transparency Spectrum through Controlled [VO3]∞ Chain Arrangements and Alkali Metal Cation Introduction

    Inorganic Chemistry · 2023-11-24

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  40. C(NH2)3MoO3(IO3): A Molybdenyl Iodate with Giant Birefringence Designed via a Cation–Anion Synergetic Interaction Strategy

    Chemistry of Materials · 2024-02-08

    Wei Zeng, Yao Tian, Xuehua Dong, Ling Huang, Hongmei Zeng, Zhien Lin, Guohong Zou

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  41. Enhancement of Birefringence in π-Conjugated Oxyfluorides Achieved via van der Waals Layered Structural Optimization

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  42. Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals

    Angewandte Chemie International Edition · 2024-06-26

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  43. Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals

    Angewandte Chemie · 2024-06-26

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  44. Bi(SO4)F·H2O and Bi(SO4)(NO3)·3H2O: Chemical Substitution-Induced Birefringence Enhancement in Bismuth Sulfates

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  45. Functional Modules Map of Unexplored Chemical Space: Guiding the Discovery of Giant Birefringent Materials

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  46. Synthesis and characterization of a two-dimensional antiferromagnet KNiB4O6F3 with triangular spin lattice

    Journal of Solid State Chemistry · 2024-10-18

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  47. The impact of anionic group arrangement on the optical properties of the arsenate series

    Journal of Materials Chemistry C · 2025-01-01

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  48. (NH 4 ) 2 Cd 2 Cl 3 F 3 and (NH 4 ) 2 Cd 2 Br 3 F 3 : The First Fluoride‐Containing d 10 Metal Mixed Halides Exhibiting Superior Ultraviolet Nonlinear Optical Properties

    Advanced Science · 2025-01-28

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  49. The birefringence in orthorhombic and triclinic lead-iodates and the functional basic units' contribution: A first-principles investigation

    Chemical Physics Letters · 2025-02-22

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  50. Series of New Alkali Metal Hafnium-Based Iodates A2Hf(IO3)6 (A = K, Rb, Cs) and Isomorphic Ba2Zn(IO3)6 with Large Birefringence

    Crystal Growth & Design · 2025-03-19

    Shuwen Zhao, Zhiyong Xue, Xin Wen, Yuchen Yan, Jindong Chen, Guang Peng, Ning Ye

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